JP2016524024A5 - - Google Patents
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- JP2016524024A5 JP2016524024A5 JP2016524204A JP2016524204A JP2016524024A5 JP 2016524024 A5 JP2016524024 A5 JP 2016524024A5 JP 2016524204 A JP2016524204 A JP 2016524204A JP 2016524204 A JP2016524204 A JP 2016524204A JP 2016524024 A5 JP2016524024 A5 JP 2016524024A5
- Authority
- JP
- Japan
- Prior art keywords
- independently
- alpha
- olefin
- hydrocarbyl
- atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- -1 1,2,3,4-tetrahydronaphthyl Chemical group 0.000 claims description 41
- 239000004711 α-olefin Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- 239000005977 Ethylene Substances 0.000 claims description 10
- 229920001519 homopolymer Polymers 0.000 claims description 10
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 10
- 239000003446 ligand Substances 0.000 claims description 10
- 125000005843 halogen group Chemical group 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 125000000129 anionic group Chemical group 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 125000005842 heteroatom Chemical group 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 125000000743 hydrocarbylene group Chemical group 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 125000004607 1,2,3,4-tetrahydroquinolinyl group Chemical group N1(CCCC2=CC=CC=C12)* 0.000 claims description 2
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 claims description 2
- 125000001622 2-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C(*)C([H])=C([H])C2=C1[H] 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims description 2
- 125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims description 2
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 claims description 2
- 230000003197 catalytic effect Effects 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 229910052735 hafnium Chemical group 0.000 claims description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
- 125000003387 indolinyl group Chemical group N1(CCC2=CC=CC=C12)* 0.000 claims description 2
- 125000001041 indolyl group Chemical group 0.000 claims description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 2
- 125000005647 linker group Chemical group 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 125000001792 phenanthrenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C=CC12)* 0.000 claims description 2
- 125000002943 quinolinyl group Chemical group N1=C(C=CC2=CC=CC=C12)* 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910007926 ZrCl Inorganic materials 0.000 description 1
- 125000003289 ascorbyl group Chemical group [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- NXPHGHWWQRMDIA-UHFFFAOYSA-M magnesium;carbanide;bromide Chemical compound [CH3-].[Mg+2].[Br-] NXPHGHWWQRMDIA-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361840624P | 2013-06-28 | 2013-06-28 | |
| US61/840,624 | 2013-06-28 | ||
| PCT/US2014/044374 WO2014210333A1 (en) | 2013-06-28 | 2014-06-26 | Molecular weight control of polyolefins using halogenated bis-phenylphenoxy catalysts |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018217837A Division JP6813556B2 (ja) | 2013-06-28 | 2018-11-21 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016524024A JP2016524024A (ja) | 2016-08-12 |
| JP2016524024A5 true JP2016524024A5 (https=) | 2017-08-24 |
| JP6441332B2 JP6441332B2 (ja) | 2018-12-19 |
Family
ID=51211353
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016524204A Active JP6441332B2 (ja) | 2013-06-28 | 2014-06-26 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
| JP2018217837A Active JP6813556B2 (ja) | 2013-06-28 | 2018-11-21 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018217837A Active JP6813556B2 (ja) | 2013-06-28 | 2018-11-21 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US9605098B2 (https=) |
| EP (2) | EP3013871B1 (https=) |
| JP (2) | JP6441332B2 (https=) |
| KR (1) | KR102218415B1 (https=) |
| CN (2) | CN113201084A (https=) |
| BR (1) | BR112015030912B1 (https=) |
| ES (2) | ES2934177T3 (https=) |
| SG (2) | SG11201510689SA (https=) |
| WO (1) | WO2014210333A1 (https=) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2938643B1 (en) | 2012-12-27 | 2018-01-31 | Dow Global Technologies LLC | Catalyst systems for olefin polymerization |
| SG11201505069VA (en) * | 2012-12-27 | 2015-07-30 | Dow Global Technologies Llc | A polymerization process for producing ethylene based polymers |
| BR112015015548B1 (pt) | 2012-12-27 | 2021-05-18 | Dow Global Technologies Llc | processo de polimerização para a produção de polímeros a base de etileno |
| CN113201084A (zh) * | 2013-06-28 | 2021-08-03 | 陶氏环球技术有限责任公司 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
| EP3161021B1 (en) | 2014-06-30 | 2019-11-20 | Dow Global Technologies LLC | Process for olefin polymerization |
| ES2769005T3 (es) * | 2014-07-24 | 2020-06-24 | Dow Global Technologies Llc | Catalizadores de bis-bifenilfenoxi para la polimerización de polímeros basados en etileno de bajo peso molecular |
| CN107787336B (zh) * | 2015-06-30 | 2021-05-28 | 陶氏环球技术有限责任公司 | 用于制备基于乙烯的聚合物的聚合方法 |
| WO2017004456A1 (en) | 2015-06-30 | 2017-01-05 | Dow Global Technologies Llc | A polymerization process for producing ethylene based polymers |
| BR112018006183B1 (pt) | 2015-09-30 | 2022-06-14 | Dow Global Technologies Llc | Pró-catalisador e processo de polimerização |
| BR112018005909B1 (pt) | 2015-09-30 | 2022-05-03 | Dow Global Technologies Llc | Pró-catalisador para a polimerização de etileno e processo de polimerização para a produção de polímeros à base de etileno |
| SG11201900653RA (en) | 2016-07-29 | 2019-02-27 | Dow Global Technologies Llc | Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization |
| JP7028885B2 (ja) * | 2017-03-15 | 2022-03-02 | ダウ グローバル テクノロジーズ エルエルシー | マルチブロックコポリマー形成用触媒系 |
| JP7173983B2 (ja) | 2017-03-31 | 2022-11-17 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合のためのビス－ビフェニル－フェノキシ触媒 |
| WO2018183056A1 (en) | 2017-03-31 | 2018-10-04 | Dow Global Technologies Llc | Germanium-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization |
| US11242415B2 (en) | 2017-09-29 | 2022-02-08 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin catalysts having an alkoxy- or amido-ligand on the metal for improved solubility |
| US11066489B2 (en) | 2017-09-29 | 2021-07-20 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin catalysts having two methylenetrialkylsilicon ligands on the metal for improved solubility |
| ES2911503T3 (es) | 2017-09-29 | 2022-05-19 | Dow Global Technologies Llc | Catalizadores de bis-fenil-fenoxi-poliolefina que tienen un ligando de metilentrialquilsilicio en el metal para mejorar la solubilidad |
| KR102100142B1 (ko) * | 2017-12-21 | 2020-04-14 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 금속-리간드 착체, 이를 포함하는 에틸렌계 중합용 촉매 조성물 및 이를 이용한 에틸렌계 중합체의 제조방법 |
| EP3774942A1 (en) * | 2018-03-30 | 2021-02-17 | Dow Global Technologies LLC | Olefin polymerization activators |
| KR102729476B1 (ko) * | 2018-03-30 | 2024-11-14 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합 활성화제 |
| SG11202101332PA (en) | 2018-08-30 | 2021-04-29 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin procatalysts having two anthracenyl ligands |
| WO2020167821A1 (en) * | 2019-02-12 | 2020-08-20 | Exxonmobil Chemical Patents Inc. | Transition metal bis(phenolate) complexes and their use as catalysts for olefin polymerization |
| US12428504B2 (en) | 2019-11-04 | 2025-09-30 | Dow Global Technologies Llc | Biphenylphenol polymerization catalysts |
| KR20220097897A (ko) | 2019-11-04 | 2022-07-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 티타늄 바이페닐페놀 중합 촉매 |
| KR20220097924A (ko) | 2019-11-04 | 2022-07-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 바이모달 촉매 시스템 |
| CN115023445B (zh) * | 2019-12-19 | 2025-03-14 | 陶氏环球技术有限责任公司 | 气相联苯酚聚合催化剂 |
| JP7627274B2 (ja) | 2020-01-31 | 2025-02-05 | ダウ グローバル テクノロジーズ エルエルシー | グループｉｉｉ及びランタニドビス－フェニル－フェノキシ金属－配位子錯体 |
| EP4097152B1 (en) | 2020-01-31 | 2025-09-03 | Dow Global Technologies LLC | Polymerization processes that include group iii and lanthanide bis-phenyl-phenoxy metal-ligand complexes and chain transfer agents |
| US20230303597A1 (en) * | 2020-12-28 | 2023-09-28 | Sabic Sk Nexlene Company Pte. Ltd. | Metal-ligand complex, catalyst composition for preparing ethylene-based polymer containing the same, and preparation method of ethylene -based polymer using the same |
| MX2023008941A (es) * | 2021-02-15 | 2023-08-11 | Dow Global Technologies Llc | Metodo para elaborar un copolimero de poli(etileno-co-1-alqueno) con distribucion de comonomero inversa. |
| CA3207940A1 (en) | 2021-02-15 | 2022-08-18 | Joseph F. DEWILDE | Biphenylphenol polymerization catalysts having improved kinetic induction times |
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| EP2938643B1 (en) * | 2012-12-27 | 2018-01-31 | Dow Global Technologies LLC | Catalyst systems for olefin polymerization |
| BR112015015548B1 (pt) | 2012-12-27 | 2021-05-18 | Dow Global Technologies Llc | processo de polimerização para a produção de polímeros a base de etileno |
| CN104854144B (zh) | 2012-12-27 | 2018-08-07 | 陶氏环球技术有限责任公司 | 乙烯类聚合物 |
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| CN113201084A (zh) * | 2013-06-28 | 2021-08-03 | 陶氏环球技术有限责任公司 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
| CN105339327B (zh) | 2013-06-28 | 2020-01-21 | 陶氏环球技术有限责任公司 | 基于乙烯的超支化寡聚物 |
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-
2014
- 2014-06-26 CN CN202110385158.5A patent/CN113201084A/zh active Pending
- 2014-06-26 ES ES14741484T patent/ES2934177T3/es active Active
- 2014-06-26 EP EP14741484.1A patent/EP3013871B1/en active Active
- 2014-06-26 EP EP21183736.4A patent/EP3925989B1/en active Active
- 2014-06-26 JP JP2016524204A patent/JP6441332B2/ja active Active
- 2014-06-26 US US14/781,419 patent/US9605098B2/en active Active
- 2014-06-26 ES ES21183736T patent/ES3062088T3/es active Active
- 2014-06-26 SG SG11201510689SA patent/SG11201510689SA/en unknown
- 2014-06-26 WO PCT/US2014/044374 patent/WO2014210333A1/en not_active Ceased
- 2014-06-26 CN CN201480033642.XA patent/CN105283474A/zh active Pending
- 2014-06-26 KR KR1020167001548A patent/KR102218415B1/ko active Active
- 2014-06-26 BR BR112015030912-7A patent/BR112015030912B1/pt active IP Right Grant
- 2014-06-26 SG SG10201802443VA patent/SG10201802443VA/en unknown
-
2017
- 2017-02-15 US US15/433,198 patent/US10144791B2/en active Active
-
2018
- 2018-11-21 JP JP2018217837A patent/JP6813556B2/ja active Active
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