JP2016524024A5 - - Google Patents
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- JP2016524024A5 JP2016524024A5 JP2016524204A JP2016524204A JP2016524024A5 JP 2016524024 A5 JP2016524024 A5 JP 2016524024A5 JP 2016524204 A JP2016524204 A JP 2016524204A JP 2016524204 A JP2016524204 A JP 2016524204A JP 2016524024 A5 JP2016524024 A5 JP 2016524024A5
- Authority
- JP
- Japan
- Prior art keywords
- independently
- alpha
- olefin
- hydrocarbyl
- atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- -1 1,2,3,4-tetrahydronaphthyl Chemical group 0.000 claims description 41
- 239000004711 α-olefin Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- 239000005977 Ethylene Substances 0.000 claims description 10
- 229920001519 homopolymer Polymers 0.000 claims description 10
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 10
- 239000003446 ligand Substances 0.000 claims description 10
- 125000005843 halogen group Chemical group 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 125000000129 anionic group Chemical group 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 125000005842 heteroatom Chemical group 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 125000000743 hydrocarbylene group Chemical group 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 125000004607 1,2,3,4-tetrahydroquinolinyl group Chemical group N1(CCCC2=CC=CC=C12)* 0.000 claims description 2
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 claims description 2
- 125000001622 2-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C(*)C([H])=C([H])C2=C1[H] 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims description 2
- 125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims description 2
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 claims description 2
- 230000003197 catalytic effect Effects 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 229910052735 hafnium Chemical group 0.000 claims description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
- 125000003387 indolinyl group Chemical group N1(CCC2=CC=CC=C12)* 0.000 claims description 2
- 125000001041 indolyl group Chemical group 0.000 claims description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 2
- 125000005647 linker group Chemical group 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 125000001792 phenanthrenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C=CC12)* 0.000 claims description 2
- 125000002943 quinolinyl group Chemical group N1=C(C=CC2=CC=CC=C12)* 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910007926 ZrCl Inorganic materials 0.000 description 1
- 125000003289 ascorbyl group Chemical group [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- NXPHGHWWQRMDIA-UHFFFAOYSA-M magnesium;carbanide;bromide Chemical compound [CH3-].[Mg+2].[Br-] NXPHGHWWQRMDIA-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361840624P | 2013-06-28 | 2013-06-28 | |
| US61/840,624 | 2013-06-28 | ||
| PCT/US2014/044374 WO2014210333A1 (en) | 2013-06-28 | 2014-06-26 | Molecular weight control of polyolefins using halogenated bis-phenylphenoxy catalysts |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018217837A Division JP6813556B2 (ja) | 2013-06-28 | 2018-11-21 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016524024A JP2016524024A (ja) | 2016-08-12 |
| JP2016524024A5 true JP2016524024A5 (https=) | 2017-08-24 |
| JP6441332B2 JP6441332B2 (ja) | 2018-12-19 |
Family
ID=51211353
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016524204A Active JP6441332B2 (ja) | 2013-06-28 | 2014-06-26 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
| JP2018217837A Active JP6813556B2 (ja) | 2013-06-28 | 2018-11-21 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018217837A Active JP6813556B2 (ja) | 2013-06-28 | 2018-11-21 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US9605098B2 (https=) |
| EP (2) | EP3925989B1 (https=) |
| JP (2) | JP6441332B2 (https=) |
| KR (1) | KR102218415B1 (https=) |
| CN (2) | CN113201084A (https=) |
| BR (1) | BR112015030912B1 (https=) |
| ES (2) | ES3062088T3 (https=) |
| SG (2) | SG10201802443VA (https=) |
| WO (1) | WO2014210333A1 (https=) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6348512B2 (ja) * | 2012-12-27 | 2018-06-27 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマーを製造するための重合法 |
| EP2938648B1 (en) | 2012-12-27 | 2019-01-30 | Dow Global Technologies LLC | A polymerization process for producing ethylene based polymers |
| SG11201503581PA (en) * | 2012-12-27 | 2015-06-29 | Dow Global Technologies Llc | Catalyst systems for olefin polymerization |
| CN113201084A (zh) * | 2013-06-28 | 2021-08-03 | 陶氏环球技术有限责任公司 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
| US10519260B2 (en) * | 2014-06-30 | 2019-12-31 | Dow Global Technologies Llc | Polymerizations for olefin-based polymers |
| JP6805125B2 (ja) * | 2014-07-24 | 2020-12-23 | ダウ グローバル テクノロジーズ エルエルシー | 低分子量エチレン系ポリマー重合用のビス−ビフェニルフェノキシ触媒 |
| ES2811135T3 (es) | 2015-06-30 | 2021-03-10 | Dow Global Technologies Llc | Un procedimiento de polimerización para producir polímeros a base de etileno |
| WO2017004462A1 (en) * | 2015-06-30 | 2017-01-05 | Dow Global Technologies Llc | A polymerization process for producing ethylene based polymers |
| ES2925720T3 (es) | 2015-09-30 | 2022-10-19 | Dow Global Technologies Llc | Un proceso de polimerización para producir polímeros a base de etileno |
| CN108350121B (zh) | 2015-09-30 | 2021-10-01 | 陶氏环球技术有限责任公司 | 主催化剂和使用其的聚合方法 |
| SG11201900653RA (en) | 2016-07-29 | 2019-02-27 | Dow Global Technologies Llc | Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization |
| SG11201908307XA (en) * | 2017-03-15 | 2019-10-30 | Dow Global Technologies Llc | Catalyst system for multi-block copolymer formation |
| WO2018183056A1 (en) | 2017-03-31 | 2018-10-04 | Dow Global Technologies Llc | Germanium-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization |
| BR112019020417B1 (pt) | 2017-03-31 | 2023-04-04 | Dow Global Technologies Llc | Sistema catalisador e processo de polimerização para produzir um polímero à base de etileno |
| CN111133010B (zh) | 2017-09-29 | 2023-05-23 | 陶氏环球技术有限责任公司 | 用于改进溶解度的在金属上具有两个亚甲基三烷基硅配体的双-苯基-苯氧基聚烯烃催化剂 |
| US11066428B2 (en) | 2017-09-29 | 2021-07-20 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin catalysts having a methylenetrialkylsilicon ligand on the metal for improved solubility |
| CN111164110A (zh) | 2017-09-29 | 2020-05-15 | 陶氏环球技术有限责任公司 | 在金属上具有烷氧基或酰胺基配体的用于改进溶解度的双-苯基-苯氧基聚烯烃催化剂 |
| KR102100142B1 (ko) * | 2017-12-21 | 2020-04-14 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 금속-리간드 착체, 이를 포함하는 에틸렌계 중합용 촉매 조성물 및 이를 이용한 에틸렌계 중합체의 제조방법 |
| KR102729476B1 (ko) * | 2018-03-30 | 2024-11-14 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합 활성화제 |
| CN112074549B (zh) * | 2018-03-30 | 2023-06-23 | 陶氏环球技术有限责任公司 | 烯烃聚合活化剂 |
| US20210309768A1 (en) | 2018-08-30 | 2021-10-07 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin procatalysts having two anthracenyl ligands |
| EP3924395A4 (en) * | 2019-02-12 | 2022-06-22 | ExxonMobil Chemical Patents Inc. | BIS(ARYL-PHENOLATE) LEWIS-BASED CATALYSTS AND METHODS THEREOF |
| CA3156383A1 (en) | 2019-11-04 | 2021-05-14 | Andrew J. Young | Bimodal catalyst systems |
| CA3156418A1 (en) | 2019-11-04 | 2021-05-14 | Rhett A. BAILLIE | Titanium biphenylphenol polymerization catalysts |
| US12428504B2 (en) | 2019-11-04 | 2025-09-30 | Dow Global Technologies Llc | Biphenylphenol polymerization catalysts |
| US12595322B2 (en) | 2019-12-19 | 2026-04-07 | Dow Global Technologies Llc | Gas-phase biphenylphenol polymerization catalysts |
| EP4097152B1 (en) | 2020-01-31 | 2025-09-03 | Dow Global Technologies LLC | Polymerization processes that include group iii and lanthanide bis-phenyl-phenoxy metal-ligand complexes and chain transfer agents |
| EP4332133A3 (en) | 2020-01-31 | 2024-05-15 | Dow Global Technologies LLC | Group iii and lanthanide bis-phenyl-phenoxy metal-ligand complexes |
| JP2024500603A (ja) * | 2020-12-28 | 2024-01-10 | サビック エスケー ネクスレン カンパニー プライヴェート リミテッド | 金属－リガンド錯体、これを含むエチレン系重合体製造用の触媒組成物およびこれを用いたエチレン系重合体の製造方法 |
| KR20230155453A (ko) * | 2021-02-15 | 2023-11-10 | 다우 글로벌 테크놀로지스 엘엘씨 | 역상 공단량체 분포를 갖는 폴리(에틸렌-코-1-알켄) 공중합체의 제조 방법 |
| EP4291586A1 (en) * | 2021-02-15 | 2023-12-20 | Dow Global Technologies LLC | Biphenylphenol polymerization catalysts having improved kinetic induction times |
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| JP6348512B2 (ja) | 2012-12-27 | 2018-06-27 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマーを製造するための重合法 |
| CN104854144B (zh) | 2012-12-27 | 2018-08-07 | 陶氏环球技术有限责任公司 | 乙烯类聚合物 |
| CN105339327B (zh) | 2013-06-28 | 2020-01-21 | 陶氏环球技术有限责任公司 | 基于乙烯的超支化寡聚物 |
| CN113201084A (zh) * | 2013-06-28 | 2021-08-03 | 陶氏环球技术有限责任公司 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
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| KR101829559B1 (ko) | 2013-09-25 | 2018-02-14 | 미쯔비시 케미컬 주식회사 | 연질 염화비닐계 수지 조성물, 성형체, 전선 피복재 및 피복된 전선 |
-
2014
- 2014-06-26 CN CN202110385158.5A patent/CN113201084A/zh active Pending
- 2014-06-26 KR KR1020167001548A patent/KR102218415B1/ko active Active
- 2014-06-26 CN CN201480033642.XA patent/CN105283474A/zh active Pending
- 2014-06-26 ES ES21183736T patent/ES3062088T3/es active Active
- 2014-06-26 ES ES14741484T patent/ES2934177T3/es active Active
- 2014-06-26 WO PCT/US2014/044374 patent/WO2014210333A1/en not_active Ceased
- 2014-06-26 EP EP21183736.4A patent/EP3925989B1/en active Active
- 2014-06-26 SG SG10201802443VA patent/SG10201802443VA/en unknown
- 2014-06-26 US US14/781,419 patent/US9605098B2/en active Active
- 2014-06-26 EP EP14741484.1A patent/EP3013871B1/en active Active
- 2014-06-26 BR BR112015030912-7A patent/BR112015030912B1/pt active IP Right Grant
- 2014-06-26 JP JP2016524204A patent/JP6441332B2/ja active Active
- 2014-06-26 SG SG11201510689SA patent/SG11201510689SA/en unknown
-
2017
- 2017-02-15 US US15/433,198 patent/US10144791B2/en active Active
-
2018
- 2018-11-21 JP JP2018217837A patent/JP6813556B2/ja active Active
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