JP6441332B2 - ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 - Google Patents
ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 Download PDFInfo
- Publication number
- JP6441332B2 JP6441332B2 JP2016524204A JP2016524204A JP6441332B2 JP 6441332 B2 JP6441332 B2 JP 6441332B2 JP 2016524204 A JP2016524204 A JP 2016524204A JP 2016524204 A JP2016524204 A JP 2016524204A JP 6441332 B2 JP6441332 B2 JP 6441332B2
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- JP
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- Prior art keywords
- alpha
- independently
- olefin
- mmol
- hydrocarbyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Crystallography & Structural Chemistry (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361840624P | 2013-06-28 | 2013-06-28 | |
| US61/840,624 | 2013-06-28 | ||
| PCT/US2014/044374 WO2014210333A1 (en) | 2013-06-28 | 2014-06-26 | Molecular weight control of polyolefins using halogenated bis-phenylphenoxy catalysts |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018217837A Division JP6813556B2 (ja) | 2013-06-28 | 2018-11-21 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016524024A JP2016524024A (ja) | 2016-08-12 |
| JP2016524024A5 JP2016524024A5 (https=) | 2017-08-24 |
| JP6441332B2 true JP6441332B2 (ja) | 2018-12-19 |
Family
ID=51211353
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016524204A Active JP6441332B2 (ja) | 2013-06-28 | 2014-06-26 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
| JP2018217837A Active JP6813556B2 (ja) | 2013-06-28 | 2018-11-21 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018217837A Active JP6813556B2 (ja) | 2013-06-28 | 2018-11-21 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US9605098B2 (https=) |
| EP (2) | EP3925989B1 (https=) |
| JP (2) | JP6441332B2 (https=) |
| KR (1) | KR102218415B1 (https=) |
| CN (2) | CN113201084A (https=) |
| BR (1) | BR112015030912B1 (https=) |
| ES (2) | ES3062088T3 (https=) |
| SG (2) | SG10201802443VA (https=) |
| WO (1) | WO2014210333A1 (https=) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6348512B2 (ja) * | 2012-12-27 | 2018-06-27 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマーを製造するための重合法 |
| EP2938648B1 (en) | 2012-12-27 | 2019-01-30 | Dow Global Technologies LLC | A polymerization process for producing ethylene based polymers |
| SG11201503581PA (en) * | 2012-12-27 | 2015-06-29 | Dow Global Technologies Llc | Catalyst systems for olefin polymerization |
| CN113201084A (zh) * | 2013-06-28 | 2021-08-03 | 陶氏环球技术有限责任公司 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
| US10519260B2 (en) * | 2014-06-30 | 2019-12-31 | Dow Global Technologies Llc | Polymerizations for olefin-based polymers |
| JP6805125B2 (ja) * | 2014-07-24 | 2020-12-23 | ダウ グローバル テクノロジーズ エルエルシー | 低分子量エチレン系ポリマー重合用のビス−ビフェニルフェノキシ触媒 |
| ES2811135T3 (es) | 2015-06-30 | 2021-03-10 | Dow Global Technologies Llc | Un procedimiento de polimerización para producir polímeros a base de etileno |
| WO2017004462A1 (en) * | 2015-06-30 | 2017-01-05 | Dow Global Technologies Llc | A polymerization process for producing ethylene based polymers |
| ES2925720T3 (es) | 2015-09-30 | 2022-10-19 | Dow Global Technologies Llc | Un proceso de polimerización para producir polímeros a base de etileno |
| CN108350121B (zh) | 2015-09-30 | 2021-10-01 | 陶氏环球技术有限责任公司 | 主催化剂和使用其的聚合方法 |
| SG11201900653RA (en) | 2016-07-29 | 2019-02-27 | Dow Global Technologies Llc | Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization |
| SG11201908307XA (en) * | 2017-03-15 | 2019-10-30 | Dow Global Technologies Llc | Catalyst system for multi-block copolymer formation |
| WO2018183056A1 (en) | 2017-03-31 | 2018-10-04 | Dow Global Technologies Llc | Germanium-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization |
| BR112019020417B1 (pt) | 2017-03-31 | 2023-04-04 | Dow Global Technologies Llc | Sistema catalisador e processo de polimerização para produzir um polímero à base de etileno |
| CN111133010B (zh) | 2017-09-29 | 2023-05-23 | 陶氏环球技术有限责任公司 | 用于改进溶解度的在金属上具有两个亚甲基三烷基硅配体的双-苯基-苯氧基聚烯烃催化剂 |
| US11066428B2 (en) | 2017-09-29 | 2021-07-20 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin catalysts having a methylenetrialkylsilicon ligand on the metal for improved solubility |
| CN111164110A (zh) | 2017-09-29 | 2020-05-15 | 陶氏环球技术有限责任公司 | 在金属上具有烷氧基或酰胺基配体的用于改进溶解度的双-苯基-苯氧基聚烯烃催化剂 |
| KR102100142B1 (ko) * | 2017-12-21 | 2020-04-14 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 금속-리간드 착체, 이를 포함하는 에틸렌계 중합용 촉매 조성물 및 이를 이용한 에틸렌계 중합체의 제조방법 |
| KR102729476B1 (ko) * | 2018-03-30 | 2024-11-14 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합 활성화제 |
| CN112074549B (zh) * | 2018-03-30 | 2023-06-23 | 陶氏环球技术有限责任公司 | 烯烃聚合活化剂 |
| US20210309768A1 (en) | 2018-08-30 | 2021-10-07 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin procatalysts having two anthracenyl ligands |
| EP3924395A4 (en) * | 2019-02-12 | 2022-06-22 | ExxonMobil Chemical Patents Inc. | BIS(ARYL-PHENOLATE) LEWIS-BASED CATALYSTS AND METHODS THEREOF |
| CA3156383A1 (en) | 2019-11-04 | 2021-05-14 | Andrew J. Young | Bimodal catalyst systems |
| CA3156418A1 (en) | 2019-11-04 | 2021-05-14 | Rhett A. BAILLIE | Titanium biphenylphenol polymerization catalysts |
| US12428504B2 (en) | 2019-11-04 | 2025-09-30 | Dow Global Technologies Llc | Biphenylphenol polymerization catalysts |
| US12595322B2 (en) | 2019-12-19 | 2026-04-07 | Dow Global Technologies Llc | Gas-phase biphenylphenol polymerization catalysts |
| EP4097152B1 (en) | 2020-01-31 | 2025-09-03 | Dow Global Technologies LLC | Polymerization processes that include group iii and lanthanide bis-phenyl-phenoxy metal-ligand complexes and chain transfer agents |
| EP4332133A3 (en) | 2020-01-31 | 2024-05-15 | Dow Global Technologies LLC | Group iii and lanthanide bis-phenyl-phenoxy metal-ligand complexes |
| JP2024500603A (ja) * | 2020-12-28 | 2024-01-10 | サビック エスケー ネクスレン カンパニー プライヴェート リミテッド | 金属-リガンド錯体、これを含むエチレン系重合体製造用の触媒組成物およびこれを用いたエチレン系重合体の製造方法 |
| KR20230155453A (ko) * | 2021-02-15 | 2023-11-10 | 다우 글로벌 테크놀로지스 엘엘씨 | 역상 공단량체 분포를 갖는 폴리(에틸렌-코-1-알켄) 공중합체의 제조 방법 |
| EP4291586A1 (en) * | 2021-02-15 | 2023-12-20 | Dow Global Technologies LLC | Biphenylphenol polymerization catalysts having improved kinetic induction times |
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| EP2938648B1 (en) | 2012-12-27 | 2019-01-30 | Dow Global Technologies LLC | A polymerization process for producing ethylene based polymers |
| SG11201503581PA (en) | 2012-12-27 | 2015-06-29 | Dow Global Technologies Llc | Catalyst systems for olefin polymerization |
| JP6348512B2 (ja) | 2012-12-27 | 2018-06-27 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマーを製造するための重合法 |
| CN104854144B (zh) | 2012-12-27 | 2018-08-07 | 陶氏环球技术有限责任公司 | 乙烯类聚合物 |
| CN105339327B (zh) | 2013-06-28 | 2020-01-21 | 陶氏环球技术有限责任公司 | 基于乙烯的超支化寡聚物 |
| CN113201084A (zh) * | 2013-06-28 | 2021-08-03 | 陶氏环球技术有限责任公司 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
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2014
- 2014-06-26 CN CN202110385158.5A patent/CN113201084A/zh active Pending
- 2014-06-26 KR KR1020167001548A patent/KR102218415B1/ko active Active
- 2014-06-26 CN CN201480033642.XA patent/CN105283474A/zh active Pending
- 2014-06-26 ES ES21183736T patent/ES3062088T3/es active Active
- 2014-06-26 ES ES14741484T patent/ES2934177T3/es active Active
- 2014-06-26 WO PCT/US2014/044374 patent/WO2014210333A1/en not_active Ceased
- 2014-06-26 EP EP21183736.4A patent/EP3925989B1/en active Active
- 2014-06-26 SG SG10201802443VA patent/SG10201802443VA/en unknown
- 2014-06-26 US US14/781,419 patent/US9605098B2/en active Active
- 2014-06-26 EP EP14741484.1A patent/EP3013871B1/en active Active
- 2014-06-26 BR BR112015030912-7A patent/BR112015030912B1/pt active IP Right Grant
- 2014-06-26 JP JP2016524204A patent/JP6441332B2/ja active Active
- 2014-06-26 SG SG11201510689SA patent/SG11201510689SA/en unknown
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2017
- 2017-02-15 US US15/433,198 patent/US10144791B2/en active Active
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2018
- 2018-11-21 JP JP2018217837A patent/JP6813556B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| BR112015030912A8 (pt) | 2020-01-28 |
| EP3925989A1 (en) | 2021-12-22 |
| SG11201510689SA (en) | 2016-01-28 |
| EP3925989B1 (en) | 2026-01-07 |
| CN113201084A (zh) | 2021-08-03 |
| CN105283474A (zh) | 2016-01-27 |
| US20170158790A1 (en) | 2017-06-08 |
| BR112015030912B1 (pt) | 2021-08-03 |
| SG10201802443VA (en) | 2018-05-30 |
| EP3013871A1 (en) | 2016-05-04 |
| US10144791B2 (en) | 2018-12-04 |
| US9605098B2 (en) | 2017-03-28 |
| JP2019049003A (ja) | 2019-03-28 |
| WO2014210333A1 (en) | 2014-12-31 |
| BR112015030912A2 (pt) | 2017-07-25 |
| ES2934177T3 (es) | 2023-02-17 |
| JP2016524024A (ja) | 2016-08-12 |
| EP3013871B1 (en) | 2022-10-19 |
| KR20160037890A (ko) | 2016-04-06 |
| US20160108156A1 (en) | 2016-04-21 |
| KR102218415B1 (ko) | 2021-02-22 |
| JP6813556B2 (ja) | 2021-01-13 |
| ES3062088T3 (en) | 2026-04-08 |
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