JP2016513060A - 脱水‐加水分解プロセスおよびそのための触媒 - Google Patents

脱水‐加水分解プロセスおよびそのための触媒 Download PDF

Info

Publication number
JP2016513060A
JP2016513060A JP2015557431A JP2015557431A JP2016513060A JP 2016513060 A JP2016513060 A JP 2016513060A JP 2015557431 A JP2015557431 A JP 2015557431A JP 2015557431 A JP2015557431 A JP 2015557431A JP 2016513060 A JP2016513060 A JP 2016513060A
Authority
JP
Japan
Prior art keywords
zeolite
fer
alkali metal
mol
dimension
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2015557431A
Other languages
English (en)
Japanese (ja)
Other versions
JP2016513060A5 (enExample
Inventor
エドワード クラーク，トーマス
エドワード クラーク，トーマス
ジャン ディッツェル，エバート
ジャン ディッツェル，エバート
ジョン ロウ，ディビッド
ジョン ロウ，ディビッド
レオ ウィリアムズ，ブルース
レオ ウィリアムズ，ブルース
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Publication of JP2016513060A publication Critical patent/JP2016513060A/ja
Publication of JP2016513060A5 publication Critical patent/JP2016513060A5/ja
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C01B39/445—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38 using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/60—Compounds characterised by their crystallite size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2015557431A 2013-02-15 2014-02-13 脱水‐加水分解プロセスおよびそのための触媒 Pending JP2016513060A (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP13155521.1 2013-02-15
EP13155521 2013-02-15
EP13180643.2 2013-08-16
EP13180643 2013-08-16
PCT/EP2014/052843 WO2014125038A1 (en) 2013-02-15 2014-02-13 Dehydration-hydrolysis processes and catalysts therefor

Publications (2)

Publication Number Publication Date
JP2016513060A true JP2016513060A (ja) 2016-05-12
JP2016513060A5 JP2016513060A5 (enExample) 2017-02-23

Family

ID=50097700

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2015557431A Pending JP2016513060A (ja) 2013-02-15 2014-02-13 脱水‐加水分解プロセスおよびそのための触媒

Country Status (12)

Country Link
US (2) US9873112B2 (enExample)
EP (1) EP2956408A1 (enExample)
JP (1) JP2016513060A (enExample)
KR (1) KR20150120434A (enExample)
CN (1) CN105102374B (enExample)
BR (1) BR112015019462A2 (enExample)
CA (1) CA2900886A1 (enExample)
RU (1) RU2706014C2 (enExample)
SG (1) SG11201506356WA (enExample)
TW (1) TW201436861A (enExample)
UA (1) UA116126C2 (enExample)
WO (1) WO2014125038A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2021533075A (ja) * 2018-07-27 2021-12-02 ビーエイエスエフ・ソシエタス・エウロパエアBasf Se 骨格型ｆｅｒを有するゼオライト材料の製造方法

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
UA116126C2 (uk) * 2013-02-15 2018-02-12 Бп Кемікалз Лімітед Способи дегідратації-гідролізу й каталізатори для цього
WO2019037760A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
WO2019037768A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
EP3672928A4 (en) 2017-08-24 2021-05-12 Bp P.L.C. PROCESS
WO2019037766A1 (en) * 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
US11180376B1 (en) * 2021-03-19 2021-11-23 Chevron U.S.A. Inc. Synthesis of zeolites having the ferrierite structure
CN114408938B (zh) * 2021-08-19 2024-07-19 复榆(张家港)新材料科技有限公司 一种全硅fer沸石及其制备方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3992466A (en) * 1975-08-13 1976-11-16 Mobil Oil Corporation Hydrocarbon conversion
US4016245A (en) * 1973-09-04 1977-04-05 Mobil Oil Corporation Crystalline zeolite and method of preparing same
JPS5585415A (en) * 1978-12-14 1980-06-27 Shell Int Research Manufacture of ferrierite
JPS62153115A (ja) * 1985-12-09 1987-07-08 シエル・インタ−ナシヨネイル・リサ−チ・マ−チヤツピイ・ベ−・ウイ フエリエライトの製造方法
US5288475A (en) * 1992-10-21 1994-02-22 Mobil Oil Corp. Synthesis of ZSM-35
JPH08502478A (ja) * 1992-10-16 1996-03-19 モービル・オイル・コーポレイション Ｚｓｍ−３５を用いたオレフィンの骨格異性化方法
JP2009531272A (ja) * 2006-03-24 2009-09-03 ユーオーピー エルエルシー ナノサイズゼオライトを調製する方法
JP2013503840A (ja) * 2009-09-03 2013-02-04 ビーピー ケミカルズ リミテッド ゼオライト触媒を用いた酢酸およびジメチルエーテルの製造方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6521783B1 (en) 1998-01-29 2003-02-18 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates
KR100454091B1 (ko) 2002-12-11 2004-10-26 한국화학연구원 미정제 메탄올로부터 디메틸에테르의 제조방법
CN1299989C (zh) * 2004-09-17 2007-02-14 中国科学院大连化学物理研究所 一种zsm－35分子筛的制备方法
EP1888224B1 (en) 2005-04-04 2015-12-09 Avantium International B.V. System and method for performing a chemical experiment
GB0607395D0 (en) * 2006-04-12 2006-05-24 Bp Chem Int Ltd Process
KR100966706B1 (ko) 2008-06-18 2010-06-29 아주대학교산학협력단 메탄올로부터 디메틸에테르를 제조하는 방법
BRPI0803764A2 (pt) 2008-06-30 2010-03-09 Petroleo Brasileiro Sa sistema catalìtico e processo de sìntese direta do éter dimetìlico a partir do gás de sìntese
UA116126C2 (uk) * 2013-02-15 2018-02-12 Бп Кемікалз Лімітед Способи дегідратації-гідролізу й каталізатори для цього

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4016245A (en) * 1973-09-04 1977-04-05 Mobil Oil Corporation Crystalline zeolite and method of preparing same
US3992466A (en) * 1975-08-13 1976-11-16 Mobil Oil Corporation Hydrocarbon conversion
JPS5585415A (en) * 1978-12-14 1980-06-27 Shell Int Research Manufacture of ferrierite
JPS62153115A (ja) * 1985-12-09 1987-07-08 シエル・インタ−ナシヨネイル・リサ−チ・マ−チヤツピイ・ベ−・ウイ フエリエライトの製造方法
JPH08502478A (ja) * 1992-10-16 1996-03-19 モービル・オイル・コーポレイション Ｚｓｍ−３５を用いたオレフィンの骨格異性化方法
US5288475A (en) * 1992-10-21 1994-02-22 Mobil Oil Corp. Synthesis of ZSM-35
JP2009531272A (ja) * 2006-03-24 2009-09-03 ユーオーピー エルエルシー ナノサイズゼオライトを調製する方法
JP2013503840A (ja) * 2009-09-03 2013-02-04 ビーピー ケミカルズ リミテッド ゼオライト触媒を用いた酢酸およびジメチルエーテルの製造方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2021533075A (ja) * 2018-07-27 2021-12-02 ビーエイエスエフ・ソシエタス・エウロパエアBasf Se 骨格型ｆｅｒを有するゼオライト材料の製造方法
JP7494174B2 (ja) 2018-07-27 2024-06-03 ビーエーエスエフ ソシエタス・ヨーロピア 骨格型ｆｅｒを有するゼオライト材料の製造方法

Also Published As

Publication number Publication date
TW201436861A (zh) 2014-10-01
WO2014125038A1 (en) 2014-08-21
CA2900886A1 (en) 2014-08-21
US9873112B2 (en) 2018-01-23
US10328420B2 (en) 2019-06-25
SG11201506356WA (en) 2015-09-29
KR20150120434A (ko) 2015-10-27
UA116126C2 (uk) 2018-02-12
RU2015139042A (ru) 2017-03-21
BR112015019462A2 (pt) 2017-07-18
CN105102374A (zh) 2015-11-25
US20180036722A1 (en) 2018-02-08
EP2956408A1 (en) 2015-12-23
US20150375217A1 (en) 2015-12-31
CN105102374B (zh) 2018-04-24
RU2706014C2 (ru) 2019-11-13

Similar Documents

Publication Publication Date Title
US10328420B2 (en) Dehydration-hydrolysis processes and catalysts therefor
US10583426B2 (en) Carbonylation catalyst and process
TWI471303B (zh) 使用經鍵結之ｈ－絲光沸石催化劑的羰基化製程
US10207975B2 (en) Dehydration-hydrolysis processes and catalysts therefor
JP5668422B2 (ja) アルミノシリケートの製造方法
KR20120020120A (ko) 카르보닐화 방법
Jin et al. Synthesis of hierarchical ZSM-5 by cetyltrimethylammonium bromide assisted self-assembly of zeolite seeds and its catalytic performances
CN109890782A (zh) 生产丁二烯的单阶段方法
JP5600923B2 (ja) アルミノシリケートの製造方法
US11104637B2 (en) Process for the conversion of monoethanolamine to ethylenediamine employing a copper-modified zeolite of the MOR framework structure
CN110997143A (zh) 包含混合金属氧化物和含具有骨架类型cha和碱土金属的沸石材料的模制品的组合物
Liang et al. Full-crystalline monolithic EU-1 zeolite: sustainable synthesis and its applications in the hydroisomerization of ethylbenzene with meta-xylene
US20140135556A1 (en) Production and Use of a Zeolitic Material in a Process for the Conversion of Oxygenates to Olefins
Yi et al. Synthesis and characterization of thermally stable mesostructured sulfated zirconia by a novel sulfate-assisted alcohothermal route
JP5720508B2 (ja) シリル化されたｃｈａ型構造を有するｈ型ゼオライトの製造方法

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20151015

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20170119

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20170119

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20171101

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20180530