CN105102374B - 脱水-水解方法及其催化剂 - Google Patents

脱水-水解方法及其催化剂 Download PDF

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Publication number
CN105102374B
CN105102374B CN201480021292.5A CN201480021292A CN105102374B CN 105102374 B CN105102374 B CN 105102374B CN 201480021292 A CN201480021292 A CN 201480021292A CN 105102374 B CN105102374 B CN 105102374B
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Prior art keywords
zeolite
axis
fer
ferrierite
mol
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Chinese (zh)
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CN105102374A (zh
Inventor
T.E.克拉克
E.J.迪策尔
D.J.劳
B.L.威廉斯
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Ineos Acetyls UK Ltd
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BP Chemicals Ltd
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C01B39/445—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38 using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/60—Compounds characterised by their crystallite size

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201480021292.5A 2013-02-15 2014-02-13 脱水-水解方法及其催化剂 Active CN105102374B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP13155521 2013-02-15
EP13155521.1 2013-02-15
EP13180643 2013-08-16
EP13180643.2 2013-08-16
PCT/EP2014/052843 WO2014125038A1 (en) 2013-02-15 2014-02-13 Dehydration-hydrolysis processes and catalysts therefor

Publications (2)

Publication Number Publication Date
CN105102374A CN105102374A (zh) 2015-11-25
CN105102374B true CN105102374B (zh) 2018-04-24

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CN201480021292.5A Active CN105102374B (zh) 2013-02-15 2014-02-13 脱水-水解方法及其催化剂

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US (2) US9873112B2 (enExample)
EP (1) EP2956408A1 (enExample)
JP (1) JP2016513060A (enExample)
KR (1) KR20150120434A (enExample)
CN (1) CN105102374B (enExample)
BR (1) BR112015019462A2 (enExample)
CA (1) CA2900886A1 (enExample)
RU (1) RU2706014C2 (enExample)
SG (1) SG11201506356WA (enExample)
TW (1) TW201436861A (enExample)
UA (1) UA116126C2 (enExample)
WO (1) WO2014125038A1 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2706014C2 (ru) * 2013-02-15 2019-11-13 Бп Кемикэлз Лимитед Способы дегидратации-гидролиза и катализаторы для них
WO2019037760A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
US11427524B2 (en) 2017-08-24 2022-08-30 Bp P.L.C. Process for dehydrating methanol to dimethyl ether product
EP3672930A4 (en) 2017-08-24 2021-05-12 Bp P.L.C. PROCESS
WO2019037764A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
JP7494174B2 (ja) * 2018-07-27 2024-06-03 ビーエーエスエフ ソシエタス・ヨーロピア 骨格型ｆｅｒを有するゼオライト材料の製造方法
US11180376B1 (en) * 2021-03-19 2021-11-23 Chevron U.S.A. Inc. Synthesis of zeolites having the ferrierite structure
CN114408938B (zh) * 2021-08-19 2024-07-19 复榆(张家港)新材料科技有限公司 一种全硅fer沸石及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3992466A (en) * 1975-08-13 1976-11-16 Mobil Oil Corporation Hydrocarbon conversion
CN1749164A (zh) * 2004-09-17 2006-03-22 中国科学院大连化学物理研究所 一种zsm－35分子筛的制备方法

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Publication number Priority date Publication date Assignee Title
US4016245A (en) 1973-09-04 1977-04-05 Mobil Oil Corporation Crystalline zeolite and method of preparing same
NL7812162A (nl) * 1978-12-14 1980-06-17 Shell Int Research Werkwijze voor de bereiding van ferrieriet.
EP0236590B1 (en) 1985-12-09 1989-12-27 Shell Internationale Researchmaatschappij B.V. Process for the preparation of ferrierite and its use as dewaxing catalyst (carrier)
WO1994008920A1 (en) * 1992-10-16 1994-04-28 Mobil Oil Corporation Olefin skeletal isomerization process using zsm-35
US5288475A (en) 1992-10-21 1994-02-22 Mobil Oil Corp. Synthesis of ZSM-35
US6521783B1 (en) 1998-01-29 2003-02-18 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates
KR100454091B1 (ko) 2002-12-11 2004-10-26 한국화학연구원 미정제 메탄올로부터 디메틸에테르의 제조방법
MX2007012278A (es) 2005-04-04 2008-10-24 Avantium Int Bv Sistema y metodo para realizar un experimento quimico.
US20070224113A1 (en) * 2006-03-24 2007-09-27 Willis Richard R Process for Preparing Nano Size Zeolites
GB0607395D0 (en) * 2006-04-12 2006-05-24 Bp Chem Int Ltd Process
KR100966706B1 (ko) 2008-06-18 2010-06-29 아주대학교산학협력단 메탄올로부터 디메틸에테르를 제조하는 방법
BRPI0803764A2 (pt) 2008-06-30 2010-03-09 Petroleo Brasileiro Sa sistema catalìtico e processo de sìntese direta do éter dimetìlico a partir do gás de sìntese
EP2292578A1 (en) 2009-09-03 2011-03-09 BP Chemicals Limited Process for producing acetic acid and dimethyl ether using a zeolite catalyst
RU2706014C2 (ru) * 2013-02-15 2019-11-13 Бп Кемикэлз Лимитед Способы дегидратации-гидролиза и катализаторы для них

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3992466A (en) * 1975-08-13 1976-11-16 Mobil Oil Corporation Hydrocarbon conversion
CN1749164A (zh) * 2004-09-17 2006-03-22 中国科学院大连化学物理研究所 一种zsm－35分子筛的制备方法

Also Published As

Publication number Publication date
CA2900886A1 (en) 2014-08-21
UA116126C2 (uk) 2018-02-12
US9873112B2 (en) 2018-01-23
BR112015019462A2 (pt) 2017-07-18
SG11201506356WA (en) 2015-09-29
US10328420B2 (en) 2019-06-25
TW201436861A (zh) 2014-10-01
JP2016513060A (ja) 2016-05-12
CN105102374A (zh) 2015-11-25
US20150375217A1 (en) 2015-12-31
RU2706014C2 (ru) 2019-11-13
US20180036722A1 (en) 2018-02-08
EP2956408A1 (en) 2015-12-23
KR20150120434A (ko) 2015-10-27
WO2014125038A1 (en) 2014-08-21
RU2015139042A (ru) 2017-03-21

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Patentee before: BP Chemicals Ltd.