BR112015019462A2 - processos de desidratação-hidrólise e catalisadores para os mesmos - Google Patents

processos de desidratação-hidrólise e catalisadores para os mesmos

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Publication number
BR112015019462A2
BR112015019462A2 BR112015019462A BR112015019462A BR112015019462A2 BR 112015019462 A2 BR112015019462 A2 BR 112015019462A2 BR 112015019462 A BR112015019462 A BR 112015019462A BR 112015019462 A BR112015019462 A BR 112015019462A BR 112015019462 A2 BR112015019462 A2 BR 112015019462A2
Authority
BR
Brazil
Prior art keywords
catalysts
dehydration
hydrolysis processes
crystalline zeolites
hydrolysis
Prior art date
Application number
BR112015019462A
Other languages
English (en)
Inventor
Leo Williams Bruce
John Law David
Jan Ditzel Evert
Edward Clark Thomas
Original Assignee
Bp Chem Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd
Publication of BR112015019462A2 publication Critical patent/BR112015019462A2/pt

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C01B39/445Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38 using at least one organic template directing agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30
    • B01J35/60
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/10Heat treatment in the presence of water, e.g. steam
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01Preparation of ethers
    • C07C41/09Preparation of ethers by dehydration of compounds containing hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01Preparation of ethers
    • C07C41/16Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00Ethers; Compounds having groups, groups or groups
    • C07C43/02Ethers
    • C07C43/03Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04Saturated ethers
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08Acetic acid
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/60Compounds characterised by their crystallite size

Abstract

resumo processos de desidratação-hidrólise e catalisadores para os mesmos zeólitos cristalinos possuindo uma estrutura fer em que os cristalitos têm uma dimensão no eixo c de cerca de 500 nanómetros (nm) ou menos, um método para a sua preparação e um processo para a coprodução de ácido acético e éter dimetílico compreendendo o passo de contato de acetato de metila e metanol, na presença de catalisadores compreendendo os zeólitos cristalinos.
BR112015019462A 2013-02-15 2014-02-13 processos de desidratação-hidrólise e catalisadores para os mesmos BR112015019462A2 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13155521 2013-02-15
EP13180643 2013-08-16
PCT/EP2014/052843 WO2014125038A1 (en) 2013-02-15 2014-02-13 Dehydration-hydrolysis processes and catalysts therefor

Publications (1)

Publication Number Publication Date
BR112015019462A2 true BR112015019462A2 (pt) 2017-07-18

Family

ID=50097700

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015019462A BR112015019462A2 (pt) 2013-02-15 2014-02-13 processos de desidratação-hidrólise e catalisadores para os mesmos

Country Status (12)

Country Link
US (2) US9873112B2 (pt)
EP (1) EP2956408A1 (pt)
JP (1) JP2016513060A (pt)
KR (1) KR20150120434A (pt)
CN (1) CN105102374B (pt)
BR (1) BR112015019462A2 (pt)
CA (1) CA2900886A1 (pt)
RU (1) RU2706014C2 (pt)
SG (1) SG11201506356WA (pt)
TW (1) TW201436861A (pt)
UA (1) UA116126C2 (pt)
WO (1) WO2014125038A1 (pt)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9873112B2 (en) * 2013-02-15 2018-01-23 Bp Chemicals Limited Dehydration-hydrolysis processes and catalysts therefor
WO2019037764A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
WO2019037768A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
WO2019037760A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
WO2019037766A1 (en) * 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
US11180376B1 (en) * 2021-03-19 2021-11-23 Chevron U.S.A. Inc. Synthesis of zeolites having the ferrierite structure

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4016245A (en) * 1973-09-04 1977-04-05 Mobil Oil Corporation Crystalline zeolite and method of preparing same
US3992466A (en) * 1975-08-13 1976-11-16 Mobil Oil Corporation Hydrocarbon conversion
NL7812162A (nl) 1978-12-14 1980-06-17 Shell Int Research Werkwijze voor de bereiding van ferrieriet.
EP0236590B1 (en) * 1985-12-09 1989-12-27 Shell Internationale Researchmaatschappij B.V. Process for the preparation of ferrierite and its use as dewaxing catalyst (carrier)
EP0664775B1 (en) 1992-10-16 1998-08-26 Mobil Oil Corporation Olefin skeletal isomerization process using zsm-35
US5288475A (en) 1992-10-21 1994-02-22 Mobil Oil Corp. Synthesis of ZSM-35
US6521783B1 (en) 1998-01-29 2003-02-18 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates
KR100454091B1 (ko) 2002-12-11 2004-10-26 한국화학연구원 미정제 메탄올로부터 디메틸에테르의 제조방법
CN1299989C (zh) * 2004-09-17 2007-02-14 中国科学院大连化学物理研究所 一种zsm-35分子筛的制备方法
CN101163543B (zh) 2005-04-04 2011-11-16 阿凡田国际有限公司 用于进行并行化学实验的系统和方法
US20070224113A1 (en) * 2006-03-24 2007-09-27 Willis Richard R Process for Preparing Nano Size Zeolites
GB0607395D0 (en) * 2006-04-12 2006-05-24 Bp Chem Int Ltd Process
KR100966706B1 (ko) 2008-06-18 2010-06-29 아주대학교산학협력단 메탄올로부터 디메틸에테르를 제조하는 방법
BRPI0803764A2 (pt) 2008-06-30 2010-03-09 Petroleo Brasileiro Sa sistema catalìtico e processo de sìntese direta do éter dimetìlico a partir do gás de sìntese
EP2292578A1 (en) * 2009-09-03 2011-03-09 BP Chemicals Limited Process for producing acetic acid and dimethyl ether using a zeolite catalyst
US9873112B2 (en) * 2013-02-15 2018-01-23 Bp Chemicals Limited Dehydration-hydrolysis processes and catalysts therefor

Also Published As

Publication number Publication date
CA2900886A1 (en) 2014-08-21
US20180036722A1 (en) 2018-02-08
JP2016513060A (ja) 2016-05-12
UA116126C2 (uk) 2018-02-12
US20150375217A1 (en) 2015-12-31
US9873112B2 (en) 2018-01-23
US10328420B2 (en) 2019-06-25
KR20150120434A (ko) 2015-10-27
SG11201506356WA (en) 2015-09-29
RU2015139042A (ru) 2017-03-21
EP2956408A1 (en) 2015-12-23
TW201436861A (zh) 2014-10-01
CN105102374A (zh) 2015-11-25
CN105102374B (zh) 2018-04-24
WO2014125038A1 (en) 2014-08-21
RU2706014C2 (ru) 2019-11-13

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B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]