UA116126C2 - Способи дегідратації-гідролізу й каталізатори для цього - Google Patents

Способи дегідратації-гідролізу й каталізатори для цього

Info

Publication number
UA116126C2
UA116126C2 UAA201508802A UAA201508802A UA116126C2 UA 116126 C2 UA116126 C2 UA 116126C2 UA A201508802 A UAA201508802 A UA A201508802A UA A201508802 A UAA201508802 A UA A201508802A UA 116126 C2 UA116126 C2 UA 116126C2
Authority
UA
Ukraine
Prior art keywords
dehydration
hydrolysis processes
catalysts therefor
catalysts
crystalline zeolites
Prior art date
Application number
UAA201508802A
Other languages
English (en)
Inventor
Томас Едвард Кларк
Еверт Ян Дітцель
Девід Джон Лоу
Брюс Лео Вільямс
Original Assignee
Бп Кемікалз Лімітед
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Бп Кемікалз Лімітед filed Critical Бп Кемікалз Лімітед
Publication of UA116126C2 publication Critical patent/UA116126C2/uk

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C01B39/445—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38 using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/60—Compounds characterised by their crystallite size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

У заявці описані кристалічні цеоліти, що мають каркасну структуру типу FER, у яких кристаліти мають розмір по осі с, рівний приблизно 500 нанометрів (нм) або менше, спосіб їх одержання й спосіб спільного одержання оцтової кислоти й диметилового ефіру, що включає стадію взаємодії метилацетату й метанолу в присутності каталізаторів, що містять кристалічні цеоліти.
UAA201508802A 2013-02-15 2014-02-13 Способи дегідратації-гідролізу й каталізатори для цього UA116126C2 (uk)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13155521 2013-02-15
EP13180643 2013-08-16
PCT/EP2014/052843 WO2014125038A1 (en) 2013-02-15 2014-02-13 Dehydration-hydrolysis processes and catalysts therefor

Publications (1)

Publication Number Publication Date
UA116126C2 true UA116126C2 (uk) 2018-02-12

Family

ID=50097700

Family Applications (1)

Application Number Title Priority Date Filing Date
UAA201508802A UA116126C2 (uk) 2013-02-15 2014-02-13 Способи дегідратації-гідролізу й каталізатори для цього

Country Status (12)

Country Link
US (2) US9873112B2 (uk)
EP (1) EP2956408A1 (uk)
JP (1) JP2016513060A (uk)
KR (1) KR20150120434A (uk)
CN (1) CN105102374B (uk)
BR (1) BR112015019462A2 (uk)
CA (1) CA2900886A1 (uk)
RU (1) RU2706014C2 (uk)
SG (1) SG11201506356WA (uk)
TW (1) TW201436861A (uk)
UA (1) UA116126C2 (uk)
WO (1) WO2014125038A1 (uk)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014125038A1 (en) * 2013-02-15 2014-08-21 Bp Chemicals Limited Dehydration-hydrolysis processes and catalysts therefor
CN111356673B (zh) 2017-08-24 2023-05-30 英国石油有限公司 甲醇脱水的方法
CN111511709B (zh) 2017-08-24 2023-05-30 英国石油有限公司 甲醇脱水方法
WO2019037768A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
CN111344272B (zh) 2017-08-24 2023-06-23 英国石油有限公司 甲醇脱水的方法
JP7494174B2 (ja) * 2018-07-27 2024-06-03 ビーエーエスエフ ソシエタス・ヨーロピア 骨格型ｆｅｒを有するゼオライト材料の製造方法
US11180376B1 (en) * 2021-03-19 2021-11-23 Chevron U.S.A. Inc. Synthesis of zeolites having the ferrierite structure
CN114408938B (zh) * 2021-08-19 2024-07-19 复榆(张家港)新材料科技有限公司 一种全硅fer沸石及其制备方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4016245A (en) * 1973-09-04 1977-04-05 Mobil Oil Corporation Crystalline zeolite and method of preparing same
US3992466A (en) * 1975-08-13 1976-11-16 Mobil Oil Corporation Hydrocarbon conversion
NL7812162A (nl) * 1978-12-14 1980-06-17 Shell Int Research Werkwijze voor de bereiding van ferrieriet.
ATE48986T1 (de) 1985-12-09 1990-01-15 Shell Int Research Verfahren zur herstellung von ferrierit und dessen verwendung als entwachsungskatalysator (traeger).
ES2121074T3 (es) 1992-10-16 1998-11-16 Mobil Oil Corp Procedimiento de isomerizacion esqueletica de la olefina utilizando el zsm-35.
US5288475A (en) * 1992-10-21 1994-02-22 Mobil Oil Corp. Synthesis of ZSM-35
US6521783B1 (en) 1998-01-29 2003-02-18 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates
KR100454091B1 (ko) 2002-12-11 2004-10-26 한국화학연구원 미정제 메탄올로부터 디메틸에테르의 제조방법
CN1299989C (zh) * 2004-09-17 2007-02-14 中国科学院大连化学物理研究所 一种zsm－35分子筛的制备方法
WO2006107187A1 (en) 2005-04-04 2006-10-12 Avantium International B.V. System and method for performing a chemical experiment
US20070224113A1 (en) * 2006-03-24 2007-09-27 Willis Richard R Process for Preparing Nano Size Zeolites
GB0607395D0 (en) * 2006-04-12 2006-05-24 Bp Chem Int Ltd Process
KR100966706B1 (ko) 2008-06-18 2010-06-29 아주대학교산학협력단 메탄올로부터 디메틸에테르를 제조하는 방법
BRPI0803764A2 (pt) 2008-06-30 2010-03-09 Petroleo Brasileiro Sa sistema catalìtico e processo de sìntese direta do éter dimetìlico a partir do gás de sìntese
EP2292578A1 (en) * 2009-09-03 2011-03-09 BP Chemicals Limited Process for producing acetic acid and dimethyl ether using a zeolite catalyst
WO2014125038A1 (en) * 2013-02-15 2014-08-21 Bp Chemicals Limited Dehydration-hydrolysis processes and catalysts therefor

Also Published As

Publication number Publication date
RU2015139042A (ru) 2017-03-21
CN105102374A (zh) 2015-11-25
US20180036722A1 (en) 2018-02-08
TW201436861A (zh) 2014-10-01
US20150375217A1 (en) 2015-12-31
BR112015019462A2 (pt) 2017-07-18
KR20150120434A (ko) 2015-10-27
CN105102374B (zh) 2018-04-24
SG11201506356WA (en) 2015-09-29
US10328420B2 (en) 2019-06-25
EP2956408A1 (en) 2015-12-23
CA2900886A1 (en) 2014-08-21
WO2014125038A1 (en) 2014-08-21
US9873112B2 (en) 2018-01-23
RU2706014C2 (ru) 2019-11-13
JP2016513060A (ja) 2016-05-12

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