UA116126C2 - Способи дегідратації-гідролізу й каталізатори для цього - Google Patents
Способи дегідратації-гідролізу й каталізатори для цьогоInfo
- Publication number
- UA116126C2 UA116126C2 UAA201508802A UAA201508802A UA116126C2 UA 116126 C2 UA116126 C2 UA 116126C2 UA A201508802 A UAA201508802 A UA A201508802A UA A201508802 A UAA201508802 A UA A201508802A UA 116126 C2 UA116126 C2 UA 116126C2
- Authority
- UA
- Ukraine
- Prior art keywords
- dehydration
- hydrolysis processes
- catalysts therefor
- catalysts
- crystalline zeolites
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000006460 hydrolysis reaction Methods 0.000 title 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
- C01B39/445—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38 using at least one organic template directing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/04—Saturated ethers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/60—Compounds characterised by their crystallite size
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
У заявці описані кристалічні цеоліти, що мають каркасну структуру типу FER, у яких кристаліти мають розмір по осі с, рівний приблизно 500 нанометрів (нм) або менше, спосіб їх одержання й спосіб спільного одержання оцтової кислоти й диметилового ефіру, що включає стадію взаємодії метилацетату й метанолу в присутності каталізаторів, що містять кристалічні цеоліти.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13155521 | 2013-02-15 | ||
EP13180643 | 2013-08-16 | ||
PCT/EP2014/052843 WO2014125038A1 (en) | 2013-02-15 | 2014-02-13 | Dehydration-hydrolysis processes and catalysts therefor |
Publications (1)
Publication Number | Publication Date |
---|---|
UA116126C2 true UA116126C2 (uk) | 2018-02-12 |
Family
ID=50097700
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
UAA201508802A UA116126C2 (uk) | 2013-02-15 | 2014-02-13 | Способи дегідратації-гідролізу й каталізатори для цього |
Country Status (12)
Country | Link |
---|---|
US (2) | US9873112B2 (uk) |
EP (1) | EP2956408A1 (uk) |
JP (1) | JP2016513060A (uk) |
KR (1) | KR20150120434A (uk) |
CN (1) | CN105102374B (uk) |
BR (1) | BR112015019462A2 (uk) |
CA (1) | CA2900886A1 (uk) |
RU (1) | RU2706014C2 (uk) |
SG (1) | SG11201506356WA (uk) |
TW (1) | TW201436861A (uk) |
UA (1) | UA116126C2 (uk) |
WO (1) | WO2014125038A1 (uk) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014125038A1 (en) * | 2013-02-15 | 2014-08-21 | Bp Chemicals Limited | Dehydration-hydrolysis processes and catalysts therefor |
CN111356673B (zh) | 2017-08-24 | 2023-05-30 | 英国石油有限公司 | 甲醇脱水的方法 |
CN111511709B (zh) | 2017-08-24 | 2023-05-30 | 英国石油有限公司 | 甲醇脱水方法 |
WO2019037768A1 (en) | 2017-08-24 | 2019-02-28 | Bp P.L.C. | PROCESS |
CN111344272B (zh) | 2017-08-24 | 2023-06-23 | 英国石油有限公司 | 甲醇脱水的方法 |
JP7494174B2 (ja) * | 2018-07-27 | 2024-06-03 | ビーエーエスエフ ソシエタス・ヨーロピア | 骨格型ferを有するゼオライト材料の製造方法 |
US11180376B1 (en) * | 2021-03-19 | 2021-11-23 | Chevron U.S.A. Inc. | Synthesis of zeolites having the ferrierite structure |
CN114408938B (zh) * | 2021-08-19 | 2024-07-19 | 复榆(张家港)新材料科技有限公司 | 一种全硅fer沸石及其制备方法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4016245A (en) * | 1973-09-04 | 1977-04-05 | Mobil Oil Corporation | Crystalline zeolite and method of preparing same |
US3992466A (en) * | 1975-08-13 | 1976-11-16 | Mobil Oil Corporation | Hydrocarbon conversion |
NL7812162A (nl) * | 1978-12-14 | 1980-06-17 | Shell Int Research | Werkwijze voor de bereiding van ferrieriet. |
ATE48986T1 (de) | 1985-12-09 | 1990-01-15 | Shell Int Research | Verfahren zur herstellung von ferrierit und dessen verwendung als entwachsungskatalysator (traeger). |
ES2121074T3 (es) | 1992-10-16 | 1998-11-16 | Mobil Oil Corp | Procedimiento de isomerizacion esqueletica de la olefina utilizando el zsm-35. |
US5288475A (en) * | 1992-10-21 | 1994-02-22 | Mobil Oil Corp. | Synthesis of ZSM-35 |
US6521783B1 (en) | 1998-01-29 | 2003-02-18 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for preparing oxygenates |
KR100454091B1 (ko) | 2002-12-11 | 2004-10-26 | 한국화학연구원 | 미정제 메탄올로부터 디메틸에테르의 제조방법 |
CN1299989C (zh) * | 2004-09-17 | 2007-02-14 | 中国科学院大连化学物理研究所 | 一种zsm-35分子筛的制备方法 |
WO2006107187A1 (en) | 2005-04-04 | 2006-10-12 | Avantium International B.V. | System and method for performing a chemical experiment |
US20070224113A1 (en) * | 2006-03-24 | 2007-09-27 | Willis Richard R | Process for Preparing Nano Size Zeolites |
GB0607395D0 (en) * | 2006-04-12 | 2006-05-24 | Bp Chem Int Ltd | Process |
KR100966706B1 (ko) | 2008-06-18 | 2010-06-29 | 아주대학교산학협력단 | 메탄올로부터 디메틸에테르를 제조하는 방법 |
BRPI0803764A2 (pt) | 2008-06-30 | 2010-03-09 | Petroleo Brasileiro Sa | sistema catalìtico e processo de sìntese direta do éter dimetìlico a partir do gás de sìntese |
EP2292578A1 (en) * | 2009-09-03 | 2011-03-09 | BP Chemicals Limited | Process for producing acetic acid and dimethyl ether using a zeolite catalyst |
WO2014125038A1 (en) * | 2013-02-15 | 2014-08-21 | Bp Chemicals Limited | Dehydration-hydrolysis processes and catalysts therefor |
-
2014
- 2014-02-13 WO PCT/EP2014/052843 patent/WO2014125038A1/en active Application Filing
- 2014-02-13 CN CN201480021292.5A patent/CN105102374B/zh active Active
- 2014-02-13 EP EP14704166.9A patent/EP2956408A1/en not_active Withdrawn
- 2014-02-13 TW TW103104739A patent/TW201436861A/zh unknown
- 2014-02-13 UA UAA201508802A patent/UA116126C2/uk unknown
- 2014-02-13 JP JP2015557431A patent/JP2016513060A/ja active Pending
- 2014-02-13 CA CA2900886A patent/CA2900886A1/en not_active Abandoned
- 2014-02-13 RU RU2015139042A patent/RU2706014C2/ru active
- 2014-02-13 BR BR112015019462A patent/BR112015019462A2/pt not_active IP Right Cessation
- 2014-02-13 KR KR1020157025340A patent/KR20150120434A/ko not_active Application Discontinuation
- 2014-02-13 SG SG11201506356WA patent/SG11201506356WA/en unknown
- 2014-02-13 US US14/767,633 patent/US9873112B2/en active Active
-
2017
- 2017-10-11 US US15/730,090 patent/US10328420B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
RU2015139042A (ru) | 2017-03-21 |
CN105102374A (zh) | 2015-11-25 |
US20180036722A1 (en) | 2018-02-08 |
TW201436861A (zh) | 2014-10-01 |
US20150375217A1 (en) | 2015-12-31 |
BR112015019462A2 (pt) | 2017-07-18 |
KR20150120434A (ko) | 2015-10-27 |
CN105102374B (zh) | 2018-04-24 |
SG11201506356WA (en) | 2015-09-29 |
US10328420B2 (en) | 2019-06-25 |
EP2956408A1 (en) | 2015-12-23 |
CA2900886A1 (en) | 2014-08-21 |
WO2014125038A1 (en) | 2014-08-21 |
US9873112B2 (en) | 2018-01-23 |
RU2706014C2 (ru) | 2019-11-13 |
JP2016513060A (ja) | 2016-05-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
UA116126C2 (uk) | Способи дегідратації-гідролізу й каталізатори для цього | |
IN2014DN06993A (uk) | ||
EP3024000A4 (en) | Dust core, coil component using same and process for producing dust core | |
SG11201602920VA (en) | Method for producing polyvinyl alcohol resin, and polyvinyl alcohol resin obtained by the method | |
EP3048101A4 (en) | 2,5-furan dicarboxylic acid production method | |
IN2012DN01991A (uk) | ||
EP3009516A4 (en) | Method for preparing sialic acid derivative | |
MY167587A (en) | Catalyst and process for the production of acetic acid and dimethyl ether | |
EP3006555A4 (en) | Fermented milk that does not undergo increase in acid level, and method for producing same | |
ZA201405035B (en) | Catalyst used in the production of ethylene and propylene from methanol and/or dimethyl ether, method for preparing the same and method for using the same | |
MX2016007297A (es) | Proceso para purificar 2,5-diclorofenol. | |
WO2015086639A3 (de) | Verfahren zur hydrierung aromatischer verbindungen | |
EP3037407A4 (en) | Method for producing 1,5-pentadiamine | |
EP2979757A4 (en) | Catalyst for methacrylic acid production, method for producing same, and method for producing methacrylic acid | |
WO2013022565A8 (en) | Olefin hydration process with an integrated membrane reactor | |
UA119435C2 (uk) | Об'єднаний спосіб одержання метанолу і метилацетату | |
IN2014DE03093A (uk) | ||
EP3015166A4 (en) | Catalyst structure, reactor, and manufacturing method for catalyst structure | |
EP2695887A4 (en) | NEW RUTHENIUM COMPLEX AND PROCESS FOR PRODUCTION OF OPTICALLY ACTIVE ALCOHOL COMPOUND USING AS CATALYST | |
EP3489212A4 (en) | PROCESS FOR THE PRODUCTION OF GUERBET ALCOHOL | |
EP2484662A4 (en) | METHOD FOR MANUFACTURING PERFLUOROSULPHONIC ACID HAVING ETHER STRUCTURE AND DERIVATIVE THEREOF, AND SURFACTANT AGENT CONTAINING FLUORINE-CONTAINING ETHER SULFONIC ACID COMPOUND AND DERIVATIVE THEREOF | |
EP3091002A4 (en) | Method for producing 5-hydroxypiperidine-2-carboxylic acid | |
EP3006422A4 (en) | Process for producing polyhydric alcohol | |
JP2014523473A5 (uk) | ||
WO2010011769A3 (en) | Systems and methods for selective alcohol production |