RU2706014C2 - Способы дегидратации-гидролиза и катализаторы для них - Google Patents

Способы дегидратации-гидролиза и катализаторы для них Download PDF

Info

Publication number
RU2706014C2
RU2706014C2 RU2015139042A RU2015139042A RU2706014C2 RU 2706014 C2 RU2706014 C2 RU 2706014C2 RU 2015139042 A RU2015139042 A RU 2015139042A RU 2015139042 A RU2015139042 A RU 2015139042A RU 2706014 C2 RU2706014 C2 RU 2706014C2
Authority
RU
Russia
Prior art keywords
zeolite
fer
alkali metal
axis
crystallites
Prior art date
Application number
RU2015139042A
Other languages
English (en)
Russian (ru)
Other versions
RU2015139042A (ru
Inventor
Томас Эдуард КЛАРК
Эверт Джан ДИТЗЕЛ
Дейвид Джон ЛО
Брюс Лео УИЛЛЬЯМС
Original Assignee
Бп Кемикэлз Лимитед
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Бп Кемикэлз Лимитед filed Critical Бп Кемикэлз Лимитед
Publication of RU2015139042A publication Critical patent/RU2015139042A/ru
Application granted granted Critical
Publication of RU2706014C2 publication Critical patent/RU2706014C2/ru

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C01B39/445—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38 using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/60—Compounds characterised by their crystallite size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
RU2015139042A 2013-02-15 2014-02-13 Способы дегидратации-гидролиза и катализаторы для них RU2706014C2 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP13155521 2013-02-15
EP13155521.1 2013-02-15
EP13180643 2013-08-16
EP13180643.2 2013-08-16
PCT/EP2014/052843 WO2014125038A1 (en) 2013-02-15 2014-02-13 Dehydration-hydrolysis processes and catalysts therefor

Publications (2)

Publication Number Publication Date
RU2015139042A RU2015139042A (ru) 2017-03-21
RU2706014C2 true RU2706014C2 (ru) 2019-11-13

Family

ID=50097700

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2015139042A RU2706014C2 (ru) 2013-02-15 2014-02-13 Способы дегидратации-гидролиза и катализаторы для них

Country Status (12)

Country Link
US (2) US9873112B2 (enExample)
EP (1) EP2956408A1 (enExample)
JP (1) JP2016513060A (enExample)
KR (1) KR20150120434A (enExample)
CN (1) CN105102374B (enExample)
BR (1) BR112015019462A2 (enExample)
CA (1) CA2900886A1 (enExample)
RU (1) RU2706014C2 (enExample)
SG (1) SG11201506356WA (enExample)
TW (1) TW201436861A (enExample)
UA (1) UA116126C2 (enExample)
WO (1) WO2014125038A1 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2956408A1 (en) * 2013-02-15 2015-12-23 BP Chemicals Limited Dehydration-hydrolysis processes and catalysts therefor
EP3672930A4 (en) 2017-08-24 2021-05-12 Bp P.L.C. PROCEDURE
WO2019037766A1 (en) * 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
CN111356673B (zh) 2017-08-24 2023-05-30 英国石油有限公司 甲醇脱水的方法
EP3672931A4 (en) 2017-08-24 2021-05-12 Bp P.L.C. PROCEDURE
JP7494174B2 (ja) * 2018-07-27 2024-06-03 ビーエーエスエフ ソシエタス・ヨーロピア 骨格型ｆｅｒを有するゼオライト材料の製造方法
US11180376B1 (en) * 2021-03-19 2021-11-23 Chevron U.S.A. Inc. Synthesis of zeolites having the ferrierite structure
CN114408938B (zh) * 2021-08-19 2024-07-19 复榆(张家港)新材料科技有限公司 一种全硅fer沸石及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3992466A (en) * 1975-08-13 1976-11-16 Mobil Oil Corporation Hydrocarbon conversion
US4016245A (en) * 1973-09-04 1977-04-05 Mobil Oil Corporation Crystalline zeolite and method of preparing same
US5288475A (en) * 1992-10-21 1994-02-22 Mobil Oil Corp. Synthesis of ZSM-35
JP2009531272A (ja) * 2006-03-24 2009-09-03 ユーオーピー エルエルシー ナノサイズゼオライトを調製する方法
WO2011027105A1 (en) * 2009-09-03 2011-03-10 Bp Chemicals Limited Process for producing acetic acid and dimethyl ether using a zeolite catalyst
RU2454398C2 (ru) * 2006-04-12 2012-06-27 Бп Кемикэлз Лимитед Способ получения карбоновых кислот и/или их производных

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7812162A (nl) * 1978-12-14 1980-06-17 Shell Int Research Werkwijze voor de bereiding van ferrieriet.
DE3667778D1 (de) * 1985-12-09 1990-02-01 Shell Int Research Verfahren zur herstellung von ferrierit und dessen verwendung als entwachsungskatalysator (traeger).
AU682461B2 (en) 1992-10-16 1997-10-09 Mobil Oil Corporation Olefin skeletal isomerization process using ZSM-35
US6521783B1 (en) 1998-01-29 2003-02-18 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates
KR100454091B1 (ko) 2002-12-11 2004-10-26 한국화학연구원 미정제 메탄올로부터 디메틸에테르의 제조방법
CN1299989C (zh) * 2004-09-17 2007-02-14 中国科学院大连化学物理研究所 一种zsm－35分子筛的制备方法
CA2602517C (en) 2005-04-04 2013-12-24 Avantium International B.V. System and method for performing a chemical experiment
KR100966706B1 (ko) 2008-06-18 2010-06-29 아주대학교산학협력단 메탄올로부터 디메틸에테르를 제조하는 방법
BRPI0803764A2 (pt) 2008-06-30 2010-03-09 Petroleo Brasileiro Sa sistema catalìtico e processo de sìntese direta do éter dimetìlico a partir do gás de sìntese
EP2956408A1 (en) * 2013-02-15 2015-12-23 BP Chemicals Limited Dehydration-hydrolysis processes and catalysts therefor

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4016245A (en) * 1973-09-04 1977-04-05 Mobil Oil Corporation Crystalline zeolite and method of preparing same
US3992466A (en) * 1975-08-13 1976-11-16 Mobil Oil Corporation Hydrocarbon conversion
US5288475A (en) * 1992-10-21 1994-02-22 Mobil Oil Corp. Synthesis of ZSM-35
JP2009531272A (ja) * 2006-03-24 2009-09-03 ユーオーピー エルエルシー ナノサイズゼオライトを調製する方法
RU2454398C2 (ru) * 2006-04-12 2012-06-27 Бп Кемикэлз Лимитед Способ получения карбоновых кислот и/или их производных
WO2011027105A1 (en) * 2009-09-03 2011-03-10 Bp Chemicals Limited Process for producing acetic acid and dimethyl ether using a zeolite catalyst

Also Published As

Publication number Publication date
US20150375217A1 (en) 2015-12-31
US10328420B2 (en) 2019-06-25
TW201436861A (zh) 2014-10-01
US9873112B2 (en) 2018-01-23
CN105102374A (zh) 2015-11-25
JP2016513060A (ja) 2016-05-12
WO2014125038A1 (en) 2014-08-21
KR20150120434A (ko) 2015-10-27
RU2015139042A (ru) 2017-03-21
US20180036722A1 (en) 2018-02-08
BR112015019462A2 (pt) 2017-07-18
SG11201506356WA (en) 2015-09-29
EP2956408A1 (en) 2015-12-23
CA2900886A1 (en) 2014-08-21
UA116126C2 (uk) 2018-02-12
CN105102374B (zh) 2018-04-24

Similar Documents

Publication Publication Date Title
US10328420B2 (en) Dehydration-hydrolysis processes and catalysts therefor
RU2698458C2 (ru) Способы дегидратации-гидролиза и катализаторы для них
JP7636213B2 (ja) Ｃｏｎ型ゼオライト、ｃｏｎ型ゼオライトの製造方法、及び低級オレフィンの製造方法
RU2696266C2 (ru) Катализатор карбонилирования и способ
KR102171666B1 (ko) 제올라이트계 물질의 제조 및 옥시게네이트의 올레핀으로의 전환 공정을 위한 용도
RU2528339C2 (ru) Способ карбонилирования
RU2656599C2 (ru) Способ карбонилирования диметилового эфира
RU2541477C2 (ru) Способ карбонилирования
US20210346942A1 (en) A molding comprising a zeolitic material having framework type mfi
Jin et al. Synthesis of hierarchical ZSM-5 by cetyltrimethylammonium bromide assisted self-assembly of zeolite seeds and its catalytic performances
JP5668422B2 (ja) アルミノシリケートの製造方法
KR20220138306A (ko) Pst-2 제올라이트 및 그 제조방법
JP7745771B2 (ja) チタンシリコン分子篩、ナノゴールド担持チタンシリコン分子篩触媒、並びに、その製造方法及び使用
US20250091886A1 (en) Zeolite bodies
US20210114006A1 (en) Bi-functional catalyst for the production of olefins from synthesis gas
Nedumaran et al. Effect of tungsten loading on zirconia impregnated MCM-41 and its catalytic activity on transesterification reaction
Yang et al. Influence of synthesis method on the properties and catalytic performance of MCM-49 zeolites

Legal Events

Date Code Title Description
PC41 Official registration of the transfer of exclusive right

Effective date: 20220118