JP2014513182A - 改良された氷上グリップ性を有するタイヤ - Google Patents
改良された氷上グリップ性を有するタイヤ Download PDFInfo
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- JP2014513182A JP2014513182A JP2014506844A JP2014506844A JP2014513182A JP 2014513182 A JP2014513182 A JP 2014513182A JP 2014506844 A JP2014506844 A JP 2014506844A JP 2014506844 A JP2014506844 A JP 2014506844A JP 2014513182 A JP2014513182 A JP 2014513182A
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- DVQHRBFGRZHMSR-UHFFFAOYSA-N sodium methyl 2,2-dimethyl-4,6-dioxo-5-(N-prop-2-enoxy-C-propylcarbonimidoyl)cyclohexane-1-carboxylate Chemical compound [Na+].C=CCON=C(CCC)[C-]1C(=O)CC(C)(C)C(C(=O)OC)C1=O DVQHRBFGRZHMSR-UHFFFAOYSA-N 0.000 description 1
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- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
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- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
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- AUMBZPPBWALQRO-UHFFFAOYSA-L zinc;n,n-dibenzylcarbamodithioate Chemical compound [Zn+2].C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1.C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1 AUMBZPPBWALQRO-UHFFFAOYSA-L 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/32—Properties characterising the ingredient of the composition containing low molecular weight liquid component
- C08L2207/324—Liquid component is low molecular weight polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1153631A FR2974538B1 (fr) | 2011-04-28 | 2011-04-28 | Pneumatique a adherence sur glace amelioree |
| FR1153631 | 2011-04-28 | ||
| PCT/EP2012/057545 WO2012146611A1 (fr) | 2011-04-28 | 2012-04-25 | Pneumatique a adhérence sur glace améliorée |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014513182A true JP2014513182A (ja) | 2014-05-29 |
| JP2014513182A5 JP2014513182A5 (enExample) | 2015-06-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014506844A Pending JP2014513182A (ja) | 2011-04-28 | 2012-04-25 | 改良された氷上グリップ性を有するタイヤ |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP2014513182A (enExample) |
| FR (1) | FR2974538B1 (enExample) |
| WO (1) | WO2012146611A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016194214A1 (en) * | 2015-05-29 | 2016-12-08 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
| WO2016194215A1 (en) * | 2015-05-29 | 2016-12-08 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
| WO2016194213A1 (en) * | 2015-05-29 | 2016-12-08 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3015501B1 (fr) | 2013-12-19 | 2017-05-26 | Michelin & Cie | Pneu dont la bande de roulement comporte des elements de sculpture avec des parois laterales rigides comportant un caoutchouc thermo-expansible a l'etat cru, ou caoutchouc mousse a l'etat cuit. |
| FR3015502B1 (fr) | 2013-12-19 | 2016-02-05 | Michelin & Cie | Pneu dont la bande de roulement comporte des elements de sculpture avec des parois laterales rigides contenant des microparticules hydrosolubles. |
| FR3015503B1 (fr) | 2013-12-19 | 2016-02-05 | Michelin & Cie | Pneu dont la bande de roulement comporte des elements de sculpture avec des parois laterales rigides comportant des microparticules d'oxyde ou carbure metallique. |
| CN107001714A (zh) * | 2014-12-15 | 2017-08-01 | 米其林集团总公司 | 具有包含橡胶组合物的胎面的雪地轮胎 |
| US10179479B2 (en) | 2015-05-19 | 2019-01-15 | Bridgestone Americas Tire Operations, Llc | Plant oil-containing rubber compositions, tread thereof and race tires containing the tread |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07500368A (ja) * | 1991-10-17 | 1995-01-12 | エクソン・ケミカル・パテンツ・インク | 輻射線硬化性イソオレフィンコポリマー |
| JP2006528253A (ja) * | 2003-07-21 | 2006-12-14 | ソシエテ ド テクノロジー ミシュラン | タイヤトレッド |
| JP2006342222A (ja) * | 2005-06-08 | 2006-12-21 | Mitsuyoshi Sato | 光硬化性樹脂組成物 |
| JP2007016205A (ja) * | 2005-06-07 | 2007-01-25 | Uni-Chemical Co Ltd | リン酸基含有不飽和単量体及び不飽和液状オリゴマーを共重合してなる導電性高分子、固体高分子電解質膜及びそれらの用途、リン酸基含有不飽和単量体の製造方法、並びにリン酸基含有不飽和単量体を用いた難燃剤及びその製造方法 |
| JP2008527157A (ja) * | 2005-01-19 | 2008-07-24 | ソシエテ ド テクノロジー ミシュラン | タイヤトレッド |
| JP2009084518A (ja) * | 2007-10-03 | 2009-04-23 | Toray Fine Chemicals Co Ltd | 接着剤組成物 |
| JP2011508029A (ja) * | 2007-12-27 | 2011-03-10 | ソシエテ ド テクノロジー ミシュラン | 冬季タイヤのトレッド用ゴム組成物 |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3878147A (en) | 1973-12-27 | 1975-04-15 | Du Pont | Composition for increasing the friction of surfaces on ice |
| US4874670A (en) * | 1987-11-30 | 1989-10-17 | The Goodyear Tire & Rubber Company | Tire having cured photopolymer air barrier coating |
| JP2894748B2 (ja) | 1989-11-17 | 1999-05-24 | 住友ゴム工業株式会社 | スタッドレスタイヤ |
| KR100758143B1 (ko) | 1997-11-28 | 2007-09-14 | 꽁빠니 제네랄 드 에따블리세망 미쉘린-미쉘린 에 씨 | 입자 응집체 형태의 충전제의 초음파 붕해 속도 측정장치및 측정방법 |
| EP1114093B1 (fr) | 1999-05-28 | 2004-10-13 | Société de Technologie Michelin | Composition de caoutchouc pour pneumatique, a base d'elastomere dienique et d'un oxyde de titane renfor ant |
| JP4252304B2 (ja) | 2000-10-13 | 2009-04-08 | ソシエテ ド テクノロジー ミシュラン | カップリング剤として使用できる多官能性オルガノシラン及びその製造方法 |
| CA2425330A1 (fr) | 2000-10-13 | 2002-04-18 | Jean-Claude Tardivat | Composition de caoutchouc comportant a titre d'agent de couplage un organosilane polyfonctionnel |
| ATE362958T1 (de) | 2001-01-02 | 2007-06-15 | Michelin Soc Tech | Kautschukmischung auf der basis eines dienelastomers und eines verstärkenden siliciumcarbids |
| JP2002211203A (ja) | 2001-01-19 | 2002-07-31 | Sumitomo Rubber Ind Ltd | スタッドレスタイヤ |
| ATE355327T1 (de) | 2001-03-12 | 2006-03-15 | Michelin Soc Tech | Kautschukzusammensetzung für reifenlauffläche |
| FR2823215B1 (fr) | 2001-04-10 | 2005-04-08 | Michelin Soc Tech | Pneumatique et bande de roulement de pneumatique comportant a titre d'agent de couplage un tetrasulfure de bis-alkoxysilane |
| JP4536375B2 (ja) | 2001-06-28 | 2010-09-01 | ソシエテ ド テクノロジー ミシュラン | 極めて低い比表面積のシリカで強化されたタイヤトレッド |
| WO2003002648A1 (fr) | 2001-06-28 | 2003-01-09 | Societe De Technologie Michelin | Bande de roulement pour pneumatique renforcee d'une silice a basse surface specifique |
| WO2003016387A1 (fr) | 2001-08-13 | 2003-02-27 | Societe De Technologie Michelin | Composition de caoutchouc dienique pour pneumatique comprenant une silice specifique comme charge renforcante |
| FR2841560B1 (fr) | 2002-07-01 | 2006-02-03 | Michelin Soc Tech | Composition de caoutchouc a base d'elastomere dienique et d'un nitrure de silicium renforcant |
| JP4633471B2 (ja) | 2002-12-19 | 2011-02-16 | ソシエテ ド テクノロジー ミシュラン | 補強アルミノシリケートに基づくタイヤゴム組成物 |
| FR2866028B1 (fr) | 2004-02-11 | 2006-03-24 | Michelin Soc Tech | Systeme plastifiant pour composition de caoutchouc |
| FR2877348B1 (fr) | 2004-10-28 | 2007-01-12 | Michelin Soc Tech | Systeme plastifiant pour composition de caoutchouc |
| FR2886305B1 (fr) | 2005-05-26 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage organosilicique et un agent de recouvrement de charge inorganique |
| FR2886306B1 (fr) | 2005-05-26 | 2007-07-06 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage organosiloxane |
| FR2886304B1 (fr) | 2005-05-26 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un systeme de couplage organosilicique |
| FR2889538B1 (fr) | 2005-08-08 | 2007-09-14 | Michelin Soc Tech | Systeme plastifiant pour compsition de caoutchouc. |
| FR2910904B1 (fr) | 2006-12-27 | 2009-03-06 | Michelin Soc Tech | Bande de roulement dont la composition comporte une poudre de gomme de xanthane |
| FR2910903B1 (fr) | 2006-12-27 | 2009-03-06 | Michelin Soc Tech | Bande de roulement dont la composition comporte une poudre de gomme de guar |
| JP2008195791A (ja) * | 2007-02-09 | 2008-08-28 | Bridgestone Corp | 変性液状ゴム組成物の製造方法 |
| FR2934273B1 (fr) | 2008-07-24 | 2010-11-05 | Michelin Soc Tech | Composition de caoutchouc pour bande de roulement de pneumatique hiver |
| JP2010254106A (ja) * | 2009-04-24 | 2010-11-11 | Bridgestone Corp | ゴムクローラ |
-
2011
- 2011-04-28 FR FR1153631A patent/FR2974538B1/fr not_active Expired - Fee Related
-
2012
- 2012-04-25 WO PCT/EP2012/057545 patent/WO2012146611A1/fr not_active Ceased
- 2012-04-25 JP JP2014506844A patent/JP2014513182A/ja active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07500368A (ja) * | 1991-10-17 | 1995-01-12 | エクソン・ケミカル・パテンツ・インク | 輻射線硬化性イソオレフィンコポリマー |
| JP2006528253A (ja) * | 2003-07-21 | 2006-12-14 | ソシエテ ド テクノロジー ミシュラン | タイヤトレッド |
| JP2008527157A (ja) * | 2005-01-19 | 2008-07-24 | ソシエテ ド テクノロジー ミシュラン | タイヤトレッド |
| JP2007016205A (ja) * | 2005-06-07 | 2007-01-25 | Uni-Chemical Co Ltd | リン酸基含有不飽和単量体及び不飽和液状オリゴマーを共重合してなる導電性高分子、固体高分子電解質膜及びそれらの用途、リン酸基含有不飽和単量体の製造方法、並びにリン酸基含有不飽和単量体を用いた難燃剤及びその製造方法 |
| JP2006342222A (ja) * | 2005-06-08 | 2006-12-21 | Mitsuyoshi Sato | 光硬化性樹脂組成物 |
| JP2009084518A (ja) * | 2007-10-03 | 2009-04-23 | Toray Fine Chemicals Co Ltd | 接着剤組成物 |
| JP2011508029A (ja) * | 2007-12-27 | 2011-03-10 | ソシエテ ド テクノロジー ミシュラン | 冬季タイヤのトレッド用ゴム組成物 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016194214A1 (en) * | 2015-05-29 | 2016-12-08 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
| WO2016194215A1 (en) * | 2015-05-29 | 2016-12-08 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
| WO2016194213A1 (en) * | 2015-05-29 | 2016-12-08 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2974538A1 (fr) | 2012-11-02 |
| WO2012146611A1 (fr) | 2012-11-01 |
| FR2974538B1 (fr) | 2013-06-14 |
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