JP2014508638A5 - - Google Patents
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- Publication number
- JP2014508638A5 JP2014508638A5 JP2013551958A JP2013551958A JP2014508638A5 JP 2014508638 A5 JP2014508638 A5 JP 2014508638A5 JP 2013551958 A JP2013551958 A JP 2013551958A JP 2013551958 A JP2013551958 A JP 2013551958A JP 2014508638 A5 JP2014508638 A5 JP 2014508638A5
- Authority
- JP
- Japan
- Prior art keywords
- mercury
- flue gas
- lime
- sorbent material
- mercury sorbent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims 31
- 229910052753 mercury Inorganic materials 0.000 claims 31
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 21
- 239000003546 flue gas Substances 0.000 claims 21
- 239000000203 mixture Substances 0.000 claims 19
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims 15
- 235000011941 Tilia x europaea Nutrition 0.000 claims 15
- 239000004571 lime Substances 0.000 claims 15
- 239000002594 sorbent Substances 0.000 claims 15
- 238000002347 injection Methods 0.000 claims 9
- 239000007924 injection Substances 0.000 claims 9
- 238000000034 method Methods 0.000 claims 9
- 238000005201 scrubbing Methods 0.000 claims 8
- 239000006227 byproduct Substances 0.000 claims 7
- 239000000463 material Substances 0.000 claims 7
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims 6
- 239000004927 clay Substances 0.000 claims 5
- 150000001768 cations Chemical class 0.000 claims 4
- 150000001879 copper Chemical class 0.000 claims 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 3
- 235000011132 calcium sulphate Nutrition 0.000 claims 3
- 239000010881 fly ash Substances 0.000 claims 3
- 238000010008 shearing Methods 0.000 claims 3
- 229910052717 sulfur Inorganic materials 0.000 claims 3
- 239000011593 sulfur Substances 0.000 claims 3
- 238000010521 absorption reaction Methods 0.000 claims 2
- 150000002500 ions Chemical class 0.000 claims 2
- 229910021647 smectite Inorganic materials 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- 239000011398 Portland cement Substances 0.000 claims 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
- 239000001110 calcium chloride Substances 0.000 claims 1
- 229910001628 calcium chloride Inorganic materials 0.000 claims 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims 1
- 239000000920 calcium hydroxide Substances 0.000 claims 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims 1
- 239000000292 calcium oxide Substances 0.000 claims 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims 1
- 239000001175 calcium sulphate Substances 0.000 claims 1
- 238000005266 casting Methods 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 229910001431 copper ion Inorganic materials 0.000 claims 1
- 229940097275 indigo Drugs 0.000 claims 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 claims 1
- 238000000634 powder X-ray diffraction Methods 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/017,539 US8420561B2 (en) | 2009-06-16 | 2011-01-31 | Flue gas scrubbing |
| US13/017,539 | 2011-01-31 | ||
| PCT/US2011/046726 WO2012106007A1 (en) | 2011-01-31 | 2011-08-05 | Flue gas scrubbing |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014508638A JP2014508638A (ja) | 2014-04-10 |
| JP2014508638A5 true JP2014508638A5 (https=) | 2014-09-18 |
| JP5923526B2 JP5923526B2 (ja) | 2016-05-24 |
Family
ID=44504266
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013551958A Expired - Fee Related JP5923526B2 (ja) | 2011-01-31 | 2011-08-05 | 煙道ガスのスクラビング |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8420561B2 (https=) |
| EP (2) | EP2670510B1 (https=) |
| JP (1) | JP5923526B2 (https=) |
| KR (1) | KR101986270B1 (https=) |
| CN (1) | CN103313770B (https=) |
| AU (1) | AU2011357684B2 (https=) |
| BR (1) | BR112013013784A2 (https=) |
| CA (2) | CA3000330A1 (https=) |
| MX (2) | MX340227B (https=) |
| PL (2) | PL2870990T3 (https=) |
| WO (1) | WO2012106007A1 (https=) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8268744B2 (en) * | 2009-06-16 | 2012-09-18 | Amcol International Corporation | High shear method for manufacturing a synthetic smectite mineral |
| US8420561B2 (en) | 2009-06-16 | 2013-04-16 | Amcol International Corporation | Flue gas scrubbing |
| GB2547364B8 (en) | 2010-10-05 | 2017-11-29 | The Queen's Univ Of Belfast | Process for removing metals from hydrocarbons |
| US9227172B2 (en) * | 2011-10-07 | 2016-01-05 | Ecolab Usa Inc. | Silica containing basic sorbent for acid gas removal |
| US8609046B2 (en) * | 2011-10-07 | 2013-12-17 | Nalco Company | Gas stream treatment process |
| US10166507B2 (en) * | 2012-03-30 | 2019-01-01 | Fuel Tech, Inc. | Process for hydrochloric acid mediation |
| EP2833989A4 (en) * | 2012-03-30 | 2015-12-09 | Fuel Tech Inc | DRY PROCESSES, APPARATUS, COMPOSITIONS AND SYSTEMS FOR REDUCTION OF SULFUR AND HCL OXIDES |
| US9802154B2 (en) * | 2012-03-30 | 2017-10-31 | Fuel Tech, Inc. | Process for sulfur dioxide, hydrochloric acid and mercury mediation |
| US8992868B2 (en) * | 2012-05-01 | 2015-03-31 | Fuel Tech, Inc. | Dry processes, apparatus compositions and systems for reducing mercury, sulfur oxides and HCl |
| DE112013003605T5 (de) * | 2012-07-20 | 2015-04-02 | Novinda Corp. | Optimierte Einsammlung von Flugasche |
| DE102012214065A1 (de) * | 2012-08-08 | 2014-02-13 | EnBW Energie Baden-Württemberg AG | Verfahren zum Entfernen von Quecksilber aus Rauchgas in einem Nasswäscher |
| WO2014031623A1 (en) * | 2012-08-20 | 2014-02-27 | Ecolab Usa Inc. | Mercury sorbents |
| US9289721B2 (en) * | 2013-02-27 | 2016-03-22 | Fuel Tech, Inc. | Process and apparatus for improving the operation of wet scrubbers |
| US9393518B2 (en) * | 2013-02-27 | 2016-07-19 | Fuel Tech, Inc. | Processes, apparatus, compositions and systems for reducing emissions of HCI and/or sulfur oxides |
| US10471385B2 (en) * | 2013-03-13 | 2019-11-12 | Novinda Corporation | Multicomponent compositions for mercury removal |
| US20160030915A1 (en) * | 2013-03-13 | 2016-02-04 | Novinda Corporation | Supported Sulfides for Mercury Capture |
| US9399597B2 (en) * | 2013-04-01 | 2016-07-26 | Fuel Tech, Inc. | Ash compositions recovered from coal combustion gases having reduced emissions of HCI and/or mercury |
| US9446351B2 (en) | 2013-11-25 | 2016-09-20 | Milliken & Company | Filtration medium and process for filtering a fluid stream |
| GB201322462D0 (en) | 2013-12-18 | 2014-02-05 | Johnson Matthey Plc | Method for preparing a sorbent |
| GB201322464D0 (en) * | 2013-12-18 | 2014-02-05 | Johnson Matthey Plc | Method for preparing a sorbent |
| WO2016184518A1 (en) * | 2015-05-20 | 2016-11-24 | S.A. Lhoist Recherche Et Developpement | Lime-based sorbent composition for mercury removal and its manufacturing process |
| CR20180165A (es) | 2015-08-21 | 2018-06-14 | Ecolab Usa Inc | Complejación y eliminación del mercurio de sistema de desulfuración de gas de combustión |
| KR20180077183A (ko) * | 2015-10-30 | 2018-07-06 | 암콜 인터내셔널 코포레이션 | 수은 흡착제를 제조하는 개선된 방법 |
| CN106822972A (zh) * | 2015-12-07 | 2017-06-13 | 山东联星能源集团有限公司 | 一种空气净化剂的制备方法 |
| CN111097373B (zh) * | 2018-10-25 | 2022-05-06 | 中国科学院生态环境研究中心 | 多孔吸附材料和载氧+吸附复合功能材料及它们的应用 |
| CN111097374B (zh) * | 2018-10-25 | 2022-05-06 | 中国科学院生态环境研究中心 | 载氧+吸附复合功能材料的制备方法及其在水体修复中的应用 |
| CN113731113B (zh) * | 2021-09-15 | 2022-05-17 | 北京工大环能科技有限公司 | 一种用于降低燃煤电站空气预热器硫酸氢铵堵塞的系统 |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3807702A (en) | 1971-06-21 | 1974-04-30 | Huber Corp J M | An improved apparatus for encapsulating a finely divided clay within an organic polymeric material |
| DE2656803C2 (de) | 1975-12-18 | 1986-12-18 | Institut Français du Pétrole, Rueil-Malmaison, Hauts-de-Seine | Verfahren zur Entfernung von in einem Gas oder in einer Flüssigkeit vorhandenem Quecksilber |
| US4361493A (en) | 1980-06-30 | 1982-11-30 | Eastman Kodak Company | Hydrophilic substrate for sorbing heavy metals |
| NZ209977A (en) | 1983-11-03 | 1988-04-29 | Calgon Carbon Corp | Mercury vapour removal by absorbent carbon and carbon molecular sieves |
| JPS61293531A (ja) * | 1985-06-21 | 1986-12-24 | Mitsubishi Heavy Ind Ltd | 廃棄物焼却排ガスの処理方法 |
| JPH0661424B2 (ja) * | 1986-03-19 | 1994-08-17 | 三菱重工業株式会社 | 燃焼排ガス中の水銀及び酸性ガス除去方法 |
| US5248641A (en) | 1990-09-17 | 1993-09-28 | Southern Clay Products, Inc. | Process for producing bentonite clays exhibiting enhanced solution viscosity properties |
| GB9022060D0 (en) | 1990-10-10 | 1990-11-21 | Ici Plc | Mercury removal |
| FR2668465B1 (fr) | 1990-10-30 | 1993-04-16 | Inst Francais Du Petrole | Procede d'elimination de mercure ou d'arsenic dans un fluide en presence d'une masse de captation de mercure et/ou d'arsenic. |
| JPH04330917A (ja) * | 1991-05-01 | 1992-11-18 | Kubota Corp | 排ガス集塵方法 |
| JP3285692B2 (ja) * | 1994-01-26 | 2002-05-27 | 日立造船株式会社 | 焼却炉における飛灰処理装置 |
| JPH09308817A (ja) * | 1996-05-22 | 1997-12-02 | Babcock Hitachi Kk | 排ガス処理方法および装置 |
| WO2001000317A1 (en) | 1999-06-30 | 2001-01-04 | Phillips Petroleum Company | Sulfur sorbent composition and sorption process |
| US7048781B1 (en) | 2002-10-07 | 2006-05-23 | Ada Technologies, Inc. | Chemically-impregnated silicate agents for mercury control |
| US6719828B1 (en) | 2001-04-30 | 2004-04-13 | John S. Lovell | High capacity regenerable sorbent for removal of mercury from flue gas |
| US7288499B1 (en) | 2001-04-30 | 2007-10-30 | Ada Technologies, Inc | Regenerable high capacity sorbent for removal of mercury from flue gas |
| US7081434B2 (en) | 2001-11-27 | 2006-07-25 | Sinha Rabindra K | Chemical formulations for the removal of mercury and other pollutants present in fluid streams |
| US7060233B1 (en) * | 2002-03-25 | 2006-06-13 | Tda Research, Inc. | Process for the simultaneous removal of sulfur and mercury |
| AU2005262871B2 (en) | 2004-06-28 | 2011-06-09 | Douglas C. Comrie | Reducing sulfur gas emissions resulting from the burning of carbonaceous fuels |
| JP2006015290A (ja) * | 2004-07-05 | 2006-01-19 | Pollars Laboratory Corp | 混合、混練装置を用いない飛灰中の重金属固定化処理方法 |
| JP2008514409A (ja) * | 2004-10-01 | 2008-05-08 | ディグドン、ウィリアム | 燃焼プロセスにおいて水銀を酸化させる組成物及び方法 |
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| US7704920B2 (en) | 2005-11-30 | 2010-04-27 | Basf Catalysts Llc | Pollutant emission control sorbents and methods of manufacture |
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| US7572421B2 (en) | 2006-06-19 | 2009-08-11 | Basf Catalysts Llc | Mercury sorbents and methods of manufacture and use |
| US7753992B2 (en) | 2006-06-19 | 2010-07-13 | Basf Corporation | Methods of manufacturing mercury sorbents and removing mercury from a gas stream |
| KR20080029351A (ko) * | 2006-09-29 | 2008-04-03 | (주)엘케이전자 | 엘이디 백라이트 장치 및 그 제조방법 |
| ES2683326T3 (es) * | 2006-11-22 | 2018-09-26 | Albemarle Corporation | Composición basada en carbono activado para secuestrar el mercurio del gas de combustión en el concreto |
| EP2173478A4 (en) * | 2007-08-02 | 2011-08-24 | Benthamite Company Llc | COMPOSITION, PRODUCTION AND USE OF SORBENT PARTICLES FOR THE DESULFURIZATION OF EXHAUST GASES |
| JP2009213999A (ja) * | 2008-03-10 | 2009-09-24 | Taiheiyo Cement Corp | 水銀含有廃棄物の処理装置及び処理方法 |
| JP2009291734A (ja) * | 2008-06-06 | 2009-12-17 | Hitachi Plant Technologies Ltd | 排ガス処理装置およびその方法 |
| JP2012509758A (ja) * | 2008-11-25 | 2012-04-26 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニー | 重金属除去用還元型硫化銅収着剤 |
| US8268744B2 (en) | 2009-06-16 | 2012-09-18 | Amcol International Corporation | High shear method for manufacturing a synthetic smectite mineral |
| US8420561B2 (en) | 2009-06-16 | 2013-04-16 | Amcol International Corporation | Flue gas scrubbing |
| CN101628201A (zh) * | 2009-08-19 | 2010-01-20 | 福建龙净脱硫脱硝工程有限公司 | 玻璃窑炉烟气污染物脱除装置及其脱除方法 |
-
2011
- 2011-01-31 US US13/017,539 patent/US8420561B2/en not_active Expired - Fee Related
- 2011-08-05 BR BR112013013784A patent/BR112013013784A2/pt not_active Application Discontinuation
- 2011-08-05 CN CN201180065066.3A patent/CN103313770B/zh not_active Expired - Fee Related
- 2011-08-05 EP EP11746725.8A patent/EP2670510B1/en not_active Not-in-force
- 2011-08-05 PL PL14189118T patent/PL2870990T3/pl unknown
- 2011-08-05 JP JP2013551958A patent/JP5923526B2/ja not_active Expired - Fee Related
- 2011-08-05 AU AU2011357684A patent/AU2011357684B2/en not_active Ceased
- 2011-08-05 MX MX2015001747A patent/MX340227B/es unknown
- 2011-08-05 PL PL11746725T patent/PL2670510T3/pl unknown
- 2011-08-05 EP EP14189118.4A patent/EP2870990B1/en not_active Not-in-force
- 2011-08-05 WO PCT/US2011/046726 patent/WO2012106007A1/en not_active Ceased
- 2011-08-05 MX MX2013008784A patent/MX2013008784A/es active IP Right Grant
- 2011-08-05 CA CA3000330A patent/CA3000330A1/en not_active Abandoned
- 2011-08-05 KR KR1020137015218A patent/KR101986270B1/ko not_active Expired - Fee Related
- 2011-08-05 CA CA2820097A patent/CA2820097C/en not_active Expired - Fee Related
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