JP2012530044A5 - - Google Patents
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- Publication number
- JP2012530044A5 JP2012530044A5 JP2012516143A JP2012516143A JP2012530044A5 JP 2012530044 A5 JP2012530044 A5 JP 2012530044A5 JP 2012516143 A JP2012516143 A JP 2012516143A JP 2012516143 A JP2012516143 A JP 2012516143A JP 2012530044 A5 JP2012530044 A5 JP 2012530044A5
- Authority
- JP
- Japan
- Prior art keywords
- graphene nanoribbon
- functionalized graphene
- alkali metal
- exposure
- electrophile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims description 66
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 53
- 229910021389 graphene Inorganic materials 0.000 claims description 46
- 239000002074 nanoribbon Substances 0.000 claims description 46
- 229910052783 alkali metal Inorganic materials 0.000 claims description 23
- 150000001340 alkali metals Chemical class 0.000 claims description 23
- 239000012039 electrophile Substances 0.000 claims description 21
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 8
- -1 carboxylic acid chlorides Chemical class 0.000 claims description 8
- 239000002041 carbon nanotube Substances 0.000 claims description 7
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 7
- 150000001735 carboxylic acids Chemical class 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 239000002048 multi walled nanotube Substances 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 150000001299 aldehydes Chemical class 0.000 claims description 4
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 claims description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 4
- 239000001569 carbon dioxide Substances 0.000 claims description 4
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 claims description 4
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 4
- 150000004820 halides Chemical class 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 4
- 150000002825 nitriles Chemical class 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 238000007142 ring opening reaction Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910052792 caesium Inorganic materials 0.000 claims description 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 125000000524 functional group Chemical group 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 2
- 150000002910 rare earth metals Chemical class 0.000 claims description 2
- 229910052701 rubidium Inorganic materials 0.000 claims description 2
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
- 239000003930 superacid Substances 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 239000011135 tin Substances 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 2
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US18713009P | 2009-06-15 | 2009-06-15 | |
| US61/187,130 | 2009-06-15 | ||
| PCT/US2010/038368 WO2010147860A1 (en) | 2009-06-15 | 2010-06-11 | Graphene nanoribbons prepared from carbon nanotubes via alkali metal exposure |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012530044A JP2012530044A (ja) | 2012-11-29 |
| JP2012530044A5 true JP2012530044A5 (enExample) | 2014-07-17 |
| JP5613230B2 JP5613230B2 (ja) | 2014-10-22 |
Family
ID=43356694
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012516143A Expired - Fee Related JP5613230B2 (ja) | 2009-06-15 | 2010-06-11 | アルカリ金属曝露によってカーボンナノチューブから製造されるグラフェンナノリボン |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8992881B2 (enExample) |
| EP (1) | EP2443062A4 (enExample) |
| JP (1) | JP5613230B2 (enExample) |
| KR (1) | KR101763224B1 (enExample) |
| CN (1) | CN102666378B (enExample) |
| BR (1) | BRPI1016033A2 (enExample) |
| CA (1) | CA2765492C (enExample) |
| MX (1) | MX2011013545A (enExample) |
| SG (2) | SG10201403233XA (enExample) |
| WO (1) | WO2010147860A1 (enExample) |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9193879B2 (en) | 2010-02-17 | 2015-11-24 | Baker Hughes Incorporated | Nano-coatings for articles |
| CA2813944A1 (en) | 2010-10-06 | 2012-04-12 | M-I L.L.C. | Graphene-based material for shale stabilization and method of use |
| KR101300765B1 (ko) | 2011-04-29 | 2013-08-29 | 한국교통대학교산학협력단 | 가용성 그라핀 용액의 제조방법 |
| US9040013B2 (en) * | 2011-08-04 | 2015-05-26 | Baker Hughes Incorporated | Method of preparing functionalized graphene |
| US9428383B2 (en) | 2011-08-19 | 2016-08-30 | Baker Hughes Incorporated | Amphiphilic nanoparticle, composition comprising same and method of controlling oil spill using amphiphilic nanoparticle |
| WO2013040356A1 (en) * | 2011-09-14 | 2013-03-21 | William Marsh Rice University | Solvent-based methods for production of graphene nanoribbons |
| KR102514830B1 (ko) | 2011-09-30 | 2023-03-30 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 양극, 리튬 이차 전지, 전기 자동차, 하이브리드 자동차, 이동체, 시스템, 및 전기 기기 |
| CN104303320A (zh) | 2011-10-21 | 2015-01-21 | 犹他大学研究基金会 | 均质多带隙装置 |
| US9550678B2 (en) | 2011-12-20 | 2017-01-24 | Basf Se | Polymeric precursors for producing graphene nanoribbons and methods for preparing them |
| US9441462B2 (en) | 2012-01-11 | 2016-09-13 | Baker Hughes Incorporated | Nanocomposites for absorption tunable sandscreens |
| CN104204131A (zh) * | 2012-01-27 | 2014-12-10 | 威廉马什莱斯大学 | 并入了磁性碳纳米带和磁性功能化碳纳米带的井筒流体和其使用方法 |
| CN102616770B (zh) * | 2012-03-28 | 2013-08-07 | 福州大学 | 一种水蒸气刻蚀碳纳米管制备石墨烯纳米带的方法 |
| EP2832688A4 (en) * | 2012-03-31 | 2015-11-25 | Oceans King Lighting Science | PROCESS FOR PREPARING GRAPHENE PAPER |
| JP6077347B2 (ja) | 2012-04-10 | 2017-02-08 | 株式会社半導体エネルギー研究所 | 非水系二次電池用正極の製造方法 |
| US9527043B2 (en) | 2012-05-17 | 2016-12-27 | Samsung Electronics Co., Ltd. | Gas separation membrane and method of preparing the same |
| KR101920716B1 (ko) * | 2012-05-17 | 2019-02-13 | 삼성전자주식회사 | 기체 분리막 및 그 제조방법 |
| US20140004327A1 (en) * | 2012-06-29 | 2014-01-02 | The University Of Kentucky Research Foundation | Few-layer graphene nanoribbon and a method of making the same |
| CN102757043B (zh) * | 2012-08-10 | 2014-07-02 | 中国科学院苏州纳米技术与纳米仿生研究所 | 一种制备定向石墨烯纳米带阵列的方法 |
| JP6207923B2 (ja) | 2012-08-27 | 2017-10-04 | 株式会社半導体エネルギー研究所 | 二次電池用正極の製造方法 |
| TW201431902A (zh) * | 2012-11-16 | 2014-08-16 | 巴斯夫歐洲公司 | 用以生產石墨烯奈米帶之聚合前驅物，以及適用於製備彼等之寡伸苯基單體 |
| CN103833023B (zh) * | 2012-11-27 | 2015-10-28 | 海洋王照明科技股份有限公司 | 石墨烯纳米带及其制备方法 |
| US8580658B1 (en) | 2012-12-21 | 2013-11-12 | Solan, LLC | Methods for fabricating graphene device topography and devices formed therefrom |
| US10468152B2 (en) * | 2013-02-21 | 2019-11-05 | Global Graphene Group, Inc. | Highly conducting and transparent film and process for producing same |
| US20140272308A1 (en) * | 2013-03-15 | 2014-09-18 | Solan, LLC | Graphite-Based Devices Incorporating A Graphene Layer With A Bending Angle |
| US9059013B2 (en) | 2013-03-21 | 2015-06-16 | International Business Machines Corporation | Self-formation of high-density arrays of nanostructures |
| TWI529128B (zh) * | 2013-08-19 | 2016-04-11 | 長庚大學 | 連續微波製作石墨烯奈米帶之系統 |
| JP6825781B2 (ja) * | 2014-06-12 | 2021-02-03 | センター ナショナル デ ラ レシェルシェ サイエンティフィック（シーエヌアールエス）Ｃｅｎｔｒｅ Ｎａｔｉｏｎａｌ Ｄｅ Ｌａ Ｒｅｃｈｅｒｃｈｅ Ｓｃｉｅｎｔｉｆｉｑｕｅ（Ｃｎｒｓ） | 剥離ナノカーボン材料の水性および有機懸濁液、その作製方法及びその使用 |
| US9840418B2 (en) | 2014-06-16 | 2017-12-12 | William Marsh Rice University | Production of graphene nanoplatelets by oxidative anhydrous acidic media |
| CA2968886A1 (en) * | 2014-11-26 | 2016-08-24 | William Marsh Rice University | Laser induced graphene hybrid materials for electronic devices |
| US11772975B2 (en) * | 2015-12-03 | 2023-10-03 | Global Graphene Group, Inc. | Chemical-free production of graphene materials |
| CN105543991B (zh) * | 2016-01-13 | 2018-06-01 | 郑州大学 | 一种螺旋结构石墨烯纤维及其制备方法和应用 |
| CN106115675B (zh) * | 2016-06-24 | 2018-04-17 | 中国科学院电工研究所 | 一种制备介孔石墨烯的方法 |
| US11246962B2 (en) | 2016-08-22 | 2022-02-15 | William Marsh Rice University | Neuronal scaffold-water soluble graphene for treatment of severed spinal cords and neuronal repair |
| US10707524B2 (en) | 2016-10-19 | 2020-07-07 | Semiconductor Energy Laboratory Co., Ltd. | Graphene compound and manufacturing method thereof, electrolyte, and power storage device |
| JP6839355B2 (ja) * | 2017-02-08 | 2021-03-10 | 富士通株式会社 | グラフェンナノリボン、グラフェンナノリボンの製造方法及び半導体装置 |
| CN107200947B (zh) * | 2017-05-22 | 2019-08-20 | 成都新柯力化工科技有限公司 | 一种石墨烯微片导电母料及其制备方法 |
| KR102170675B1 (ko) * | 2017-06-23 | 2020-10-27 | 주식회사 엘지화학 | 탄소 나노튜브 섬유 집합체의 인장강도 향상 방법 |
| US10465291B2 (en) * | 2017-09-26 | 2019-11-05 | California Institute Of Technology | Method and system for growth of graphene nanostripes by plasma enhanced chemical vapor deposition |
| CN108190959B (zh) * | 2018-01-23 | 2020-05-08 | 福州大学 | 一种基于熔融碱金属液插入剥离制备单层硫化钼的方法 |
| CN108117064B (zh) * | 2018-03-01 | 2021-07-09 | 上海理工大学 | 一种褶皱石墨烯的制备方法 |
| CN108383110B (zh) * | 2018-04-18 | 2020-01-10 | 天津大学 | 一种氟化石墨烯纳米带的制备方法 |
| CN109835884B (zh) * | 2019-03-27 | 2022-07-19 | 王奉瑾 | 一种利用液态金属碱制备石墨烯的方法 |
| CN111039284A (zh) * | 2020-01-17 | 2020-04-21 | 中山大学 | 一种超窄石墨烯纳米带的制备方法 |
| CN115650213A (zh) * | 2022-06-28 | 2023-01-31 | 重庆大学 | 一种高单晶纯单层石墨烯纳米带阵列及其制备方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008515654A (ja) | 2004-10-12 | 2008-05-15 | ナノシス・インク． | 導電性ポリマー及び半導体ナノワイヤに基づいてプラスチック電子部品を製造するための完全に集積化された有機層プロセス |
| US8481421B2 (en) * | 2007-07-25 | 2013-07-09 | California Institute Of Technology | Functional anchors connecting graphene-like carbon to metal |
| TW201012749A (en) * | 2008-08-19 | 2010-04-01 | Univ Rice William M | Methods for preparation of graphene nanoribbons from carbon nanotubes and compositions, thin films and devices derived therefrom |
-
2010
- 2010-06-11 BR BRPI1016033A patent/BRPI1016033A2/pt not_active IP Right Cessation
- 2010-06-11 WO PCT/US2010/038368 patent/WO2010147860A1/en not_active Ceased
- 2010-06-11 KR KR1020127001075A patent/KR101763224B1/ko not_active Expired - Fee Related
- 2010-06-11 US US13/378,528 patent/US8992881B2/en active Active
- 2010-06-11 CA CA2765492A patent/CA2765492C/en not_active Expired - Fee Related
- 2010-06-11 EP EP10789979.1A patent/EP2443062A4/en not_active Withdrawn
- 2010-06-11 CN CN201080034953.XA patent/CN102666378B/zh not_active Expired - Fee Related
- 2010-06-11 SG SG10201403233XA patent/SG10201403233XA/en unknown
- 2010-06-11 JP JP2012516143A patent/JP5613230B2/ja not_active Expired - Fee Related
- 2010-06-11 MX MX2011013545A patent/MX2011013545A/es active IP Right Grant
- 2010-06-11 SG SG2011092186A patent/SG176826A1/en unknown
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