JP2012514126A5 - - Google Patents
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- Publication number
- JP2012514126A5 JP2012514126A5 JP2011544623A JP2011544623A JP2012514126A5 JP 2012514126 A5 JP2012514126 A5 JP 2012514126A5 JP 2011544623 A JP2011544623 A JP 2011544623A JP 2011544623 A JP2011544623 A JP 2011544623A JP 2012514126 A5 JP2012514126 A5 JP 2012514126A5
- Authority
- JP
- Japan
- Prior art keywords
- procatalyst
- hydrogen
- temperature
- substituted phenylene
- aromatic diester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000034 method Methods 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 239000002243 precursor Substances 0.000 claims description 10
- -1 phenylene aromatic diester Chemical class 0.000 claims description 9
- 230000002140 halogenating effect Effects 0.000 claims description 8
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims description 4
- GXNXZJMAFGKLQI-UHFFFAOYSA-N (2-benzoyloxy-5-tert-butyl-3-methylphenyl) benzoate Chemical compound C=1C=CC=CC=1C(=O)OC=1C(C)=CC(C(C)(C)C)=CC=1OC(=O)C1=CC=CC=C1 GXNXZJMAFGKLQI-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 239000007857 degradation product Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- 150000002431 hydrogen Chemical class 0.000 claims 4
- 125000003545 alkoxy group Chemical group 0.000 claims 3
- 125000004429 atom Chemical group 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 229910052736 halogen Inorganic materials 0.000 claims 3
- 150000002367 halogens Chemical class 0.000 claims 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- GBMGZWZFFDWLGC-UHFFFAOYSA-N (2-benzoyloxy-4-tert-butylphenyl) benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC(C(C)(C)C)=CC=C1OC(=O)C1=CC=CC=C1 GBMGZWZFFDWLGC-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14195908P | 2008-12-31 | 2008-12-31 | |
| US14190208P | 2008-12-31 | 2008-12-31 | |
| US61/141,959 | 2008-12-31 | ||
| US61/141,902 | 2008-12-31 | ||
| PCT/US2009/069929 WO2010078503A1 (en) | 2008-12-31 | 2009-12-31 | Enhanced procatalyst composition and process |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016093313A Division JP6097435B2 (ja) | 2008-12-31 | 2016-05-06 | 強化されたプロ触媒組成物 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012514126A JP2012514126A (ja) | 2012-06-21 |
| JP2012514126A5 true JP2012514126A5 (https=) | 2013-02-21 |
| JP5969210B2 JP5969210B2 (ja) | 2016-08-17 |
Family
ID=44952766
Family Applications (7)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011544621A Expired - Fee Related JP5731988B2 (ja) | 2008-12-31 | 2009-12-31 | プロピレン系ポリマー、物品およびその製造プロセス |
| JP2011544619A Active JP5607647B2 (ja) | 2008-12-31 | 2009-12-31 | プロピレン耐衝撃性コポリマーおよび方法 |
| JP2011544618A Expired - Fee Related JP5770103B2 (ja) | 2008-12-31 | 2009-12-31 | ランダムプロピレンコポリマー組成物、製品及び方法 |
| JP2011544623A Expired - Fee Related JP5969210B2 (ja) | 2008-12-31 | 2009-12-31 | 強化されたプロ触媒組成物及びプロセス |
| JP2011544626A Expired - Fee Related JP5461583B2 (ja) | 2008-12-31 | 2009-12-31 | 置換フェニレン芳香族ジエステルの製造 |
| JP2014174169A Active JP6066968B2 (ja) | 2008-12-31 | 2014-08-28 | プロピレン耐衝撃性コポリマーおよび方法 |
| JP2016093313A Expired - Fee Related JP6097435B2 (ja) | 2008-12-31 | 2016-05-06 | 強化されたプロ触媒組成物 |
Family Applications Before (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011544621A Expired - Fee Related JP5731988B2 (ja) | 2008-12-31 | 2009-12-31 | プロピレン系ポリマー、物品およびその製造プロセス |
| JP2011544619A Active JP5607647B2 (ja) | 2008-12-31 | 2009-12-31 | プロピレン耐衝撃性コポリマーおよび方法 |
| JP2011544618A Expired - Fee Related JP5770103B2 (ja) | 2008-12-31 | 2009-12-31 | ランダムプロピレンコポリマー組成物、製品及び方法 |
Family Applications After (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011544626A Expired - Fee Related JP5461583B2 (ja) | 2008-12-31 | 2009-12-31 | 置換フェニレン芳香族ジエステルの製造 |
| JP2014174169A Active JP6066968B2 (ja) | 2008-12-31 | 2014-08-28 | プロピレン耐衝撃性コポリマーおよび方法 |
| JP2016093313A Expired - Fee Related JP6097435B2 (ja) | 2008-12-31 | 2016-05-06 | 強化されたプロ触媒組成物 |
Country Status (11)
| Country | Link |
|---|---|
| US (7) | US8778826B2 (https=) |
| EP (5) | EP2373699A1 (https=) |
| JP (7) | JP5731988B2 (https=) |
| KR (5) | KR20110117124A (https=) |
| CN (6) | CN102482376B (https=) |
| BR (5) | BRPI0918706B1 (https=) |
| MX (6) | MX342632B (https=) |
| MY (5) | MY159677A (https=) |
| RU (5) | RU2553475C2 (https=) |
| SG (5) | SG172448A1 (https=) |
| WO (5) | WO2010078480A1 (https=) |
Families Citing this family (104)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7893003B2 (en) * | 2007-08-24 | 2011-02-22 | Dow Global Technologies Inc. | Catalyst composition with mixed selectivity control agent and method |
| CN101848946B (zh) | 2007-08-24 | 2013-06-12 | 陶氏环球技术有限责任公司 | 气相聚合方法 |
| EP2315790B1 (en) * | 2008-08-21 | 2018-04-25 | W.R. Grace & CO. - CONN. | High melt flow propylene impact copolymer and method |
| JP5731988B2 (ja) * | 2008-12-31 | 2015-06-10 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | プロピレン系ポリマー、物品およびその製造プロセス |
| JP6046349B2 (ja) * | 2008-12-31 | 2016-12-14 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 置換フェニレン芳香族ジエステルの製造 |
| US8378045B2 (en) * | 2008-12-31 | 2013-02-19 | Dow Global Technologies Llc | Thermoformed article with high stiffness and good optics |
| PL2373702T3 (pl) | 2008-12-31 | 2018-07-31 | W.R. Grace & Co.-Conn. | Kompozycja prekatalizatora z wewnętrznym donorem w postaci podstawionego aromatycznego diestru 1,2-fenylenowego oraz sposób |
| US8263520B2 (en) * | 2009-12-02 | 2012-09-11 | Dow Global Technologies Llc | Two atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture |
| MY159696A (en) * | 2010-02-26 | 2017-01-13 | W R Grace & Co -Conn | Halogenated amide ester and internal electron donor with same |
| WO2011106494A1 (en) | 2010-02-26 | 2011-09-01 | Dow Global Technologies Llc | Procatalyst composition with substituted amide ester internal electron donor |
| CN101845171A (zh) * | 2010-04-20 | 2010-09-29 | 广州呈和科技有限公司 | 聚丙烯增刚成核剂组合物 |
| US20140107274A1 (en) * | 2010-12-20 | 2014-04-17 | Braskem America, Inc. | Propylene-based compositions of enhanced appearance and excellent mold flowability |
| US9434796B2 (en) | 2010-12-21 | 2016-09-06 | W. R. Grace & Co.-Conn. | Catalyst composition with alkoxyalkyl ester internal electron donor and polymer from same |
| US20120157295A1 (en) * | 2010-12-21 | 2012-06-21 | Linfeng Chen | Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product |
| MX2013007356A (es) * | 2010-12-21 | 2014-01-23 | Dow Global Technologies Llc | Proceso para producir polimeros basados en propileno con alto indice de fluidez y productos preparados a partir de los mismos. |
| US8604146B2 (en) * | 2010-12-21 | 2013-12-10 | Dow Global Technologies Llc | Catalyst composition with alkoxyalkyl ester internal electron donor and polymer from same |
| US9382342B2 (en) | 2010-12-21 | 2016-07-05 | W. R. Grace & Co.-Conn. | Procatalyst composition with alkoxyalkyl 2-propenoate internal electron donor and polymer from same |
| US20120157645A1 (en) * | 2010-12-21 | 2012-06-21 | Linfeng Chen | Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same |
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| EP2681248A1 (en) * | 2011-03-01 | 2014-01-08 | Dow Global Technologies LLC | Process for improving bulk density with multi-contact procatalyst and product |
| CN103403088B (zh) | 2011-03-10 | 2016-02-10 | 巴塞尔聚烯烃意大利有限责任公司 | 聚烯烃基容器 |
| WO2012135189A2 (en) * | 2011-03-29 | 2012-10-04 | Dow Global Technologies Llc | Production of substituted phenylene aromatic diesters |
| CA2742454C (en) * | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Methods for controlling ethylene copolymer properties |
| RU2014106216A (ru) * | 2011-07-28 | 2015-09-10 | У.Р.Грейс Энд Ко.-Конн. | Полимер на основе пропилена с низким содержанием золы и способ |
| EP2736930B1 (en) * | 2011-07-28 | 2016-04-06 | W.R. Grace & Co.-Conn. | Propylene/ethylene copolymer film for heat seal |
| US9133286B2 (en) | 2011-08-30 | 2015-09-15 | W. R. Grace & Co.-Conn | Production of substituted phenylene dibenzoate internal electron donor and procatalyst with same |
| EP2607384A1 (en) * | 2011-12-21 | 2013-06-26 | Basell Poliolefine Italia S.r.l. | Catalyst system for the polymerization of olefins |
| EP2610274A1 (en) * | 2011-12-30 | 2013-07-03 | Borealis AG | Propylene random copolymer |
| KR101677602B1 (ko) * | 2012-07-14 | 2016-11-18 | 인디언 오일 코퍼레이션 리미티드 | 1,2-페닐렌디오에이트를 내부 공여체로서 포함하는 지글러-나타 촉매계 및 그의 제조 방법 |
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| ES2652323T5 (es) * | 2013-05-22 | 2021-10-19 | Borealis Ag | Copolímero de propileno para embalaje de pared delgada |
| US10336840B2 (en) | 2013-10-29 | 2019-07-02 | W. R. Grace & Co.-Conn. | Propylene ethylene random copolymer suitable for pipe |
| CN105705528B (zh) * | 2013-11-15 | 2018-11-09 | 陶氏环球技术有限责任公司 | 聚烯烃组合物和产生其的方法 |
| RU2731442C2 (ru) | 2013-11-21 | 2020-09-02 | У.Р. Грейс Энд Ко.-Конн | Получение полимеров на основе пропилена с высоким содержанием сомономера |
| MX366147B (es) | 2013-11-22 | 2019-06-28 | Borealis Ag | Homopolimero de propileno de baja emision. |
| PL3074429T3 (pl) | 2013-11-26 | 2024-07-08 | W.R. Grace & Co. - Conn. | Wytwarzanie udarowych kopolimerów propylenu i wyrobów |
| CN105764936B (zh) * | 2013-11-27 | 2018-05-11 | 格雷斯公司 | 主催化剂颗粒及抗冲共聚物的聚合方法 |
| EP3083723B1 (en) | 2013-12-20 | 2022-01-19 | Saudi Basic Industries Corporation | Catalyst system for polymerisation of an olefin |
| KR102365377B1 (ko) | 2013-12-20 | 2022-02-21 | 사우디 베이식 인더스트리즈 코포레이션 | 올레핀 중합용 촉매 시스템 |
| BR112016013951B1 (pt) | 2013-12-20 | 2022-02-22 | Sabic Global Technologies B.V. | Processo para a preparação de um pró-catalisador para polimerização de uma olefina, uso de uma benzamida, composição de catalisador, pró-catalisador e processo para a preparação de poliolefinas compreendendo o mesmo |
| MX2016008039A (es) | 2013-12-20 | 2017-05-12 | Saudi Basic Ind Corp | Sistema catalizador para polimerizacion de una olefina. |
| EP3083722B1 (en) * | 2013-12-20 | 2021-11-10 | Saudi Basic Industries Corporation | Catalyst system for polymerisation of an olefin |
| JP2017502148A (ja) * | 2013-12-23 | 2017-01-19 | ブラスケム アメリカ インコーポレイテッドＢｒａｓｋｅｍ Ａｍｅｒｉｃａ，Ｉｎｃ． | 向上した外観および優れた流動性のプロピレン系組成物 |
| CN105899599B (zh) | 2014-01-15 | 2018-10-02 | 埃克森美孚化学专利公司 | 基于丙烯的抗冲共聚物 |
| US10465025B2 (en) | 2014-01-15 | 2019-11-05 | Exxonmobil Chemical Patents Inc. | Low comonomer propylene-based impact copolymers |
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| US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
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| US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
| US9428598B2 (en) | 2014-02-07 | 2016-08-30 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| JP6720142B2 (ja) * | 2014-08-21 | 2020-07-08 | ダウ グローバル テクノロジーズ エルエルシー | 接着剤組成物 |
| KR102388264B1 (ko) * | 2014-08-21 | 2022-04-20 | 다우 글로벌 테크놀로지스 엘엘씨 | 핫 멜트 접착제 조성물 |
| EP3015503A1 (en) | 2014-10-27 | 2016-05-04 | Borealis AG | Heterophasic polypropylene with improved stiffness/impact balance |
| US9593184B2 (en) | 2014-10-28 | 2017-03-14 | Formosa Plastics Corporation, Usa | Oxalic acid diamides as modifiers for polyolefin catalysts |
| CN107075207B (zh) | 2014-11-19 | 2018-07-27 | 博里利斯股份公司 | 基于丙烯均聚物的注射成型制品 |
| BR112017026534B1 (pt) * | 2015-06-12 | 2021-12-07 | Sabic Global Technologies B.V. | Copolímero de propileno heterofásico, seu processo para a fabricação e uso, artigo que o compreende |
| BR112018008756A2 (pt) * | 2015-11-02 | 2018-10-30 | Braskem America Inc | resinas poliméricas à base de propileno e de polipropileno de homopolímero, composição de polipropileno de copolímero de impacto, e, artigo moldado |
| EP3184587B1 (en) * | 2015-12-21 | 2020-03-18 | Borealis AG | Extruded articles with improved optical properties |
| US10633463B2 (en) | 2015-12-31 | 2020-04-28 | Braskem America, Inc. | Non-phthalate catalyst system and its use in the polymerization of olefins |
| US9777084B2 (en) | 2016-02-19 | 2017-10-03 | Formosa Plastics Corporation, Usa | Catalyst system for olefin polymerization and method for producing olefin polymer |
| WO2017178046A1 (en) | 2016-04-13 | 2017-10-19 | Borealis Ag | Injection molded article based on propylene homopolymer |
| EP3260489B1 (en) | 2016-06-24 | 2019-12-25 | Borealis AG | Novel polypropylene compositions with low fogging |
| US11427660B2 (en) | 2016-08-17 | 2022-08-30 | Formosa Plastics Corporation, Usa | Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same |
| CN110023351B (zh) * | 2016-10-06 | 2022-04-26 | 格雷斯公司 | 采用内给电子体的组合制得的主催化剂组合物 |
| US9815920B1 (en) | 2016-10-14 | 2017-11-14 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| WO2018167305A1 (en) * | 2017-03-17 | 2018-09-20 | Sabic Global Technologies B.V. | Process for preparing a procatalyst for polymerization of olefins |
| EP3596136A1 (en) * | 2017-03-17 | 2020-01-22 | SABIC Global Technologies B.V. | Process for the polymerization of a polyolefin |
| JP7222912B2 (ja) * | 2017-04-12 | 2023-02-15 | ダブリュー・アール・グレース・アンド・カンパニー－コーン | 低ｖｏｃ含有量のプロピレンコポリマーの製造方法 |
| US10822438B2 (en) | 2017-05-09 | 2020-11-03 | Formosa Plastics Corporation | Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer |
| US10124324B1 (en) | 2017-05-09 | 2018-11-13 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| US11390700B2 (en) | 2017-05-18 | 2022-07-19 | Borealis Ag | Propylene-ethylene random copolymer with improved irradiation resistance |
| RU2692246C1 (ru) * | 2017-06-15 | 2019-06-24 | Индийская Нефтяная Корпорация Лимитэд | Внешний донор для полимеризации олефинов |
| TWI766025B (zh) * | 2017-06-28 | 2022-06-01 | 日商迪愛生股份有限公司 | 活性酯化合物及硬化性組成物 |
| WO2019004418A1 (ja) * | 2017-06-30 | 2019-01-03 | 三井化学株式会社 | プロピレン系重合体、その製造方法、プロピレン系樹脂組成物および成形体 |
| US10920053B2 (en) | 2017-10-16 | 2021-02-16 | Exxonmobil Chemical Patents Inc. | Propylene impact copolymer blends with improved gloss |
| WO2019094216A1 (en) | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
| WO2019141462A1 (en) | 2018-01-22 | 2019-07-25 | Borealis Ag | Nucleated c3c4 copolymers |
| EP4215582B1 (en) | 2018-04-10 | 2024-12-04 | Borealis AG | Bimodal polypropylene random copolymer with improved gamma-irradiation resistance |
| CN108484810B (zh) * | 2018-05-04 | 2020-08-21 | 江苏煦和新材料有限公司 | 一种制备高熔体强度聚丙烯的方法 |
| EP3617238A1 (en) | 2018-08-28 | 2020-03-04 | Borealis AG | Propylene random copolymer with specific comonomer distribution |
| WO2020176341A1 (en) * | 2019-02-27 | 2020-09-03 | Milliken & Company | Method for making heterophasic polymer compositions |
| PL3947552T3 (pl) * | 2019-04-05 | 2024-12-02 | W. R. Grace & Co.-Conn. | Kompozycja kopolimeru polipropylenu o odporności na uderzenia w temperaturze poniżej zera |
| US11891460B2 (en) * | 2019-05-10 | 2024-02-06 | W. R. Grace & Co.-Conn. | Activated catalyst components for olefin polymerization |
| EP4031590A4 (en) * | 2019-09-18 | 2023-10-11 | W. R. Grace & Co.-Conn | Catalyst composition for polyolefin polymers |
| KR20230029678A (ko) * | 2020-06-29 | 2023-03-03 | 더블유.알. 그레이스 앤드 캄파니-콘. | 높은 강성 특성을 갖는 프탈레이트-무함유 폴리프로필렌 단일중합체 |
| EP4178802A4 (en) * | 2020-07-11 | 2024-08-14 | W. R. Grace & Co.-Conn | PROPYLENE-BUTENE COPOLYMER AND COMPOSITIONS MADE THEREFROM |
| KR20230091125A (ko) * | 2020-10-23 | 2023-06-22 | 더블유.알. 그레이스 앤드 캄파니-콘. | Voc 함량이 감소한 충격 저항성 폴리프로필렌 중합체 조성물 |
| EP4359448A1 (en) | 2021-06-25 | 2024-05-01 | Braskem, S.A. | Propylene preliminary polymerization |
| US12435168B2 (en) * | 2022-09-12 | 2025-10-07 | Formosa Plastics Corporation, U.S.A. | High ductility, high modulus and phthalate free impact resistant propylene copolymer |
| CN120380039A (zh) | 2022-12-23 | 2025-07-25 | 北欧化工股份公司 | 聚丙烯共聚物的生产方法 |
| JP2026504551A (ja) | 2023-02-10 | 2026-02-05 | ダブリュー・アール・グレース・アンド・カンパニー－コーン | 廃液流れから溶剤を分離するプロセス |
| US20250066513A1 (en) | 2023-08-23 | 2025-02-27 | Formosa Plastics Corporation, U.S.A. | Catalyst System For Enhanced Stereo-Specificity Of Olefin Polymerization |
| US20250066514A1 (en) | 2023-08-24 | 2025-02-27 | Formosa Plastics Corporation, U.S.A. | Catalysts component and process for the production of polypropylene having high melt flow rate with high isotacticity |
| US20250109218A1 (en) | 2023-09-29 | 2025-04-03 | Formosa Plastics Corporation, U.S.A. | Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors |
| US20250115687A1 (en) | 2023-10-06 | 2025-04-10 | Formosa Plastics Corporation, U.S.A. | Production method for solid catalyst component for polymerizing olefins, and catalyst for polymerizaing olefins |
| US20250115686A1 (en) | 2023-10-09 | 2025-04-10 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing silane and process for the production of polypropylene having high isotacticity at high melt flow rate |
| US20250297039A1 (en) | 2024-03-19 | 2025-09-25 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing diglycidylester components and its use for the production of polypropylene having high isotacticity at high melt flow rate |
| WO2025219533A1 (en) | 2024-04-18 | 2025-10-23 | Borealis Gmbh | Process for the preparation of a propylene homopolymer |
| WO2025219537A1 (en) | 2024-04-18 | 2025-10-23 | Borealis Gmbh | Process for propylene polymerization with optimized prepolymerization conditions |
| EP4682176A1 (en) * | 2024-07-17 | 2026-01-21 | Borealis GmbH | Zinc adipate-nucleated propylene-ethylene random copolymer compositions |
| WO2026063967A1 (en) | 2024-09-19 | 2026-03-26 | Formosa Plastics Corporation, Usa | Olefin polymerization ziegler-natta catalyst components and process for the production of olefin polymers therewith |
| WO2026067166A1 (zh) * | 2024-09-25 | 2026-04-02 | 国家能源投资集团有限责任公司 | 内给电子体化合物、催化剂组分及烯烃聚合方法 |
| CN120483875B (zh) * | 2025-07-10 | 2025-10-21 | 营口市向阳催化剂有限责任公司 | 取代亚苯基芳族二酯的制备方法及其在催化剂制备中的应用 |
Family Cites Families (101)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3214469A (en) | 1958-01-15 | 1965-10-26 | Polaroid Corp | Dihydroxyphenylalkanoic acid amide derivatives |
| US5066737A (en) | 1990-10-22 | 1991-11-19 | Shell Oil Company | Olefin polymerization catalyst |
| US5151399A (en) | 1990-10-18 | 1992-09-29 | Shell Oil Company | Olefin polymerization catalyst |
| US5077357A (en) | 1990-10-22 | 1991-12-31 | Shell Oil Company | Olefin polymerization catalyst |
| US5082907A (en) | 1990-10-18 | 1992-01-21 | Shell Oil Company | Olefin polymerization catalyst |
| US5106806A (en) | 1990-10-18 | 1992-04-21 | Shell Oil Company | Olefin polymerization catalyst |
| ZA716958B (en) | 1970-10-30 | 1973-01-31 | Hoffmann La Roche | Phenylalanine amides |
| US3925338A (en) | 1973-03-16 | 1975-12-09 | Monsanto Co | Control of polymer particle size in olefin polymerization |
| DE2658866C3 (de) * | 1976-12-24 | 1979-10-31 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von mehrwertigen substituierten Phenolen |
| IT1209255B (it) * | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| US4442276A (en) * | 1982-02-12 | 1984-04-10 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing or copolymerizing olefins |
| JPS5991107A (ja) | 1982-11-17 | 1984-05-25 | Toho Titanium Co Ltd | オレフイン類重合用触媒成分の製造方法 |
| JPS6023404A (ja) | 1983-07-20 | 1985-02-06 | Toho Titanium Co Ltd | オレフィン類重合用触媒成分 |
| US4612299A (en) | 1984-07-09 | 1986-09-16 | Amoco Corporation | Magnesium carboxylate supports |
| US4540679A (en) | 1984-03-23 | 1985-09-10 | Amoco Corporation | Magnesium hydrocarbyl carbonate supports |
| US4866022A (en) | 1984-03-23 | 1989-09-12 | Amoco Corporation | Olefin polymerization catalyst |
| US4579836A (en) | 1985-05-22 | 1986-04-01 | Amoco Corporation | Exhaustively prepolymerized supported alpha-olefin polymerization catalyst |
| US4614830A (en) * | 1985-08-09 | 1986-09-30 | Sterling Drug Inc. | Esterification process |
| JPH06104693B2 (ja) | 1986-01-06 | 1994-12-21 | 東邦チタニウム株式会社 | オレフイン類重合用触媒 |
| JPS62205140A (ja) * | 1986-03-03 | 1987-09-09 | Mitsubishi Paper Mills Ltd | 重合体用可塑剤 |
| EP0268685B2 (en) | 1986-05-06 | 1996-08-07 | Toho Titanium Co. Ltd. | Catalyst for polymerizing olefins |
| US4710482A (en) | 1986-06-18 | 1987-12-01 | Shell Oil Company | Olefin polymerization catalyst component |
| JPS63277944A (ja) * | 1987-03-03 | 1988-11-15 | Kiroku Sozai Sogo Kenkyusho:Kk | 温度管理示温ラベル |
| CA1310955C (en) | 1987-03-13 | 1992-12-01 | Mamoru Kioka | Process for polymerization of olefins and polymerization catalyst |
| EP0284708B1 (en) | 1987-04-03 | 1996-01-31 | Fina Technology, Inc. | Metallocene catalyst systems for olefin polymerization having a silicon hydrocarbyl bridge. |
| US4927797A (en) | 1987-04-09 | 1990-05-22 | Fina Technology, Inc. | Catalyst system for the polymerization of olefins |
| US5066738A (en) | 1987-04-09 | 1991-11-19 | Fina Technology, Inc. | Polymerization of olefins with an improved catalyst system using a new electron donor |
| US4882380A (en) * | 1987-07-07 | 1989-11-21 | Union Carbide Chemicals And Plastics Company Inc. | Process for the production of impact polypropylene copolymers |
| JPH01224351A (ja) * | 1988-03-02 | 1989-09-07 | Mitsui Petrochem Ind Ltd | 芳香族カルボン酸アリールエステル類の製造法 |
| EP0350170B2 (en) | 1988-06-17 | 2001-09-12 | Mitsui Chemicals, Inc. | Process for polymerising olefins and polymerisation catalyst therefor |
| US5247031A (en) | 1988-09-13 | 1993-09-21 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst component, process for production thereof, olefin polymerization catalyst, and process for polymerizing olefins |
| KR920007040B1 (ko) | 1988-09-14 | 1992-08-24 | 미쓰이세끼유 가가꾸 고오교오 가부시끼가이샤 | 올레핀 중합용 촉매와 그 촉매의 성분 및 그 촉매에 의한 올레핀 중합법과 그 폴리올레핀에 의한 필름 및 사출성형품 |
| US4946816A (en) | 1989-08-21 | 1990-08-07 | Amoco Corporation | Morphology-controlled olefin polymerization catalyst |
| JP2909550B2 (ja) * | 1989-08-31 | 1999-06-23 | 三井化学株式会社 | アルキルフェノール類の製造方法 |
| US5247032A (en) | 1989-12-29 | 1993-09-21 | Mitsui Petrochemical Industries, Ltd. | Solid catalyst components for olefin polymerization and processes for the polymerization of olefin using same |
| JP2940684B2 (ja) | 1989-12-29 | 1999-08-25 | 三井化学株式会社 | オレフィン重合用固体状触媒成分およびこの触媒成分を用いたオレフィンの重合方法 |
| US5034361A (en) | 1990-05-24 | 1991-07-23 | Shell Oil Company | Catalyst precursor production |
| US5146028A (en) | 1990-10-18 | 1992-09-08 | Shell Oil Company | Olefin polymerization catalyst and process of polymerization |
| US5229342A (en) | 1990-10-18 | 1993-07-20 | Shell Oil Company | Olefin polymerization catalyst |
| DE4117144A1 (de) * | 1991-05-25 | 1992-11-26 | Basf Ag | Hochfliessfaehige propylen-ethylen-copolymerisate |
| JP2699047B2 (ja) | 1992-10-22 | 1998-01-19 | 昭和電工株式会社 | プロピレン系重合体の製造方法 |
| GB9300318D0 (en) * | 1993-01-08 | 1993-03-03 | Oxford Analytical Instr Ltd | Improvements relating to sample monitoring |
| IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
| US5674630A (en) * | 1995-05-08 | 1997-10-07 | Union Carbide Chemicals & Plastics Technology Corporation | Polymer compositions and cast films |
| JPH09227437A (ja) * | 1995-12-19 | 1997-09-02 | Daiso Co Ltd | カテコール誘導体の製造法 |
| JP3697011B2 (ja) | 1997-02-27 | 2005-09-21 | 三井化学株式会社 | プロピレン重合体 |
| GB2323363A (en) | 1997-03-19 | 1998-09-23 | Shell Int Research | Propylene polymer composition |
| FI980342A0 (fi) * | 1997-11-07 | 1998-02-13 | Borealis As | Polymerroer och -roerkopplingar |
| ATE234310T1 (de) * | 1997-12-23 | 2003-03-15 | Borealis Tech Oy | Magnesium-,halogen- und alkoxy-enthaldendes produkt |
| KR100334163B1 (ko) * | 1998-12-04 | 2002-10-25 | 삼성종합화학주식회사 | 올레핀중합또는공중합방법 |
| FI991057A0 (fi) | 1999-05-07 | 1999-05-07 | Borealis As | Korkean jäykkyyden propeenipolymeerit ja menetelmä niiden valmistamiseksi |
| JP3808243B2 (ja) * | 1999-07-27 | 2006-08-09 | 三井化学株式会社 | 軟質樹脂組成物 |
| JP3986216B2 (ja) | 1999-08-19 | 2007-10-03 | 三井化学株式会社 | 非水電解液およびそれを用いた二次電池 |
| JP2001096926A (ja) * | 1999-10-04 | 2001-04-10 | Showa Highpolymer Co Ltd | フェノール系三核体組成物及びそれからなる感熱記録材料用顕色剤 |
| US6554154B1 (en) | 2000-02-11 | 2003-04-29 | Solo Cup Company | Thermoformed container having improved strength to weight ratio in sidewall |
| JP2002012583A (ja) * | 2000-04-28 | 2002-01-15 | Sumitomo Chem Co Ltd | アミン誘導体の製造方法 |
| DE60104509T2 (de) * | 2000-05-31 | 2005-08-11 | Basell Poliolefine Italia S.P.A. | Propylenpolymerzusammensetzung mit verbesserter schlagzähigkeit und sehr guten optischen eigenschaften |
| ATE543859T1 (de) | 2000-12-22 | 2012-02-15 | Basell Poliolefine Srl | Polyolefinfolien für das thermoformen |
| US6534574B1 (en) | 2001-03-24 | 2003-03-18 | Milliken & Company | Highly nucleated thermoplastic articles |
| US6825146B2 (en) | 2001-05-29 | 2004-11-30 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst compositions and method of preparation |
| DE60106219T2 (de) * | 2001-06-27 | 2006-03-09 | Borealis Technology Oy | Propylen-Copolymer mit zufälliger Comonomerverteilung und Verfahren zu seiner Herstellung |
| US6960635B2 (en) | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
| CN1169845C (zh) * | 2002-02-07 | 2004-10-06 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用 |
| EP1364986A1 (en) * | 2002-05-21 | 2003-11-26 | Borealis Technology Oy | Polypropylene compositions especially for pipes |
| EP1507806B1 (en) * | 2002-05-29 | 2006-10-11 | Basell Poliolefine Italia S.r.l. | Butene-1 (co)polymers and process for their preparation |
| EP1515996A2 (en) * | 2002-06-14 | 2005-03-23 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition and polymerization process using mixtures of electron donors |
| ES2335409T3 (es) * | 2003-06-24 | 2010-03-26 | UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLC | Composicion catalitica y proceso de polimerizacion usando mezcla de donadores y electrones de tipo silano. |
| CN1229400C (zh) * | 2003-09-18 | 2005-11-30 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其催化剂 |
| US20060223956A1 (en) | 2003-09-23 | 2006-10-05 | Linfeng Chen | Catalyst composition with mixed sca and propylene polymerization process |
| EP1668046B8 (en) | 2003-09-23 | 2021-04-21 | W.R. Grace & CO. - CONN. | Self limiting catalyst composition and propylene polymerization process |
| JP2005112764A (ja) * | 2003-10-07 | 2005-04-28 | Toagosei Co Ltd | 芳香族エステルの製造方法 |
| FR2869035B1 (fr) | 2004-04-16 | 2006-07-14 | Pierre Fabre Medicament Sa | Derives (poly)aminoalkylaminoacetamide d'epipodophyllotoxine leur procede de preparation et leurs applications en therapeutique comme agent anticancereux |
| JP4413069B2 (ja) | 2004-04-28 | 2010-02-10 | 富士フイルム株式会社 | 平版印刷原版および平版印刷方法 |
| US7351778B2 (en) * | 2004-04-30 | 2008-04-01 | China Petroleum & Chemical Corporation | Catalyst component for olefin polymerization and catalyst comprising the same |
| EP1778780B1 (en) | 2004-08-18 | 2009-01-14 | Basell Poliolefine Italia S.r.l. | Stretch blow-molded containers from ziegler natta propylene polymer compositions |
| AU2005279786B2 (en) | 2004-08-31 | 2012-01-19 | Dow Global Technologies Llc | Composition suitable for thermoformable sheets and articles made therefrom |
| US20070202285A1 (en) | 2004-12-15 | 2007-08-30 | Fina Technology, Inc. | Articles having improved clarity, prepared from propylene-ethylene copolymers |
| AU2005319179B2 (en) | 2004-12-21 | 2011-10-13 | Dow Global Technologies Llc | Polypropylene-based adhesive compositions |
| US7491781B2 (en) | 2005-03-08 | 2009-02-17 | Ineos Usa Llc | Propylene polymer catalyst donor component |
| DE602006007572D1 (de) | 2005-05-12 | 2009-08-13 | Basell Poliolefine Srl | Propylen-ethylen-copolymere und herstellungsverfahren dafür |
| ATE469928T1 (de) | 2005-10-21 | 2010-06-15 | Basell Polyolefine Gmbh | Statistische polypropylencopolymere mit hohen schmelzflussraten für spritzguss- und schmelzblasanwendungen |
| CN100532405C (zh) * | 2005-10-26 | 2009-08-26 | 中国石油化工股份有限公司 | 用于乙烯聚合的催化剂组分及其制备方法 |
| JP2007175028A (ja) * | 2005-12-28 | 2007-07-12 | Koojin Bio Kk | 閉鎖系細胞培養容器、閉鎖系細胞培養用キット、及び閉鎖系細胞培養容器の製造方法 |
| MX2008015361A (es) | 2006-06-01 | 2008-12-16 | Sunoco Inc R&M | Polipropileno de alta cristalinidad de indice de flujo de fusion alto. |
| TW200817315A (en) | 2006-06-16 | 2008-04-16 | Sanol Arznei Schwarz Gmbh | Entacapone-derivatives |
| ES2536254T3 (es) | 2006-06-30 | 2015-05-21 | Borealis Technology Oy | Copolímero de polipropileno al azar con alto flujo del fundido |
| CN101490101B (zh) * | 2006-07-18 | 2011-11-02 | 三井化学株式会社 | 固态钛催化剂成分、烯烃聚合用催化剂及烯烃聚合方法 |
| JP4857093B2 (ja) | 2006-11-29 | 2012-01-18 | 日本ポリプロ株式会社 | 深絞り容器 |
| PL2185600T3 (pl) | 2007-08-24 | 2019-07-31 | W.R. Grace & Co. - Conn. | Samohamująca kompozycja katalityczna bez silanu |
| US7893003B2 (en) * | 2007-08-24 | 2011-02-22 | Dow Global Technologies Inc. | Catalyst composition with mixed selectivity control agent and method |
| CN101848946B (zh) | 2007-08-24 | 2013-06-12 | 陶氏环球技术有限责任公司 | 气相聚合方法 |
| JP5740159B2 (ja) * | 2007-12-21 | 2015-06-24 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 二座内部供与体を有する自己制限性触媒組成物 |
| JP4944058B2 (ja) | 2008-03-31 | 2012-05-30 | 株式会社エフピコ | ポリプロピレン系樹脂シート及びポリプロピレン系樹脂容器 |
| CN101318886B (zh) * | 2008-07-04 | 2011-05-04 | 浙江理工大学 | 一种邻羟基苯基烷基酮的合成方法 |
| US8003558B2 (en) * | 2008-07-29 | 2011-08-23 | Basf Corporation | Internal donor for olefin polymerization catalysts |
| EP2315790B1 (en) * | 2008-08-21 | 2018-04-25 | W.R. Grace & CO. - CONN. | High melt flow propylene impact copolymer and method |
| JP5731988B2 (ja) * | 2008-12-31 | 2015-06-10 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | プロピレン系ポリマー、物品およびその製造プロセス |
| PL2373702T3 (pl) | 2008-12-31 | 2018-07-31 | W.R. Grace & Co.-Conn. | Kompozycja prekatalizatora z wewnętrznym donorem w postaci podstawionego aromatycznego diestru 1,2-fenylenowego oraz sposób |
| US8378045B2 (en) * | 2008-12-31 | 2013-02-19 | Dow Global Technologies Llc | Thermoformed article with high stiffness and good optics |
| JP6046349B2 (ja) * | 2008-12-31 | 2016-12-14 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 置換フェニレン芳香族ジエステルの製造 |
| US8263520B2 (en) | 2009-12-02 | 2012-09-11 | Dow Global Technologies Llc | Two atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture |
-
2009
- 2009-12-31 JP JP2011544621A patent/JP5731988B2/ja not_active Expired - Fee Related
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