JP2011014894A - 光電変換装置および光電変換装置の作製方法 - Google Patents
光電変換装置および光電変換装置の作製方法 Download PDFInfo
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Abstract
【解決手段】光電変換機能を備えた第1のセルと、光電変換機能を備えた第2のセルと、第1のセルおよび第2のセルを固着し、且つ電気的に接続する機能を備えた、構造体と、を有する光電変換装置とする。その結果、pin接合とpin接合との十分な導電性を確保した、半導体接合を直列接続する多接合タイプの光電変換装置を提供することができる。また当該構成により、十分な起電力を確保することが可能である。
【選択図】図1
Description
発明の一態様にかかる光電変換装置は、少なくとも二つのセルを備える。当該セルは、光電変換機能を有する最小単位である光電変換層の単層構造又は積層構造で構成される。さらに光電変換装置は、導電性粒子をはじめとする導電体を含む樹脂によって形成される少なくとも1つの構造体を有し、該構造体が二つのセルの間に挟まれている。図1を用いて、発明の一態様にかかる光電変換装置の構成について説明する。
本実施の形態では、開示する発明の光電変換装置の作製方法について、図2(A)に示した光電変換装置を例に挙げて説明する。
本実施の形態では、光電変換層を具備するセルを、プラスチック基板(可撓性を有する基板)上に接着して作製する構成について説明する。具体的には、ガラスやセラミックなど耐熱性の高い支持基板上に剥離層及び絶縁層を介して光電変換層を含む被剥離層形成した後、剥離層から支持基板と被剥離層とを分離して、分離した被剥離層をプラスチック基板上に接着することで、プラスチック基板上にセルを作製する構成について一例を示し説明する。なお本実施の形態では、光入射面とは反対側の面に配置されるセル(ボトムセル)の作製について説明を行う。光入射面に配置されるセル(トップセル)に本実施の形態で説明する作製方法で作製するセルを作製する場合は、電極及び光電変換層を構成する層の積層順序を適宜変更すればよい。
本実施の形態では、単結晶半導体基板をガラスやセラミックなどの支持基板上に貼り合わせて作製する光電変換層を具備するセルの作製方法に関し、一例を示し説明する。なお本実施の形態では、光入射面とは反対側の面に配置されるセル(ボトムセル)の作製について説明を行う。光入射面に配置されるセル(トップセル)に本実施の形態で説明する作製方法で作製するセルを作製する場合は、電極及び光電変換層を構成する層の積層順序を適宜変更すればよい。
本実施の形態では、単結晶半導体基板を用いて作製される光電変換層を具備するセルの作製方法に関し、一例を示し説明する。なお本実施の形態では、光入射面とは反対側の面に配置されるセル(ボトムセル)の作製について説明を行う。光入射面に配置されるセル(トップセル)に本実施の形態で説明する作製方法で作製するセルを作製する場合は、電極及び光電変換層を構成する層の積層順序を適宜変更すればよい。
本実施の形態では、セルを直列に接続した光電変換装置の例について説明する(図10参照)。
本実施の形態では、光電変換装置の作製に用いることができる装置の例について、図面を参照して説明する。
実施の形態1乃至7などにより得られる光電変換装置を用いて、太陽光発電モジュールを製造することができる。本実施の形態では、実施の形態によって得られる光電変換装置を用いた太陽光発電モジュールの例を図13(A)に示す。太陽光発電モジュール5028は、支持基板4002上に設けられた光電変換層4020により構成されている。支持基板4002と光電変換層4020の間には、支持基板4002側から絶縁層、第1の電極が設けられている。また、第1の電極は補助電極4016と接続している。
図14に、実施の形態8で示した太陽光発電モジュール5028を用いた太陽光発電システムの例を示す。DC−DCコンバータ等を具備する充電制御回路5029は、一又は複数の太陽光発電モジュール5028から供給される電力を制御して、蓄電池5030を充電する。また充電制御回路5029は、蓄電池5030が十分に充電されている場合、一又は複数の太陽光発電モジュール5028から供給される電力を負荷5031に直接出力するよう制御する。
図15(A)および図15(B)に、実施の形態8で示した太陽光発電モジュール5028をルーフ部分に用いた車両6000(乗用自動車)の例を示す。太陽光発電モジュール5028は、コンバータ6002を介してバッテリーまたはキャパシタ6004に接続されている。すなわち、バッテリーまたはキャパシタ6004は、太陽光発電モジュール5028から供給される電力を用いて充電される。また、エンジン6006の動作状況をモニタ6008で監視して、その状況に応じて充電・放電を選択させる構成としても良い。
一実施形態に係る光電変換装置の出力から、外部電源を用いることなく、交流電力を安定的に取り出すことのできるインバータの一態様を図16に示す。
本実施の形態では、図19を参照して、光発電システムの一例を示す。この光発電システムは、住宅等に設置される構成を示す。
図20で示すように、セル7096が形成された第1の面を内側に対向させ、導電体7100が分散された有機樹脂7102を間に挟むように重ね合わせた一対の基板7098の周辺部分は、機械的強度を持たせるために枠体7088が設けられている。
本実施の形態では、複数の光電変換層を有することによる光電変換効率の向上の様子を確認した。具体的には、計算機シミュレーションにより、非晶質シリコンを用いた光電変換層と単結晶シリコンを用いた光電変換層についての光電変換効率(量子効率)の波長依存を求めた。計算ソフトとしてはデバイスシュミレータ(Silvaco社製Atlas)を用いた。
102 セル
103 構造体
104 基板
105 セル
106 導電体
107 有機樹脂
110 導電膜
111 光電変換層
112 導電膜
113 p層
114 i層
115 n層
120 導電膜
121 光電変換層
121a 光電変換層
121b 光電変換層
122 導電膜
123 n層
124 i層
125 p層
131 光電変換層
133 p層
135 n層
141a 光電変換層
141b 光電変換層
143 p層
145 n層
151 光電変換層
152 光電変換層
153 p層
154 i層
155 n層
156 p層
157 i層
158 n層
159 光電変換層
160 p層
161 i層
162 n層
163 中間層
600 導電体
602 光電変換領域
604 端子領域
606 接続端子
608 接続端子
610 光電変換領域
612 導通部
614 光電変換領域
616 導通部
1000 トランスファー室
1002 ロード・アンロード室
1004 成膜室
1006 成膜室
1008 成膜室
1010 成膜室
1012 成膜室
1020 搬送ロボット
1101 単結晶半導体基板
1101a 単結晶半導体基板
1101b 単結晶半導体基板
1102 保護層
1103 半導体層
1104 脆化層
1105 導電膜
1106 絶縁層
1107 支持基板
1108 分離基板
1109 半導体層
1110 半導体層
1111 光電変換層
1112 導電膜
1201 支持基板
1202 剥離層
1203 絶縁層
1204 導電膜
1205 半導体層
1206 半導体層
1207 半導体層
1208 仮支持基板
1209 剥離用接着材
1210 接着材層
1211 プラスチック基板
1212 導電膜
1221 光電変換層
1301 単結晶半導体基板
1302 テクスチャ構造
1303 半導体層
1304 導電膜
1305 半導体層
1306 導電膜
1307 光電変換層
2100 トランスファー室
2102 分析室
2104 表面処理室
2106 成膜室
2108 ロード室
2110 成膜室
2112 成膜室
2114 成膜室
2120 搬送ロボット
2140 トランスファー室
2142 成膜室
2144 成膜室
2146 成膜室
2148 アンロード室
2150 成膜室
2152 成膜室
2154 成膜室
2160 搬送ロボット
2180 連結室
4002 支持基板
4016 補助電極
4018 電極
4020 光電変換層
5026 裏面電極
5027 裏面電極
5028 太陽光発電モジュール
5029 充電制御回路
5030 蓄電池
5031 負荷
6000 車両
6002 コンバータ
6004 キャパシタ
6006 エンジン
6008 モニタ
6010 ラジエータ
6012 循環ポンプ
7002 光電変換装置
7004 コンデンサ
7006 スイッチングレギュレータ
7008 パルス幅変調回路
7010 バンドパスフィルタ
7012 アッテネータ
7014 三角波発生回路
7016 コンパレータ
7020 スイッチングトランジスタ
7021 平滑容量
7022 インダクタ
7024 ダイオード
7026 スイッチングトランジスタ
7027 スイッチングトランジスタ
7028 スイッチングトランジスタ
7029 スイッチングトランジスタ
7030 パルス幅変調波
7032 正弦波
7050 光電変換装置
7052 直流開閉器
7054 充電制御回路
7056 蓄電装置
7058 インバータ
7060 分電盤
7062 交流開閉器
7064 トランス
7068 配電線
7070 電気器具
7096 セル
7080 導電性部材
7082 配線部材
7084 封止樹脂
7088 枠体
7090 蓄電装置
7092 端子
7094 逆流防止ダイオード
7098 基板
7100 導電体
7102 有機樹脂
Claims (14)
- 光電変換機能を備えた第1のセルと、
光電変換機能を備えた第2のセルと、
前記第1のセルおよび前記第2のセルを固着し、且つ電気的に接続する機能を備えた、構造体と、
を有する光電変換装置。 - 第1の基板上に形成された光電変換機能を備えた第1のセルと、
第2の基板上に形成された光電変換機能を備えた第2のセルと、
前記第1のセルおよび前記第2のセルを固着し、且つ電気的に接続する機能を備えた、構造体と、
を有する光電変換装置。 - 請求項2において、
前記第1のセル及び前記第2のセルが前記構造体を介して対向することにより、前記第1の基板及び前記第2の基板が外側に配置された光電変換装置。 - 請求項1乃至請求項3のいずれか一において、
前記第1のセルは、第1の導電膜と第2の導電膜とに挟持された第1の光電変換層、を有し、
前記第2のセルは、第3の導電膜と第4の導電膜とに挟持された第2の光電変換層、を有する光電変換装置。 - 請求項4において、
前記第1の光電変換層は、第1のp型半導体層及び第1のn型半導体層を有し、
前記第2の光電変換層は、第2のp型半導体層及び第2のn型半導体層を有する光電変換装置。 - 請求項4または請求項5において、
前記第1のp型半導体層と前記第1のn型半導体層との間に、第1のi型半導体層を有し、
前記第2のp型半導体層と前記第2のn型半導体層との間に、第2のi型半導体層を有する光電変換装置。 - 請求項1乃至請求項6のいずれか一において、
前記第1のセルまたは前記第2のセルは、非晶質シリコン、結晶性シリコン、単結晶シリコンのいずれかを含む光電変換装置。 - 光電変換機能を備えた第1のセルを形成し、
光電変換機能を備えた第2のセルを形成し、
導電体を含む樹脂によって、前記第1のセルと前記第2のセルとを固着し、且つ電気的に接続する光電変換装置の作製方法。 - 第1の基板上に光電変換機能を備えた第1のセルを形成し、
第2の基板上に光電変換機能を備えた第2のセルを形成し、
導電体を含む樹脂によって、前記第1のセルと前記第2のセルとを固着し、且つ電気的に接続する光電変換装置の作製方法。 - 請求項8または請求項9において、
前記第1のセル及び前記第2のセルを、前記構造体を介して対向させることにより、前記第1の基板及び前記第2の基板を外側に配置させる光電変換装置の作製方法。 - 請求項8乃至請求項10のいずれか一において、
前記第1のセルとして、第1の導電膜と、第1の光電変換層と、第2の導電膜と、の積層構造を形成し、
前記第2のセルとして、第3の導電膜と、第2の光電変換層と、第4の導電膜と、の積層構造を形成する光電変換装置の作製方法。 - 請求項11において、
前記第1の光電変換層は、第1のp型半導体層と、第1のn型半導体層と、を積層して形成し、
前記第2の光電変換層は、第2のp型半導体層と、第2のn型半導体層と、を積層して形成する光電変換装置の作製方法。 - 請求項11または請求項12において、
前記第1のp型半導体層と前記第1のn型半導体層との間に、第1のi型半導体層を形成し、
前記第2のp型半導体層と前記第2のn型半導体層との間に、第2のi型半導体層を形成する光電変換装置の作製方法。 - 請求項8乃至請求項13のいずれか一において、
前記第1のセルまたは前記第2のセルを、非晶質シリコン、結晶性シリコン、単結晶シリコンのいずれかを含んで形成する光電変換装置の作製方法。
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JPWO2022102128A1 (ja) * | 2020-11-16 | 2022-05-19 | ||
JP7247421B2 (ja) | 2020-11-16 | 2023-03-28 | 株式会社東芝 | 多層接合型光電変換素子およびその製造方法 |
Also Published As
Publication number | Publication date |
---|---|
TWI500172B (zh) | 2015-09-11 |
TW201108433A (en) | 2011-03-01 |
KR101732397B1 (ko) | 2017-05-04 |
US20100307558A1 (en) | 2010-12-09 |
JP2015097286A (ja) | 2015-05-21 |
JP6049771B2 (ja) | 2016-12-21 |
WO2010140522A1 (en) | 2010-12-09 |
KR20120038407A (ko) | 2012-04-23 |
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