JP2010509108A - 発熱ファブリックおよびその製造方法 - Google Patents
発熱ファブリックおよびその製造方法 Download PDFInfo
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- JP2010509108A JP2010509108A JP2009537079A JP2009537079A JP2010509108A JP 2010509108 A JP2010509108 A JP 2010509108A JP 2009537079 A JP2009537079 A JP 2009537079A JP 2009537079 A JP2009537079 A JP 2009537079A JP 2010509108 A JP2010509108 A JP 2010509108A
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- Prior art keywords
- conductive
- layer
- conductive fabric
- resin
- conductive layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
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- D06M17/10—Polyurethanes polyurea
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- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
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- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
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- D06M15/63—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing sulfur in the main chain, e.g. polysulfones
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
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-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
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- D10B2401/00—Physical properties
- D10B2401/16—Physical properties antistatic; conductive
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
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- H05K1/092—Dispersed materials, e.g. conductive pastes or inks
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/02—Fillers; Particles; Fibers; Reinforcement materials
- H05K2201/0275—Fibers and reinforcement materials
- H05K2201/0278—Polymeric fibers
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/02—Fillers; Particles; Fibers; Reinforcement materials
- H05K2201/0275—Fibers and reinforcement materials
- H05K2201/029—Woven fibrous reinforcement or textile
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
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- H05K2201/032—Materials
- H05K2201/0329—Intrinsically conductive polymer [ICP]; Semiconductive polymer
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
- H05K3/28—Applying non-metallic protective coatings
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Abstract
Description
W=I2R
R=ρL/S
W:電力、R:抵抗、ρ:比抵抗、L:導線の長さ、S:断面積
(比較例1)
前記の実施例7と同一であるが、伝導層を形成しなかった。
1.耐洗濯性
* 試験方法(KS K ISO 6330)
前記それぞれの実施例から製造されたファブリックを洗濯し、これらの抵抗の変化を測定することにより、耐洗濯性が確保される条件を把握した。具体的に水平型ドラム式洗濯機(WDCR 1010、韓国LG Electronics、Inc)で洗剤を用いず、ウールコース(57分)、高温乾燥条件(1時間)の後、それぞれのファブリックの抵抗値および変化率を測定した。その結果は下記表1の通りである。
実施例7および8と関連した試料から相対的に低い抵抗増加率が示した。
* 試験方法(KS K ISO 6330)
バインダーの含有量は、それぞれ0〜20重量%まで変化させて、これらの洗濯後の抵抗値および抵抗変化率を測定した。その結果は下記表2の通りである。
一般に、抵抗が一定の水準以上に高まると、電圧印加時に過負荷による電流の流れに妨害を受けることになる。したがって、本発明の一実施例によるファブリックにも、伝導層にも発熱現象が発生し得、特に、電源接続部位、パターン形状に発生する。電極の厚さ、幅、バインダーの混合量の変数値を変更して測定した(測定方法:熱画像カメラ、InfraCAM、FLIR system)。
表3は、実施例1(0%)、11(5%)、7(10%)、12(15%)、13(20%)による発熱パターンのデータである。前記結果からバインダーの混合量が増加するほど発熱温度が増加する現象が発生した。これは、伝導層を構成する無機成分に非伝導性物質(有機物質)が混合されることにより、電気伝導性を低下させた結果のためであると判断できる。一方、前記試験1でのように、バインダーを混合した実施例で耐洗濯性が増加する現象を考慮すると、耐洗濯性と電気伝導度間の最適条件を導き出さなければならないことが分かる。このような点からバインダーの混合量は10〜15重量%が最も望ましいと判断できる。
表4は実施例7(1cm)および実施例17(2cm)における発熱パターンのデータである。実施例7によるファブリックの場合は50℃前後で発熱が発生した。これは電荷の流れが容易でないものと判断できる。一方、実施例17の場合は発熱現象が低下するものと観察された。
表5は実施例7(10μm)および実施例18(20μm)における発熱パターンのデータである。データでのように、実施例7は約45℃前後で発熱が形成され、実施例18は約29℃前後で発熱現象が観察された。これにより、電荷は伝導層の厚さにも影響を受けると判断できる。
実施例7および比較例1を対象としてASTM D 503494方法で引張実験を実施した。具体的にそれぞれのファブリック試験片は幅50±1mm、長さ150mmに形成し、ファブリックをA、B、C、Dの4部分に切って、各引張強度をインストロン(Instron 4444、seriesIX)を用いて機械的物性を測定した。その結果は表6と図13〜16の通りである。この時、荷重(Load cell)2kN、距離(gauge length)75±1mm、引張速度(crosshead speed)300mm±10mm/minにし、5回以上測定した。
100 基層
200 プライマ層
300 伝導層
400 絶縁層
Claims (36)
- 伝導性ファブリックにおいて、
合成繊維、再生繊維または天然繊維で形成された基層と、
予め設計された電気的なパターンによって自由な形成が可能な伝導層と、
前記伝導層の損傷を防止するための絶縁層を含み、
前記各層は順次積層されて形成されることを特徴とする伝導性ファブリック。 - 前記基層と伝導層との間に基層の表面均一性のために形成されたプライマ層をさらに含むことを特徴とする請求項1に記載の伝導性ファブリック。
- 前記プライマ層は、ポリウレタン系樹脂、アクリル系樹脂、およびシリコン系樹脂などからなる群より選択される1つ以上から形成されることを特徴とする請求項2に記載の伝導性ファブリック。
- 前記プライマ層は、撥水層と共に複層構造で形成されることを特徴とする請求項2に記載の伝導性ファブリック。
- 前記伝導層は、伝導性高分子、炭素、銀のような金属物質および前記物質とバインダーの混合物からなる群より選択される1つ以上から形成されることを特徴とする請求項1に記載の伝導性ファブリック。
- 前記伝導性高分子は、ポリアニリン、ポリピロールおよびポリチオフェンからなる群より選択される1つ以上であることを特徴とする請求項5に記載の伝導性ファブリック。
- 前記伝導層を形成する金属物質とバインダーは、重量基準に90:10〜80:20の含有量比で含まれることを特徴とする請求項5に記載の伝導性ファブリック。
- 前記バインダーは、ポリウレタン系樹脂、アクリル系樹脂、シリコン系樹脂、メラミン系樹脂およびエポキシ系樹脂からなる群より選択される1つ以上であることを特徴とする請求項5に記載の伝導性ファブリック。
- 前記バインダーは水分散性ポリウレタンであることを特徴とする請求項8に記載の伝導性ファブリック。
- 前記伝導層は厚さが2〜500μmであることを特徴とする請求項1に記載の伝導性ファブリック。
- 前記伝導層は厚さが10〜20μmであることを特徴とする請求項10に記載の伝導性ファブリック。
- 前記伝導層は幅が10〜20mmであることを特徴とする請求項1に記載の伝導性ファブリック。
- 前記絶縁層は、ポリウレタン系樹脂、アクリル系樹脂、シリコン系樹脂、ポリエステル系樹脂、PVC系樹脂、およびポリテトラフルオロエチレン(PTFE)樹脂からなる群より選択される1つ以上をコーティング、プリンティングまたはラミネーティングによって形成することを特徴とする請求項1に記載の伝導性ファブリック。
- 前記伝導層に折れ部分が形成される場合、直線回路よりも相対的に幅が広い形状に形成されることを特徴とする請求項1に記載の伝導性ファブリック。
- 前記形状は円形または楕円形などであることを特徴とする請求項14に記載の伝導性ファブリック。
- 前記ファブリックの洗濯前後の抵抗値差は0.5〜4Ωであることを特徴とする請求項1に記載の伝導性ファブリック。
- 基層、伝導層および絶縁層を含む伝導性ファブリックの製造方法において、
合成繊維、再生繊維または天然繊維で形成された基層の上部に通電可能な伝導層を形成するステップと、
前記伝導層の上部に伝導層の損傷を防止するための絶縁層を形成するステップと、を含むことを特徴とする伝導性ファブリックの製造方法。 - 前記伝導層を形成する前に前記基層の上部に伝導層の厚さを均一に維持するためのプライマ層を形成するステップをさらに含むことを特徴とする請求項17に記載の伝導性ファブリックの製造方法。
- 前記プライマ層は、撥水層と共に複層構造で形成されることを特徴とする請求項18に記載の伝導性ファブリックの製造方法。
- 前記伝導層を形成する前に、基層の表面を平滑にし、基層の空隙を埋め、耐屈曲性を補完するために、前記基層のファブリックを圧搾ローラで加圧するカレンダリングステップをさらに含むことを特徴とする請求項17に記載の伝導性ファブリックの製造方法。
- 前記カレンダリングステップの後に、前記伝導性ファブリックの空隙を選択的に埋め、絶縁および耐洗濯性、耐屈曲性を補完するために、透湿防水/防水ステップをさらに含むことを特徴とする請求項17に記載の伝導性ファブリックの製造方法。
- 前記プライマ層は、ナイフローラ方式、オーバーロールコーティング、フローティングナイフコーティング、またはナイフオーバーコーティングによって形成されることを特徴とする請求項18または19に記載の伝導性ファブリックの製造方法。
- 前記プライマ層は、ポリウレタン系樹脂、アクリル系樹脂、およびシリコン系樹脂などからなる群より選択される1つ以上から形成されることを特徴とする請求項18または19に記載の伝導性ファブリックの製造方法。
- 前記伝導層は、伝導性高分子、炭素、銀のような金属物質および前記物質とバインダーの混合物からなる群より選択される1つ以上から形成されることを特徴とする請求項17に記載の伝導性ファブリックの製造方法。
- 前記伝導性高分子は、ポリアニリン、ポリピロールおよびポリチオフェンからなる群より選択される1つ以上であることを特徴とする請求項24に記載の伝導性ファブリックの製造方法。
- 前記伝導層を形成する金属物質とバインダーは、重量基準に90:10〜80:20で含まれることを特徴とする請求項24に記載の伝導性ファブリックの製造方法。
- 前記バインダーは、ポリウレタン系樹脂、アクリル系樹脂、シリコン系樹脂、メラミン系樹脂およびエポキシ系樹脂からなる群より選択される1つ以上であることを特徴とする請求項24に記載の伝導性ファブリックの製造方法。
- 前記バインダーは水分散性ポリウレタンであることを特徴とする請求項27に記載の伝導性ファブリックの製造方法。
- 前記伝導層は2〜500μm厚さで形成されることを特徴とする請求項17に記載の伝導性ファブリックの製造方法。
- 前記伝導層は厚さが10〜20μmであることを特徴とする請求項29に記載の伝導性ファブリックの製造方法。
- 前記伝導層は幅が10〜20mmであることを特徴とする請求項17に記載の伝導性ファブリックの製造方法。
- 前記絶縁層は、ポリウレタン系樹脂、アクリル系樹脂、シリコン系樹脂、ポリエステル系樹脂、PVC系樹脂、およびポリテトラフルオロエチレン(PTFE)樹脂からなる群より選択される1つ以上をコーティング、プリンティングまたはラミネーティングによって形成することを特徴とする請求項17に記載の伝導性ファブリックの製造方法。
- 前記絶縁層は、直接コーティングの場合は乾燥式コーティングで、ラミネーティングの場合はホットメルト型ドット式またはグラビア方式で形成されることを特徴とする請求項32伝導性ファブリックの製造方法。
- 前記伝導層に、折れ部分が形成される場合、直線回路よりも相対的に幅が広い形状に形成されることを特徴とする請求項17に記載の伝導性ファブリックの製造方法。
- 前記形状は円形または楕円形などであることを特徴とする請求項34に記載の伝導性ファブリックの製造方法。
- 前記ファブリックの洗濯前後の抵抗値差は0.5〜4Ωであることを特徴とする請求項17に記載の伝導性ファブリックの製造方法。
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Also Published As
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WO2008060101A1 (en) | 2008-05-22 |
KR20080043730A (ko) | 2008-05-19 |
CA2669657A1 (en) | 2008-05-22 |
RU2449069C2 (ru) | 2012-04-27 |
EP2084324A1 (en) | 2009-08-05 |
EP2084324A4 (en) | 2010-05-19 |
CA2669657C (en) | 2013-06-25 |
RU2009118193A (ru) | 2010-12-20 |
US8003198B2 (en) | 2011-08-23 |
KR100945051B1 (ko) | 2010-03-05 |
US20100279086A1 (en) | 2010-11-04 |
CN101542039B (zh) | 2011-12-07 |
EP2084324B1 (en) | 2013-12-04 |
CN101542039A (zh) | 2009-09-23 |
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