JP2010089259A - 光応答性ガス発生材料、マイクロポンプ及びマイクロ流体デバイス - Google Patents
光応答性ガス発生材料、マイクロポンプ及びマイクロ流体デバイス Download PDFInfo
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- JP2010089259A JP2010089259A JP2009279460A JP2009279460A JP2010089259A JP 2010089259 A JP2010089259 A JP 2010089259A JP 2009279460 A JP2009279460 A JP 2009279460A JP 2009279460 A JP2009279460 A JP 2009279460A JP 2010089259 A JP2010089259 A JP 2010089259A
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- gas generating
- generating material
- photoresponsive
- photoresponsive gas
- gas
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Abstract
【解決手段】基板内に微細流路8、9が形成されているマイクロ流体デバイスのマイクロポンプに用いられるガス発生剤であって、光酸発生剤と、酸刺激応答性ガス発生剤とを含む光応答性ガス発生材料13、及び該光応答性ガス発生材料13が内部に収納されているマイクロポンプ10。
【選択図】図1
Description
本発明の光応答性ガス発生材料は、光酸発生剤と、酸刺激ガス発生剤とを含む。本発明の光応答性ガス発生材料は、光酸発生剤及び酸刺激ガス発生剤を含むので、光が照射されると、光酸発生剤から酸を発生し、該酸が酸刺激ガス発生剤と反応して、ガスを速やかに発生する。
本発明では、光応答性ガス発生材料は、バインダー樹脂をさらに含んでいてもよい。この場合、錠剤状、微粒子状、フィルム状などの形態への光応答性ガス発生材料の加工が容易になる。また、光応答性ガス発生材料の形態を強固に維持することができる。
本発明の光応答性ガス発生材料は、光増感剤をさらに含むことが好ましい。光応答性ガス発生材料が光増感剤を含む場合には、光の照射によりガスをより一層速やかに発生させることができる。
上記光応答性ガス発生材料は、ガスの発生を補助したり、ガス発生の連鎖を止めたり、多孔性支持体へ浸透を補助する目的で、光分解性のアゾ化合物や過酸化物、ラジカルスカベンジャー、溶剤等適宜の添加物を含んでいてもよい。
図1(a)及び(b)は、本発明の第1の実施形態に係るマイクロポンプを備えるマイクロ流体デバイスの模式的正面断面図及び該マイクロポンプの構造を示す部分切欠拡大正面断面図である。
図3は、本発明の第2の実施形態としてのマイクロ流体デバイスの模式的正面断面図である。
図4に、本発明の第3の実施形態に係るマイクロ流体デバイスとしてのマイクロ化学チップを正面断面図で示す。
図5は、第4の実施形態に係るマイクロ流体デバイスの断面図である。図5に示すように、本実施形態では、バリア層221は、ガス発生層220の外周に位置する外周部221aにおいて、全周にわたって基板210に接合されている。これにより、基板210とバリア層221との間に実質的に気密された空間が形成されている。そして、その気密空間内にガス発生層220が配置されている。
図6は、第5の実施形態に係るマイクロ流体デバイスの断面図である。図6に示すように、開口214aに接続された1本または複数本の溝220bがガス発生層220に形成されていてもよい。そうすることで、ガス発生層220の開口214aから離れた部分において発生したガスも効率的にマイクロ流路214に供給することが可能となる。
(実施例1)
光酸発生剤としての2,3,4,4’−テトラヒドロキシべンゾフェノン35重量部と、酸刺激ガス発生剤としての炭酸水素ナトリウム75重量部とを配合した。配合物をプレス法により固め、錠剤状光応答性ガス発生材料を得た。
実施例1記載の配合に、光増感剤としての2,4−ジメチルチオキサントン4.8重量部をさらに配合したこと以外は実施例1と同様にして、錠剤状光応答性ガス発生材料を得た。
実施例2記載の配合に、テトラヒドロフランとエタノールとの1:1(重量比)混合溶媒100重量部に、バインダー樹脂としてのメタクリル酸メチル・アクリルアミド共重合体(メタクリル酸メチルとアクリルアミドとを85:15の共重合比(重量比)で共重合したもの、重量平均分子量65500)50重量部をさらに配合した。配合物を乾燥させ、錠剤状光応答性ガス発生材料を得た。
バインダー樹脂としてのメタクリル酸メチル・アクリルアミド共重合体(メタクリル酸メチルとアクリルアミドとを85:15の共重合比(重量比)で共重合したもの、重量平均分子量65500)を100重量部としたこと以外は実施例3と同様にして、錠剤状光応答性ガス発生材料を得た。
実施例3で得られた光応答性ガス発生材料を、貧溶媒としてのメタノール中にスポッティングし、液滴状となったものを乾燥した後、メッシュで回収することにより微粒子状光応答性ガス発生材料を得た。光応答性ガス発生微粒子の粒子径は、走査電子顕微鏡(SEM)により観察した結果、約100μmであった。
実施例3で得られた光応答性ガス発生材料を、PETフィルム上にキャストにより塗布し、乾燥することによりフィルム状光応答性ガス発生材料を得た。乾燥後の光応答性ガス発生フィルムの厚みは約100μmであった。
光酸発生剤としての2,3,4,4’−テトラヒドロキシべンゾフェノン35重量部と、酸刺激ガス発生剤としての炭酸水素ナトリウム75重量部の代わりに、光の照射により分解するアゾ化合物として、2,2‘−アゾビスイソブチロニトリル110重量部を配合したこと以外は実施例2同様にして、の光応答性ガス発生材料を得た。
〔ガス発生量評価〕
紫外線透過性の石英ガラスで密閉されており、ガスが通るチューブ及びガス量測定用のメスピペットを備えるガス発生定量測定装置を用意した。該ガス発生定量測定装置は、チューブの一方から水を流し込み、メスピペットの基準線まで水を満たした状態を初期状態として、この初期状態からチャンバーから発生したガスにより変化する水位を計測するものである。
◎:1.5mL以上
○:1.0mL以上、1.5mL未満
△:0.5以上、1.0mL未満
×:0.5mL未満
結果を下記の表1に示す。
実施例1〜6及び比較例1で得られた光応答性ガス発生材料を、温度60℃に保たれた暗室に1週間放置した。その後、同様にして、ガス発生量を測定し、初期ガス発生量と比較した。
×:初期のガス発生量と比べガス発生量が80%以下となった。
2…基板
3…ベースプレート
4〜6…中間プレート
4a…貫通孔
6a…貫通孔
7…トッププレート
8,9…微細流路
10…マイクロポンプ
11…ガス発生室
12…光学窓
13…光応答性ガス発生材料
14…流路
17…反射部材
17a…貫通孔
18…測定セル
20…マイクロポンプ
21…光応答性ガス発生材料
31…マイクロ流体デバイス
32…基板
33…ベースプレート
33a…貫通孔
33b,33c…溝
34…中間プレート
34a…貫通孔
34b…溝
35…トッププレート
36…光応答性ガス発生部材
37…ガスバリア層
38,39…遮光層
102A…基板
103A…ベースプレート
104A〜106A…中間プレート
107A…トッププレート
108,109…微細流路
110…マイクロポンプ
111…ガス発生室
112…光学窓
113…光応答性ガス発生材料
131…マイクロ化学チップ
210…基板
210a…表面
210c…溝
214…マイクロ流路
214a…開口
220…ガス発生層
220a…連通孔
220b…溝
221…バリア層
221a…外周部
Claims (16)
- 基板内に微細流路が形成されているマイクロ流体デバイスのマイクロポンプに用いられる光応答性ガス発生材料であって、
光酸発生剤と、酸刺激ガス発生剤とを含むことを特徴とする、光応答性ガス発生材料。 - 酸刺激ガス発生剤の配合量が、光酸発生剤から発生する酸と化学等量以上の配合量である、請求項1記載の光応答性ガス発生材料。
- バインダー樹脂をさらに含む、請求項1又は2に記載の光応答性ガス発生材料。
- バインダー樹脂100重量部に対して、光酸発生剤10重量部〜300重量部、酸刺激ガス発生剤10重量部〜300重量部を含有する、請求項3記載の光応答性ガス発生材料。
- 基板内に微細流路が形成されているマイクロ流体デバイスのマイクロポンプに用いられる光応答性ガス発生材料であって、
コバルトアミン系錯体、カルバミン酸o−ニトロベンジル、オキシムエステル、下記の式(1)で表わされる光の照射によりアミンを発生させるカルバモイルオキシイミノ基含有化合物、及び下記の式(2)で表わされるカルボン酸(a1)と塩基性化合物(a2)との塩からなる群から選択された少なくとも1種である光塩基発生剤(A)と、
塩基増殖剤(B)とを含む、光応答性ガス発生材料。
- 塩基増殖剤の配合量が、光塩基発生剤100重量部に対して、50〜200重量部の配合量である、請求項5記載の光応答性ガス発生材料。
- アミノアルキル化合物(C)をさらに含む、請求項5又は6に記載の光応答性ガス発生材料。
- バインダー樹脂をさらに含む、請求項5〜7のいずれか1項に記載の光応答性ガス発生材料。
- バインダー樹脂100重量部に対して、それぞれ光塩基発生剤(A)20〜500重量部、塩基増殖剤(B)10〜1000重量部を含有する、請求項6記載の光応答性ガス発生材料。
- 錠剤状あるいは微粒子状あるいはフィルム状の形態である請求項1〜9記載のいずれか1項記載の光応答性ガス発生材料。
- 請求項1〜9のいずれか1項に記載の光応答ガス発生材料と、前記光応答ガス発生材料を支持する支持部材とを備える光応答性ガス発生部材。
- 基板内に微細流路が形成されているマイクロ流体デバイスに用いられるマイクロポンプであって、
前記マイクロポンプ内に請求項1〜10のいずれか1項に記載の光応答性ガス発生材料、該光応答性ガス発生材料からなる光応答性ガス発生錠剤、該光応答性ガス発生材料からなる光応答性ガス発生微粒子、及び該光応答性ガス発生材料からなる光応答性ガス発生フィルムの内の少なくとも1つが収納されていることを特徴とする、マイクロポンプ。 - 前記基板内に前記マイクロポンプを形成するためのガス発生室が形成されており、ガス発生室に臨むように、前記基板の一面に光学窓が設けられており、前記ガス発生室内に、前記光応答性ガス発生材料が収納されている、請求項11に記載のマイクロポンプ。
- 請求項1〜10のいずれか1項記載の光応答性ガス発生材料が、フィルム状光応答性ガス発生材料であり、前記基板にマイクロポンプを形成するために基板表面に開口しているガス発生部が形成されており、該ガス発生部が前記フィルム状光応答性ガス発生材料により閉成されるように、前記基板の表面に前記フィルム状光応答性ガス発生材料が貼付されている、マイクロポンプ。
- 基板内に微細流路が形成されているマイクロ流体デバイスであって、
前記基板が少なくとも2つの前記マイクロポンプが内蔵されている第1のプレートと、該第1のプレートに積層されており、かつ微細流路を構成するための溝もしくは貫通孔を有する第2のプレートとを有し、前記マイクロポンプが、駆動源として請求項1〜10のいずれか1項に記載の光応答性ガス発生材料を有するマイクロ流体デバイス。 - 前記微細流路が複数設けられており、平面視において、隣接する前記微細流路の開口相互間に設けられ、前記ガス発生部を遮光する遮光層をさらに備える、請求項13に記載のマイクロ流体デバイス。
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- 2009-03-11 KR KR1020127021671A patent/KR101276424B1/ko not_active IP Right Cessation
- 2009-03-11 EP EP09720375.6A patent/EP2258951B1/en active Active
- 2009-03-11 JP JP2009511287A patent/JP4454694B2/ja active Active
- 2009-03-11 WO PCT/JP2009/054622 patent/WO2009113566A1/ja active Application Filing
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JP2013010171A (ja) * | 2011-06-30 | 2013-01-17 | Sekisui Chem Co Ltd | マイクロポンプ及びマイクロ流体デバイス |
US8853292B2 (en) | 2012-04-05 | 2014-10-07 | Ricoh Company, Ltd. | Active ray curable composition, active ray curable ink composition for inkjet printing, active ray curable adhesive composition, and method for stabilizing active ray curable composition |
JP5162731B1 (ja) * | 2012-06-08 | 2013-03-13 | 積水化学工業株式会社 | ガス発生材及びマイクロポンプ |
WO2013183175A1 (ja) | 2012-06-08 | 2013-12-12 | 積水化学工業株式会社 | ガス発生材及びマイクロポンプ |
US8986630B2 (en) | 2012-06-08 | 2015-03-24 | Sekisui Chemical Co., Ltd. | Gas-generating material and micro pump |
WO2014061355A1 (ja) | 2012-10-15 | 2014-04-24 | 積水化学工業株式会社 | ガス発生材及びマイクロポンプ |
US10731062B2 (en) | 2012-10-15 | 2020-08-04 | Sekisui Chemical Co., Ltd. | Gas-generating material and micropump |
JP2014118325A (ja) * | 2012-12-17 | 2014-06-30 | Sekisui Chem Co Ltd | マイクロポンプ用ガス発生材及びマイクロポンプ |
JP2015054798A (ja) * | 2013-09-12 | 2015-03-23 | 積水化学工業株式会社 | マイクロポンプにおけるガスの発生方法 |
WO2022092150A1 (ja) * | 2020-11-02 | 2022-05-05 | 積水化学工業株式会社 | マイクロ流路チップ、細胞分析装置、細胞分析システム、及び細胞分析方法 |
Also Published As
Publication number | Publication date |
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KR20100137411A (ko) | 2010-12-30 |
JP4454694B2 (ja) | 2010-04-21 |
KR20120098967A (ko) | 2012-09-05 |
JPWO2009113566A1 (ja) | 2011-07-21 |
KR101276424B1 (ko) | 2013-06-19 |
WO2009113566A1 (ja) | 2009-09-17 |
EP2258951A1 (en) | 2010-12-08 |
CN101978173B (zh) | 2013-12-25 |
CN101978173A (zh) | 2011-02-16 |
KR101211292B1 (ko) | 2012-12-11 |
US20110014096A1 (en) | 2011-01-20 |
EP2258951A4 (en) | 2016-01-20 |
JP5530164B2 (ja) | 2014-06-25 |
US8771612B2 (en) | 2014-07-08 |
EP2258951B1 (en) | 2018-08-22 |
US20140134075A1 (en) | 2014-05-15 |
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