JP2014118325A - マイクロポンプ用ガス発生材及びマイクロポンプ - Google Patents
マイクロポンプ用ガス発生材及びマイクロポンプ Download PDFInfo
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- JP2014118325A JP2014118325A JP2012274874A JP2012274874A JP2014118325A JP 2014118325 A JP2014118325 A JP 2014118325A JP 2012274874 A JP2012274874 A JP 2012274874A JP 2012274874 A JP2012274874 A JP 2012274874A JP 2014118325 A JP2014118325 A JP 2014118325A
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- Prior art keywords
- gas generating
- generating material
- micropump
- gas
- mass
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Abstract
【解決手段】本発明に係るマイクロポンプ用ガス発生材11aは、マイクロポンプ1に用いられる。ガス発生材11aは、アクリル系粘着剤と、アゾ化合物又はアジド化合物であるガス発生剤と、タッキファイヤーとを含む。上記タッキファイヤーのハーゼン色数は200以下であり、かつSP値は8.5以上である。
【選択図】図1
Description
上記ガス発生材は上記アクリル系粘着剤を含む。上記ガス発生材が上記アクリル系粘着剤を含むことによって、上記ガス発生材を基材などの接着対象部材に接着させることができる。さらに、上記ガス発生材が上記アクリル系粘着剤を含むことによって、上記ガス発生材を錠剤状、微粒子状及びフィルム状等の形態とすることが容易になる。上記ガス発生材が錠剤状、微粒子状及びフィルム状等の形態であると、上記ガス発生材を接着対象部材に容易に接着させることができる。また、上記ガス発生剤を上記ガス発生材中に強固に保持することができる。上記アクリル系粘着剤は、上記ガス発生材において、バインダー樹脂として用いることができる。上記アクリル系粘着剤は、(メタ)アクリロイル基を有することが好ましい。上記(メタ)アクリロイル基は、アクリロイル基又はメタクリロイル基を示す。上記アクリル系粘着剤は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記ガス発生材は上記ガス発生剤を含む。上記ガス発生剤は、アゾ化合物又はアジド化合物である。上記ガス発生剤は、熱又は光等の外部刺激が加わった際にガスを発生させる。上記アゾ化合物又は上記アジド化合物は、特に限定されず、公知のアゾ化合物又はアジド化合物であってもよい。上記ガス発生剤は、上記アゾ化合物であることが好ましく、上記アジド化合物であることも好ましい。上記ガス発生剤は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記式(2−1)中、m+n=2〜20、m≧1、n≧1、q+r=10〜35、q≧5、r≧5であり、Aは、−OCH2CH2CH2CH2−、−OCH2CH2−、又はOCH2CH(CH3)−であり、Bは、−CH2CH(CH2N3)O−であり、R1は、−CH2CH2−、−CH2CH2CH2CH2−、−CH2CH(CH3)−、−[(CH2CH2O)xCH2CH2]−、又は[(CH2CH2CH2CH2O)yCH2CH2CH2CH2]−である。上記R1におけるxは10〜25、yは5〜20である。
上記ガス発生材は上記タッキファイヤーを含む。上記タッキファイヤーの使用により、ガス発生材の接着対象部材に対する初期接着力及び初期アンカー力がより一層高くなる。また、上記タッキファイヤーのハーゼン色数は200以下である。このため、ガス発生材の透明性が高くなる。上記タッキファイヤーのSP値は8.5以上である。このことによっても、タッキファイヤーと他の成分との相溶性が高くなり、ガス発生材の透明性が高くなる。
δ:溶解度パラメーター
D:密度
G:各官能基の分子引力定数
M:分子量
上記ガス発生材は、シランカップリング剤を含むことが好ましい。上記シランカップリング剤の使用により、ガス発生材の接着対象部材に対する初期接着力及び初期アンカー力がより一層高くなる。特に、上記タッキファイヤーと上記シランカップリング剤との併用は、ガス発生材の接着対象部材に対する初期接着力及び初期アンカー力の向上に大きく寄与する。さらに、上記タッキファイヤーと上記シランカップリング剤との併用は、ガス発生材におけるガスの発生に伴う接着力及びアンカー力の低下の抑制に大きく寄与する。上記シランカップリング剤は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記ガス発生材は、第三級アミンを含むことが好ましい。上記第三級アミンは特に限定されない。上記第三級アミンとしては、環状アミン、トリアルキルアミン及び芳香族アミン等が挙げられる。上記環状アミン及び上記芳香族アミンはそれぞれ、第三級アミンの構造を有する。
上記ガス発生材は、光増感剤を含むことが好ましい。上記光増感剤は、ガス発生剤への光による刺激を増幅する効果を有する。よって、上記ガス発生材が光増感剤を含むことにより、少ない光照射量によって、ガスを発生させ、放出させることができる。また、より広い波長領域の光によって、ガスを発生させ、放出させることができる。上記光増感剤は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記ガス発生材は、架橋剤及び無機充填材等を含んでもいてもよい。上記ガス発生材は、上記架橋剤を含むことがより好ましい。但し、上記ガス発生材は、上記架橋剤を含んでいなくてもよい。上記架橋剤の使用により、上記ガス発生材の初期接着力がより一層高くなる。
図2は、本発明の第2の実施形態に係るマイクロポンプの略図的断面図である。
n−ブチルアクリレート(日本触媒社製)96質量部と、アクリル酸(日本触媒社製)4質量部と、イルガキュア907(長瀬産業社製)0.05質量部と、酢酸エチル200質量部とを混合して、混合物を得た。次に、この混合物に、紫外線を4時間照射して、アクリル共重合体であるアクリル系粘着剤Aを作製した。バインダー樹脂Aの重量平均分子量は、約61万であった。得られたアクリル系粘着剤AのSP値は7以上、10.5以下の範囲内である。
GAP4006(グリシジルアジドポリマー、日油社製)
ロジンエステル樹脂1(荒川化学社製「パインエステルKE359」、ハーゼン色数40、水酸基価44、SP値8.86)
変性テルペン樹脂(ヤスハラケミカル社製「YSレジンTR105」、ハーゼン色数120、SP値8.73)
スチレン樹脂(ヤスハラケミカル社製「YSレジンSX100」、ハーゼン色数60、SP値9.14)
テルペンフェノール樹脂1(ヤスハラケミカル社製「YSレジスターTH130」、ハーゼン色数40、SP値8.82)
フェノール性アルファメチルスチレン(アリゾナケミカル社製「Sylvares 600」、ハーゼン色数60、水酸基価22、SP値8.56)
テルペンフェノール樹脂2(荒川化学社製「パインエステルKE311」、ハーゼン色数40、水酸基価0、SP値8.1)
ロジンエステル樹脂2(ヤスハラケミカル社製「YSポリスター K125」、ハーゼン色数1000以上、SP値8.49)
N−2−(アミノエチル)−3−アミノプロピルメチルジメトキシシラン(アミノ基を有するシランカップリング剤、信越化学工業社製「KBM−602」)
光増感剤:2−イソプロピルチオキサントン(DKSHジャパン社製「IPX」)
架橋剤:N,N,N’,N’−テトラグリシジル−1,3−ベンゼンジ(メタンアミン)(綜研化学社製「E−AX」、トルエン5%液)
第三級アミン:トリプロピルアミン(トリn−プロピルアミン)
アクリル系粘着剤A95質量部と溶剤である酢酸エチル567質量部とを配合した。アクリル系粘着剤A95質量部(但し、溶剤である酢酸エチル567質量部をアクリル系粘着剤Aと共に配合してある)と、ガス発生剤であるGAP4006(グリシジルアジドポリマー、日油社製)110質量部と、アミノ基を有するシランカップリング剤であるN−2−(アミノエチル)−3−アミノプロピルメチルジメトキシシラン(信越化学工業社製「KBM−602」)0.001質量部と、第三級アミンであるトリプロピルアミン(トリn−プロピルアミン)5質量部と、光増感剤である2−イソプロピルチオキサントン(DKSHジャパン社製「IPX」)3.5質量部と、架橋剤であるN,N,N’,N’−テトラグリシジル−1,3−ベンゼンジ(メタンアミン)(綜研化学社製「E−AX」、トルエン5%液)2質量部とを混合し、フィルム状に加工した。このフィルムを110℃で5分間加熱して、溶剤である酢酸エチルを除去した。これを離型PETフィルムで保護し、常温で一日(24時間)保管して、フィルム状のガス発生材を得た。
配合成分の種類及び配合量(単位は質量部)を下記の表1に示すように変更したこと以外は実施例1と同様にして、ガス発生材を得て、マイクロポンプを作製した。なお、下記の表1では、フィルム状のガス発生材を得る際に揮発により除去される溶剤の使用量の記載は省略した。
(1)ガス発生量
ガス発生量の測定では、得られたマイクロポンプにおいて、380nmの紫外線LED(ナイトレイドセミコンダクター社製「NS375L−5RFS」)を120秒間照射したときのガスの発生量を測定した。ガス発生量の測定方法は、マイクロ流路10bとメスピペットとをシリコンチューブでつなぎ、この中を水で充填し、その後、ガス発生材に紫外線を照射し、発生したガスによるメスピペットの体積変化を読み取る方法とした。
上記(1)ガス発生量の評価と同様にガス発生量の試験を行った。上記メスピペットの先端に内径100μ長さ10cmの細い管を取り付け、マイクロ流路の先端にガスの噴き出しを止める抵抗を取り付け、ガス溜まりの確認を行った。ガス溜まりとは、光を照射した面積よりも更に広い範囲にガスが発生しているように見える現象である。上記(1)ガス発生量の評価と同様にガス発生量の試験を行い、テープのガス溜まりの様子を観察した。
図3に示すように、ポリカーボネート板51に対して、フィルム状のガス発生材52を貼り付けた。その状態で、接着力を評価した。
図4に示すように、セロファンテープ61(基材61Aと粘着層61Bとを有する)の粘着層61B面と、得られたフィルム状のガス発生材62とを互いに貼り合わせた。その状態で、アンカー力を評価した。
得られたガス発生材の外観を目視で観察した。
10…基材
10a…主面
10b…マイクロ流路
10c…ポンプ室
11a、11b…ガス発生材
12…ガスバリア層
21…光照射装置
Claims (7)
- マイクロポンプに用いられるガス発生材であって、
アクリル系粘着剤と、
アゾ化合物又はアジド化合物であるガス発生剤と、
タッキファイヤーとを含み、
前記タッキファイヤーのハーゼン色数が200以下であり、かつSP値が8.5以上である、マイクロポンプ用ガス発生材。 - 前記アクリル系粘着剤100質量部に対して、前記タッキファイヤーの含有量が3質量部以上、35質量部以下である、請求項1に記載のマイクロポンプ用ガス発生材。
- 前記タッキファイヤーがロジンエステル樹脂である、請求項1又は2に記載のマイクロポンプ用ガス発生材。
- シランカップリング剤をさらに含む、請求項1〜3のいずれか1項に記載のマイクロポンプ用ガス発生材。
- 前記タッキファイヤーがロジンエステル樹脂であり、かつ前記ロジンエステル樹脂の水酸基価が20以上である、請求項1〜4のいずれか1項に記載のマイクロポンプ用ガス発生材。
- 前記アクリル系粘着剤100質量部に対して、前記タッキファイヤーの含有量が3質量部以上、15質量部以下である、請求項1〜5のいずれか1項に記載のマイクロポンプ用ガス発生材。
- 請求項1〜6のいずれか1項に記載のマイクロポンプ用ガス発生材と、
マイクロ流路が形成された基材とを備え、
前記マイクロポンプ用ガス発生材は、前記マイクロポンプ用ガス発生材において発生したガスが前記マイクロ流路に供給されるように配されている、マイクロポンプ。
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