JP2009545548A5 - - Google Patents
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- Publication number
- JP2009545548A5 JP2009545548A5 JP2009522186A JP2009522186A JP2009545548A5 JP 2009545548 A5 JP2009545548 A5 JP 2009545548A5 JP 2009522186 A JP2009522186 A JP 2009522186A JP 2009522186 A JP2009522186 A JP 2009522186A JP 2009545548 A5 JP2009545548 A5 JP 2009545548A5
- Authority
- JP
- Japan
- Prior art keywords
- range
- zsm
- zeolite
- catalyst
- hydrodealkylation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims 15
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 7
- 229910021536 Zeolite Inorganic materials 0.000 claims 6
- 239000010457 zeolite Substances 0.000 claims 6
- 239000003054 catalyst Substances 0.000 claims 5
- 229910052751 metal Inorganic materials 0.000 claims 5
- 239000002184 metal Substances 0.000 claims 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 5
- 239000000203 mixture Substances 0.000 claims 4
- 239000004215 Carbon black (E152) Substances 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- 125000001931 aliphatic group Chemical group 0.000 claims 3
- -1 alkyl aromatic compound Chemical class 0.000 claims 3
- 229930195733 hydrocarbon Natural products 0.000 claims 3
- 150000002430 hydrocarbons Chemical class 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 claims 2
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 claims 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical group CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 239000011230 binding agent Substances 0.000 claims 2
- 238000003763 carbonization Methods 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 238000005470 impregnation Methods 0.000 claims 2
- 229910052697 platinum Inorganic materials 0.000 claims 2
- UOHMMEJUHBCKEE-UHFFFAOYSA-N prehnitene Chemical compound CC1=CC=C(C)C(C)=C1C UOHMMEJUHBCKEE-UHFFFAOYSA-N 0.000 claims 2
- ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical compound CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 claims 2
- VIDOPANCAUPXNH-UHFFFAOYSA-N 1,2,3-triethylbenzene Chemical compound CCC1=CC=CC(CC)=C1CC VIDOPANCAUPXNH-UHFFFAOYSA-N 0.000 claims 1
- BAMWORSGQSUNSC-UHFFFAOYSA-N 1-ethyl-2,3,4-trimethylbenzene Chemical compound CCC1=CC=C(C)C(C)=C1C BAMWORSGQSUNSC-UHFFFAOYSA-N 0.000 claims 1
- QUBBAXISAHIDNM-UHFFFAOYSA-N 1-ethyl-2,3-dimethylbenzene Chemical group CCC1=CC=CC(C)=C1C QUBBAXISAHIDNM-UHFFFAOYSA-N 0.000 claims 1
- HYFLWBNQFMXCPA-UHFFFAOYSA-N 1-ethyl-2-methylbenzene Chemical compound CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 1
- 235000018936 Vitellaria paradoxa Nutrition 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 125000002723 alicyclic group Chemical group 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 1
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 239000006185 dispersion Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- NZFVWAOONXJZIQ-UHFFFAOYSA-N heptan-4-ylbenzene Chemical compound CCCC(CCC)C1=CC=CC=C1 NZFVWAOONXJZIQ-UHFFFAOYSA-N 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 claims 1
- 238000005342 ion exchange Methods 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 150000002751 molybdenum Chemical class 0.000 claims 1
- ZMCCBULBRKMZTH-UHFFFAOYSA-N molybdenum platinum Chemical compound [Mo].[Pt] ZMCCBULBRKMZTH-UHFFFAOYSA-N 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 150000002894 organic compounds Chemical class 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims 1
- 238000000197 pyrolysis Methods 0.000 claims 1
- 239000012266 salt solution Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 claims 1
- 238000004230 steam cracking Methods 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 238000007740 vapor deposition Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
- 229910001928 zirconium oxide Inorganic materials 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2006A001548 | 2006-08-03 | ||
| IT001548A ITMI20061548A1 (it) | 2006-08-03 | 2006-08-03 | Composizioni catalitiche per idrodealchilazioni altamente selettive di idrocarburi alchilaromatici |
| PCT/EP2007/006984 WO2008015027A1 (en) | 2006-08-03 | 2007-08-02 | Catalytic compositions for the highly selective hydrodealkylation of alkylaromatic hydrocarbons |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009545548A JP2009545548A (ja) | 2009-12-24 |
| JP2009545548A5 true JP2009545548A5 (enExample) | 2010-09-16 |
| JP5456466B2 JP5456466B2 (ja) | 2014-03-26 |
Family
ID=37993637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009522186A Expired - Fee Related JP5456466B2 (ja) | 2006-08-03 | 2007-08-02 | アルキル芳香族炭化水素の非常に選択的な水素化脱アルキル化のための触媒組成物 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8168844B2 (enExample) |
| EP (1) | EP2046920B1 (enExample) |
| JP (1) | JP5456466B2 (enExample) |
| CN (1) | CN101517043B (enExample) |
| EA (1) | EA016750B1 (enExample) |
| ES (1) | ES2589592T3 (enExample) |
| HU (1) | HUE030013T2 (enExample) |
| IT (1) | ITMI20061548A1 (enExample) |
| PL (1) | PL2046920T3 (enExample) |
| WO (1) | WO2008015027A1 (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9174892B2 (en) | 2010-01-19 | 2015-11-03 | Uop Llc | Process for increasing a mole ratio of methyl to phenyl |
| US8598395B2 (en) * | 2010-01-19 | 2013-12-03 | Uop Llc | Process for increasing a mole ratio of methyl to phenyl |
| CN102781889B (zh) * | 2010-02-03 | 2015-11-25 | 埃克森美孚化学专利公司 | 重质芳族烃原料的烷基转移 |
| KR101359973B1 (ko) * | 2011-12-27 | 2014-02-12 | 주식회사 포스코 | 방향족 화합물로부터 자일렌 생산을 위한 트랜스 알킬화 촉매 |
| WO2013182534A1 (en) | 2012-06-05 | 2013-12-12 | Saudi Basic Industries Corporation | Process for producing btx from a c5-c12 hydrocarbon mixture |
| CN103657708A (zh) * | 2012-09-07 | 2014-03-26 | 中国石油天然气集团公司 | 一种用于催化汽油芳构化改质的催化剂 |
| US10793491B2 (en) | 2014-06-13 | 2020-10-06 | Sabic Global Technologies B.V. | Process for producing benzene from C5-C12 hydrocarbon mixture |
| CN106661465B (zh) | 2014-06-13 | 2019-06-14 | Sabic环球技术有限责任公司 | 由c5-c12烃混合物生产苯的方法 |
| US10501388B2 (en) | 2015-08-21 | 2019-12-10 | Sabic Global Technologies B.V. | Process for producing BTX from a C5—C12 hydrocarbon mixture |
| EP3176243A1 (en) | 2015-12-03 | 2017-06-07 | SABIC Global Technologies B.V. | Process for preparing a hydrocracking catalyst |
| US10865348B2 (en) | 2016-07-13 | 2020-12-15 | Sabic Global Technologies B.V. | Process which does simultaneous dehydrochlorination and hydrocracking of pyrolysis oils from mixed plastic pyrolysis while achieving selective hydrodealkylation of C9+ aromatics |
| US20180019165A1 (en) | 2016-07-14 | 2018-01-18 | Entegris, Inc. | CVD Mo DEPOSITION BY USING MoOCl4 |
| EP3458190A1 (en) | 2016-08-02 | 2019-03-27 | SABIC Global Technologies B.V. | Process for preparing hydrocracking catalyst |
| US10093873B2 (en) | 2016-09-06 | 2018-10-09 | Saudi Arabian Oil Company | Process to recover gasoline and diesel from aromatic complex bottoms |
| CN109689842B (zh) | 2016-09-12 | 2021-01-29 | 沙特基础工业全球技术有限公司 | 加氢裂化方法 |
| CN110088244A (zh) | 2016-10-17 | 2019-08-02 | 沙特基础全球技术有限公司 | 由c5-c12烃混合物生产btx的方法 |
| WO2018104382A1 (en) * | 2016-12-08 | 2018-06-14 | Shell Internationale Research Maatschappij B.V. | Process for preparing a molybdenum-platinum-based catalyst for the synthesis of benzene by transalkylation |
| US10053401B1 (en) | 2017-02-16 | 2018-08-21 | Saudi Arabian Oil Company | Process for recovery of light alkyl mono-aromatic compounds from heavy alkyl aromatic and alkyl-bridged non-condensed alkyl aromatic compounds |
| US10508066B2 (en) | 2017-02-16 | 2019-12-17 | Saudi Arabian Oil Company | Methods and systems of upgrading heavy aromatics stream to petrochemical feedstock |
| US11279663B2 (en) | 2017-02-16 | 2022-03-22 | Saudi Arabian Oil Company | Methods and systems of upgrading heavy aromatics stream to petrochemical feedstock |
| US11066344B2 (en) | 2017-02-16 | 2021-07-20 | Saudi Arabian Oil Company | Methods and systems of upgrading heavy aromatics stream to petrochemical feedstock |
| EP3834931A1 (en) * | 2018-03-14 | 2021-06-16 | Saudi Arabian Oil Company | Composite zeolite catalysts for heavy reformate conversion into xylenes |
| JP2020196685A (ja) * | 2019-06-04 | 2020-12-10 | 東ソー株式会社 | ベンゼン製造用触媒システム及びそれを用いたベンゼンの製造方法 |
| CN112237941A (zh) * | 2019-07-19 | 2021-01-19 | 国家能源投资集团有限责任公司 | 芳构化催化剂及其制备方法和低碳烯烃芳构化方法 |
| US10899685B1 (en) | 2019-10-07 | 2021-01-26 | Saudi Arabian Oil Company | Catalytic hydrodearylation of heavy aromatic stream containing dissolved hydrogen |
| US11267769B2 (en) | 2019-10-07 | 2022-03-08 | Saudi Arabian Oil Company | Catalytic hydrodearylation of heavy aromatic streams containing dissolved hydrogen with fractionation |
| CN114426456B (zh) * | 2020-10-10 | 2024-08-30 | 中国石油化工股份有限公司 | 苯与重芳烃烷基转移和甲苯甲基化的组合工艺 |
| US11613714B2 (en) | 2021-01-13 | 2023-03-28 | Saudi Arabian Oil Company | Conversion of aromatic complex bottoms to useful products in an integrated refinery process |
| JP2022127708A (ja) * | 2021-02-22 | 2022-09-01 | 東ソー株式会社 | ベンゼンの製造方法 |
| US11591526B1 (en) | 2022-01-31 | 2023-02-28 | Saudi Arabian Oil Company | Methods of operating fluid catalytic cracking processes to increase coke production |
| CN115007199A (zh) * | 2022-05-19 | 2022-09-06 | 化学与精细化工广东省实验室 | 一种碳九及以上重质芳烃加氢脱烷基催化剂及其制备方法 |
| CN117138811A (zh) * | 2022-05-23 | 2023-12-01 | 中国石油化工股份有限公司 | 加氢脱烷基催化剂及其制备方法和应用 |
| CN119680527B (zh) * | 2024-11-28 | 2025-12-16 | 甬江实验室 | 负载型碱金属氢化物作为芳烃加氢脱烷基化反应催化剂的应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3992468A (en) * | 1974-03-01 | 1976-11-16 | Institut Francais Du Petrole, Des Carburants Et Lubrifiants Et Entreprise De Recherches Et D'activities Petrolieres Elf | Process for the catalytic hydrodealkylation of alkylaromatic hydrocarbons |
| JPS55129232A (en) | 1979-03-29 | 1980-10-06 | Teijin Yuka Kk | Isomerization of xylenes |
| JPS56147636A (en) * | 1980-04-17 | 1981-11-16 | Teijin Yuka Kk | Isomerization method for xylenes and its catalyst composition |
| CA1227809A (en) * | 1983-10-17 | 1987-10-06 | Nancy A. Kutz | Modification of hydrocarbon conversion processes over crystalline aluminosilicate zeolite-based catalysts by incorporation of a molybdenum compound |
| US4899011A (en) * | 1986-01-15 | 1990-02-06 | Mobil Oil Corporation | Xylene isomerization process to exhaustively convert ethylbenzene and non-aromatics |
| US4899012A (en) * | 1988-10-17 | 1990-02-06 | Uop | Catalyst for the isomerization of aromatics |
| DE69031214T2 (de) * | 1989-12-13 | 1998-02-26 | Mobil Oil Corporation, New York, N.Y. | Verfahren zur katalytischen konversion einer c9+ -aromatischen charge |
| US5877374A (en) * | 1997-04-02 | 1999-03-02 | Chevron Chemical Company | Low pressure hydrodealkylation of ethylbenzene and xylene isomerization |
| US7148391B1 (en) * | 2002-11-14 | 2006-12-12 | Exxonmobil Chemical Patents Inc. | Heavy aromatics processing |
| ITMI20040077A1 (it) * | 2004-01-22 | 2004-04-22 | Polimeri Europa Spa | Procedimento per la idrodealchilazione catalitica di idrocarburi alchilaromatici |
| ITMI20040554A1 (it) | 2004-03-23 | 2004-06-23 | Polimeri Europa Spa | Procedimento per la idrodealchilazione catalitica selettiva di idrocarburi alchilaromatici |
-
2006
- 2006-08-03 IT IT001548A patent/ITMI20061548A1/it unknown
-
2007
- 2007-08-02 PL PL07801540T patent/PL2046920T3/pl unknown
- 2007-08-02 EP EP07801540.1A patent/EP2046920B1/en active Active
- 2007-08-02 WO PCT/EP2007/006984 patent/WO2008015027A1/en not_active Ceased
- 2007-08-02 ES ES07801540.1T patent/ES2589592T3/es active Active
- 2007-08-02 CN CN200780035892.7A patent/CN101517043B/zh active Active
- 2007-08-02 EA EA200900205A patent/EA016750B1/ru not_active IP Right Cessation
- 2007-08-02 US US12/375,830 patent/US8168844B2/en active Active
- 2007-08-02 JP JP2009522186A patent/JP5456466B2/ja not_active Expired - Fee Related
- 2007-08-02 HU HUE07801540A patent/HUE030013T2/hu unknown
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