CN101517043B - 用于烷基芳族烃的高选择性加氢脱烷基化的催化组合物 - Google Patents
用于烷基芳族烃的高选择性加氢脱烷基化的催化组合物 Download PDFInfo
- Publication number
- CN101517043B CN101517043B CN200780035892.7A CN200780035892A CN101517043B CN 101517043 B CN101517043 B CN 101517043B CN 200780035892 A CN200780035892 A CN 200780035892A CN 101517043 B CN101517043 B CN 101517043B
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- CN
- China
- Prior art keywords
- catalyst
- hydrodealkylation
- zsm
- zeolite
- platinum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
- C10G47/18—Crystalline alumino-silicate carriers the catalyst containing platinum group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1096—Aromatics or polyaromatics
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2006A001548 | 2006-08-03 | ||
| IT001548A ITMI20061548A1 (it) | 2006-08-03 | 2006-08-03 | Composizioni catalitiche per idrodealchilazioni altamente selettive di idrocarburi alchilaromatici |
| PCT/EP2007/006984 WO2008015027A1 (en) | 2006-08-03 | 2007-08-02 | Catalytic compositions for the highly selective hydrodealkylation of alkylaromatic hydrocarbons |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101517043A CN101517043A (zh) | 2009-08-26 |
| CN101517043B true CN101517043B (zh) | 2013-08-14 |
Family
ID=37993637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200780035892.7A Active CN101517043B (zh) | 2006-08-03 | 2007-08-02 | 用于烷基芳族烃的高选择性加氢脱烷基化的催化组合物 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8168844B2 (enExample) |
| EP (1) | EP2046920B1 (enExample) |
| JP (1) | JP5456466B2 (enExample) |
| CN (1) | CN101517043B (enExample) |
| EA (1) | EA016750B1 (enExample) |
| ES (1) | ES2589592T3 (enExample) |
| HU (1) | HUE030013T2 (enExample) |
| IT (1) | ITMI20061548A1 (enExample) |
| PL (1) | PL2046920T3 (enExample) |
| WO (1) | WO2008015027A1 (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9174892B2 (en) | 2010-01-19 | 2015-11-03 | Uop Llc | Process for increasing a mole ratio of methyl to phenyl |
| US8598395B2 (en) * | 2010-01-19 | 2013-12-03 | Uop Llc | Process for increasing a mole ratio of methyl to phenyl |
| SG191570A1 (en) * | 2010-02-03 | 2013-07-31 | Exxonmobil Chem Patents Inc | Transalkylation of heavy aromatic hydrocarbon feedstocks |
| KR101359973B1 (ko) * | 2011-12-27 | 2014-02-12 | 주식회사 포스코 | 방향족 화합물로부터 자일렌 생산을 위한 트랜스 알킬화 촉매 |
| CN104395436B (zh) * | 2012-06-05 | 2016-10-05 | 沙特基础工业公司 | 由c5-c12烃混合物生产btx的方法 |
| CN103657708A (zh) * | 2012-09-07 | 2014-03-26 | 中国石油天然气集团公司 | 一种用于催化汽油芳构化改质的催化剂 |
| SG11201609049VA (en) | 2014-06-13 | 2016-12-29 | Sabic Global Technologies Bv | Process for producing benzene from a c5-c12 hydrocarbon mixture |
| EP3155072B1 (en) | 2014-06-13 | 2020-05-27 | SABIC Global Technologies B.V. | Process for producing benzene from a c5-c12 hydrocarbon mixture |
| CN107922292A (zh) | 2015-08-21 | 2018-04-17 | 沙特基础工业全球技术有限公司 | 用于由c5‑c12烃混合物生产btx的方法 |
| EP3176243A1 (en) | 2015-12-03 | 2017-06-07 | SABIC Global Technologies B.V. | Process for preparing a hydrocracking catalyst |
| JP6999637B2 (ja) * | 2016-07-13 | 2022-01-18 | サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ | 炭素数9以上の芳香族化合物類の選択的水素化脱アルキル化を達成しつつ、混合プラスチック熱分解からの熱分解油の脱塩化水素と水素化クラッキングを同時に行う方法 |
| CN109661481B (zh) | 2016-07-14 | 2021-11-30 | 恩特格里斯公司 | 使用MoOC14的CVD Mo沉积 |
| US10710058B2 (en) | 2016-08-02 | 2020-07-14 | Sabic Global Technologies B.V. | Process for preparing hydrocracking catalyst |
| US10093873B2 (en) | 2016-09-06 | 2018-10-09 | Saudi Arabian Oil Company | Process to recover gasoline and diesel from aromatic complex bottoms |
| WO2018047093A1 (en) | 2016-09-12 | 2018-03-15 | Sabic Global Technologies B.V. | Hydrocracking process |
| EA201990982A1 (ru) | 2016-10-17 | 2019-10-31 | Способ получения бтк из смеси углеводородов с5-с12 | |
| RU2757851C2 (ru) * | 2016-12-08 | 2021-10-21 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения катализатора на основе молибдена и платины для синтеза бензола путем трансалкилирования |
| US10053401B1 (en) | 2017-02-16 | 2018-08-21 | Saudi Arabian Oil Company | Process for recovery of light alkyl mono-aromatic compounds from heavy alkyl aromatic and alkyl-bridged non-condensed alkyl aromatic compounds |
| US10508066B2 (en) | 2017-02-16 | 2019-12-17 | Saudi Arabian Oil Company | Methods and systems of upgrading heavy aromatics stream to petrochemical feedstock |
| US11066344B2 (en) | 2017-02-16 | 2021-07-20 | Saudi Arabian Oil Company | Methods and systems of upgrading heavy aromatics stream to petrochemical feedstock |
| US11279663B2 (en) | 2017-02-16 | 2022-03-22 | Saudi Arabian Oil Company | Methods and systems of upgrading heavy aromatics stream to petrochemical feedstock |
| EP3834931A1 (en) * | 2018-03-14 | 2021-06-16 | Saudi Arabian Oil Company | Composite zeolite catalysts for heavy reformate conversion into xylenes |
| JP2020196685A (ja) * | 2019-06-04 | 2020-12-10 | 東ソー株式会社 | ベンゼン製造用触媒システム及びそれを用いたベンゼンの製造方法 |
| CN112237941A (zh) * | 2019-07-19 | 2021-01-19 | 国家能源投资集团有限责任公司 | 芳构化催化剂及其制备方法和低碳烯烃芳构化方法 |
| US11267769B2 (en) | 2019-10-07 | 2022-03-08 | Saudi Arabian Oil Company | Catalytic hydrodearylation of heavy aromatic streams containing dissolved hydrogen with fractionation |
| US10899685B1 (en) | 2019-10-07 | 2021-01-26 | Saudi Arabian Oil Company | Catalytic hydrodearylation of heavy aromatic stream containing dissolved hydrogen |
| CN114426456B (zh) * | 2020-10-10 | 2024-08-30 | 中国石油化工股份有限公司 | 苯与重芳烃烷基转移和甲苯甲基化的组合工艺 |
| US11613714B2 (en) | 2021-01-13 | 2023-03-28 | Saudi Arabian Oil Company | Conversion of aromatic complex bottoms to useful products in an integrated refinery process |
| JP2022127708A (ja) * | 2021-02-22 | 2022-09-01 | 東ソー株式会社 | ベンゼンの製造方法 |
| US11591526B1 (en) | 2022-01-31 | 2023-02-28 | Saudi Arabian Oil Company | Methods of operating fluid catalytic cracking processes to increase coke production |
| CN115007199A (zh) * | 2022-05-19 | 2022-09-06 | 化学与精细化工广东省实验室 | 一种碳九及以上重质芳烃加氢脱烷基催化剂及其制备方法 |
| CN117138811A (zh) * | 2022-05-23 | 2023-12-01 | 中国石油化工股份有限公司 | 加氢脱烷基催化剂及其制备方法和应用 |
| CN119680527B (zh) * | 2024-11-28 | 2025-12-16 | 甬江实验室 | 负载型碱金属氢化物作为芳烃加氢脱烷基化反应催化剂的应用 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4331822A (en) * | 1979-03-29 | 1982-05-25 | Teijin Petrochemical Industries Ltd. | Isomerization of xylene |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3992468A (en) * | 1974-03-01 | 1976-11-16 | Institut Francais Du Petrole, Des Carburants Et Lubrifiants Et Entreprise De Recherches Et D'activities Petrolieres Elf | Process for the catalytic hydrodealkylation of alkylaromatic hydrocarbons |
| JPS56147636A (en) * | 1980-04-17 | 1981-11-16 | Teijin Yuka Kk | Isomerization method for xylenes and its catalyst composition |
| CA1227809A (en) | 1983-10-17 | 1987-10-06 | Nancy A. Kutz | Modification of hydrocarbon conversion processes over crystalline aluminosilicate zeolite-based catalysts by incorporation of a molybdenum compound |
| US4899011A (en) * | 1986-01-15 | 1990-02-06 | Mobil Oil Corporation | Xylene isomerization process to exhaustively convert ethylbenzene and non-aromatics |
| US4899012A (en) * | 1988-10-17 | 1990-02-06 | Uop | Catalyst for the isomerization of aromatics |
| WO1991008998A1 (en) * | 1989-12-13 | 1991-06-27 | Mobil Oil Corporation | A process for the catalytic conversion of a c9+ aromatics feed |
| US5877374A (en) * | 1997-04-02 | 1999-03-02 | Chevron Chemical Company | Low pressure hydrodealkylation of ethylbenzene and xylene isomerization |
| US7148391B1 (en) * | 2002-11-14 | 2006-12-12 | Exxonmobil Chemical Patents Inc. | Heavy aromatics processing |
| ITMI20040077A1 (it) * | 2004-01-22 | 2004-04-22 | Polimeri Europa Spa | Procedimento per la idrodealchilazione catalitica di idrocarburi alchilaromatici |
| ITMI20040554A1 (it) * | 2004-03-23 | 2004-06-23 | Polimeri Europa Spa | Procedimento per la idrodealchilazione catalitica selettiva di idrocarburi alchilaromatici |
-
2006
- 2006-08-03 IT IT001548A patent/ITMI20061548A1/it unknown
-
2007
- 2007-08-02 CN CN200780035892.7A patent/CN101517043B/zh active Active
- 2007-08-02 EA EA200900205A patent/EA016750B1/ru not_active IP Right Cessation
- 2007-08-02 WO PCT/EP2007/006984 patent/WO2008015027A1/en not_active Ceased
- 2007-08-02 EP EP07801540.1A patent/EP2046920B1/en active Active
- 2007-08-02 US US12/375,830 patent/US8168844B2/en active Active
- 2007-08-02 JP JP2009522186A patent/JP5456466B2/ja not_active Expired - Fee Related
- 2007-08-02 ES ES07801540.1T patent/ES2589592T3/es active Active
- 2007-08-02 HU HUE07801540A patent/HUE030013T2/hu unknown
- 2007-08-02 PL PL07801540T patent/PL2046920T3/pl unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4331822A (en) * | 1979-03-29 | 1982-05-25 | Teijin Petrochemical Industries Ltd. | Isomerization of xylene |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2589592T3 (es) | 2016-11-15 |
| ITMI20061548A1 (it) | 2008-02-04 |
| EP2046920A1 (en) | 2009-04-15 |
| JP5456466B2 (ja) | 2014-03-26 |
| CN101517043A (zh) | 2009-08-26 |
| JP2009545548A (ja) | 2009-12-24 |
| EA016750B1 (ru) | 2012-07-30 |
| EA200900205A1 (ru) | 2009-08-28 |
| US8168844B2 (en) | 2012-05-01 |
| WO2008015027A8 (en) | 2008-04-17 |
| HUE030013T2 (hu) | 2017-04-28 |
| US20090272672A1 (en) | 2009-11-05 |
| EP2046920B1 (en) | 2016-06-08 |
| WO2008015027A1 (en) | 2008-02-07 |
| PL2046920T3 (pl) | 2017-03-31 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |