JP2009513792A - シクロブタンジオール及び少なくとも1種の燐化合物を含むポリエステル組成物 - Google Patents
シクロブタンジオール及び少なくとも1種の燐化合物を含むポリエステル組成物 Download PDFInfo
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- JP2009513792A JP2009513792A JP2008538015A JP2008538015A JP2009513792A JP 2009513792 A JP2009513792 A JP 2009513792A JP 2008538015 A JP2008538015 A JP 2008538015A JP 2008538015 A JP2008538015 A JP 2008538015A JP 2009513792 A JP2009513792 A JP 2009513792A
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- polyester
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- dicarboxylic acid
- polyester composition
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- 229920000728 polyester Polymers 0.000 title claims abstract description 1364
- 239000000203 mixture Substances 0.000 title claims abstract description 535
- -1 phosphorus compound Chemical class 0.000 title claims abstract description 302
- 229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 237
- 239000011574 phosphorus Substances 0.000 title claims abstract description 237
- NBBUYPNTAABDEY-UHFFFAOYSA-N cyclobutane-1,1-diol Chemical compound OC1(O)CCC1 NBBUYPNTAABDEY-UHFFFAOYSA-N 0.000 title description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 1150
- FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical group CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 claims abstract description 584
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical group OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 claims abstract description 562
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 524
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 claims abstract description 400
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 323
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 251
- KKEYFWRCBNTPAC-UHFFFAOYSA-N terephthalic acid group Chemical group C(C1=CC=C(C(=O)O)C=C1)(=O)O KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 247
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 210
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 209
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 200
- 239000011541 reaction mixture Substances 0.000 claims description 179
- 238000000034 method Methods 0.000 claims description 110
- 229910019142 PO4 Inorganic materials 0.000 claims description 50
- 150000002148 esters Chemical class 0.000 claims description 49
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 48
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 48
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 46
- 239000000047 product Substances 0.000 claims description 44
- 125000004437 phosphorous atom Chemical group 0.000 claims description 42
- 239000003054 catalyst Substances 0.000 claims description 41
- 238000004519 manufacturing process Methods 0.000 claims description 41
- 239000010452 phosphate Substances 0.000 claims description 40
- 238000010438 heat treatment Methods 0.000 claims description 33
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 31
- 150000003606 tin compounds Chemical class 0.000 claims description 31
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 28
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 26
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 claims description 24
- 229920000515 polycarbonate Polymers 0.000 claims description 23
- 239000004417 polycarbonate Substances 0.000 claims description 23
- 239000006085 branching agent Substances 0.000 claims description 21
- 229920000642 polymer Polymers 0.000 claims description 20
- 238000002425 crystallisation Methods 0.000 claims description 19
- 239000011701 zinc Substances 0.000 claims description 18
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 16
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 16
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 16
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 16
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 16
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 16
- 229910052787 antimony Inorganic materials 0.000 claims description 16
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 16
- 229910017052 cobalt Inorganic materials 0.000 claims description 16
- 239000010941 cobalt Substances 0.000 claims description 16
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 16
- 229910052733 gallium Inorganic materials 0.000 claims description 16
- 229910052732 germanium Inorganic materials 0.000 claims description 16
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 16
- 229910052744 lithium Inorganic materials 0.000 claims description 16
- 229910052749 magnesium Inorganic materials 0.000 claims description 16
- 239000011777 magnesium Substances 0.000 claims description 16
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 16
- 239000010936 titanium Substances 0.000 claims description 16
- 229910052719 titanium Inorganic materials 0.000 claims description 16
- 229910052725 zinc Inorganic materials 0.000 claims description 16
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 14
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 14
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 12
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 11
- 238000001125 extrusion Methods 0.000 claims description 10
- 150000003018 phosphorus compounds Chemical class 0.000 claims description 9
- WBWXVCMXGYSMQA-UHFFFAOYSA-N 3,9-bis[2,4-bis(2-phenylpropan-2-yl)phenoxy]-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical group C=1C=C(OP2OCC3(CO2)COP(OC=2C(=CC(=CC=2)C(C)(C)C=2C=CC=CC=2)C(C)(C)C=2C=CC=CC=2)OC3)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 WBWXVCMXGYSMQA-UHFFFAOYSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 8
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 8
- 229920002492 poly(sulfone) Polymers 0.000 claims description 8
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 8
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 7
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 7
- 238000006068 polycondensation reaction Methods 0.000 claims description 7
- 239000004793 Polystyrene Substances 0.000 claims description 6
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 6
- 229920002223 polystyrene Polymers 0.000 claims description 6
- JWOWIZVDYKUULJ-UHFFFAOYSA-N 2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical group C1OPOCC11COPOC1 JWOWIZVDYKUULJ-UHFFFAOYSA-N 0.000 claims description 5
- 229920001601 polyetherimide Polymers 0.000 claims description 5
- 150000003609 titanium compounds Chemical class 0.000 claims description 5
- FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical group C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 238000001746 injection moulding Methods 0.000 claims description 4
- 229920001643 poly(ether ketone) Polymers 0.000 claims description 4
- 229920012287 polyphenylene sulfone Polymers 0.000 claims description 4
- 229920005990 polystyrene resin Polymers 0.000 claims description 4
- 150000003457 sulfones Chemical class 0.000 claims description 4
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 claims 3
- 239000012963 UV stabilizer Substances 0.000 claims 3
- 239000004917 carbon fiber Substances 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 239000003086 colorant Substances 0.000 claims 3
- 239000000945 filler Substances 0.000 claims 3
- 239000003365 glass fiber Substances 0.000 claims 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 3
- 239000002667 nucleating agent Substances 0.000 claims 3
- 150000003016 phosphoric acids Chemical class 0.000 claims 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 3
- 239000004014 plasticizer Substances 0.000 claims 3
- 239000004609 Impact Modifier Substances 0.000 claims 2
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 claims 2
- 238000000071 blow moulding Methods 0.000 claims 2
- 235000008429 bread Nutrition 0.000 claims 2
- 235000021170 buffet Nutrition 0.000 claims 2
- LUZSPGQEISANPO-UHFFFAOYSA-N butyltin Chemical compound CCCC[Sn] LUZSPGQEISANPO-UHFFFAOYSA-N 0.000 claims 2
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 claims 2
- WNVQCJNZEDLILP-UHFFFAOYSA-N dimethyl(oxo)tin Chemical compound C[Sn](C)=O WNVQCJNZEDLILP-UHFFFAOYSA-N 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 235000013361 beverage Nutrition 0.000 claims 1
- 238000010102 injection blow moulding Methods 0.000 claims 1
- 238000010103 injection stretch blow moulding Methods 0.000 claims 1
- 239000003607 modifier Substances 0.000 claims 1
- 235000021317 phosphate Nutrition 0.000 description 48
- VEIOBOXBGYWJIT-UHFFFAOYSA-N cyclohexane;methanol Chemical compound OC.OC.C1CCCCC1 VEIOBOXBGYWJIT-UHFFFAOYSA-N 0.000 description 39
- 150000002009 diols Chemical class 0.000 description 24
- 125000000217 alkyl group Chemical group 0.000 description 20
- BXGYYDRIMBPOMN-UHFFFAOYSA-N 2-(hydroxymethoxy)ethoxymethanol Chemical compound OCOCCOCO BXGYYDRIMBPOMN-UHFFFAOYSA-N 0.000 description 18
- 239000000126 substance Substances 0.000 description 18
- 125000003118 aryl group Chemical group 0.000 description 16
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 14
- 239000002253 acid Substances 0.000 description 14
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 14
- 239000000178 monomer Substances 0.000 description 14
- 238000006116 polymerization reaction Methods 0.000 description 14
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 12
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 12
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 11
- 229920001634 Copolyester Polymers 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 10
- 230000009477 glass transition Effects 0.000 description 10
- 150000002334 glycols Chemical class 0.000 description 10
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 10
- 239000003017 thermal stabilizer Substances 0.000 description 10
- 230000007704 transition Effects 0.000 description 10
- 230000008025 crystallization Effects 0.000 description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 8
- 150000003014 phosphoric acid esters Chemical class 0.000 description 8
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 7
- 238000002347 injection Methods 0.000 description 7
- 239000007924 injection Substances 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- JBKPAMWOSAMZIV-UHFFFAOYSA-N 1-methylcyclobutane-1,3-diol Chemical compound CC1(O)CC(O)C1 JBKPAMWOSAMZIV-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 6
- MKRXFCTUDBWWFU-UHFFFAOYSA-N 1,2,2,4-tetramethylcyclobutane-1,3-diol Chemical compound CC1C(O)C(C)(C)C1(C)O MKRXFCTUDBWWFU-UHFFFAOYSA-N 0.000 description 5
- 239000004970 Chain extender Substances 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 150000008064 anhydrides Chemical class 0.000 description 5
- 230000001066 destructive effect Effects 0.000 description 5
- 150000001991 dicarboxylic acids Chemical class 0.000 description 5
- 238000005886 esterification reaction Methods 0.000 description 5
- 238000005187 foaming Methods 0.000 description 5
- 230000036961 partial effect Effects 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 125000000547 substituted alkyl group Chemical group 0.000 description 5
- WIGMBAFWGLANJY-UHFFFAOYSA-N 2,3-dihydroindene-1,1-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)(C(O)=O)CCC2=C1 WIGMBAFWGLANJY-UHFFFAOYSA-N 0.000 description 4
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 4
- FFLVJCFHFFETDX-UHFFFAOYSA-N OC.OC.C1CCC=CC1 Chemical compound OC.OC.C1CCC=CC1 FFLVJCFHFFETDX-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 4
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 235000012438 extruded product Nutrition 0.000 description 4
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 4
- 235000013772 propylene glycol Nutrition 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- CGSLYBDCEGBZCG-UHFFFAOYSA-N Octicizer Chemical compound C=1C=CC=CC=1OP(=O)(OCC(CC)CCCC)OC1=CC=CC=C1 CGSLYBDCEGBZCG-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 238000003490 calendering Methods 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- STENYDAIMALDKF-UHFFFAOYSA-N cyclobutane-1,3-diol Chemical compound OC1CC(O)C1 STENYDAIMALDKF-UHFFFAOYSA-N 0.000 description 3
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 3
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- JIKVJUUIMIGAAO-UHFFFAOYSA-N diphenylphosphinous acid Chemical compound C=1C=CC=CC=1P(O)C1=CC=CC=C1 JIKVJUUIMIGAAO-UHFFFAOYSA-N 0.000 description 3
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- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 2
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- GMDYXEOXDDKKAW-UHFFFAOYSA-N CC(C)(O)C.C1=CCCCC1 Chemical compound CC(C)(O)C.C1=CCCCC1 GMDYXEOXDDKKAW-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- 125000005418 aryl aryl group Chemical group 0.000 description 2
- 150000007860 aryl ester derivatives Chemical class 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 125000006267 biphenyl group Chemical group 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
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- C08G63/16—Dicarboxylic acids and dihydroxy compounds
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- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L2666/66—Substances characterised by their function in the composition
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Landscapes
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- Compositions Of Macromolecular Compounds (AREA)
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Applications Claiming Priority (59)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US73138905P | 2005-10-28 | 2005-10-28 | |
| US73145405P | 2005-10-28 | 2005-10-28 | |
| US73886905P | 2005-11-22 | 2005-11-22 | |
| US73905805P | 2005-11-22 | 2005-11-22 | |
| US75069305P | 2005-12-15 | 2005-12-15 | |
| US75069205P | 2005-12-15 | 2005-12-15 | |
| US75054705P | 2005-12-15 | 2005-12-15 | |
| US75068205P | 2005-12-15 | 2005-12-15 | |
| US78659606P | 2006-03-28 | 2006-03-28 | |
| US78657106P | 2006-03-28 | 2006-03-28 | |
| US39077306A | 2006-03-28 | 2006-03-28 | |
| US78657206P | 2006-03-28 | 2006-03-28 | |
| US78659806P | 2006-03-28 | 2006-03-28 | |
| US78654706P | 2006-03-28 | 2006-03-28 | |
| US11/390,750 US20060287480A1 (en) | 2005-06-17 | 2006-03-28 | Outdoor shelters comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/391,124 US20060234073A1 (en) | 2005-03-02 | 2006-03-28 | Multilayered, transparent articles containing polyesters comprising a cyclobutanediol and a process for their preparation |
| US11/390,811 US7868128B2 (en) | 2005-06-17 | 2006-03-28 | Skylights and windows comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/391,137 US7985827B2 (en) | 2005-06-17 | 2006-03-28 | Polyester compositions which comprise cyclobutanediol having certain cis/trans ratios |
| US11/390,672 US20060287479A1 (en) | 2005-06-17 | 2006-03-28 | Polyester compositions containing cyclobutanediol and articles made therefrom |
| US11/390,826 US7906610B2 (en) | 2005-06-17 | 2006-03-28 | Food service products comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/390,655 US8067525B2 (en) | 2005-06-17 | 2006-03-28 | Film(s) and/or sheet(s) comprising polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and high glass transition temperature |
| US11/390,883 US7834129B2 (en) | 2005-06-17 | 2006-03-28 | Restaurant smallware comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/391,485 US7842776B2 (en) | 2005-06-17 | 2006-03-28 | Appliance parts comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/390,751 US7803440B2 (en) | 2005-06-17 | 2006-03-28 | Bottles comprising polyester compositions which comprise cyclobutanediol |
| US11/391,156 US7812112B2 (en) | 2005-06-17 | 2006-03-28 | Outdoor signs comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/390,865 US20060287485A1 (en) | 2005-06-17 | 2006-03-28 | Sound barriers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/391,125 US20070010650A1 (en) | 2005-06-17 | 2006-03-28 | Tough amorphous polyester compositions |
| US11/391,576 US7803441B2 (en) | 2005-06-17 | 2006-03-28 | Intravenous components comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/391,642 US7510768B2 (en) | 2005-06-17 | 2006-03-28 | Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein |
| US11/391,571 US20060287494A1 (en) | 2005-06-17 | 2006-03-28 | Polyester compositions containing high amounts of cyclobutanediol and articles made therefrom |
| US11/390,814 US20060286327A1 (en) | 2005-06-17 | 2006-03-28 | Retort containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/390,812 US7959836B2 (en) | 2005-03-02 | 2006-03-28 | Process for the preparation of transparent, shaped articles containing polyesters comprising a cyclobutanediol |
| US11/390,846 US7955674B2 (en) | 2005-03-02 | 2006-03-28 | Transparent polymer blends containing polyesters comprising a cyclobutanediol and articles prepared therefrom |
| US11/390,752 US8063173B2 (en) | 2005-06-17 | 2006-03-28 | Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom |
| US11/391,063 US7576171B2 (en) | 2005-06-17 | 2006-03-28 | Pacifiers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/390,631 US7855267B2 (en) | 2005-06-17 | 2006-03-28 | Film(s) and/or sheet(s) comprising polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and moderate glass transition temperature |
| US11/390,836 US20060286330A1 (en) | 2005-06-17 | 2006-03-28 | Sterilization containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/390,630 US7807774B2 (en) | 2005-06-17 | 2006-03-28 | Vending machines comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3,-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/391,565 US7781562B2 (en) | 2005-06-17 | 2006-03-28 | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| US11/390,827 US7893188B2 (en) | 2005-06-17 | 2006-03-28 | Baby bottles comprising polyester compositions which comprise cyclobutanediol |
| US11/390,671 US8063172B2 (en) | 2005-06-17 | 2006-03-28 | Film(s) and/or sheet(s) made using polyester compositions containing low amounts of cyclobutanediol |
| US11/390,955 US7915376B2 (en) | 2005-06-17 | 2006-03-28 | Containers comprising polyester compositions which comprise cyclobutanediol |
| US11/391,659 US20060287496A1 (en) | 2005-06-17 | 2006-03-28 | Polyester compositions comprising minimal amounts of cyclobutanediol |
| US11/390,809 US7959998B2 (en) | 2005-03-02 | 2006-03-28 | Transparent, oxygen-scavenging compositions containing polyesters comprising a cyclobutanediol and articles prepared therefrom |
| US11/390,722 US7893187B2 (en) | 2005-06-17 | 2006-03-28 | Glass laminates comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/390,864 US7812111B2 (en) | 2005-06-17 | 2006-03-28 | LCD films comprising polyester compositions formed from 2,2,4,4-tetramethy1-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/390,794 US8119761B2 (en) | 2005-06-17 | 2006-03-28 | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom |
| US11/390,847 US20060287484A1 (en) | 2005-06-17 | 2006-03-28 | Opththalmic devices comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/390,654 US20060287477A1 (en) | 2005-06-17 | 2006-03-28 | Greenhouses comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4- cyclohexanedimethanol |
| US11/391,505 US7838620B2 (en) | 2005-06-17 | 2006-03-28 | Thermoformed sheet(s) comprising polyester compositions which comprise cyclobutanediol |
| US11/390,629 US7803439B2 (en) | 2005-06-17 | 2006-03-28 | Blood therapy containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/390,882 US20060287486A1 (en) | 2005-06-17 | 2006-03-28 | Optical media comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/391,495 US7807775B2 (en) | 2005-06-17 | 2006-03-28 | Point of purchase displays comprising polyester compositions formed from 2,2,4,4-tetramethyl-1, 3,-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/390,858 US7951900B2 (en) | 2005-06-17 | 2006-03-28 | Dialysis filter housings comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/390,908 US7462684B2 (en) | 2005-03-02 | 2006-03-28 | Preparation of transparent, multilayered articles containing polyesters comprising a cyclobutanediol and homogeneous polyamide blends |
| US11/390,793 US20060286389A1 (en) | 2005-06-17 | 2006-03-28 | Protein-resistant articles comprising cyclobutanediol |
| US11/390,563 US7902320B2 (en) | 2005-06-17 | 2006-03-28 | Graphic art films comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US11/390,853 US20070270569A1 (en) | 2005-06-17 | 2006-03-28 | Film(s) and/or sheet(s) made from polyester compositions containing cyclobutanediol and articles made therefrom |
| PCT/US2006/042069 WO2007053460A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound |
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| JP2009513792A true JP2009513792A (ja) | 2009-04-02 |
| JP2009513792A5 JP2009513792A5 (enExample) | 2009-12-17 |
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| JP2008538072A Withdrawn JP2009513799A (ja) | 2005-10-28 | 2006-10-27 | 最小量のシクロブタンジオールを含むポリエステル組成物 |
| JP2008537968A Pending JP2009513791A (ja) | 2005-10-28 | 2006-10-27 | シクロブタンジオール並びにある種の熱安定剤及び/又はそれらの反応生成物を含むポリエステル組成物 |
| JP2008538073A Active JP5543713B2 (ja) | 2005-10-28 | 2006-10-27 | 特定の組合せのインヘレント粘度と中程度のガラス転移温度を有するシクロブタンジオールを含むポリエステル組成物及びそれから製造される物品 |
| JP2008538074A Active JP5543714B2 (ja) | 2005-10-28 | 2006-10-27 | 高いガラス転移温度を有するシクロブタンジオールを含むポリエステル組成物及びそれから製造される物品 |
| JP2013185077A Active JP6325782B2 (ja) | 2005-10-28 | 2013-09-06 | シクロブタンジオール並びにある種の熱安定剤及び/又はそれらの反応生成物を含むポリエステル組成物 |
| JP2015020169A Active JP6325991B2 (ja) | 2005-10-28 | 2015-02-04 | シクロブタンジオール並びにある種の熱安定剤及び/又はそれらの反応生成物を含むポリエステル組成物 |
| JP2016188242A Pending JP2017039941A (ja) | 2005-10-28 | 2016-09-27 | シクロブタンジオール並びにある種の熱安定剤及び/又はそれらの反応生成物を含むポリエステル組成物 |
| JP2017249028A Pending JP2018083952A (ja) | 2005-10-28 | 2017-12-26 | シクロブタンジオール並びにある種の熱安定剤及び/又はそれらの反応生成物を含むポリエステル組成物 |
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| JP2008537968A Pending JP2009513791A (ja) | 2005-10-28 | 2006-10-27 | シクロブタンジオール並びにある種の熱安定剤及び/又はそれらの反応生成物を含むポリエステル組成物 |
| JP2008538073A Active JP5543713B2 (ja) | 2005-10-28 | 2006-10-27 | 特定の組合せのインヘレント粘度と中程度のガラス転移温度を有するシクロブタンジオールを含むポリエステル組成物及びそれから製造される物品 |
| JP2008538074A Active JP5543714B2 (ja) | 2005-10-28 | 2006-10-27 | 高いガラス転移温度を有するシクロブタンジオールを含むポリエステル組成物及びそれから製造される物品 |
| JP2013185077A Active JP6325782B2 (ja) | 2005-10-28 | 2013-09-06 | シクロブタンジオール並びにある種の熱安定剤及び/又はそれらの反応生成物を含むポリエステル組成物 |
| JP2015020169A Active JP6325991B2 (ja) | 2005-10-28 | 2015-02-04 | シクロブタンジオール並びにある種の熱安定剤及び/又はそれらの反応生成物を含むポリエステル組成物 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2009513791A (ja) * | 2005-10-28 | 2009-04-02 | イーストマン ケミカル カンパニー | シクロブタンジオール並びにある種の熱安定剤及び/又はそれらの反応生成物を含むポリエステル組成物 |
| WO2013065740A1 (ja) * | 2011-11-01 | 2013-05-10 | ミドリ安全株式会社 | 樹脂組成物及び成形体 |
| JP2015174348A (ja) * | 2014-03-15 | 2015-10-05 | 三菱樹脂株式会社 | ボイル処理用食品包装フィルム、深絞り包装体用底材、および深絞り包装体 |
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| US7959998B2 (en) | 2005-03-02 | 2011-06-14 | Eastman Chemical Company | Transparent, oxygen-scavenging compositions containing polyesters comprising a cyclobutanediol and articles prepared therefrom |
| US7959836B2 (en) | 2005-03-02 | 2011-06-14 | Eastman Chemical Company | Process for the preparation of transparent, shaped articles containing polyesters comprising a cyclobutanediol |
| US7955674B2 (en) | 2005-03-02 | 2011-06-07 | Eastman Chemical Company | Transparent polymer blends containing polyesters comprising a cyclobutanediol and articles prepared therefrom |
| US7834129B2 (en) * | 2005-06-17 | 2010-11-16 | Eastman Chemical Company | Restaurant smallware comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US7462684B2 (en) | 2005-03-02 | 2008-12-09 | Eastman Chemical Company | Preparation of transparent, multilayered articles containing polyesters comprising a cyclobutanediol and homogeneous polyamide blends |
| US7704605B2 (en) | 2006-03-28 | 2010-04-27 | Eastman Chemical Company | Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein |
| WO2007123631A1 (en) * | 2006-03-28 | 2007-11-01 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound |
| US8586701B2 (en) | 2005-10-28 | 2013-11-19 | Eastman Chemical Company | Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US8193302B2 (en) | 2005-10-28 | 2012-06-05 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof |
| US9598533B2 (en) | 2005-11-22 | 2017-03-21 | Eastman Chemical Company | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| US7737246B2 (en) | 2005-12-15 | 2010-06-15 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor |
| US9169388B2 (en) | 2006-03-28 | 2015-10-27 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
| WO2007139655A1 (en) * | 2006-05-23 | 2007-12-06 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
| CA2666585A1 (en) * | 2006-10-27 | 2008-05-02 | Eastman Chemical Company | Polyester compositions |
| CN101801174B (zh) * | 2007-07-15 | 2012-02-15 | 格林百奥生态材料科技(上海)有限公司 | 可干燥木产品的太阳能温室 |
| EP2225084B1 (en) | 2007-11-21 | 2013-05-29 | Eastman Chemical Company | Plastic baby bottles, other blow molded articles, and processes for their manufacture |
| US8501287B2 (en) | 2007-11-21 | 2013-08-06 | Eastman Chemical Company | Plastic baby bottles, other blow molded articles, and processes for their manufacture |
| US8895654B2 (en) | 2008-12-18 | 2014-11-25 | Eastman Chemical Company | Polyester compositions which comprise spiro-glycol, cyclohexanedimethanol, and terephthalic acid |
| US9062197B2 (en) | 2009-03-27 | 2015-06-23 | Eastman Chemical Company | Polyester blends |
| FR2957152B1 (fr) * | 2010-03-04 | 2012-08-03 | Christian Dalloz Sunoptics | Nouveau materiau composite a usage optique ainsi que son procede d'obtention |
| US8973405B2 (en) | 2010-06-17 | 2015-03-10 | Johns Manville | Apparatus, systems and methods for reducing foaming downstream of a submerged combustion melter producing molten glass |
| US8707740B2 (en) | 2011-10-07 | 2014-04-29 | Johns Manville | Submerged combustion glass manufacturing systems and methods |
| US9776903B2 (en) | 2010-06-17 | 2017-10-03 | Johns Manville | Apparatus, systems and methods for processing molten glass |
| US9096452B2 (en) | 2010-06-17 | 2015-08-04 | Johns Manville | Methods and systems for destabilizing foam in equipment downstream of a submerged combustion melter |
| US8997525B2 (en) | 2010-06-17 | 2015-04-07 | Johns Manville | Systems and methods for making foamed glass using submerged combustion |
| US8707739B2 (en) | 2012-06-11 | 2014-04-29 | Johns Manville | Apparatus, systems and methods for conditioning molten glass |
| US8973400B2 (en) | 2010-06-17 | 2015-03-10 | Johns Manville | Methods of using a submerged combustion melter to produce glass products |
| US8650914B2 (en) | 2010-09-23 | 2014-02-18 | Johns Manville | Methods and apparatus for recycling glass products using submerged combustion |
| US10322960B2 (en) | 2010-06-17 | 2019-06-18 | Johns Manville | Controlling foam in apparatus downstream of a melter by adjustment of alkali oxide content in the melter |
| US9021838B2 (en) | 2010-06-17 | 2015-05-05 | Johns Manville | Systems and methods for glass manufacturing |
| US8875544B2 (en) | 2011-10-07 | 2014-11-04 | Johns Manville | Burner apparatus, submerged combustion melters including the burner, and methods of use |
| US8769992B2 (en) | 2010-06-17 | 2014-07-08 | Johns Manville | Panel-cooled submerged combustion melter geometry and methods of making molten glass |
| US8991215B2 (en) | 2010-06-17 | 2015-03-31 | Johns Manville | Methods and systems for controlling bubble size and bubble decay rate in foamed glass produced by a submerged combustion melter |
| US9032760B2 (en) | 2012-07-03 | 2015-05-19 | Johns Manville | Process of using a submerged combustion melter to produce hollow glass fiber or solid glass fiber having entrained bubbles, and burners and systems to make such fibers |
| EP2677001A4 (en) | 2011-02-18 | 2016-10-19 | Midori Anzen Co Ltd | TRANSPARENT RESIN COMPOSITION WITH GOOD CHEMICAL RESISTANCE, DURABILITY AND STABILITY UNDER NATURAL AMBIENT CONDITIONS, IN MORE DIFFICULT NATURAL AMBIENT CONDITIONS, AND IN SIMILAR OR DIFFICULT CONDITIONS OF USE, AND PRODUCT USING THE SAME |
| US9421308B2 (en) | 2011-02-22 | 2016-08-23 | Polyone Corporation | Polyester compounds suitable for hydroclaving |
| JP2013001090A (ja) * | 2011-06-21 | 2013-01-07 | Nippon Kararingu Kk | カード用シート |
| JP2013001089A (ja) * | 2011-06-21 | 2013-01-07 | Nippon Kararingu Kk | カード用シート |
| US20140221599A1 (en) | 2011-10-28 | 2014-08-07 | Nissin Dental Products Inc. | Molded body for dental use |
| US8669314B2 (en) | 2012-02-03 | 2014-03-11 | Sabic Innovative Plastics Ip B.V. | Hydrolytic stability in polycarbonate compositions |
| US20130217830A1 (en) * | 2012-02-16 | 2013-08-22 | Eastman Chemical Company | Clear Semi-Crystalline Articles with Improved Heat Resistance |
| US9533905B2 (en) | 2012-10-03 | 2017-01-03 | Johns Manville | Submerged combustion melters having an extended treatment zone and methods of producing molten glass |
| US9273206B2 (en) | 2012-07-09 | 2016-03-01 | Eastman Chemical Company | Ternary blends of terephthalate or isophthalate polyesters containing EG, CHDM and TMCD |
| WO2014055199A1 (en) | 2012-10-03 | 2014-04-10 | Johns Manville | Methods and systems for destabilizing foam in equipment downstream of a submerged combustion melter |
| US9227865B2 (en) | 2012-11-29 | 2016-01-05 | Johns Manville | Methods and systems for making well-fined glass using submerged combustion |
| US10131563B2 (en) | 2013-05-22 | 2018-11-20 | Johns Manville | Submerged combustion burners |
| US10138151B2 (en) | 2013-05-22 | 2018-11-27 | Johns Manville | Submerged combustion burners and melters, and methods of use |
| US9777922B2 (en) | 2013-05-22 | 2017-10-03 | Johns Mansville | Submerged combustion burners and melters, and methods of use |
| EP2999923B1 (en) | 2013-05-22 | 2018-08-15 | Johns Manville | Submerged combustion melter with improved burner and corresponding method |
| US10654740B2 (en) | 2013-05-22 | 2020-05-19 | Johns Manville | Submerged combustion burners, melters, and methods of use |
| PL3003997T3 (pl) | 2013-05-30 | 2021-11-02 | Johns Manville | Palniki do spalania pod powierzchnią cieczy ze środkami usprawniającymi mieszanie przeznaczone do pieców do topienia szkła oraz zastosowanie |
| US9731990B2 (en) | 2013-05-30 | 2017-08-15 | Johns Manville | Submerged combustion glass melting systems and methods of use |
| WO2015009300A1 (en) | 2013-07-18 | 2015-01-22 | Johns Manville | Fluid cooled combustion burner and method of making said burner |
| WO2015147114A1 (ja) * | 2014-03-28 | 2015-10-01 | 富士フイルム株式会社 | (メタ)アクリル系樹脂組成物、フィルム、偏光板保護フィルム、偏光板及び液晶表示装置 |
| WO2015199062A1 (ja) * | 2014-06-25 | 2015-12-30 | ユニチカ株式会社 | 樹脂組成物およびその成形体 |
| EP3262100A1 (en) | 2015-02-27 | 2018-01-03 | SABIC Global Technologies B.V. | Process to make low color polyetherimide by halo-displacement and low color polyetherimide |
| US10584210B2 (en) | 2015-02-27 | 2020-03-10 | Sabic Global Technologies B.V. | Polyetherimide with improved color, and methods of manufacture thereof |
| US10435511B2 (en) | 2015-05-29 | 2019-10-08 | Sabic Global Technologies B.V. | Polyetherimide of improved color and process of preparing |
| US9751792B2 (en) | 2015-08-12 | 2017-09-05 | Johns Manville | Post-manufacturing processes for submerged combustion burner |
| US10041666B2 (en) | 2015-08-27 | 2018-08-07 | Johns Manville | Burner panels including dry-tip burners, submerged combustion melters, and methods |
| US10670261B2 (en) | 2015-08-27 | 2020-06-02 | Johns Manville | Burner panels, submerged combustion melters, and methods |
| US9815726B2 (en) | 2015-09-03 | 2017-11-14 | Johns Manville | Apparatus, systems, and methods for pre-heating feedstock to a melter using melter exhaust |
| US9982884B2 (en) | 2015-09-15 | 2018-05-29 | Johns Manville | Methods of melting feedstock using a submerged combustion melter |
| US10837705B2 (en) | 2015-09-16 | 2020-11-17 | Johns Manville | Change-out system for submerged combustion melting burner |
| US10081563B2 (en) | 2015-09-23 | 2018-09-25 | Johns Manville | Systems and methods for mechanically binding loose scrap |
| US10144666B2 (en) | 2015-10-20 | 2018-12-04 | Johns Manville | Processing organics and inorganics in a submerged combustion melter |
| EP3804667A1 (en) | 2016-03-08 | 2021-04-14 | Mitsui Chemicals, Inc. | Mouthpiece, sheet for production of mouthpiece unit, and production method of mouthpiece |
| US10246362B2 (en) | 2016-06-22 | 2019-04-02 | Johns Manville | Effective discharge of exhaust from submerged combustion melters and methods |
| US10301208B2 (en) | 2016-08-25 | 2019-05-28 | Johns Manville | Continuous flow submerged combustion melter cooling wall panels, submerged combustion melters, and methods of using same |
| US10337732B2 (en) | 2016-08-25 | 2019-07-02 | Johns Manville | Consumable tip burners, submerged combustion melters including same, and methods |
| US10196294B2 (en) | 2016-09-07 | 2019-02-05 | Johns Manville | Submerged combustion melters, wall structures or panels of same, and methods of using same |
| US10233105B2 (en) | 2016-10-14 | 2019-03-19 | Johns Manville | Submerged combustion melters and methods of feeding particulate material into such melters |
| MX2019004883A (es) | 2016-10-28 | 2019-06-20 | Ppg Ind Ohio Inc | Revestimientos para incrementar las distancias de deteccion de infrarrojo cercano. |
| US11427688B2 (en) * | 2017-04-17 | 2022-08-30 | Eastman Chemical Company | Copolyesters plasticized with polymeric plasticizer |
| US11512198B2 (en) * | 2017-06-21 | 2022-11-29 | Eastman Chemical Company | Polyvinyl chloride and copolyester compositions and articles made using these compositions |
| US10384854B2 (en) | 2017-06-28 | 2019-08-20 | Bemis Company, Inc. | Packaging sheet for elevated-temperature use |
| CN113056746B (zh) | 2018-11-13 | 2023-12-29 | Ppg工业俄亥俄公司 | 检测隐藏图案的方法 |
| US11561329B2 (en) | 2019-01-07 | 2023-01-24 | Ppg Industries Ohio, Inc. | Near infrared control coating, articles formed therefrom, and methods of making the same |
| EP4004082A4 (en) * | 2019-07-31 | 2023-05-31 | Eastman Chemical (China) Co., Ltd. | IMPROVED HARD COATED POLYESTER ITEMS |
| US20230110863A1 (en) | 2020-02-28 | 2023-04-13 | Kyoeisha Chemical Co., Ltd. | Thermosetting resin composition and transesterification reaction catalyst |
| JP2023520584A (ja) * | 2020-04-06 | 2023-05-17 | イーストマン ケミカル カンパニー | 樹脂ブレンド製の結晶化可能な収縮性フィルムおよび熱成形性シート |
| US11458220B2 (en) | 2020-11-12 | 2022-10-04 | Singletto Inc. | Microbial disinfection for personal protection equipment |
| CA3220673A1 (en) * | 2021-06-17 | 2022-12-22 | Eastman Chemical Company | Polyester/polyester elastomer compositions |
| WO2023206073A1 (en) * | 2022-04-26 | 2023-11-02 | Eastman Chemical (China) Co., Ltd. | Flame retardant copolyester compositions |
| US12359369B2 (en) | 2022-08-11 | 2025-07-15 | Singletto Inc. | Skin protection against microbial particles |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5989663A (en) * | 1996-12-30 | 1999-11-23 | Eastman Chemical Company | Blow-molding polyesters from terephthalic acid, 2, 2, 4, 4-tetramethyl-1,3-cyclobutanediol, and ethylene glycol |
| US6043322A (en) * | 1996-12-28 | 2000-03-28 | Eastman Chemical Company | Clear polycarbonate and polyester blends |
| JP2003165832A (ja) * | 2001-03-28 | 2003-06-10 | Toyobo Co Ltd | ポリエステルおよびその製造方法並びにフイルム |
| JP2004161801A (ja) * | 2002-11-08 | 2004-06-10 | Asahi Denka Kogyo Kk | ポリエステル系可塑剤及び塩素含有樹脂組成物 |
| JP2005132952A (ja) * | 2003-10-30 | 2005-05-26 | Asahi Denka Kogyo Kk | ポリエステル樹脂組成物 |
| JP2005521772A (ja) * | 2002-03-27 | 2005-07-21 | イーストマン ケミカル カンパニー | 黄色度の低下したポリエステル/ポリカーボネートブレンド |
| JP2008544022A (ja) * | 2005-06-17 | 2008-12-04 | イーストマン ケミカル カンパニー | インヘレント粘度と中程度のガラス転移温度との特定の組合せを有するシクロブタンジオールを含むポリエステル組成物及びそれから製造された物品 |
Family Cites Families (323)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL16356C (enExample) | 1924-07-22 | |||
| GB478303A (en) | 1936-07-13 | 1938-01-13 | Henry Dreyfus | Improvements in the manufacture of ketene, acetic anhydride or a homologue thereof |
| GB478326A (en) | 1936-07-17 | 1938-01-17 | Henry Dreyfus | Improvements in the manufacture of ketene, acetic anhydride or a homologue thereof |
| US2278537A (en) | 1937-10-19 | 1942-04-07 | Celanese Corp | Manufacture of aliphatic compounds |
| US2720507A (en) | 1952-10-03 | 1955-10-11 | Eastman Kodak Co | Organo-metallic tin catalysts for preparation of polyesters |
| US2806064A (en) | 1954-02-23 | 1957-09-10 | Celanese Corp | Production of anhydrous ketenes |
| BE592181A (enExample) | 1955-12-22 | |||
| IT595468A (enExample) * | 1957-08-22 | |||
| US2936324A (en) * | 1958-04-14 | 1960-05-10 | Eastman Kodak Co | Preparation of 2, 2, 4, 4-tetraalkylcyclobutane-1, 3-diols |
| US3030335A (en) * | 1959-01-02 | 1962-04-17 | Gen Electric | Aromatic polycarbonate reaction products |
| FR1291273A (fr) | 1959-01-21 | 1962-04-20 | Eastman Kodak Co | Nouveau procédé pour la préparation d'un superpolyester linéaire et produit obtenu |
| GB993121A (en) | 1959-01-21 | 1965-05-26 | Eastman Kodak Co | Linear superpolyester production |
| US3075952A (en) | 1959-01-21 | 1963-01-29 | Eastman Kodak Co | Solid phase process for linear superpolyesters |
| US3201474A (en) | 1959-09-24 | 1965-08-17 | Eastman Kodak Co | Process of manufacturing dialkyl ketenes |
| US3313777A (en) | 1959-12-18 | 1967-04-11 | Eastman Kodak Co | Linear polyesters and polyester-amides from 2, 2, 4, 4-tetraalkyl-1, 3-cyclobutanediols |
| FR83790E (fr) * | 1959-12-18 | 1964-10-09 | Kodak Pathe | Nouveaux polymères dérivés des 2, 2, 4, 4-tétraalcoyl-1, 3-cyclobutanediols et leurs applications industrielles |
| FR1278284A (fr) * | 1959-12-18 | 1961-12-08 | Kodak Pathe | Nouveaux polymères dérivés des 2, 2, 4, 4-tétraalcoyl-1, 3-cyclobutanediols et leurs applications industrielles |
| US3000906A (en) | 1960-02-05 | 1961-09-19 | Eastman Kodak Co | Purification of pivalolactone |
| US3062852A (en) | 1960-03-30 | 1962-11-06 | Eastman Kodak Co | Esters of 2, 2, 4, 4-tetraalkylcyclobutane-1, 3-diols |
| BE615850Q (fr) | 1960-12-16 | 1962-07-16 | Eastman Kodak Co | Nouveaux polymères dérivés des 2,2,4,4-tétraalcoyl-1,3-cyclobutanediols et leurs applications industrielles |
| US3227764A (en) | 1960-12-30 | 1966-01-04 | Eastman Kodak Co | Separation of cis and trans isomers of tetraalkyl - 1,3 - cyclobutanediols and novel compound obtained thereby |
| US3207814A (en) | 1961-01-03 | 1965-09-21 | Gen Electric | Carbonate-polyester copolymer resinous compositions |
| US3091600A (en) * | 1961-01-05 | 1963-05-28 | Eastman Kodak Co | Linear aromatic acid copolyesters modified with dimer glycols having 36 carbons |
| US3236899A (en) | 1961-02-23 | 1966-02-22 | Eastman Kodak Co | Treatment of 2, 2, 4, 4-tetraalkyl-1, 3-cyclobutanediols |
| US3360547A (en) | 1961-05-01 | 1967-12-26 | Eastman Kodak Co | Polyesters of tetraalkylcyclobutanediol |
| US3259469A (en) | 1961-07-26 | 1966-07-05 | Eastman Kodak Co | Apparatus for manufacturing ketenes |
| GB951818A (en) * | 1961-08-18 | 1964-03-11 | Kunoshima Kagaku Kogyo Kabushi | Polyester moulding materials |
| US3287390A (en) | 1961-08-21 | 1966-11-22 | Mcneilab Inc | 2, 2, 4, 4-tetramethylcyclobutyl compounds |
| US3317466A (en) | 1961-09-14 | 1967-05-02 | Eastman Kodak Co | Three-dimensional polycyclic bisphenol polycarbonates and polyesters |
| US3254047A (en) | 1961-09-14 | 1966-05-31 | Eastman Kodak Co | Additives for increasing modulus of elasticity of polycarbonate films |
| US3190928A (en) | 1961-09-27 | 1965-06-22 | Eastman Kodak Co | Preparation of tetraalkylcyclo-butanediols |
| US3249652A (en) * | 1962-10-24 | 1966-05-03 | Du Pont | Segmented copolyester of 2, 2, 4, 4-tetramethyl-1, 3-cyclobutylene terephthalate andethylene terephthalate |
| DE1520178A1 (de) | 1963-02-09 | 1969-12-04 | Kalle Ag | Verfahren zur Herstellung von Polyaethylenterephthalat |
| US3312741A (en) * | 1963-04-29 | 1967-04-04 | Eastman Kodak Co | 2, 2-dialkyl-3-alkoxy cyclobutanone derivatives |
| US3288854A (en) | 1963-07-05 | 1966-11-29 | Eastman Kodak Co | Addition of dialkylketenes to alkoxyacetylenes |
| US3329722A (en) | 1964-01-10 | 1967-07-04 | Englehard Ind Inc | Production of 3-hydroxy-2, 2, 4, 4-tetraalkyl-cyclobutanones |
| DE1997729U (de) | 1964-05-04 | 1968-12-05 | Eastman Kodak Co | Vorrichtung zur herstellung von ketenen durch pyrolyse von zu ketenen spaltbaren verbindungen |
| GB1090241A (en) | 1964-05-13 | 1967-11-08 | Kodak Ltd | Polyester insulating layers |
| FR1434658A (fr) | 1964-05-13 | 1966-04-08 | Eastman Kodak Co | Conducteurs électriques à nouvelle couche isolante |
| FR1456345A (fr) | 1964-12-07 | 1966-10-21 | Eastman Kodak Co | Nouveau procédé de préparation de polyesters et nouveaux produits obtenus |
| US3544514A (en) * | 1965-01-15 | 1970-12-01 | Bayer Ag | Process for the production of thermoplastic polycarbonates |
| US3366689A (en) * | 1965-03-31 | 1968-01-30 | Daikin Ind Ltd | Process for manufacturing ketenes |
| FR1432471A (fr) | 1965-05-12 | 1966-03-18 | Eastman Kodak Co | Procédé de préparation de diols cycliques par hydrogénation catalytique des cétones correspondantes |
| US3484339A (en) | 1966-05-02 | 1969-12-16 | Eastman Kodak Co | Blends of polyesters containing free carboxyl groups and laminate thereof |
| US3541059A (en) | 1967-04-19 | 1970-11-17 | Calgon C0Rp | Novel reaction products of glycidyl esters and alkali metal sulfite or bisulfite,and polymers thereof |
| US3502620A (en) | 1967-05-11 | 1970-03-24 | Eastman Kodak Co | Branched polyesters containing terminal carboxyl groups |
| US3546177A (en) | 1968-03-07 | 1970-12-08 | Eastman Kodak Co | Polyesters containing sterically hindered trialkyl phosphates |
| GB1278284A (en) | 1969-08-16 | 1972-06-21 | Norman Wood | Improvements in or relating to the manufacture of resonators of stringed musical instruments |
| US3629202A (en) * | 1969-09-12 | 1971-12-21 | Eastman Kodak Co | Treating polyesters with organic acids for improved stability |
| UST873016I4 (en) * | 1969-11-28 | 1970-04-28 | Defensive publication | |
| JPS4920078B1 (enExample) | 1970-09-26 | 1974-05-22 | ||
| BR7107279D0 (pt) * | 1970-11-02 | 1973-03-29 | Fiber Industries Inc | Um processo para a producao de poliesteres formadores de fibras por polimerizacao de condensacao e composicao formadora de fibra obtida |
| BE794938A (fr) | 1972-02-02 | 1973-08-02 | Eastman Kodak Co | Nouveau procede de preparation de copolyesters et applications |
| US3915913A (en) * | 1972-08-15 | 1975-10-28 | Eastman Kodak Co | Hot melt polymer blends |
| US3799953A (en) | 1972-09-01 | 1974-03-26 | Bayer Ag | 1,4-bis(4,'4''-dihydroxy-triphenylmethyl)benzene |
| JPS557853B2 (enExample) * | 1974-04-09 | 1980-02-28 | ||
| US3907754A (en) | 1974-06-19 | 1975-09-23 | Eastman Kodak Co | Process and catalyst-inhibitor system for preparing synthetic linear polyester |
| US4056504A (en) * | 1974-08-16 | 1977-11-01 | Bayer Aktiengesellschaft | Polycarbonate molding compositions |
| US3962189A (en) | 1974-11-01 | 1976-06-08 | Eastman Kodak Company | Process and catalyst-inhibitor systems for preparing synthetic linear polyesters |
| US4185009A (en) | 1975-01-03 | 1980-01-22 | Bayer Aktiengesellschaft | Branched, high-molecular weight thermoplastic polycarbonates |
| US4001184A (en) * | 1975-03-31 | 1977-01-04 | General Electric Company | Process for preparing a branched polycarbonate |
| US4010145A (en) | 1975-05-12 | 1977-03-01 | Eastman Kodak Company | Process and catalyst inhibitor systems for preparing synthetic linear polyesters |
| US4046933A (en) * | 1975-09-16 | 1977-09-06 | Ppg Industries, Inc. | Laminated window structure and its method of fabrication |
| US4156069A (en) * | 1976-04-02 | 1979-05-22 | Allied Chemical Corporation | Bisphenol-A/terephthalate/carbonate melt processable copolymers |
| US4084889A (en) * | 1976-07-28 | 1978-04-18 | Vischer Optics, Inc. | Eyeglass frame |
| US4125572A (en) * | 1976-12-14 | 1978-11-14 | General Electric Company | Thermoplastic molding composition |
| US4188314A (en) * | 1976-12-14 | 1980-02-12 | General Electric Company | Shaped article obtained from a carbonate-polyester composition |
| US4391954A (en) * | 1976-12-14 | 1983-07-05 | General Electric Company | Thermoplastic molding composition |
| US4160383A (en) | 1977-12-27 | 1979-07-10 | Will Ross Inc. | Unitary sample-vent-valve assembly |
| DE2842004A1 (de) | 1978-09-27 | 1980-04-10 | Bayer Ag | Verfahren zur herstellung von modifizierten polycarbonat-formmassen |
| US4194038A (en) * | 1979-01-25 | 1980-03-18 | Allied Chemical Corporation | Poly(ester-carbonates) from dicarboxylic acid chlorides |
| DE2921868A1 (de) | 1979-05-30 | 1980-12-04 | Karl Obser | Sportkabine |
| US4263364A (en) | 1979-12-14 | 1981-04-21 | Eastman Kodak Company | Stampable reinforced thermoplastic polyester sheets |
| DE3164692D1 (en) | 1980-04-30 | 1984-08-16 | Dainippon Ink & Chemicals | Ultraviolet-transmissible composition |
| EP0078609B1 (en) * | 1980-04-30 | 1987-05-06 | Imperial Chemical Industries Plc | 3-hydroxybutyric acid polymers |
| US4430484A (en) | 1981-01-14 | 1984-02-07 | General Electric Company | Polyester-carbonate resin blends |
| US4356299A (en) | 1982-02-04 | 1982-10-26 | Rohm And Haas Company | Catalyst system for a polyethylene terephthalate polycondensation |
| US4384106A (en) * | 1982-03-09 | 1983-05-17 | Owens-Illinois, Inc. | Copolyesters |
| US4379802A (en) | 1982-04-21 | 1983-04-12 | Eastman Kodak Company | Stampable reinforced thermoplastic polyester sheet with improved surface finish |
| US4424140A (en) | 1982-06-03 | 1984-01-03 | Union Carbide Corporation | Stabilization of polycondensation catalysts |
| US4431793A (en) * | 1982-06-09 | 1984-02-14 | General Electric Company | Aromatic polycarbonate end capped with branched chain alkyl acyl halide or acid |
| US4786692A (en) * | 1982-12-20 | 1988-11-22 | General Electric Company | High strength, reduced heat distortion temperature thermoplastic composition |
| US4469861A (en) | 1982-12-27 | 1984-09-04 | General Electric Company | Polycarbonate composition from branched chain dihydric phenol |
| US4465820A (en) | 1983-06-03 | 1984-08-14 | General Electric Company | Copolyestercarbonates |
| US4426512A (en) * | 1983-06-09 | 1984-01-17 | Eastman Kodak Company | Polyester containers having improved gas barrier properties |
| US4452933A (en) | 1983-06-09 | 1984-06-05 | General Electric Company | Stabilized polyester-polycarbonate blends and stabilization process therefor |
| US4578437A (en) | 1983-08-01 | 1986-03-25 | Eastman Kodak Company | Copolyester/polyester blends having reduced carbon dioxide permeability |
| US4480086A (en) * | 1983-09-09 | 1984-10-30 | Eastman Kodak Company | Radiation-resistant copolyesters |
| US4525504A (en) | 1983-10-24 | 1985-06-25 | Eastman Kodak Company | Stabilized polyester compositions suitable for outdoor applications |
| US4642959A (en) | 1983-11-29 | 1987-02-17 | Swiech Jr Tom E | Vending machine panels |
| US4939186A (en) * | 1984-02-10 | 1990-07-03 | General Electric Company | Enhancing color stability to sterilizing radiation of polymer compositions |
| US4587437A (en) * | 1984-03-19 | 1986-05-06 | Rockwell International Corporation | Coupling/decoupling capacitor multiplier |
| US4578295A (en) * | 1984-07-16 | 1986-03-25 | Owens-Illinois, Inc. | High barrier polymer blend and articles prepared therefrom |
| JPS61213147A (ja) | 1985-03-18 | 1986-09-22 | 鐘淵化学工業株式会社 | 芳香族ポリエステル系積層体及び液晶表示部品 |
| US5239020A (en) | 1985-08-21 | 1993-08-24 | Eastman Kodak Company | Polyester/polycarbonate blends |
| AU603076B2 (en) | 1985-12-09 | 1990-11-08 | W.R. Grace & Co.-Conn. | Polymeric products and their manufacture |
| EP0273144A3 (en) | 1986-12-15 | 1990-03-21 | General Electric Company | Cross-linked branched polycarbonate composition |
| JPH0741907B2 (ja) * | 1986-12-27 | 1995-05-10 | 三菱瓦斯化学株式会社 | 多層容器 |
| GB8705712D0 (en) | 1987-03-11 | 1987-04-15 | Du Pont Canada | Lid for food trays |
| SE8702840D0 (sv) * | 1987-07-10 | 1987-07-10 | Plm Ab | Barrierforsterkning |
| US4749773A (en) | 1987-07-27 | 1988-06-07 | Eastman Kodak Company | Condensation polymers containing methine ultraviolet radiation-absorbing residues and shaped articles produced therefrom |
| JP2608429B2 (ja) * | 1987-11-09 | 1997-05-07 | 東レ・ダウコーニング・シリコーン株式会社 | パターン形成用材料およびパターン形成方法 |
| US4882412A (en) | 1987-11-30 | 1989-11-21 | Eastman Kodak Company | Polyester polymer containing the residue of the UV absorbing benzopyran compound and shaped articles produced therefrom |
| US4892922A (en) | 1987-11-30 | 1990-01-09 | Eastman Kodak Company | Polyester polymer containing the residue of a benzopyran colorant compound and shaped articles produced therefrom |
| JPS63199259A (ja) * | 1987-12-25 | 1988-08-17 | Kanegafuchi Chem Ind Co Ltd | 成形用変性ポリエステル組成物 |
| US4981898A (en) | 1987-12-31 | 1991-01-01 | General Electric Company | Polycarbonate-polyester blends |
| US4892923A (en) | 1988-02-22 | 1990-01-09 | Eastman Kodak Company | Polyester compositions containing the residue of a naphthopyran compound and shaped articles produced therefrom |
| US4826903A (en) | 1988-02-22 | 1989-05-02 | Eastman Kodak Company | Condensation polymer containing the residue of an acyloxystyrl compound and shaped articles produced therefrom |
| GB2216919B (en) | 1988-04-08 | 1991-11-13 | Stc Plc | Kiosk housing for telephone equipment |
| US4976057A (en) * | 1988-07-21 | 1990-12-11 | Bianchi Dennis R | Simulated neon sign |
| US4845188A (en) | 1988-08-19 | 1989-07-04 | Eastman Kodak Company | Condensation polymers containing methine ultraviolet radiation-absorbing residues and shaped articles produced therefrom |
| US5000991B2 (en) | 1988-12-01 | 2000-07-11 | Sekisui Plastics | Process for producing polyester resin foam and polyester resin foam sheet |
| US4937134A (en) * | 1989-04-17 | 1990-06-26 | The Dow Chemical Company | Elastomeric optical interference films |
| US5326584A (en) * | 1989-04-24 | 1994-07-05 | Drexel University | Biocompatible, surface modified materials and method of making the same |
| US5191038A (en) * | 1989-06-01 | 1993-03-02 | General Electric Company | Preparation of branched polycarbonate composition from cyclic aromatic polycarbonate oligomer, polyhydric phenol and polycarbonate |
| US5017679A (en) | 1989-08-30 | 1991-05-21 | Eastman Kodak Company | Polyesters terminated with carboxycyclohexanecarboxylate groups |
| US6288161B1 (en) * | 1990-01-31 | 2001-09-11 | Pechiney Emballage Flexible Europe | Barrier compositions and articles made therefrom |
| CA2035149A1 (en) | 1990-02-06 | 1991-08-07 | Charles E. Lundy | Blends of polycarbonates and aliphatic polyesters |
| IE65907B1 (en) * | 1990-02-26 | 1995-11-29 | Lonza Ag | New 3-hydroxy-2-cyclobuten-1-one salts their preparation and use |
| US5224958A (en) * | 1990-05-04 | 1993-07-06 | The Research Foundation Of State University Of New York | Silicone elastomer line prosthetic devices and methods of manufacture |
| US5017680A (en) * | 1990-07-03 | 1991-05-21 | Eastman Kodak Company | Process and catalyst-inhibitor systems for preparing poly(ethylene terephthalate) |
| US5486562A (en) * | 1990-07-12 | 1996-01-23 | General Electric Company | Modifications of poly(alkylene cyclohexanedicarboxylate) blends |
| AU649710B2 (en) * | 1990-09-11 | 1994-06-02 | Mitsubishi Gas Chemical Company, Inc. | Polyamide resin composition and film therefrom |
| US5219510A (en) | 1990-09-26 | 1993-06-15 | Eastman Kodak Company | Method of manufacture of cellulose ester film |
| US5104450A (en) * | 1990-09-26 | 1992-04-14 | Eastman Kodak Company | Formulations of cellulose esters with arylene-bis(diaryl phosphate)s |
| DE4036359A1 (de) * | 1990-11-15 | 1992-05-21 | Hoechst Ag | Verfahren zur verminderung der verfaerbung einer kunststoff-formmasse bei der verarbeitungstemperatur |
| US6495656B1 (en) | 1990-11-30 | 2002-12-17 | Eastman Chemical Company | Copolyesters and fibrous materials formed therefrom |
| ATE199383T1 (de) * | 1990-11-30 | 2001-03-15 | Eastman Chem Co | Aliphatisch-aromatische copolyester |
| US5292783A (en) * | 1990-11-30 | 1994-03-08 | Eastman Kodak Company | Aliphatic-aromatic copolyesters and cellulose ester/polymer blends |
| US5118760A (en) * | 1990-12-26 | 1992-06-02 | Eastman Kodak Company | Impact resistant polymer blends |
| US5142088A (en) | 1991-01-28 | 1992-08-25 | General Electric Company | Preparation of branched polycarbonates and chloroformates, and intermediates therefor |
| US5434227A (en) * | 1991-05-08 | 1995-07-18 | Daicel Chemical Industries, Ltd. | Process for producing polycarbonate |
| JP2613502B2 (ja) * | 1991-05-31 | 1997-05-28 | 東洋紡績株式会社 | 制振材料用粘弾性樹脂組成物 |
| US5310787A (en) * | 1991-06-04 | 1994-05-10 | Du Pont-Mitsui Polychemicals Co., Ltd. | Polyester packaging material |
| EP0544008B1 (en) | 1991-06-17 | 1996-03-27 | Seiko Epson Corporation | Phase difference elemental film, phase difference plate and liquid crystal display using same |
| US5169994A (en) | 1991-08-20 | 1992-12-08 | Eastman Kodak Company | Process for the manufacture of 2,2,4,4-tetramethycyclobutanediol |
| US5256761A (en) | 1991-09-23 | 1993-10-26 | Eastman Kodak Company | Polyester coatings containing covalently-bound mesogenic monomers |
| DE69216343T2 (de) * | 1991-10-04 | 1997-07-31 | Oki Electric Ind Co Ltd | Thermoreversibles Aufzeichnungsmaterial und thermoreversibles Aufzeichnungsverfahren, das dieses Material verwendet |
| JP2797804B2 (ja) | 1992-01-09 | 1998-09-17 | 日本電気株式会社 | バックライト及び液晶表示装置 |
| US5207967A (en) * | 1992-03-02 | 1993-05-04 | Eastman Kodak Company | Multicomponent polyester/polycarbonate blends with improved impact strength and processability |
| US5422189A (en) * | 1992-10-01 | 1995-06-06 | Minnesota Mining And Manufacturing Company | Flexible optically uniform sign face substrate |
| BE1006297A3 (nl) | 1992-10-26 | 1994-07-12 | Axxis Nv | Kunststofplaat, een werkwijze voor de vervaardiging daarvan en vormdelen die de plaat bevatten. |
| US5494992A (en) | 1993-01-29 | 1996-02-27 | Daicel Chemical Industries, Ltd. | (Co)polycarbonate and process for producing the same |
| US5288764A (en) * | 1993-01-29 | 1994-02-22 | Amoco Corporation | Increased throughput in foaming and other melt fabrication of polyester |
| US5258556A (en) | 1993-02-01 | 1993-11-02 | Eastman Kodak Company | Process for the manufacture of 2,2,4,4-tetramethylcyclobutanediol |
| US5372879A (en) | 1993-02-22 | 1994-12-13 | Teijin Limited | Biaxially oriented polyester film |
| JPH06279577A (ja) * | 1993-03-29 | 1994-10-04 | Mitsui Toatsu Chem Inc | ポリヒドロキシカルボン酸の製造方法 |
| CN1099044A (zh) | 1993-04-16 | 1995-02-22 | 大世吕化学工业株式会社 | (共)聚碳酸酯的制备方法 |
| US5382292A (en) * | 1993-07-28 | 1995-01-17 | Eastman Kodak Company | Edge guide lubricating fluid delivery apparatus |
| US5372864A (en) | 1993-09-03 | 1994-12-13 | Eastman Chemical Company | Toners for polyesters |
| IL110514A0 (en) | 1993-10-04 | 1994-10-21 | Eastman Chem Co | Concentrates for improving polyester compositions and a method for preparing such compositions |
| US5354791A (en) * | 1993-10-19 | 1994-10-11 | General Electric Company | Epoxy-functional polyester, polycarbonate with metal phosphate |
| US5378796A (en) * | 1994-02-09 | 1995-01-03 | Eastman Chemical Company | Process for preparing copolyesters |
| JPH07309937A (ja) * | 1994-05-16 | 1995-11-28 | Kanegafuchi Chem Ind Co Ltd | ポリエステルの製造方法 |
| US5475144A (en) | 1994-06-08 | 1995-12-12 | The University Of Delaware | Catalyst and process for synthesis of ketenes from carboxylic acids |
| DE69529032T2 (de) | 1994-08-25 | 2003-05-08 | Kyodo Printing Co., Ltd. | Copolyesterharz, Polymermischung und Verpackungsmaterial daraus |
| US5442036A (en) * | 1994-09-06 | 1995-08-15 | Eastman Chemical Company | Branched copolyesters especially suitable for extrusion blow molding |
| US5498668A (en) | 1994-10-31 | 1996-03-12 | Eastman Chemical Company | Blends of certain polyesters with acrylics |
| EP0714764A3 (en) | 1994-12-02 | 1997-03-05 | Gen Electric | Improved impact resistant composite |
| US5534609A (en) * | 1995-02-03 | 1996-07-09 | Osi Specialties, Inc. | Polysiloxane compositions |
| CA2171584A1 (en) | 1995-04-11 | 1996-10-12 | James P. Mason | Compositions having low birefringence |
| JPH08301995A (ja) * | 1995-04-27 | 1996-11-19 | Chisso Corp | 含水2−ブチル−2−エチル−1,3−プロパンジオールを用いたポリエステルの製造方法 |
| US5650453A (en) * | 1995-04-28 | 1997-07-22 | General Electric Company | UV curable epoxysilicone blend compositions |
| US5480926A (en) * | 1995-04-28 | 1996-01-02 | Eastman Chemical Company | Blends of ultraviolet absorbers and polyesters |
| JP3448158B2 (ja) * | 1995-05-31 | 2003-09-16 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | コポリエステル組成物 |
| US5506014A (en) * | 1995-09-01 | 1996-04-09 | Eastman Chemical Company | Pet copolyesters containing succinic and naphthalenedicarboxylic acid moieties having improved barrier properties |
| US5868704A (en) * | 1995-09-18 | 1999-02-09 | W. L. Gore & Associates, Inc. | Balloon catheter device |
| US5633340A (en) * | 1995-09-21 | 1997-05-27 | Eastman Chemical Company | Polyester molding compositions |
| US5696176A (en) | 1995-09-22 | 1997-12-09 | Eastman Chemical Company | Foamable polyester compositions having a low level of unreacted branching agent |
| US5552512A (en) | 1995-10-06 | 1996-09-03 | Eastman Chemical Company | Thermoplastic copolyesters having improved gas barrier properties |
| AUPN605595A0 (en) * | 1995-10-19 | 1995-11-09 | Amcor Limited | A hot fill container |
| US5608031A (en) | 1995-11-30 | 1997-03-04 | Eastman Chemical Company | Polyesters modified with 1,4-cyclohexaned imethanol having high clarity prepared utilizing an antimony containing catalyst/stabilizer system |
| US5688874A (en) * | 1995-12-22 | 1997-11-18 | Eastman Chemical Company | Process for preparing blends of poly(ethylene terephthalate) and poly(ethylene 2,6-naphthalenedicarboxylate) |
| TW381104B (en) | 1996-02-20 | 2000-02-01 | Eastman Chem Co | Process for preparing copolyesters of terephthalic acid, ethylene glycol, and 1,4-cyclohexanedimethanol |
| JP3745776B2 (ja) | 1996-04-05 | 2006-02-15 | 帝人株式会社 | ボトル用エチレンテレフタレート/エチレン―2,6―ナフタレンジカルボキシレート共重合体 |
| US5656715A (en) | 1996-06-26 | 1997-08-12 | Eastman Chemical Company | Copolyesters based on 1,4-cyclohexanedimethanol having improved stability |
| US5977347A (en) | 1996-07-30 | 1999-11-02 | Daicel Chemical Industries, Ltd. | Cellulose acetate propionate |
| JPH10120776A (ja) * | 1996-09-02 | 1998-05-12 | Mitsui Chem Inc | 脂肪族ポリエステルの製造方法 |
| US5814679A (en) * | 1996-10-18 | 1998-09-29 | General Electric Company | Premium release photo-curable silicone compositions |
| US5783307A (en) | 1996-11-04 | 1998-07-21 | Eastman Chemical Company | UV stabilized multi-layer structures with detectable UV protective layers and a method of detection |
| US5863622A (en) | 1996-12-05 | 1999-01-26 | Hoechst Celanese Corporation | Polarizer laminates comprising coextruded liquid crystal polymer moieties and integral thermoplastic cover layers |
| US6005059A (en) | 1996-12-28 | 1999-12-21 | Eastman Chemical Company | Clear polycarbonate and polyester blends |
| US5942585A (en) | 1996-12-28 | 1999-08-24 | Eastman Chemical Company | Polycarbonate and polyester blends |
| US6037424A (en) * | 1996-12-28 | 2000-03-14 | Eastman Chemical Company | Clear blends of polycarbonates and polyesters |
| US5955565A (en) | 1996-12-28 | 1999-09-21 | Eastman Chemical Company | Polyesters from terephthalic acid, 2,2,4,4-tetramethyl-1,3-cyclobutanediol and ethylene glycol |
| US6011124A (en) | 1996-12-28 | 2000-01-04 | Eastman Chemical Company | Blends of bisphenol a polycarbonate and polyesters |
| US6084019A (en) * | 1996-12-31 | 2000-07-04 | Eastman Chemical Corporation | High I.V. polyester compositions containing platelet particles |
| US5859116A (en) * | 1997-01-21 | 1999-01-12 | Eastman Chemical Company | Clarity and adjustable shrinkage of shrink films using miscible polyester blends |
| US6114575A (en) * | 1997-03-25 | 2000-09-05 | Bp Amoco Corporation | Process for preparing 2,6-naphthalenedicarboxylic acid |
| US5902631A (en) * | 1997-06-03 | 1999-05-11 | Wang; Lixiao | Lubricity gradient for medical devices |
| DE19727709A1 (de) | 1997-06-30 | 1999-01-07 | Bayer Ag | Verfahren zur Herstellung von verzweigten Polycarbonaten |
| US6309718B1 (en) | 1997-07-25 | 2001-10-30 | Eastman Chemical Company | Large polyester containers and method for making same |
| FR2766964B1 (fr) | 1997-07-29 | 1999-10-29 | Pixtech Sa | Procede d'assemblage sous vide d'un ecran plat de visualisation |
| US5958539A (en) | 1997-08-26 | 1999-09-28 | Eastman Chemical Company | Thermoplastic article having textile fiber fabric embedded therein |
| US5907026A (en) * | 1997-08-27 | 1999-05-25 | General Electric Company | Polycarbonate compositions comprising polyester resins and ultraviolet light absorbers |
| SG70651A1 (en) | 1997-09-15 | 2000-02-22 | Gen Electric | Aliphatic polyester-acrylic blend molding composition having good ductility and weatherability |
| US6030671A (en) * | 1998-01-09 | 2000-02-29 | Msc Specialty Films, Inc. | Low emissivity window films |
| US5925507A (en) | 1998-01-14 | 1999-07-20 | Eastman Kodak Company | Photographic film base and photographic elements |
| EP1049495A2 (en) | 1998-01-23 | 2000-11-08 | Pall Corporation | Biological fluid treatment system |
| US6846440B2 (en) * | 1998-03-17 | 2005-01-25 | Eastman Chemical Company | Polyester resin compositions for calendering |
| DE19811773A1 (de) | 1998-03-18 | 1999-09-23 | Wolff Walsrode Ag | Thermoplastische, biologisch abbaubare und kompostierbare opake Folie und Verfahren zu deren Herstellung |
| US6012597A (en) * | 1998-03-18 | 2000-01-11 | Mitsubishi Plastics, Inc. | Polyester bottle with a handle and method of manufacturing the same |
| US6025061A (en) * | 1998-04-23 | 2000-02-15 | Hna Holdings, Inc. | Sheets formed from polyesters including isosorbide |
| US6126992A (en) | 1998-04-23 | 2000-10-03 | E.I. Dupont De Nemours And Company | Optical articles comprising isosorbide polyesters and method for making same |
| US5958581A (en) * | 1998-04-23 | 1999-09-28 | Hna Holdings, Inc. | Polyester film and methods for making same |
| US6063465A (en) * | 1998-04-23 | 2000-05-16 | Hna Holdings, Inc. | Polyester container and method for making same |
| US5959066A (en) * | 1998-04-23 | 1999-09-28 | Hna Holdings, Inc. | Polyesters including isosorbide as a comonomer and methods for making same |
| US6140422A (en) * | 1998-04-23 | 2000-10-31 | E.I. Dupont De Nemours And Company | Polyesters including isosorbide as a comonomer blended with other thermoplastic polymers |
| US6063495A (en) * | 1998-04-23 | 2000-05-16 | Hna Holdings, Inc. | Polyester fiber and methods for making same |
| US6063464A (en) * | 1998-04-23 | 2000-05-16 | Hna Holdings, Inc. | Isosorbide containing polyesters and methods for making same |
| US6150494A (en) | 1998-04-30 | 2000-11-21 | Eastman Chemical Company | Polymers containing optical brightener compounds copolymerized therein and methods of making and using therefor |
| GB9902808D0 (en) * | 1998-05-06 | 1999-03-31 | Dow Corning Sa | Adhesive device |
| TW500765B (en) * | 1998-05-13 | 2002-09-01 | Sumitomo Chemical Co | Thermoplastic resin composition and heat-resistant tray for IC |
| US5962625A (en) * | 1998-06-24 | 1999-10-05 | Eastman Chemical Company | High clarity polyester containing sub-visual antimony phosphate derivatives particles |
| US6211309B1 (en) * | 1998-06-29 | 2001-04-03 | Basf Corporation | Water-dispersable materials |
| US6727294B2 (en) * | 1998-07-28 | 2004-04-27 | Mitsubishi Engineering-Plastics Corporation | Thermoplastic resin composition containing a naphthalene dicarboxylic acid moiety and an aliphatic diol moiety |
| US6639067B1 (en) * | 1998-09-09 | 2003-10-28 | Willard C. Brinegar | Continuous process for the production of anhydrosugar alcohols |
| US6255523B1 (en) | 1998-09-18 | 2001-07-03 | Mcwhorter Technologies, Inc. | Power coatings based on branched oligoesters and non-emissive uretdione polyisocyanates |
| JP2001066701A (ja) | 1999-08-25 | 2001-03-16 | Mitsubishi Rayon Co Ltd | 光拡散性シートおよび透過型スクリーン |
| GB9902823D0 (en) * | 1998-12-23 | 1999-03-31 | Dow Corning Sa | Biocompatible coatings |
| US6232504B1 (en) * | 1998-12-29 | 2001-05-15 | University Of Delaware | Functionalized monolith catalyst and process for production of ketenes |
| WO2000044819A1 (en) * | 1999-01-28 | 2000-08-03 | Eastman Chemical Company | Photocurable coatings for polyester articles |
| US6320042B1 (en) * | 1999-03-03 | 2001-11-20 | Konica Corporation | Polarizing plate protective cellulose triacetate film |
| US6221556B1 (en) * | 1999-03-05 | 2001-04-24 | General Electric Company | Article for optical data storage device |
| JP2000352620A (ja) | 1999-03-31 | 2000-12-19 | Konica Corp | 光学フィルム、偏光板及び液晶表示装置 |
| US6001910A (en) | 1999-04-09 | 1999-12-14 | National Starch And Chemical Investment Holding Corporation | Use of anionic or cationic plasticizers with sulfonated polyesters in hot melt formulations |
| US6120889A (en) * | 1999-06-03 | 2000-09-19 | Eastman Chemical Company | Low melt viscosity amorphous copolyesters with enhanced glass transition temperatures |
| US6183848B1 (en) * | 1999-06-03 | 2001-02-06 | Eastman Chemical Company | Low melt viscosity amorphous copolyesters with enhanced glass transition temperatures having improved gas barrier properties |
| US6287656B1 (en) * | 1999-06-03 | 2001-09-11 | Eastman Chemical Corporation | Low melt viscosity amorphous copolyesters having improved resistance to lipids |
| EP1066825A1 (en) | 1999-06-17 | 2001-01-10 | The Procter & Gamble Company | An anti-microbial body care product |
| US6191209B1 (en) * | 1999-06-30 | 2001-02-20 | Ciba Specialty Chemicals Corporation | Polyester compositions of low residual aldehyde content |
| US20030032737A1 (en) | 1999-06-30 | 2003-02-13 | Stephen Andrews | Polyester compositions of low residual aldehyde content |
| US7176252B2 (en) * | 1999-07-29 | 2007-02-13 | Dover Chemical Corporation | Solid melt blended phosphite composites |
| CA2384356A1 (en) | 1999-09-27 | 2001-04-05 | Ciba Specialty Chemicals Holding Inc. | Polyester compositions of low residual aldehyde content |
| JP2001098086A (ja) | 1999-09-29 | 2001-04-10 | Fuji Photo Film Co Ltd | セルロースエステルフイルムの製造方法およびセルロースエステルフイルムの複屈折率上昇方法 |
| JP4373577B2 (ja) | 1999-11-25 | 2009-11-25 | 帝人化成株式会社 | 光拡散性芳香族ポリカーボネート樹脂組成物 |
| US6576309B2 (en) * | 1999-12-02 | 2003-06-10 | Associated Packaging Enterprises | Thermoplastic compositions having high dimensional stability |
| US6352783B1 (en) * | 1999-12-13 | 2002-03-05 | Eastman Kodak Company | Copolyester containing 4,4'-biphenyldicarboxylic acid, 1,4-cyclohexanedimethanol and an ultraviolet light absorbing compound and articles made therefrom |
| AU3687401A (en) * | 2000-02-11 | 2001-08-20 | U S Army Inst Of Surgical Res | Pacifier pulse oximeter sensor |
| US6354986B1 (en) * | 2000-02-16 | 2002-03-12 | Gambro, Inc. | Reverse-flow chamber purging during centrifugal separation |
| DE10009756B4 (de) * | 2000-03-01 | 2004-03-25 | Ems-Chemie Ag | Farblose, hochtransparente Polyamid-Blends mit verbesserter Spannungsrissbeständigkeit |
| JP2001273723A (ja) * | 2000-03-28 | 2001-10-05 | Matsushita Electric Ind Co Ltd | ハードディスク装置、媒体及び情報集合体 |
| US6225436B1 (en) * | 2000-04-07 | 2001-05-01 | The Dow Chemical Company | Polycarbonate preparation process |
| US6593425B2 (en) | 2000-05-31 | 2003-07-15 | General Electric Company | Data storage media containing transparent polycarbonate blends |
| US6803442B2 (en) * | 2000-06-05 | 2004-10-12 | Ftex, Incorporated | Masterbatch method for processing polyester resin and articles thereof |
| FR2810040B1 (fr) | 2000-06-09 | 2004-04-09 | Roquette Freres | Procede de purification d'une composition contenant au moins un produit de deshydratation interne d'un sucre hydrogene |
| US6458915B1 (en) * | 2000-10-13 | 2002-10-01 | Eastman Chemical Company | Process for producing poly(1,4-cyclohexylenedimethylene 1,4-cyclohexanedicarboxylate) and the reactor grade polyester therefrom |
| EP1349882A4 (en) | 2000-11-09 | 2006-07-05 | Avery Dennison Corp | POLYMERIC FLUORESCENT ARTICLES WITH PROTECTIVE LAYER FORMED FROM ULTRAVIOLET LIGHT-ABSORBING POLYMER |
| US6448334B1 (en) | 2000-12-19 | 2002-09-10 | General Electric Company | Translucent polycarbonate composition, method for preparation thereof, and articles derived therefrom |
| US6635698B2 (en) | 2000-12-22 | 2003-10-21 | General Electric Company | Flame retardant polycarbonate polyester composition |
| ATE352583T1 (de) | 2000-12-29 | 2007-02-15 | Ciba Sc Holding Ag | Polyesterzusammensetzungen mit geringem restaldehydgehalt |
| US6573328B2 (en) * | 2001-01-03 | 2003-06-03 | Loctite Corporation | Low temperature, fast curing silicone compositions |
| US6323304B1 (en) | 2001-01-12 | 2001-11-27 | General Electric Company | Melt polycarbonate catalyst systems |
| US6551688B2 (en) | 2001-02-28 | 2003-04-22 | Eastman Chemical Company | Calendered polyester films or sheets having a haze value of less than five percent |
| US20020198297A1 (en) | 2001-03-02 | 2002-12-26 | Odorisio Paul A. | Polyester and polyamide compositions of low residual aldehyde content |
| US6908650B2 (en) | 2001-03-02 | 2005-06-21 | Ciba Specialty Chemicals Corporation | Polyester and polyamide compositions of low residual aldehyde content |
| ES2269697T3 (es) | 2001-03-28 | 2007-04-01 | Ciba Specialty Chemicals Holding Inc. | Procedimiento para la preparacion de un poliester estabilizado. |
| US7030181B2 (en) | 2001-04-11 | 2006-04-18 | Eastman Chemical Company | Films prepared from plasticized polyesters |
| US6586165B2 (en) * | 2001-04-27 | 2003-07-01 | Eastman Kodak Company | Photographic elements coated on transparent support with reflective protective overcoat |
| US6733716B2 (en) * | 2001-05-21 | 2004-05-11 | Sabel Plastechs Inc. | Method of making a stretch/blow molded article (bottle) with an integral projection such as a handle |
| US6599994B2 (en) * | 2001-07-18 | 2003-07-29 | Eastman Chemical Company | Polyester blends and heat shrinkable films made therefrom |
| US6740377B2 (en) | 2001-09-14 | 2004-05-25 | Eastman Chemical Company | Polyester having improved crystallization behavior and extrusion blow molded articles made therefrom |
| US6669980B2 (en) * | 2001-09-18 | 2003-12-30 | Scimed Life Systems, Inc. | Method for spray-coating medical devices |
| JP2003105073A (ja) * | 2001-09-27 | 2003-04-09 | Asahi Kasei Corp | 脂肪族ポリエステルの製造方法 |
| US6773653B2 (en) * | 2001-10-05 | 2004-08-10 | Avery Dennison Corporation | In-mold labeling method |
| KR100459654B1 (ko) * | 2001-10-12 | 2004-12-03 | 에스케이케미칼주식회사 | 1,4-사이클로헥산디메탄올이 공중합된 폴리에스테르수지의 제조방법 |
| US6437083B1 (en) * | 2001-12-06 | 2002-08-20 | General Electric Company | Process for preparing branched aromatic polycarbonates |
| US6504002B1 (en) * | 2001-12-21 | 2003-01-07 | General Electric Company | Process for the production of branched melt polycarbonate by late addition of fries-inducing catalyst |
| ES2286405T3 (es) * | 2002-02-01 | 2007-12-01 | Basf Corporation | Extendedores de cadena oligomeros para el procesamiento, procesamiento y reciclado de polimeros de condensacion, sintesis, composiciones y aplicaciones. |
| US7037576B2 (en) * | 2002-02-06 | 2006-05-02 | Eastman Chemical Company | Polyester or copolyester/polyolefin laminate structures and methods of making the same |
| US6721102B2 (en) * | 2002-03-11 | 2004-04-13 | Eastman Kodak Company | Surface formed complex polymer lenses for visible light diffusion |
| US20030195295A1 (en) | 2002-04-16 | 2003-10-16 | General Electric Company | Miscible blends of polyesters and polycarbonates with good thermal characteristics, and related processes and articles |
| US6818730B2 (en) * | 2002-04-26 | 2004-11-16 | E. I. Du Pont De Nemours And Company | Process to produce polyesters which incorporate isosorbide |
| US6742533B2 (en) | 2002-06-04 | 2004-06-01 | Charles J. Olson | Temporary outdoor shelter |
| US6656577B1 (en) * | 2002-06-14 | 2003-12-02 | E. I. Du Pont De Nemours & Company | Process for making poly(ethylene-co-isosorbide) terephthalate polymer |
| JP2004035657A (ja) * | 2002-07-01 | 2004-02-05 | Toyobo Co Ltd | 共重合ポリエステルの製造方法 |
| DE60332949D1 (de) | 2002-07-24 | 2010-07-22 | Covidien Ag | Verfahren zum schmieren von injektionsnadeln mit strahlenhärtbarem silikonmaterial |
| DE60317282T2 (de) * | 2002-09-17 | 2008-02-14 | Mitsubishi Gas Chemical Co., Inc. | Polyesterharzzusammensetzung |
| US6818276B2 (en) * | 2002-10-24 | 2004-11-16 | Eastman Kodak Company | Light management film with colorant receiving layer |
| WO2004039860A1 (ja) | 2002-10-31 | 2004-05-13 | Mitsubishi Chemical Corporation | ポリエステル樹脂、ポリエステル樹脂組成物及びこれを用いて得られるシート、フィルム並びに中空成形容器 |
| US6914120B2 (en) * | 2002-11-13 | 2005-07-05 | Eastman Chemical Company | Method for making isosorbide containing polyesters |
| WO2004044265A2 (en) * | 2002-11-13 | 2004-05-27 | Technology Resource International Corporation | Protective coatings and methods of applying and using the same |
| US6896966B2 (en) * | 2002-11-22 | 2005-05-24 | Eastman Chemical Company | Articles of manufacture incorporating polyester/polycarbonate blends |
| AU2003295672B2 (en) * | 2002-12-10 | 2008-05-22 | Johnson Polymer, Llc | High flow engineering theremoplastic compositions and products made therefrom |
| US7482397B2 (en) | 2003-01-13 | 2009-01-27 | Eastman Chemical Company | Polycarbonate compositions |
| US20040143041A1 (en) | 2003-01-13 | 2004-07-22 | Pearson Jason Clay | Polyester compositions |
| US7004583B2 (en) * | 2003-01-29 | 2006-02-28 | East Bay Technologies | Eyewear lenses and methods of manufacturing |
| JP2004244497A (ja) | 2003-02-13 | 2004-09-02 | Konica Minolta Holdings Inc | セルロースエステルフィルム、偏光板及び液晶表示装置 |
| JP2004292558A (ja) | 2003-03-26 | 2004-10-21 | Konica Minolta Holdings Inc | セルロースエステルフィルムとその製造方法および偏光板保護フィルム |
| US6818293B1 (en) | 2003-04-24 | 2004-11-16 | Eastman Chemical Company | Stabilized polyester fibers and films |
| TW200427727A (en) | 2003-05-20 | 2004-12-16 | Mitsubishi Plastics Inc | Aliphatic polyester based resin reflection film and reflection plate |
| US7046439B2 (en) | 2003-05-22 | 2006-05-16 | Eastman Kodak Company | Optical element with nanoparticles |
| CN1809766B (zh) | 2003-06-17 | 2010-05-26 | 帝人化成株式会社 | 正下型背光式液晶显示装置及光漫射板 |
| US20050010017A1 (en) * | 2003-07-11 | 2005-01-13 | Blakely Dale Milton | Addition of UV inhibitors to pet process for maximum yield |
| JP2007521378A (ja) | 2003-07-11 | 2007-08-02 | イーストマン ケミカル カンパニー | 最大歩留りのためのpetプロセスへのuv吸収剤の添加 |
| EP1666521B1 (en) | 2003-09-11 | 2014-03-26 | Teijin Dupont Films Japan Limited | Polyester film |
| US7237360B2 (en) | 2003-09-23 | 2007-07-03 | Cemusa, Inc. | Shelter |
| JP4384636B2 (ja) | 2003-09-25 | 2009-12-16 | 大阪瓦斯株式会社 | ポリエステル樹脂組成物ならびに光学材料 |
| US7235623B2 (en) * | 2003-11-26 | 2007-06-26 | Eastman Chemical Company | Polyester compositions for calendering |
| DE602004027292D1 (de) * | 2003-12-02 | 2010-07-01 | Eastman Chem Co | Hohlraumhaltige polyesterschrumpffolie |
| US20050119359A1 (en) | 2003-12-02 | 2005-06-02 | Shelby Marcus D. | Void-containing polyester shrink film |
| US7169880B2 (en) | 2003-12-04 | 2007-01-30 | Eastman Chemical Company | Shaped articles from cycloaliphatic polyester compositions |
| US8192676B2 (en) * | 2004-02-12 | 2012-06-05 | Valspar Sourcing, Inc. | Container having barrier properties and method of manufacturing the same |
| US20060004151A1 (en) * | 2004-06-30 | 2006-01-05 | General Electric Company | Copolymers containing indan moieties and blends thereof |
| CN101048275A (zh) | 2004-08-31 | 2007-10-03 | 因维斯塔技术有限公司 | 具有低雾度的聚酯-聚酰胺共混物 |
| US20060094858A1 (en) * | 2004-10-28 | 2006-05-04 | Turner Sam R | Novel copolyester compositions with improved impact strength at low temperatures |
| US8071695B2 (en) * | 2004-11-12 | 2011-12-06 | Eastman Chemical Company | Polyeste blends with improved stress whitening for film and sheet applications |
| US7582690B2 (en) | 2004-11-19 | 2009-09-01 | Eastman Chemical Company | Stabilized aliphatic polyester compositions |
| US7375154B2 (en) * | 2004-12-06 | 2008-05-20 | Eastman Chemical Company | Polyester/polyamide blend having improved flavor retaining property and clarity |
| US20060135668A1 (en) * | 2004-12-21 | 2006-06-22 | Hayes Richard A | Polyesters containing natural mineral materials, processes for producing such polyesters, and shaped articles produced therefrom |
| US7114623B2 (en) | 2005-02-04 | 2006-10-03 | John Robinson | Point of purchase display with interchangeable placards |
| WO2007053549A1 (en) | 2005-10-28 | 2007-05-10 | Eastman Chemical Company | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| US7955533B2 (en) | 2005-03-02 | 2011-06-07 | Eastman Chemical Company | Process for the preparation of transparent shaped articles |
| US7964258B2 (en) | 2005-03-02 | 2011-06-21 | Eastman Chemical Company | Transparent, oxygen-scavenging compositions and articles prepared therefrom |
| US7968164B2 (en) | 2005-03-02 | 2011-06-28 | Eastman Chemical Company | Transparent polymer blends and articles prepared therefrom |
| US7959836B2 (en) | 2005-03-02 | 2011-06-14 | Eastman Chemical Company | Process for the preparation of transparent, shaped articles containing polyesters comprising a cyclobutanediol |
| US7955674B2 (en) | 2005-03-02 | 2011-06-07 | Eastman Chemical Company | Transparent polymer blends containing polyesters comprising a cyclobutanediol and articles prepared therefrom |
| US7959998B2 (en) | 2005-03-02 | 2011-06-14 | Eastman Chemical Company | Transparent, oxygen-scavenging compositions containing polyesters comprising a cyclobutanediol and articles prepared therefrom |
| US20060199871A1 (en) | 2005-03-02 | 2006-09-07 | Hale Wesley R | Multilayered, transparent articles and a process for their preparation |
| US20060270773A1 (en) | 2005-05-26 | 2006-11-30 | Hale Wesley R | Polyester-polycarbonate blends for diffuser sheets with improved luminance |
| US20060270806A1 (en) | 2005-05-26 | 2006-11-30 | Hale Wesley R | Miscible high Tg polyester/polymer blend compositions and films formed therefrom |
| ATE505500T1 (de) * | 2005-10-28 | 2011-04-15 | Eastman Chem Co | Polyesterzusammensetzungen mit cyclobutandiol mit hoher glasübergangstemperatur und daraus hergestellte artikel |
| US7427430B2 (en) * | 2005-12-29 | 2008-09-23 | Honeywell International Inc. | Polyamide blend composition having excellent gas barrier performance |
-
2006
- 2006-10-27 AT AT06836651T patent/ATE505500T1/de not_active IP Right Cessation
- 2006-10-27 WO PCT/US2006/042069 patent/WO2007053460A1/en not_active Ceased
- 2006-10-27 JP JP2008538015A patent/JP2009513792A/ja not_active Withdrawn
- 2006-10-27 KR KR1020087009998A patent/KR20080059259A/ko not_active Withdrawn
- 2006-10-27 AT AT06827057T patent/ATE486904T1/de not_active IP Right Cessation
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- 2006-10-27 WO PCT/US2006/042291 patent/WO2007053548A2/en not_active Ceased
- 2006-10-27 JP JP2008538072A patent/JP2009513799A/ja not_active Withdrawn
- 2006-10-27 EP EP06827057A patent/EP1940908B1/en active Active
- 2006-10-27 CA CA002625671A patent/CA2625671A1/en not_active Abandoned
- 2006-10-27 CN CN201310050023.9A patent/CN103351583B/zh active Active
- 2006-10-27 US US12/091,570 patent/US8299204B2/en active Active
- 2006-10-27 PL PL06826819T patent/PL1940955T3/pl unknown
- 2006-10-27 CA CA002625823A patent/CA2625823A1/en not_active Abandoned
- 2006-10-27 WO PCT/US2006/041917 patent/WO2007053434A1/en not_active Ceased
- 2006-10-27 BR BRPI0618017-5A patent/BRPI0618017A2/pt not_active IP Right Cessation
- 2006-10-27 KR KR1020087009995A patent/KR101410145B1/ko active Active
- 2006-10-27 KR KR1020087009816A patent/KR101410122B1/ko active Active
- 2006-10-27 MX MX2008005531A patent/MX2008005531A/es unknown
- 2006-10-27 US US12/091,566 patent/US20080293857A1/en not_active Abandoned
- 2006-10-27 CA CA002625842A patent/CA2625842A1/en not_active Abandoned
- 2006-10-27 WO PCT/US2006/042293 patent/WO2007053550A1/en not_active Ceased
- 2006-10-27 EP EP06836651A patent/EP1940907B1/en active Active
- 2006-10-27 JP JP2008537968A patent/JP2009513791A/ja active Pending
- 2006-10-27 CA CA002625846A patent/CA2625846A1/en not_active Abandoned
- 2006-10-27 KR KR1020087009977A patent/KR20080066704A/ko not_active Withdrawn
- 2006-10-27 CA CA002625817A patent/CA2625817A1/en not_active Abandoned
- 2006-10-27 MY MYPI20081313A patent/MY146987A/en unknown
- 2006-10-27 JP JP2008538073A patent/JP5543713B2/ja active Active
- 2006-10-27 PL PL06827057T patent/PL1940908T3/pl unknown
- 2006-10-27 JP JP2008538074A patent/JP5543714B2/ja active Active
-
2008
- 2008-04-25 KR KR1020087010007A patent/KR101274934B1/ko active Active
-
2013
- 2013-09-06 JP JP2013185077A patent/JP6325782B2/ja active Active
-
2015
- 2015-02-04 JP JP2015020169A patent/JP6325991B2/ja active Active
-
2016
- 2016-09-27 JP JP2016188242A patent/JP2017039941A/ja active Pending
-
2017
- 2017-12-26 JP JP2017249028A patent/JP2018083952A/ja active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6043322A (en) * | 1996-12-28 | 2000-03-28 | Eastman Chemical Company | Clear polycarbonate and polyester blends |
| US5989663A (en) * | 1996-12-30 | 1999-11-23 | Eastman Chemical Company | Blow-molding polyesters from terephthalic acid, 2, 2, 4, 4-tetramethyl-1,3-cyclobutanediol, and ethylene glycol |
| JP2003165832A (ja) * | 2001-03-28 | 2003-06-10 | Toyobo Co Ltd | ポリエステルおよびその製造方法並びにフイルム |
| JP2005521772A (ja) * | 2002-03-27 | 2005-07-21 | イーストマン ケミカル カンパニー | 黄色度の低下したポリエステル/ポリカーボネートブレンド |
| JP2004161801A (ja) * | 2002-11-08 | 2004-06-10 | Asahi Denka Kogyo Kk | ポリエステル系可塑剤及び塩素含有樹脂組成物 |
| JP2005132952A (ja) * | 2003-10-30 | 2005-05-26 | Asahi Denka Kogyo Kk | ポリエステル樹脂組成物 |
| JP2008544022A (ja) * | 2005-06-17 | 2008-12-04 | イーストマン ケミカル カンパニー | インヘレント粘度と中程度のガラス転移温度との特定の組合せを有するシクロブタンジオールを含むポリエステル組成物及びそれから製造された物品 |
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| US10093796B2 (en) | 2011-11-01 | 2018-10-09 | Midori Anzen Co., Ltd. | Resin composition and molded body |
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