JP2008115075A5 - - Google Patents
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- Publication number
- JP2008115075A5 JP2008115075A5 JP2007312520A JP2007312520A JP2008115075A5 JP 2008115075 A5 JP2008115075 A5 JP 2008115075A5 JP 2007312520 A JP2007312520 A JP 2007312520A JP 2007312520 A JP2007312520 A JP 2007312520A JP 2008115075 A5 JP2008115075 A5 JP 2008115075A5
- Authority
- JP
- Japan
- Prior art keywords
- composite oxide
- positive electrode
- lithium
- active material
- electrode active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000002131 composite material Substances 0.000 claims description 123
- 229910052744 lithium Inorganic materials 0.000 claims description 82
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 81
- 239000002245 particle Substances 0.000 claims description 56
- 239000000203 mixture Substances 0.000 claims description 42
- 239000011163 secondary particle Substances 0.000 claims description 41
- 239000007774 positive electrode material Substances 0.000 claims description 29
- 239000011164 primary particle Substances 0.000 claims description 26
- 229910052759 nickel Inorganic materials 0.000 claims description 24
- 229910052748 manganese Inorganic materials 0.000 claims description 23
- 229910052782 aluminium Inorganic materials 0.000 claims description 17
- 229910052802 copper Inorganic materials 0.000 claims description 15
- 229910052718 tin Inorganic materials 0.000 claims description 15
- 229910052804 chromium Inorganic materials 0.000 claims description 14
- 229910052732 germanium Inorganic materials 0.000 claims description 14
- 229910052742 iron Inorganic materials 0.000 claims description 14
- 229910052719 titanium Inorganic materials 0.000 claims description 14
- 229910052725 zinc Inorganic materials 0.000 claims description 14
- 239000011149 active material Substances 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- 239000011255 nonaqueous electrolyte Substances 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000002482 conductive additive Substances 0.000 claims description 2
- 239000011572 manganese Substances 0.000 description 43
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 29
- 230000000052 comparative effect Effects 0.000 description 16
- 238000003860 storage Methods 0.000 description 14
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 13
- 239000010949 copper Substances 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 11
- 238000010304 firing Methods 0.000 description 11
- 239000003960 organic solvent Substances 0.000 description 11
- 239000010936 titanium Substances 0.000 description 11
- 239000008151 electrolyte solution Substances 0.000 description 8
- 238000011049 filling Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- -1 polytetrafluoroethylene Polymers 0.000 description 8
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000007773 negative electrode material Substances 0.000 description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- 239000002033 PVDF binder Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 238000010828 elution Methods 0.000 description 4
- 238000012423 maintenance Methods 0.000 description 4
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 229910014689 LiMnO Inorganic materials 0.000 description 3
- 229910012752 LiNi0.5Mn0.5O2 Inorganic materials 0.000 description 3
- 229910013870 LiPF 6 Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 238000007873 sieving Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
- 229910013372 LiC 4 Inorganic materials 0.000 description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000005518 polymer electrolyte Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- YTZKOQUCBOVLHL-UHFFFAOYSA-N tert-butylbenzene Chemical compound CC(C)(C)C1=CC=CC=C1 YTZKOQUCBOVLHL-UHFFFAOYSA-N 0.000 description 2
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 1
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 description 1
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
- FZKPQHFEMFIDNR-UHFFFAOYSA-N 2-hydroxyethyl hydrogen sulfite Chemical compound OCCOS(O)=O FZKPQHFEMFIDNR-UHFFFAOYSA-N 0.000 description 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 1
- 229910001148 Al-Li alloy Inorganic materials 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910000733 Li alloy Inorganic materials 0.000 description 1
- 229910007975 Li-Ga Inorganic materials 0.000 description 1
- 229910008029 Li-In Inorganic materials 0.000 description 1
- 229910008367 Li-Pb Inorganic materials 0.000 description 1
- 229910015015 LiAsF 6 Inorganic materials 0.000 description 1
- 229910013063 LiBF 4 Inorganic materials 0.000 description 1
- 229910013684 LiClO 4 Inorganic materials 0.000 description 1
- 229910014393 LiNi1/2Mn1/2O2 In Inorganic materials 0.000 description 1
- 229910014447 LiNi1/3Mn1/3M1/3O2 Inorganic materials 0.000 description 1
- 229910012513 LiSbF 6 Inorganic materials 0.000 description 1
- 229910006620 Li—Ga Inorganic materials 0.000 description 1
- 229910006670 Li—In Inorganic materials 0.000 description 1
- 229910006738 Li—Pb Inorganic materials 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- 229910019064 Mg-Si Inorganic materials 0.000 description 1
- 229910019406 Mg—Si Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000006182 cathode active material Substances 0.000 description 1
- 150000005678 chain carbonates Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 150000005676 cyclic carbonates Chemical class 0.000 description 1
- HHNHBFLGXIUXCM-GFCCVEGCSA-N cyclohexylbenzene Chemical compound [CH]1CCCC[C@@H]1C1=CC=CC=C1 HHNHBFLGXIUXCM-GFCCVEGCSA-N 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 150000008423 fluorobenzenes Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 239000001989 lithium alloy Substances 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 1
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007312520A JP4813450B2 (ja) | 2001-11-22 | 2007-12-03 | リチウム含有複合酸化物およびそれを用いた非水二次電池 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001357729 | 2001-11-22 | ||
| JP2001357729 | 2001-11-22 | ||
| JP2007312520A JP4813450B2 (ja) | 2001-11-22 | 2007-12-03 | リチウム含有複合酸化物およびそれを用いた非水二次電池 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002338430A Division JP4070585B2 (ja) | 2001-11-22 | 2002-11-21 | リチウム含有複合酸化物およびそれを用いた非水二次電池 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008115075A JP2008115075A (ja) | 2008-05-22 |
| JP2008115075A5 true JP2008115075A5 (enExample) | 2009-01-22 |
| JP4813450B2 JP4813450B2 (ja) | 2011-11-09 |
Family
ID=39501327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007312520A Expired - Lifetime JP4813450B2 (ja) | 2001-11-22 | 2007-12-03 | リチウム含有複合酸化物およびそれを用いた非水二次電池 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4813450B2 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10161057B2 (en) | 2011-03-31 | 2018-12-25 | Toda Kogyo Corporation | Manganese/nickel composite oxide particles and process for producing the manganese nickel composite oxide particles, positive electrode active substance particles for non-aqueous electrolyte secondary batteries and process for producing the positive electrode active substance particles, and non-aqueous electrolyte secondary battery |
| JP5737513B2 (ja) * | 2011-07-07 | 2015-06-17 | 戸田工業株式会社 | 非水電解質二次電池用正極活物質粒子粉末及びその製造方法、並びに非水電解質二次電池 |
| JP2013191381A (ja) * | 2012-03-13 | 2013-09-26 | Nissan Motor Co Ltd | 平板積層型電池およびその製造方法 |
| US20150380723A1 (en) * | 2013-02-11 | 2015-12-31 | Basf Se | Active cathode material and its use in rechargeable electrochemical cells |
| EP2954576B1 (en) | 2013-02-11 | 2018-05-30 | Basf Se | Active cathode material and its use in rechargeable electrochemical cells |
| WO2014133069A1 (ja) * | 2013-02-28 | 2014-09-04 | 日産自動車株式会社 | 正極活物質、正極材料、正極および非水電解質二次電池 |
| US9306212B2 (en) | 2013-07-19 | 2016-04-05 | Samsung Sdi Co., Ltd. | Positive active material for rechargeable lithium battery, and positive electrode and rechargeable lithium battery including the same |
| JP6096985B1 (ja) * | 2015-09-14 | 2017-03-15 | 株式会社東芝 | 非水電解質電池及び電池パック |
| JP7054479B2 (ja) | 2016-04-04 | 2022-04-14 | 株式会社Gsユアサ | 蓄電素子 |
| JP2018006346A (ja) * | 2017-08-16 | 2018-01-11 | Jx金属株式会社 | リチウムイオン電池用正極活物質、リチウムイオン電池用正極、及び、リチウムイオン電池 |
| CN115380405A (zh) * | 2020-04-16 | 2022-11-22 | 三洋电机株式会社 | 非水电解质二次电池用正极活性物质、及非水电解质二次电池 |
| CN115943504A (zh) * | 2020-08-28 | 2023-04-07 | 三洋电机株式会社 | 非水电解质二次电池用正极及非水电解质二次电池 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3550783B2 (ja) * | 1994-05-16 | 2004-08-04 | 東ソー株式会社 | リチウム含有遷移金属複合酸化物及びその製造方法並びにその用途 |
| JP3008793B2 (ja) * | 1994-12-16 | 2000-02-14 | 松下電器産業株式会社 | リチウム二次電池用正極活物質の製造法 |
| JP3130813B2 (ja) * | 1995-11-24 | 2001-01-31 | 富士化学工業株式会社 | リチウムニッケル複合酸化物、その製造方法および二次電池用正極活物質 |
| JP3897387B2 (ja) * | 1995-12-29 | 2007-03-22 | 株式会社ジーエス・ユアサコーポレーション | リチウム二次電池用正極活物質の製造方法 |
| JP3561607B2 (ja) * | 1997-05-08 | 2004-09-02 | 三洋電機株式会社 | 非水電解質二次電池及び正極材料の製造方法 |
| JP3524762B2 (ja) * | 1998-03-19 | 2004-05-10 | 三洋電機株式会社 | リチウム二次電池 |
| JPH11307094A (ja) * | 1998-04-20 | 1999-11-05 | Chuo Denki Kogyo Co Ltd | リチウム二次電池用正極活物質とリチウム二次電池 |
| JP3653409B2 (ja) * | 1999-01-29 | 2005-05-25 | 三洋電機株式会社 | リチウム二次電池用正極活物質及びその製造方法、この正極活物質を用いたリチウム二次電池用正極及びその製造方法、この正極を用いたリチウム二次電池及びその製造方法 |
| JP2000260432A (ja) * | 1999-03-09 | 2000-09-22 | Mitsubishi Electric Corp | 正極活物質およびその製造方法並びに上記正極活物質を用いたリチウムイオン二次電池 |
| JP4086654B2 (ja) * | 2000-11-16 | 2008-05-14 | 日立マクセル株式会社 | リチウム含有複合酸化物およびその製造方法、並びに非水二次電池 |
| JP2002298843A (ja) * | 2001-03-29 | 2002-10-11 | Sumitomo Metal Mining Co Ltd | 非水系電解質二次電池用正極活物質およびその製造方法 |
| JP4649801B2 (ja) * | 2001-08-24 | 2011-03-16 | 株式会社Gsユアサ | リチウム二次電池用正極活物質及びそれを用いたリチウム二次電池 |
| JP3675439B2 (ja) * | 2001-11-27 | 2005-07-27 | 日本電気株式会社 | 二次電池用正極活物質およびそれを用いた二次電池用正極および二次電池 |
-
2007
- 2007-12-03 JP JP2007312520A patent/JP4813450B2/ja not_active Expired - Lifetime
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