JP2007506836A5 - - Google Patents

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Publication number
JP2007506836A5
JP2007506836A5 JP2006527986A JP2006527986A JP2007506836A5 JP 2007506836 A5 JP2007506836 A5 JP 2007506836A5 JP 2006527986 A JP2006527986 A JP 2006527986A JP 2006527986 A JP2006527986 A JP 2006527986A JP 2007506836 A5 JP2007506836 A5 JP 2007506836A5
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Japan
Prior art keywords
substituted
composition
actinic radiation
unsubstituted
photopolymerizable composition
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JP2006527986A
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JP2007506836A (ja
JP4546477B2 (ja
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Priority claimed from US10/672,554 external-priority patent/US7026367B2/en
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Claims (4)

  1. 式I
    Figure 2007506836
    (式中、Ar1が、置換フェニル、非置換もしくは置換C7-30アリール、または非置換もしくは置換C3-30ヘテロアリールであり、前記置換Ar1が、電子吸引基であるか、または電子供与基と結合した状態の電子吸引基である置換基を有する)のアニオンを有し、かつ少なくとも1つの炭素原子および正に荷電した窒素原子または正に荷電したリン原子のいずれかを含有するカチオンを有する、アリールスルフィン酸塩;および
    トリアリールスルホニウム塩;
    を含む組成物であって、その組成物が400から1000ナノメートル未満の範囲の波長の化学線に暴露されたときにラジカルを形成し、又その組成物が400から1000ナノメートル未満の範囲の波長の化学線を吸収する添加成分を含まない、組成物
  2. エチレン性不飽和モノマーと、式I
    Figure 2007506836
    (式中、Ar1は、置換フェニル、非置換もしくは置換C7-30アリール、または非置換もしくは置換C3-30ヘテロアリールであり、前記置換Ar1が、電子吸引基であるか、または電子供与基と結合した状態の電子吸引基である置換基を有する)のアニオン;および
    トリアリールスルホニウムカチオン;を含むトリアリールスルホニウムアリールスルフィン酸塩と、を含む組成物であって、その組成物が400から1000ナノメートル未満の範囲の波長の化学線に暴露されたときにラジカルを形成し、又その組成物が400から1000ナノメートル未満の範囲の波長の化学線を吸収する添加成分を含まない、組成物
  3. 光重合性組成物がゲル化または硬化するまで、光重合性組成物に化学線を照射することを含む、光重合方法であって、前記光重合性組成物が:
    エチレン性不飽和モノマー;
    式I
    Figure 2007506836
    (式中、Ar1が、置換フェニル、非置換もしくは置換C7-30アリール、または非置換もしくは置換C3-30ヘテロアリールであり、前記置換Ar1が、電子吸引基であるか、または電子供与基と結合した状態の電子吸引基である置換基を有する)のアニオンを有し、かつ少なくとも1つの炭素原子および正に荷電した窒素原子または正に荷電したリン原子のいずれかを含有するカチオンを有するアリールスルフィン酸塩;
    トリアリールスルホニウム塩;
    を含む、光重合方法であって、その光重合性組成物が化学線に暴露されたときにラジカルを形成し、又その光重合性組成物が化学線を競合的に吸収する添加成分を含まない組成物である、光重合方法
  4. 光重合性組成物がゲル化または硬化するまで、光重合性組成物に化学線を照射することを含む、光重合方法であって、前記光重合性組成物が:
    エチレン性不飽和モノマー;
    式I
    Figure 2007506836
    (式中、Ar1が、置換フェニル、非置換もしくは置換C7-30アリール、または非置換もしくは置換C3-30ヘテロアリールであり、前記置換Ar1が、電子吸引基であるか、または電子供与基と結合した状態の電子吸引基である置換基を有する)のアニオンを有し、かつトリアリールスルホニウムイオンであるカチオンを有するアリールスルフィナートトリアリールスルホニウム塩;
    を含む、光重合方法であって、その光重合性組成物が化学線に暴露されたときにラジカルを形成し、又その光重合性組成物が化学線を競合的に吸収する添加成分を含まない組成物である、光重合方法
JP2006527986A 2003-09-26 2004-08-05 トリアリールスルホニウムおよびアリールスルフィン酸イオンを有する光開始剤 Expired - Fee Related JP4546477B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/672,554 US7026367B2 (en) 2003-09-26 2003-09-26 Photoiniators having triarylsulfonium and arylsulfinate ions
PCT/US2004/025281 WO2005034885A1 (en) 2003-09-26 2004-08-05 Photoinitiators having triarylsulfonium and arylsulfinate ions

Publications (3)

Publication Number Publication Date
JP2007506836A JP2007506836A (ja) 2007-03-22
JP2007506836A5 true JP2007506836A5 (ja) 2007-09-20
JP4546477B2 JP4546477B2 (ja) 2010-09-15

Family

ID=34376395

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006527986A Expired - Fee Related JP4546477B2 (ja) 2003-09-26 2004-08-05 トリアリールスルホニウムおよびアリールスルフィン酸イオンを有する光開始剤

Country Status (6)

Country Link
US (2) US7026367B2 (ja)
EP (1) EP1684698B1 (ja)
JP (1) JP4546477B2 (ja)
KR (1) KR101128245B1 (ja)
CN (1) CN1859893B (ja)
WO (1) WO2005034885A1 (ja)

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