JP2007302879A - 光増感色素 - Google Patents
光増感色素 Download PDFInfo
- Publication number
- JP2007302879A JP2007302879A JP2007099752A JP2007099752A JP2007302879A JP 2007302879 A JP2007302879 A JP 2007302879A JP 2007099752 A JP2007099752 A JP 2007099752A JP 2007099752 A JP2007099752 A JP 2007099752A JP 2007302879 A JP2007302879 A JP 2007302879A
- Authority
- JP
- Japan
- Prior art keywords
- dye
- formula
- photosensitizing dye
- present
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003504 photosensitizing agent Substances 0.000 title claims abstract description 75
- 230000002165 photosensitisation Effects 0.000 title claims abstract description 69
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 29
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 21
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 229910052702 rhenium Inorganic materials 0.000 claims description 3
- 239000000975 dye Substances 0.000 abstract description 70
- 238000010521 absorption reaction Methods 0.000 abstract description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 150000001768 cations Chemical class 0.000 abstract 1
- 229930192474 thiophene Natural products 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 37
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 18
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- 238000000862 absorption spectrum Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 6
- 239000012043 crude product Substances 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 239000012044 organic layer Substances 0.000 description 6
- 229910010413 TiO 2 Inorganic materials 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical class [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- -1 mercury ions Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 3
- OHZAHWOAMVVGEL-UHFFFAOYSA-N 2,2'-bithiophene Chemical compound C1=CSC(C=2SC=CC=2)=C1 OHZAHWOAMVVGEL-UHFFFAOYSA-N 0.000 description 2
- VURYAECWUXGHIB-UHFFFAOYSA-N 3-octyl-2-thiophen-2-ylthiophene Chemical compound C1=CSC(C=2SC=CC=2)=C1CCCCCCCC VURYAECWUXGHIB-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000003480 eluent Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 230000031700 light absorption Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 2
- 238000005381 potential energy Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- LAXRNWSASWOFOT-UHFFFAOYSA-J (cymene)ruthenium dichloride dimer Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Ru+2].[Ru+2].CC(C)C1=CC=C(C)C=C1.CC(C)C1=CC=C(C)C=C1 LAXRNWSASWOFOT-UHFFFAOYSA-J 0.000 description 1
- VMKOFRJSULQZRM-UHFFFAOYSA-N 1-bromooctane Chemical compound CCCCCCCCBr VMKOFRJSULQZRM-UHFFFAOYSA-N 0.000 description 1
- 0 CCC(C)(*)c1c2nccnc2c(C(C)(C)C)[s]1 Chemical compound CCC(C)(*)c1c2nccnc2c(C(C)(C)C)[s]1 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- KWTSZCJMWHGPOS-UHFFFAOYSA-M chloro(trimethyl)stannane Chemical compound C[Sn](C)(C)Cl KWTSZCJMWHGPOS-UHFFFAOYSA-M 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004440 column chromatography Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004770 highest occupied molecular orbital Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
- 229940006461 iodide ion Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/30—Coordination compounds
- H10K85/341—Transition metal complexes, e.g. Ru(II)polypyridine complexes
- H10K85/344—Transition metal complexes, e.g. Ru(II)polypyridine complexes comprising ruthenium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2027—Light-sensitive devices comprising an oxide semiconductor electrode
- H01G9/2031—Light-sensitive devices comprising an oxide semiconductor electrode comprising titanium oxide, e.g. TiO2
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Photovoltaic Devices (AREA)
- Hybrid Cells (AREA)
- Pyridine Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Description
I.Murase,Nippon Kagaku Zasshi,1956,77,682 G.MnerkerおよびF.H.Case,J.Am.Chem.Soc.,1958,80,2745 D.WenkertおよびR.B.Woodward,J.Org,Chem.,1983,48,283 M.Gratzel,J.Photochem.A,2004,164,3、 M.K.Nazeeruddin他、J.Am.Chem.Soc.1993,115,6382 M.K.Nazeeruddin他、J.Am.Chem.Soc.,2001,123,1613 Michael Gratzel他、J.Am.Chem.Soc.2005,127,808 C.Klein他、Inorg.Chem,2005,44,178 Annual Book of ASTM Standard,G159−98 Standard tabels for references solar spectral irradiance at air mass 1.5:direct normal and hemispherical for a 37° tilted surface、Vol.14.04(2003)
X1は次の一般式(3):
Claims (12)
- X1およびX2が同じ基を表し、X2が前記式(3)を表す請求項1記載の光増感色素。
- X1およびX2が同じ基を表し、X2が前記式(4)を表す請求項3記載の光増感色素。
- X1およびX2が同じ基を表し、X2が前記式(5)を表す請求項5記載の光増感色素。
- X1およびX2が同じ基を表し、X2が前記式(6)を表す請求項7記載の光増感色素。
- X1およびX2が同じ基を表し、X2が前記式(7)を表す請求項9記載の光増感色素。
- X1およびX2が同じ基を表し、X2が前記式(8)を表す請求項11記載の光増感色素。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW095116728A TWI319424B (en) | 2006-05-11 | 2006-05-11 | Photosensitizer dye |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2007302879A true JP2007302879A (ja) | 2007-11-22 |
JP4676970B2 JP4676970B2 (ja) | 2011-04-27 |
Family
ID=38701311
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007099752A Expired - Fee Related JP4676970B2 (ja) | 2006-05-11 | 2007-04-05 | 光増感色素 |
Country Status (3)
Country | Link |
---|---|
US (1) | US7321037B2 (ja) |
JP (1) | JP4676970B2 (ja) |
TW (1) | TWI319424B (ja) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009082163A2 (en) * | 2007-12-26 | 2009-07-02 | Dongjin Semichem Co., Ltd. | Novel ru-type sensitizers and method of preparing the same |
JP2009215539A (ja) * | 2008-02-19 | 2009-09-24 | National Central Univ | 感光剤染料 |
WO2009131183A1 (ja) * | 2008-04-24 | 2009-10-29 | シャープ株式会社 | ピリジン系金属錯体、それを用いた光電極およびそれを備えた色素増感太陽電池 |
WO2010021378A1 (ja) * | 2008-08-22 | 2010-02-25 | 日本化薬株式会社 | 色素増感型光電変換素子 |
JP2010084003A (ja) * | 2008-09-30 | 2010-04-15 | Jsr Corp | 色素、色素増感太陽電池及びその製造方法 |
KR101048172B1 (ko) | 2008-12-24 | 2011-07-08 | 한양대학교 산학협력단 | 유기 금속 염료, 이를 구비하는 광감성 기판, 및 염료 감응태양전지 |
KR101050470B1 (ko) | 2010-04-05 | 2011-07-20 | 삼성에스디아이 주식회사 | 루테늄 착체 및 이를 이용한 염료감응 태양전지 |
WO2011115137A1 (ja) * | 2010-03-16 | 2011-09-22 | 宇部興産株式会社 | 置換ビピリジル基を有する二核ルテニウム錯体色素を有する光電変換素子、及び光化学電池 |
US8143399B2 (en) | 2008-02-19 | 2012-03-27 | National Central University | Photosensitizer dye |
JP2012508227A (ja) * | 2008-11-11 | 2012-04-05 | エコール ポリテクニーク フェデラル ドゥ ローザンヌ(エーペーエフエル) | 色素増感された光起電性素子の増感剤用の新規な固定配位子 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4201035B2 (ja) * | 2006-09-05 | 2008-12-24 | セイコーエプソン株式会社 | 電池素子および電子機器 |
US7645879B2 (en) * | 2008-02-19 | 2010-01-12 | National Central University | Photosensitizer dye |
CN101235214B (zh) * | 2008-02-27 | 2012-07-04 | 中国科学院长春应用化学研究所 | 有机钌染料及染料敏化太阳能电池 |
CN101412855B (zh) * | 2008-12-04 | 2011-09-28 | 中国科学院长春应用化学研究所 | 含推S,Se或Te电子基团的联吡啶钌染料及其在染料敏化太阳电池中的应用 |
TWI434894B (zh) * | 2010-05-19 | 2014-04-21 | Univ Nat Central | 有機與無機光敏染料 |
JP4980479B2 (ja) * | 2010-06-02 | 2012-07-18 | 富士フイルム株式会社 | 金属錯体色素、光電変換素子及び色素増感太陽電池 |
CN102277007B (zh) * | 2010-06-08 | 2013-09-11 | 国立清华大学 | 无硫氰酸根配基的光敏剂及敏化染料太阳能电池 |
TWI403514B (zh) * | 2011-01-12 | 2013-08-01 | Univ Nat Central | Photosensitive dye and its manufacturing method |
JP5913223B2 (ja) * | 2012-09-28 | 2016-04-27 | 富士フイルム株式会社 | 金属錯体色素、光電変換素子、色素増感太陽電池、色素溶液および色素吸着電極 |
ITMI20121672A1 (it) * | 2012-10-05 | 2014-04-06 | Eni Spa | Colorante organico per una cella solare sensibilizzata da colorante |
CN103145761B (zh) * | 2012-12-27 | 2016-03-23 | 中国科学院上海硅酸盐研究所 | 利用重结晶法提纯钌络合物粗产品的方法 |
CN103897428B (zh) * | 2012-12-28 | 2016-08-03 | 中国科学院上海硅酸盐研究所 | 联吡啶钌类络合物的合成方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07500630A (ja) * | 1992-08-21 | 1995-01-19 | エコール ポリテクニーク フェデラル ドゥ ローザンヌ (エーペーエフエル) | 有機化合物 |
JP2001237000A (ja) * | 2000-02-22 | 2001-08-31 | Fuji Photo Film Co Ltd | 光電変換素子および光電池ならびに金属錯体色素 |
JP2003342488A (ja) * | 2002-05-30 | 2003-12-03 | Toyota Central Res & Dev Lab Inc | 金属錯体色素、光電極及び色素増感型太陽電池 |
JP2005330469A (ja) * | 2004-04-16 | 2005-12-02 | Jsr Corp | 色素および色素増感太陽電池 |
-
2006
- 2006-05-11 TW TW095116728A patent/TWI319424B/zh not_active IP Right Cessation
- 2006-09-21 US US11/533,769 patent/US7321037B2/en active Active
-
2007
- 2007-04-05 JP JP2007099752A patent/JP4676970B2/ja not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07500630A (ja) * | 1992-08-21 | 1995-01-19 | エコール ポリテクニーク フェデラル ドゥ ローザンヌ (エーペーエフエル) | 有機化合物 |
JP2001237000A (ja) * | 2000-02-22 | 2001-08-31 | Fuji Photo Film Co Ltd | 光電変換素子および光電池ならびに金属錯体色素 |
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US7321037B2 (en) | 2008-01-22 |
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