WO2009082163A3 - Novel ru-type sensitizers and method of preparing the same - Google Patents

Novel ru-type sensitizers and method of preparing the same Download PDF

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Publication number
WO2009082163A3
WO2009082163A3 PCT/KR2008/007631 KR2008007631W WO2009082163A3 WO 2009082163 A3 WO2009082163 A3 WO 2009082163A3 KR 2008007631 W KR2008007631 W KR 2008007631W WO 2009082163 A3 WO2009082163 A3 WO 2009082163A3
Authority
WO
WIPO (PCT)
Prior art keywords
preparing
dye
same
novel
solar cell
Prior art date
Application number
PCT/KR2008/007631
Other languages
French (fr)
Other versions
WO2009082163A2 (en
Inventor
Ho-Gi Bae
Chong-Chan Lee
Jong-Hyub Baek
Hoe-Taek Yang
Original Assignee
Dongjin Semichem Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongjin Semichem Co., Ltd. filed Critical Dongjin Semichem Co., Ltd.
Priority to CN2008801230215A priority Critical patent/CN101910322A/en
Priority to JP2010540573A priority patent/JP2011510107A/en
Publication of WO2009082163A2 publication Critical patent/WO2009082163A2/en
Publication of WO2009082163A3 publication Critical patent/WO2009082163A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B57/00—Other synthetic dyes of known constitution
    • C09B57/10—Metal complexes of organic compounds not being dyes in uncomplexed form
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B45/00—Complex metal compounds of azo dyes
    • C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
    • C09B45/04—Azo compounds in general
    • C09B45/12—Azo compounds in general other metal compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B45/00—Complex metal compounds of azo dyes
    • C09B45/38—Preparation from compounds with —OH and —COOH adjacent in the same ring or in peri position
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/30—Coordination compounds
    • H10K85/341—Transition metal complexes, e.g. Ru(II)polypyridine complexes
    • H10K85/344—Transition metal complexes, e.g. Ru(II)polypyridine complexes comprising ruthenium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2027—Light-sensitive devices comprising an oxide semiconductor electrode
    • H01G9/2031—Light-sensitive devices comprising an oxide semiconductor electrode comprising titanium oxide, e.g. TiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/542—Dye sensitized solar cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Hybrid Cells (AREA)
  • Photovoltaic Devices (AREA)

Abstract

The present invention relates to novel Ru-type dye and a method for preparing the same, more specifically to dye which is be used for a dye-sensitized solar cell to show remarkably improved photoelectric transformation efficiency compared to the existing dye, strengthens bonding force with titanium dioxide, and has excellent Jsc(short circuit photocurrent density) and molar absorption coefficient, thus largely improving the efficiency of solar cell, and a method for preparing the same.
PCT/KR2008/007631 2007-12-26 2008-12-24 Novel ru-type sensitizers and method of preparing the same WO2009082163A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2008801230215A CN101910322A (en) 2007-12-26 2008-12-24 Novel Ru-type sensitizers and method for the production thereof
JP2010540573A JP2011510107A (en) 2007-12-26 2008-12-24 Novel ruthenium dye and method for producing the same

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
KR20070137757 2007-12-26
KR10-2007-0137757 2007-12-26
KR20080062484 2008-06-30
KR10-2008-0062484 2008-06-30
KR10-2008-0068596 2008-07-15
KR20080068596 2008-07-15

Publications (2)

Publication Number Publication Date
WO2009082163A2 WO2009082163A2 (en) 2009-07-02
WO2009082163A3 true WO2009082163A3 (en) 2009-10-29

Family

ID=40801695

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2008/007631 WO2009082163A2 (en) 2007-12-26 2008-12-24 Novel ru-type sensitizers and method of preparing the same

Country Status (5)

Country Link
JP (1) JP2011510107A (en)
KR (1) KR20090071426A (en)
CN (1) CN101910322A (en)
TW (1) TW200938594A (en)
WO (1) WO2009082163A2 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI370120B (en) * 2008-01-31 2012-08-11 Everlight Chem Ind Corp Ruthenium complex
CN101235214B (en) 2008-02-27 2012-07-04 中国科学院长春应用化学研究所 Organic ruthenium dye and dye sensitization solar battery
WO2010055470A1 (en) * 2008-11-11 2010-05-20 Ecole Polytechnique Federale De Lausanne (Epfl) Photoelectric conversion devices comprising novel ligands and sensitizers
KR101050470B1 (en) * 2010-04-05 2011-07-20 삼성에스디아이 주식회사 Ruthenium complex and dye sensitized fuel cell using the same
JP5775675B2 (en) * 2010-05-17 2015-09-09 富士フイルム株式会社 Photoelectric conversion element, photoelectrochemical cell, and dye solution for photoelectric conversion element
JP4980479B2 (en) * 2010-06-02 2012-07-18 富士フイルム株式会社 Metal complex dye, photoelectric conversion element, and dye-sensitized solar cell
CN103189452A (en) * 2010-11-01 2013-07-03 株式会社东进世美肯 Novel ruthenium-based dye and method for producing same
CN102477045A (en) * 2010-11-30 2012-05-30 中国科学院上海有机化学研究所 Bithiophene quinoid compound, its preparation method, intermediate thereof and its application
JP5893390B2 (en) * 2011-03-31 2016-03-23 富士フイルム株式会社 Photoelectric conversion element and dye-sensitized solar cell
JP5809954B2 (en) * 2011-12-15 2015-11-11 富士フイルム株式会社 Photoelectric conversion element and dye-sensitized solar cell
CN102993085B (en) * 2012-11-28 2014-08-20 河南省商业科学研究所有限责任公司 Synthesis method of 2, 2'-(2, 2'-dipyridyl-4, 4'-dimethyl) di-malononitrile and substitute for 2, 2'-(2, 2'-dipyridyl-4, 4'-dimethyl) di-malononitrile
CN103351332B (en) * 2013-07-22 2016-01-27 聊城大学 The synthetic method of Conjugate extended carboxyl bipyridine ligand and ruthenium based dye thereof and application
CN103554996B (en) * 2013-10-11 2016-03-02 华中科技大学 The ruthenium complex dye of cation and the dye sensitization solar battery of preparation thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040010840A (en) * 2001-07-06 2004-01-31 니폰 가야꾸 가부시끼가이샤 Photoelectric conversion element sensitized with coloring matter
WO2007091525A1 (en) * 2006-02-08 2007-08-16 Shimane Prefectural Government Photosensitizer dye
JP2007302879A (en) * 2006-05-11 2007-11-22 National Central Univ Photosensitizing dye

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040010840A (en) * 2001-07-06 2004-01-31 니폰 가야꾸 가부시끼가이샤 Photoelectric conversion element sensitized with coloring matter
WO2007091525A1 (en) * 2006-02-08 2007-08-16 Shimane Prefectural Government Photosensitizer dye
JP2007302879A (en) * 2006-05-11 2007-11-22 National Central Univ Photosensitizing dye

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHEN, C. Y. ET AL.: "A Ruthenium Complex with Superhigh Light-Havesting capacity for Dye- Sensitized Solar Cells.", ANGEWANDTE CHEMIE INTERNATIONAL EDITION., vol. 45, 4 September 2006 (2006-09-04), pages 5822 - 5825 *

Also Published As

Publication number Publication date
JP2011510107A (en) 2011-03-31
TW200938594A (en) 2009-09-16
WO2009082163A2 (en) 2009-07-02
CN101910322A (en) 2010-12-08
KR20090071426A (en) 2009-07-01

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