JP2006519257A5 - - Google Patents
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- Publication number
- JP2006519257A5 JP2006519257A5 JP2006508773A JP2006508773A JP2006519257A5 JP 2006519257 A5 JP2006519257 A5 JP 2006519257A5 JP 2006508773 A JP2006508773 A JP 2006508773A JP 2006508773 A JP2006508773 A JP 2006508773A JP 2006519257 A5 JP2006519257 A5 JP 2006519257A5
- Authority
- JP
- Japan
- Prior art keywords
- product
- zone
- reactant
- withdrawn
- liquid fraction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000007788 liquid Substances 0.000 claims 24
- 239000000376 reactant Substances 0.000 claims 21
- 238000006243 chemical reaction Methods 0.000 claims 19
- 238000000034 method Methods 0.000 claims 11
- 238000004821 distillation Methods 0.000 claims 10
- 238000009833 condensation Methods 0.000 claims 6
- 230000005494 condensation Effects 0.000 claims 6
- 238000000926 separation method Methods 0.000 claims 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 6
- 238000006116 polymerization reaction Methods 0.000 claims 5
- 238000011027 product recovery Methods 0.000 claims 5
- 238000011084 recovery Methods 0.000 claims 5
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 claims 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 4
- 125000004432 carbon atom Chemical group C* 0.000 claims 4
- 239000003112 inhibitor Substances 0.000 claims 4
- 239000007791 liquid phase Substances 0.000 claims 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 239000012071 phase Substances 0.000 claims 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims 1
- CYUZOYPRAQASLN-UHFFFAOYSA-N 3-prop-2-enoyloxypropanoic acid Chemical compound OC(=O)CCOC(=O)C=C CYUZOYPRAQASLN-UHFFFAOYSA-N 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- 238000006845 Michael addition reaction Methods 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 238000005886 esterification reaction Methods 0.000 claims 1
- 239000003456 ion exchange resin Substances 0.000 claims 1
- 229920003303 ion-exchange polymer Polymers 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45074603P | 2003-02-28 | 2003-02-28 | |
| US60/450,746 | 2003-02-28 | ||
| PCT/US2004/004948 WO2004078679A2 (en) | 2003-02-28 | 2004-02-19 | Process for conducting equilibrium-limited reactions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2006519257A JP2006519257A (ja) | 2006-08-24 |
| JP2006519257A5 true JP2006519257A5 (https=) | 2007-04-12 |
| JP5059400B2 JP5059400B2 (ja) | 2012-10-24 |
Family
ID=32962524
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006508773A Expired - Lifetime JP5059400B2 (ja) | 2003-02-28 | 2004-02-19 | 平衡制限反応の実施方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7569721B2 (https=) |
| EP (1) | EP1611082B1 (https=) |
| JP (1) | JP5059400B2 (https=) |
| KR (1) | KR101136783B1 (https=) |
| CN (1) | CN100345816C (https=) |
| BR (1) | BRPI0408043B1 (https=) |
| DE (1) | DE602004028591D1 (https=) |
| MX (1) | MX256948B (https=) |
| WO (1) | WO2004078679A2 (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10357222A1 (de) * | 2003-12-08 | 2005-06-30 | Basf Ag | Anschlussstutzen für Messgeräte und mit einem solchen Anschlussstutzen versehene Messsonde |
| DE102005043719A1 (de) * | 2005-09-13 | 2007-03-15 | Röhm Gmbh | Vorrichtung und Verfahren für kontinuierlich durchgeführte Gleichgewichtsreaktionen |
| WO2012071158A1 (en) | 2010-11-22 | 2012-05-31 | Rohm And Haas Company | Acrylate production process |
| SG11201510267TA (en) | 2013-06-28 | 2016-01-28 | Dow Global Technologies Llc | Fouling-resistant distillation column and process for the manufacture of compounds |
| FR3014870B1 (fr) * | 2013-12-13 | 2015-12-11 | Arkema France | Procede de production d'esters (meth)acryliques |
| SG11201703365VA (en) | 2014-10-31 | 2017-05-30 | Dow Global Technologies Llc | Process for in situ water removal from an oxidative esterification reaction using a coupled reactor-distillation system |
| KR102151747B1 (ko) * | 2018-11-23 | 2020-09-03 | 지에스칼텍스 주식회사 | 알킬 카르복실산 에스테르의 제조 방법 및 알킬 카르복실산 에스테르의 제조 장치 |
| WO2022270495A1 (ja) * | 2021-06-21 | 2022-12-29 | 旭化成株式会社 | 反応システム及び反応方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3776947A (en) | 1972-10-10 | 1973-12-04 | Nippon Catalytic Chem Ind | Continuous esterification process |
| DE2548561C2 (de) | 1975-10-30 | 1983-09-29 | Hoechst Ag, 6230 Frankfurt | Verfahren zur kontinuierlichen Herstellung dioctylätherfreien 2-Äthyl- hexylacrylats |
| JPS6317844A (ja) | 1986-07-09 | 1988-01-25 | Nippon Shokubai Kagaku Kogyo Co Ltd | 不飽和カルボン酸エステルの製造方法 |
| DE4019781A1 (de) | 1990-06-21 | 1992-01-02 | Basf Ag | Verfahren zur herstellung von monoethylenisch ungesaettigten carbonsaeureestern |
| US5231222A (en) | 1991-07-02 | 1993-07-27 | Union Carbide Chemicals & Plastics Technology Corporation | Esterification process |
| JP3346822B2 (ja) | 1993-03-31 | 2002-11-18 | 三菱化学株式会社 | アクリル酸エステル又はメタクリル酸エステルの製造法 |
| FR2721313B1 (fr) | 1994-06-17 | 1996-07-19 | Atochem Elf Sa | Procédé de fabrication d'acrylates d'alkyle par estérification directe. |
| DE19536178A1 (de) | 1995-09-28 | 1997-04-03 | Basf Ag | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Alkylestern der (Meth)acrylsäure |
| DE19536191A1 (de) | 1995-09-28 | 1997-04-03 | Basf Ag | Verfahren zum Verestern von (Meth)acrylsäure mit einem Alkanol |
| DE19604267A1 (de) * | 1996-02-06 | 1997-08-07 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von Alkylestern der (Meth)acrylsäure |
| DE19604253A1 (de) | 1996-02-06 | 1997-08-07 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von Alkylestern der (Meth)acrylsäure |
| WO1998052903A1 (en) * | 1997-05-20 | 1998-11-26 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for conducting equilibrium-limited reactions |
| BR9714713A (pt) | 1997-05-20 | 2000-07-04 | Union Carbide Chem Plastic | Processos para o refino de acrilato de butila |
| DE69812682T2 (de) | 1997-10-31 | 2003-12-18 | Celanese International Corp., Dallas | Entfernung von schwefel aus einem acrylatstrom |
| JP4242964B2 (ja) | 1999-03-09 | 2009-03-25 | 株式会社日本触媒 | （メタ）アクリル酸および／またはそのエステルの精製方法 |
| JP3782607B2 (ja) * | 1999-04-20 | 2006-06-07 | 株式会社日本触媒 | エステル化物の製造方法 |
| US6482976B1 (en) * | 1999-06-17 | 2002-11-19 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for conducting equilibrium-limited reactions |
| JP2003521478A (ja) | 1999-06-17 | 2003-07-15 | ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション | 平衡律速反応を行う方法 |
-
2004
- 2004-02-19 BR BRPI0408043-2A patent/BRPI0408043B1/pt not_active IP Right Cessation
- 2004-02-19 DE DE602004028591T patent/DE602004028591D1/de not_active Expired - Lifetime
- 2004-02-19 MX MXPA05009158 patent/MX256948B/es active IP Right Grant
- 2004-02-19 JP JP2006508773A patent/JP5059400B2/ja not_active Expired - Lifetime
- 2004-02-19 EP EP04712871A patent/EP1611082B1/en not_active Expired - Lifetime
- 2004-02-19 KR KR1020057016051A patent/KR101136783B1/ko not_active Expired - Lifetime
- 2004-02-19 WO PCT/US2004/004948 patent/WO2004078679A2/en not_active Ceased
- 2004-02-19 US US10/544,817 patent/US7569721B2/en active Active
- 2004-02-19 CN CNB2004800048414A patent/CN100345816C/zh not_active Expired - Fee Related
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