JP2006517602A5 - - Google Patents
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- JP2006517602A5 JP2006517602A5 JP2006501101A JP2006501101A JP2006517602A5 JP 2006517602 A5 JP2006517602 A5 JP 2006517602A5 JP 2006501101 A JP2006501101 A JP 2006501101A JP 2006501101 A JP2006501101 A JP 2006501101A JP 2006517602 A5 JP2006517602 A5 JP 2006517602A5
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- JP
- Japan
- Prior art keywords
- pigment composition
- encapsulated pigment
- aspect ratio
- substantially spherical
- high aspect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 claims 17
- 239000000049 pigment Substances 0.000 claims 14
- 239000011324 bead Substances 0.000 claims 11
- 239000002245 particle Substances 0.000 claims 7
- 239000000463 material Substances 0.000 claims 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 4
- 239000003086 colorant Substances 0.000 claims 3
- 239000000178 monomer Substances 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 2
- -1 alkyl methacrylate Chemical compound 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 238000005755 formation reaction Methods 0.000 claims 2
- 239000010445 mica Substances 0.000 claims 2
- 229910052618 mica group Inorganic materials 0.000 claims 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims 2
- 239000011541 reaction mixture Substances 0.000 claims 2
- 239000000725 suspension Substances 0.000 claims 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- OCQDPIXQTSYZJL-UHFFFAOYSA-N 1,4-bis(butylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NCCCC)=CC=C2NCCCC OCQDPIXQTSYZJL-UHFFFAOYSA-N 0.000 claims 1
- BLFZMXOCPASACY-UHFFFAOYSA-N 1,4-bis(propan-2-ylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NC(C)C)=CC=C2NC(C)C BLFZMXOCPASACY-UHFFFAOYSA-N 0.000 claims 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 1-ethenyl-4-methylbenzene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N 2-methyl-2-propenoic acid methyl ester Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
- 229940095259 Butylated Hydroxytoluene Drugs 0.000 claims 1
- 239000004322 Butylated hydroxytoluene Substances 0.000 claims 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims 1
- YAAQEISEHDUIFO-UHFFFAOYSA-N C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 Chemical compound C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 YAAQEISEHDUIFO-UHFFFAOYSA-N 0.000 claims 1
- 239000004609 Impact Modifier Substances 0.000 claims 1
- ZZSIDSMUTXFKNS-UHFFFAOYSA-N Perylene Red Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N(C(=O)C=1C2=C3C4=C(OC=5C=CC=CC=5)C=1)C(=O)C2=CC(OC=1C=CC=CC=1)=C3C(C(OC=1C=CC=CC=1)=CC1=C2C(C(N(C=3C(=CC=CC=3C(C)C)C(C)C)C1=O)=O)=C1)=C2C4=C1OC1=CC=CC=C1 ZZSIDSMUTXFKNS-UHFFFAOYSA-N 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 claims 1
- TVRGPOFMYCMNRB-UHFFFAOYSA-N Quinizarine Green SS Chemical compound C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1 TVRGPOFMYCMNRB-UHFFFAOYSA-N 0.000 claims 1
- 239000006096 absorbing agent Substances 0.000 claims 1
- 229920002877 acrylic styrene acrylonitrile Polymers 0.000 claims 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
- 230000000996 additive Effects 0.000 claims 1
- 125000005250 alkyl acrylate group Chemical group 0.000 claims 1
- 230000003078 antioxidant Effects 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 229910052626 biotite Inorganic materials 0.000 claims 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 239000003431 cross linking reagent Substances 0.000 claims 1
- 239000008393 encapsulating agent Substances 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 239000003063 flame retardant Substances 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- VCTOKJRTAUILIH-UHFFFAOYSA-N manganese(2+);sulfide Chemical compound [S-2].[Mn+2] VCTOKJRTAUILIH-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000011159 matrix material Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- LGDNMDSHQLWPAK-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;5-phenylpenta-2,4-dienenitrile Chemical compound COC(=O)C(C)=C.N#CC=CC=CC1=CC=CC=C1 LGDNMDSHQLWPAK-UHFFFAOYSA-N 0.000 claims 1
- 229910052627 muscovite Inorganic materials 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 229920003023 plastic Polymers 0.000 claims 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims 1
- 239000004926 polymethyl methacrylate Substances 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 239000002516 radical scavenger Substances 0.000 claims 1
- 239000011342 resin composition Substances 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 229910001220 stainless steel Inorganic materials 0.000 claims 1
- 239000010935 stainless steel Substances 0.000 claims 1
- VRRFSFYSLSPWQY-UHFFFAOYSA-N sulfanylidenecobalt Chemical compound [Co]=S VRRFSFYSLSPWQY-UHFFFAOYSA-N 0.000 claims 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 claims 1
- 239000000375 suspending agent Substances 0.000 claims 1
- 238000010557 suspension polymerization reaction Methods 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000004408 titanium dioxide Substances 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N α-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims 1
Claims (10)
- 1個以上の略球形ビーズを含む封入顔料組成物であって、各々の略球形ビーズが封入用材料に1個以上の高アスペクト比粒子を封入したものからなり、封入用材料に封入された高アスペクト比粒子の平均重量割合が顔料ビーズの重量を基準にして0.1〜25重量%であり、略球形ビーズの平均直径が10μm〜300μmである、封入顔料組成物。
- 前記高アスペクト比粒子が、アルミニウム、金、銀、銅、ニッケル、チタン、ステンレス鋼、硫化ニッケル、硫化コバルト、硫化マンガン、金属酸化物、白雲母、黒雲母、合成雲母、二酸化チタン被覆雲母、金属被覆ガラスフレーク又は着色剤の1種類以上を含む、請求項1記載の封入顔料組成物。
- 前記封入用材料が、スチレン、α−メチルスチレン、p−メチルスチレン、アクリロニトリル、アルキルアクリレート、アルキルメタクリレート、メチルメタクリレート、ジビニルベンゼン及びこれらの混合物からなる群から選択される1種以上のモノマーから誘導された構造単位を有するポリマーを含む、請求項1又は請求項2記載の封入顔料組成物。
- 前記封入用材料が、ポリスチレン、ポリメチルメタクリレート、スチレン−アクリロニトリル共重合体、メチルメタクリレート−スチレン−アクリロニトリル共重合体又はアクリロニトリル−スチレン−アクリレート共重合体の1種以上を含む、請求項1又は請求項2記載の封入顔料組成物。
- 当該封入顔料組成物がさらに1種以上の添加剤を含む、請求項1乃至請求項4のいずれか1項記載の封入顔料組成物。
- 前記1種以上の添加剤が、着色剤、熱安定剤、酸化防止剤、ブチル化ヒドロキシトルエン、ラジカル掃去剤、ビニル系モノマー、充填材、耐衝撃性改良剤、紫外線吸収剤又は難燃剤の1種類以上を含む、請求項5記載の封入顔料組成物。
- 前記着色剤が、Solvent Blue 35、Solvent Blue 36、Disperse Violet 26、Solvent Green 3、Anaplast Orange LFP、Morplas Red 36又はPerylene Redの1種類以上を含む、請求項6記載の封入顔料組成物。
- 1個以上の略球形ビーズを含む封入顔料組成物であって、各々の略球形ビーズが封入用材料に1個以上の高アスペクト比アルミニウムフレークを封入したものからなり、封入用材料が、スチレンである少なくとも1種のモノマーから誘導された構造単位を有するポリマーを含有し、フレークの平均アスペクト比が1.5:1〜40:1であり、当該封入顔料組成物がフレークを0.1〜25重量%含有する、封入顔料組成物。
- プラスチックマトリックス材料と請求項1乃至請求項8のいずれか1項記載の封入顔料組成物とを含む樹脂組成物。
- 1個以上の略球形ビーズを含む封入顔料組成物の懸濁重合による製造方法であって、略球形ビーズが封入用材料に1個以上の高アスペクト比粒子を封入したものからなるものであり、当該方法が、
高アスペクト比粒子をモノマー又はポリマーの少なくとも1種及び架橋剤に分散して懸濁混合物を形成し、
懸濁混合物を懸濁剤を含有する水性混合物に添加し、
水性反応混合物を加熱、混合して、略球形ビーズの形成を促し、こうして略球形ビーズのほとんどが1以上の高アスペクト比粒子を、加工中に高アスペクト比粒子が剥離しないような程度まで封入し、
略球形ビーズの形成後、水性反応混合物を奪活し、
略球形ビーズを集める
工程を含む方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/351,386 US7312257B2 (en) | 2003-01-23 | 2003-01-23 | Polymer encapsulation of high aspect ratio materials and methods of making same |
US10/351,386 | 2003-01-23 | ||
PCT/US2004/001727 WO2004065475A1 (en) | 2003-01-23 | 2004-01-22 | Polymer encapsulation of high aspect ratio materials and methods of making same |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2006517602A JP2006517602A (ja) | 2006-07-27 |
JP2006517602A5 true JP2006517602A5 (ja) | 2007-03-08 |
JP5382992B2 JP5382992B2 (ja) | 2014-01-08 |
Family
ID=32735782
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006501101A Expired - Fee Related JP5382992B2 (ja) | 2003-01-23 | 2004-01-22 | 高アスペクト比材料のポリマー封入物及びその製造方法 |
Country Status (8)
Country | Link |
---|---|
US (2) | US7312257B2 (ja) |
EP (1) | EP1590401B1 (ja) |
JP (1) | JP5382992B2 (ja) |
KR (1) | KR101077375B1 (ja) |
CN (1) | CN1764691B (ja) |
AT (1) | ATE357478T1 (ja) |
DE (1) | DE602004005423T2 (ja) |
WO (1) | WO2004065475A1 (ja) |
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-
2003
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-
2004
- 2004-01-22 JP JP2006501101A patent/JP5382992B2/ja not_active Expired - Fee Related
- 2004-01-22 CN CN2004800079910A patent/CN1764691B/zh not_active Expired - Fee Related
- 2004-01-22 WO PCT/US2004/001727 patent/WO2004065475A1/en active IP Right Grant
- 2004-01-22 EP EP04704443A patent/EP1590401B1/en not_active Expired - Lifetime
- 2004-01-22 KR KR1020057013574A patent/KR101077375B1/ko active IP Right Grant
- 2004-01-22 AT AT04704443T patent/ATE357478T1/de not_active IP Right Cessation
- 2004-01-22 DE DE602004005423T patent/DE602004005423T2/de not_active Expired - Lifetime
-
2007
- 2007-06-06 US US11/758,814 patent/US20070232724A1/en not_active Abandoned
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