JP2006507382A - ポリマーをｕｖ−線の作用に対して安定化するための、ｕｖ−吸収剤を含有するポリマー粉末の使用 - Google Patents

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Publication number

JP2006507382A

JP2006507382A JP2004552557A JP2004552557A JP2006507382A JP 2006507382 A JP2006507382 A JP 2006507382A JP 2004552557 A JP2004552557 A JP 2004552557A JP 2004552557 A JP2004552557 A JP 2004552557A JP 2006507382 A JP2006507382 A JP 2006507382A

Authority

JP

Japan

Prior art keywords

group

polymer

butyl

bis

acid

Prior art date

2002-11-21

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Pending

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• 239000006096 absorbing agent Substances 0.000 title claims abstract description 40
• 239000000843 powder Substances 0.000 title claims abstract description 39
• 230000009471 action Effects 0.000 title claims abstract description 28
• 239000000203 mixture Substances 0.000 claims abstract description 90
• 239000003381 stabilizer Substances 0.000 claims abstract description 73
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 24
• 229910052760 oxygen Inorganic materials 0.000 claims abstract description 24
• 239000001301 oxygen Substances 0.000 claims abstract description 24
• 229920000098 polyolefin Polymers 0.000 claims abstract description 23
• 230000000087 stabilizing effect Effects 0.000 claims abstract description 11
• 238000000034 method Methods 0.000 claims abstract description 9
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• 150000001875 compounds Chemical class 0.000 claims description 87
• 150000001412 amines Chemical class 0.000 claims description 22
• 150000002989 phenols Chemical class 0.000 claims description 15
• 239000002245 particle Substances 0.000 claims description 10
• 239000011159 matrix material Substances 0.000 claims description 8
• AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 8
• XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 8
• 229910017053 inorganic salt Inorganic materials 0.000 claims description 7
• 150000002696 manganese Chemical class 0.000 claims description 3
• 150000003003 phosphines Chemical class 0.000 claims description 2
• 150000003751 zinc Chemical class 0.000 claims description 2
• 150000000703 Cerium Chemical class 0.000 claims 1
• 159000000007 calcium salts Chemical class 0.000 claims 1
• 159000000014 iron salts Chemical class 0.000 claims 1
• 159000000003 magnesium salts Chemical class 0.000 claims 1
• 230000005855 radiation Effects 0.000 abstract 2
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• 229910052757 nitrogen Inorganic materials 0.000 description 53
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• 239000001257 hydrogen Substances 0.000 description 42
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• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 22
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 21
• 150000002431 hydrogen Chemical class 0.000 description 20
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 20
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• 125000004432 carbon atom Chemical group C* 0.000 description 12
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• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 11
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• OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 8
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• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 8
• KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
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• 239000011593 sulfur Substances 0.000 description 8
• 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 7
• WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 7
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• 229910052791 calcium Inorganic materials 0.000 description 7
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 7
• 150000001993 dienes Chemical class 0.000 description 7
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
• DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical class [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 7
• 239000000178 monomer Substances 0.000 description 7
• TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 7
• 229920006324 polyoxymethylene Polymers 0.000 description 7
• 229910052725 zinc Inorganic materials 0.000 description 7
• 239000011701 zinc Substances 0.000 description 7
• 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 6
• PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 6
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
• FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 description 6
• YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical compound NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 description 6
• 239000004698 Polyethylene Substances 0.000 description 6
• 239000004721 Polyphenylene oxide Substances 0.000 description 6
• 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 6
• 150000007513 acids Chemical class 0.000 description 6
• 125000000217 alkyl group Chemical group 0.000 description 6
• WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 6
• 150000001735 carboxylic acids Chemical class 0.000 description 6
• NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 6
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• WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical group OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 6
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• 150000003254 radicals Chemical class 0.000 description 6
• 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 6
• 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 5
• ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 5
• 125000002252 acyl group Chemical group 0.000 description 5
• 125000002947 alkylene group Chemical group 0.000 description 5
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• DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
• BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 4
• ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
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• CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 4
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• QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1