JP2006198461A - 複合逆浸透膜およびその製造方法、ならびにそれを用いた水処理方法 - Google Patents
複合逆浸透膜およびその製造方法、ならびにそれを用いた水処理方法 Download PDFInfo
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- JP2006198461A JP2006198461A JP2005010142A JP2005010142A JP2006198461A JP 2006198461 A JP2006198461 A JP 2006198461A JP 2005010142 A JP2005010142 A JP 2005010142A JP 2005010142 A JP2005010142 A JP 2005010142A JP 2006198461 A JP2006198461 A JP 2006198461A
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- reverse osmosis
- osmosis membrane
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- 238000001223 reverse osmosis Methods 0.000 title claims abstract description 52
- 238000000034 method Methods 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 150000001875 compounds Chemical class 0.000 title abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 104
- 239000004952 Polyamide Substances 0.000 claims abstract description 24
- 229920002647 polyamide Polymers 0.000 claims abstract description 24
- 150000001412 amines Chemical class 0.000 claims abstract description 22
- 239000002346 layers by function Substances 0.000 claims abstract description 20
- 150000002357 guanidines Chemical class 0.000 claims abstract description 9
- 239000002131 composite material Substances 0.000 claims description 49
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 34
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- 238000000926 separation method Methods 0.000 claims description 26
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 17
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 17
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- 150000004820 halides Chemical class 0.000 claims description 15
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 14
- 230000007423 decrease Effects 0.000 claims description 10
- 229920006037 cross link polymer Polymers 0.000 claims description 7
- 239000011780 sodium chloride Substances 0.000 claims description 7
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- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 claims description 3
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- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
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- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
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- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical group NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- 238000012696 Interfacial polycondensation Methods 0.000 description 2
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- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
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- 239000003377 acid catalyst Substances 0.000 description 2
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- 125000003277 amino group Chemical group 0.000 description 2
- RPHKINMPYFJSCF-UHFFFAOYSA-N benzene-1,3,5-triamine Chemical group NC1=CC(N)=CC(N)=C1 RPHKINMPYFJSCF-UHFFFAOYSA-N 0.000 description 2
- UWCPYKQBIPYOLX-UHFFFAOYSA-N benzene-1,3,5-tricarbonyl chloride Chemical compound ClC(=O)C1=CC(C(Cl)=O)=CC(C(Cl)=O)=C1 UWCPYKQBIPYOLX-UHFFFAOYSA-N 0.000 description 2
- 238000011033 desalting Methods 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
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- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
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- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
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- 239000000047 product Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- FUPAJKKAHDLPAZ-UHFFFAOYSA-N 1,2,3-triphenylguanidine Chemical compound C=1C=CC=CC=1NC(=NC=1C=CC=CC=1)NC1=CC=CC=C1 FUPAJKKAHDLPAZ-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical group NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical group NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- 230000010933 acylation Effects 0.000 description 1
- 238000005917 acylation reaction Methods 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- HAMNKKUPIHEESI-UHFFFAOYSA-N aminoguanidine Chemical compound NNC(N)=N HAMNKKUPIHEESI-UHFFFAOYSA-N 0.000 description 1
- ARCGXLSVLAOJQL-UHFFFAOYSA-N anhydrous trimellitic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
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- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- FDQSRULYDNDXQB-UHFFFAOYSA-N benzene-1,3-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC(C(Cl)=O)=C1 FDQSRULYDNDXQB-UHFFFAOYSA-N 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
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- 229940015043 glyoxal Drugs 0.000 description 1
- PKWIYNIDEDLDCJ-UHFFFAOYSA-N guanazole Chemical compound NC1=NNC(N)=N1 PKWIYNIDEDLDCJ-UHFFFAOYSA-N 0.000 description 1
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- LVPMIMZXDYBCDF-UHFFFAOYSA-N isocinchomeronic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)N=C1 LVPMIMZXDYBCDF-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- KVKFRMCSXWQSNT-UHFFFAOYSA-N n,n'-dimethylethane-1,2-diamine Chemical group CNCCNC KVKFRMCSXWQSNT-UHFFFAOYSA-N 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
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- QQVIHTHCMHWDBS-UHFFFAOYSA-N perisophthalic acid Natural products OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
- DBMHTLOVZSDLFD-UHFFFAOYSA-N piperidin-1-ylmethanamine Chemical group NCN1CCCCC1 DBMHTLOVZSDLFD-UHFFFAOYSA-N 0.000 description 1
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- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical group CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- ZZYXNRREDYWPLN-UHFFFAOYSA-N pyridine-2,3-diamine Chemical group NC1=CC=CN=C1N ZZYXNRREDYWPLN-UHFFFAOYSA-N 0.000 description 1
- GJAWHXHKYYXBSV-UHFFFAOYSA-N pyridinedicarboxylic acid Natural products OC(=O)C1=CC=CN=C1C(O)=O GJAWHXHKYYXBSV-UHFFFAOYSA-N 0.000 description 1
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellityc acid Natural products OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
- Y02A20/131—Reverse-osmosis
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Laminated Bodies (AREA)
- Polyamides (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
【解決手段】界面活性剤を含む水を処理するための複合逆浸透膜であって、架橋ポリアミド分離機能層が多孔性支持膜上に形成され、該架橋ポリアミドは多官能アミン成分としてグアニジン類を含有し、グアニジン類が架橋ポリアミド機能層中で化学的に結合した複合逆浸透膜。
【選択図】なし
Description
ここで、透過水量低下率を以下のように定義する。すなわち、25℃において、pH6.5、濃度が2,000mg/lの塩化ナトリウム水溶液を用い操作圧力0.5MPaにて複合逆浸透膜を透過させて3時間ろ過した後の透過水量を前透過水量(F1)とし、続いて、この塩化ナトリウム水溶液にノニオン界面活性剤(ポリオキシエチレン(10)オクチルフェニルエーテル)を濃度が100mg/lになるように前記水溶液に添加してから0.5MPaの圧力で1時間経過後の透過水量を後透過水量(F2)としたときに、以下の数式(1)で定義される。
ポリエステル繊維からなる、縦30cm横20cmの大きさの抄紙不織布基材をガラス板上に固定し、その上にポリスルホンの15重量%ジメチルホルムアミド(DMF)溶液を、200μmの厚みで、25℃にてキャストし、ただちに純水中に浸漬して5分間放置し、次いで、90℃、2分間熱水中で処理して微多孔性支持膜(以下、FT−PS支持膜という)を得た。このFT−PS支持膜の厚さは200〜210μmであり、純水透過係数は圧力0.1MPa、液温25℃、雰囲気温度25℃で測定したとき0.01〜0.03g/cm2・sec・atmであった。
実施例1においてメタフェニレンジアミンが0.8重量%である水溶液を用いた以外は実施例1と同様に製膜、評価を行った。
実施例1においてグアニジンが0.5重量%である水溶液を用いて、膜を炭酸ナトリウム1重量%と、ラウリル硫酸ナトリウム0.3重量%とを含む水溶液に2分間浸漬する前段階まで実施例1と同様に製膜した。
実施例1のうち、グアニジン組成比0%の水溶液を用いた以外は実施例1と同様に製膜、評価を行った。
実施例3の全アミン成分のうち、グアニジン組成比0%の水溶液を用いた以外は実施例3と同様に製膜、評価を行った。
Claims (7)
- 多官能アミン成分と多官能酸ハロゲン化物からなる架橋ポリアミド分離機能層が多孔性支持膜上に形成されてなる複合逆浸透膜において、該架橋ポリアミド分離機能層中に多官能アミン成分としてグアニジン類を用い、かつ該グアニジン類が架橋ポリアミド機能層中で化学的に結合した複合逆浸透膜。
- 架橋ポリアミド分離機能層の表面を架橋重合体が被覆していることを特徴とする請求項1に記載の複合逆浸透膜。
- 25℃において、pH6.5、NaCl濃度が2,000mg/lである水溶液を0.5MPaの圧力で3時間ろ過した後の透過水量をF1とし、続いて、ポリオキシエチレン(10)オクチルフェニルエーテルを100mg/lの濃度となるように前記水溶液に加えた水溶液を0.5MPaの圧力で1時間ろ過した後の透過水量をF2としたとき、透過水量低下率[=1−(F2/F1)]の値が0.4以下である請求項1または2に記載の複合逆浸透膜。
- 25℃において、pH6.5、NaCl濃度が2,000mg/lである水溶液を0.5MPaの圧力を加えて3時間ろ過したときの透過水量が0.4m3/m2・日以上である請求項1〜3のいずれかに記載の複合逆浸透膜。
- 多官能アミン成分を含有する水溶液と多官能酸ハロゲン化物を含有する有機溶液とを反応させて、多孔性支持膜上に架橋ポリアミド膜を形成させる複合逆浸透膜の製造方法であって、前記多官能アミン成分を含有する水溶液中にグアニジン類を含有させてグアニジン類濃度を20〜80質量%とし、該グアニジン類を架橋ポリアミド機能層中で化学的に結合させることを特徴とする複合逆浸透膜の製造方法。
- 請求項1〜4のいずれかの複合逆浸透膜を用いて界面活性剤を含む水を処理する水処理方法。
- 請求項5に記載の方法により得られた複合逆浸透膜を用いて界面活性剤を含む水を処理する水処理方法。
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Cited By (10)
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05253454A (ja) * | 1992-03-11 | 1993-10-05 | Daicel Chem Ind Ltd | 新規複合分離膜およびそれを用いた排水の処理方法 |
JP2001079373A (ja) * | 1999-09-17 | 2001-03-27 | Saehan Ind Inc | ポリアミド逆浸透複合膜の製造方法 |
JP2001327840A (ja) * | 2000-05-25 | 2001-11-27 | Toray Ind Inc | 複合半透膜およびその製造方法 |
JP2004025102A (ja) * | 2002-06-24 | 2004-01-29 | Saehan Ind Inc | 耐汚染性に優れた選択的分離膜製造方法 |
JP2004050144A (ja) * | 2002-07-24 | 2004-02-19 | Toray Ind Inc | 排水処理用分離膜およびその製造方法 |
-
2005
- 2005-01-18 JP JP2005010142A patent/JP4539341B2/ja not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05253454A (ja) * | 1992-03-11 | 1993-10-05 | Daicel Chem Ind Ltd | 新規複合分離膜およびそれを用いた排水の処理方法 |
JP2001079373A (ja) * | 1999-09-17 | 2001-03-27 | Saehan Ind Inc | ポリアミド逆浸透複合膜の製造方法 |
JP2001327840A (ja) * | 2000-05-25 | 2001-11-27 | Toray Ind Inc | 複合半透膜およびその製造方法 |
JP2004025102A (ja) * | 2002-06-24 | 2004-01-29 | Saehan Ind Inc | 耐汚染性に優れた選択的分離膜製造方法 |
JP2004050144A (ja) * | 2002-07-24 | 2004-02-19 | Toray Ind Inc | 排水処理用分離膜およびその製造方法 |
Cited By (20)
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US9636643B2 (en) | 2010-12-21 | 2017-05-02 | General Electric Company | Polymeric matrices formed from monomers comprising a protected amine group |
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CN105008031A (zh) * | 2013-02-28 | 2015-10-28 | 东丽株式会社 | 复合半透膜 |
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