JP2005529200A - 照射硬化可能な樹脂組成物及びそれを用いるラピッドプロトタイピング法 - Google Patents

照射硬化可能な樹脂組成物及びそれを用いるラピッドプロトタイピング法 Download PDF

Info

Publication number
JP2005529200A
JP2005529200A JP2004502060A JP2004502060A JP2005529200A JP 2005529200 A JP2005529200 A JP 2005529200A JP 2004502060 A JP2004502060 A JP 2004502060A JP 2004502060 A JP2004502060 A JP 2004502060A JP 2005529200 A JP2005529200 A JP 2005529200A
Authority
JP
Japan
Prior art keywords
composition
weight
group
component
ethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2004502060A
Other languages
English (en)
Japanese (ja)
Other versions
JP2005529200A5 (OSRAM
Inventor
ティエス,ジェンス,クリストフ
ディアス,アイリン,ジョルゲ,アンゲロ,アタナシウス
ロウトン,ジョン,アラン
ウィンミル,デイビッド,エル.
シュ,ジゲン
ヨウ,シャオロン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DSM IP Assets BV
Original Assignee
DSM IP Assets BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DSM IP Assets BV filed Critical DSM IP Assets BV
Publication of JP2005529200A publication Critical patent/JP2005529200A/ja
Publication of JP2005529200A5 publication Critical patent/JP2005529200A5/ja
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/027Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/106Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/06Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/10Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06Polymers provided for in subclass C08G
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/16Cyclic ethers having four or more ring atoms
    • C08G65/18Oxetanes
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0037Production of three-dimensional images
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/038Macromolecular compounds which are rendered insoluble or differentially wettable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Optics & Photonics (AREA)
  • Epoxy Resins (AREA)
  • Polyethers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
JP2004502060A 2002-05-03 2003-05-01 照射硬化可能な樹脂組成物及びそれを用いるラピッドプロトタイピング法 Pending JP2005529200A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US37723902P 2002-05-03 2002-05-03
PCT/NL2003/000320 WO2003093901A1 (en) 2002-05-03 2003-05-01 Radiation curable resin composition and rapid prototyping process using the same

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2010036379A Division JP5656419B2 (ja) 2002-05-03 2010-02-22 照射硬化可能な樹脂組成物及びそれを用いるラピッドプロトタイピング法

Publications (2)

Publication Number Publication Date
JP2005529200A true JP2005529200A (ja) 2005-09-29
JP2005529200A5 JP2005529200A5 (OSRAM) 2006-09-14

Family

ID=29401462

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2004502060A Pending JP2005529200A (ja) 2002-05-03 2003-05-01 照射硬化可能な樹脂組成物及びそれを用いるラピッドプロトタイピング法
JP2010036379A Expired - Lifetime JP5656419B2 (ja) 2002-05-03 2010-02-22 照射硬化可能な樹脂組成物及びそれを用いるラピッドプロトタイピング法

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2010036379A Expired - Lifetime JP5656419B2 (ja) 2002-05-03 2010-02-22 照射硬化可能な樹脂組成物及びそれを用いるラピッドプロトタイピング法

Country Status (8)

Country Link
US (3) US7183040B2 (OSRAM)
EP (2) EP1502155B1 (OSRAM)
JP (2) JP2005529200A (OSRAM)
KR (3) KR20120086737A (OSRAM)
CN (2) CN100576069C (OSRAM)
AU (1) AU2003224516A1 (OSRAM)
ES (1) ES2405107T3 (OSRAM)
WO (1) WO2003093901A1 (OSRAM)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006503154A (ja) * 2002-10-18 2006-01-26 ディーエスエム アイピー アセッツ ビー.ブイ. 硬化性組成物およびそれを用いるラピッドプロトタイピング方法
JP2007513234A (ja) * 2003-12-02 2007-05-24 ディーエスエム アイピー アセッツ ビー.ブイ. 難燃性の放射線硬化性組成物
JP2008533273A (ja) * 2005-03-18 2008-08-21 ペルストルプ スペシヤルテイ ケミカルズ アーベー 紫外線硬化性樹脂組成物
JP2009513764A (ja) * 2005-10-27 2009-04-02 ハンツマン アドバンスト マテリアルズ (スイッツァランド) ゲーエムベーハー アンチモンを含まない光硬化性樹脂組成物及び三次元物品
JP2009173781A (ja) * 2008-01-25 2009-08-06 Cmet Inc 光学的立体造形用樹脂組成物
JP2010520947A (ja) * 2007-03-14 2010-06-17 ハンツマン・アドヴァンスト・マテリアルズ・(スイッツランド)・ゲーエムベーハー Abs様物品を製造するための光硬化性組成物
JP2011509313A (ja) * 2007-11-27 2011-03-24 ハンツマン・アドバンスド・マテリアルズ・アメリカズ・エルエルシー 高透明性を有する三次元物品を製造するための光硬化型樹脂組成物
JP2013023574A (ja) * 2011-07-21 2013-02-04 Jsr Corp 光学的立体造形用放射線硬化性液状樹脂組成物、及びそれを光硬化させて得られる光造形物
WO2015137504A1 (ja) * 2014-03-14 2015-09-17 コニカミノルタ株式会社 3d造形用光硬化性組成物および3d造形物の製造方法

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0212062D0 (en) * 2002-05-24 2002-07-03 Vantico Ag Jetable compositions
US20040137368A1 (en) * 2003-01-13 2004-07-15 3D Systems, Inc. Stereolithographic resins containing selected oxetane compounds
US20050040564A1 (en) * 2003-08-18 2005-02-24 Jones Oliver Systems and methods for using norbornene based curable materials
WO2005021248A1 (ja) * 2003-08-27 2005-03-10 Fuji Photo Film Co., Ltd. 三次元造形物の製造方法
US7232850B2 (en) * 2003-10-03 2007-06-19 Huntsman Advanced Materials Americas Inc. Photocurable compositions for articles having stable tensile properties
US20070149667A1 (en) * 2003-10-16 2007-06-28 Dsm Ip Assets B.V. Curable compositions and rapid prototyping process using the same
WO2005045525A1 (en) * 2003-11-06 2005-05-19 Dsm Ip Assets B.V. Curable compositions and rapid prototyping process using the same
US20070267134A1 (en) * 2004-09-03 2007-11-22 Konarski Mark M Photoinitiated Cationic Epoxy Compositions
JP4702784B2 (ja) * 2005-08-08 2011-06-15 ソニー株式会社 液体吐出型記録ヘッドの流路構成材料
US7279210B2 (en) * 2005-09-07 2007-10-09 3M Innovative Properties Company Curable compositions, methods of making and using the same, and articles therefrom
WO2007031505A1 (en) 2005-09-13 2007-03-22 Huntsman Advanced Materials (Switzerland) Gmbh Photocurable compositions for preparing abs-like articles
EP1939234B2 (en) * 2005-09-29 2018-04-11 Cmet Inc. Resin composition for optical three-dimensional molded object
JP5068454B2 (ja) * 2005-12-06 2012-11-07 富士フイルム株式会社 インク組成物、インクジェット記録方法、印刷物、平版印刷版の製造方法、及び平版印刷版
JP5280615B2 (ja) * 2006-06-16 2013-09-04 シーメット株式会社 光学的立体造形用樹脂組成物
JP2008024871A (ja) * 2006-07-24 2008-02-07 Fujifilm Corp インク組成物、インクジェット記録方法、印刷物、平版印刷版の製造方法、及び平版印刷版
US20080103226A1 (en) 2006-10-31 2008-05-01 Dsm Ip Assets B.V. Photo-curable resin composition
WO2008115057A1 (en) 2007-03-20 2008-09-25 Dsm Ip Assets B.V. Stereolithography resin compositions and three-dimensional objects made therefrom
US20090004579A1 (en) * 2007-06-27 2009-01-01 Dsm Ip Assets B.V. Clear and colorless three-dimensional articles made via stereolithography and method of making said articles
JP5284833B2 (ja) * 2008-03-31 2013-09-11 富士フイルム株式会社 フォトスペーサーの製造方法
JP5446902B2 (ja) * 2009-03-05 2014-03-19 Dic株式会社 カチオン重合性接着剤及びそれを用いて得られた偏光板
KR101714798B1 (ko) 2009-03-13 2017-03-09 디에스엠 아이피 어셋츠 비.브이. 방사선-경화성 수지 조성물 및 이를 이용한 쾌속 3차원 이미지화 방법
US11725395B2 (en) 2009-09-04 2023-08-15 Välinge Innovation AB Resilient floor
US8365499B2 (en) 2009-09-04 2013-02-05 Valinge Innovation Ab Resilient floor
KR20120058554A (ko) 2009-09-04 2012-06-07 뵈린게 이노베이션 에이비이 기계식 잠금 시스템을 구비하는 탄성 바닥판 조립 방법
PL2524090T3 (pl) 2010-01-11 2022-06-13 Välinge Innovation AB Pokrycie powierzchni z konstrukcją blokującą
CN102385250A (zh) * 2011-06-29 2012-03-21 南昌大学 一种紫外激光固化快速成型光敏树脂及制备方法
RS59933B1 (sr) 2011-08-29 2020-03-31 Ceraloc Innovation Ab Mehanički sistem za blokiranje namenjen za podne panele
JP2014048556A (ja) * 2012-09-03 2014-03-17 Sumitomo Chemical Co Ltd 感光性樹脂組成物
UA111803C2 (uk) * 2012-10-05 2016-06-10 Кроноплюс Текнікал Аг Підлогова панель для зовнішнього застосування
CN102981362A (zh) * 2012-11-14 2013-03-20 南昌大学 4,5-环氧环己烷-1,2-二甲酸二缩水甘油酯作为预聚物制备立体光刻快速成型光敏树脂的方法及应用
EP3358101B1 (en) 2013-03-25 2019-11-06 Välinge Innovation AB Floorboards provided with a mechanical locking system and a method to produce such a locking system
CN104345562B (zh) 2013-08-09 2020-04-24 帝斯曼知识产权资产管理有限公司 用于增材制造的低粘度液体辐射可固化的牙对准器模具树脂组合物
AU2015309679B2 (en) 2014-08-29 2020-01-16 Välinge Innovation AB Vertical joint system for a surface covering panel
JP6205522B2 (ja) * 2015-03-26 2017-09-27 東京応化工業株式会社 ネガ型感光性組成物、パターン形成方法
US10837181B2 (en) 2015-12-17 2020-11-17 Valinge Innovation Ab Method for producing a mechanical locking system for panels
CN108779321B (zh) * 2016-03-30 2021-04-02 株式会社Adeka 固化性组合物、固化物的制造方法、及其固化物
ES3007336T3 (en) 2016-09-30 2025-03-19 Vaelinge Innovation Ab Set of panels assembled by vertical displacement and locked together in the vertical and horizontal direction
EP3315292A1 (en) * 2016-10-28 2018-05-02 DSM IP Assets B.V. Thermosetting compositions and forming three-dimensional objects therefrom
JP7701780B2 (ja) 2016-10-28 2025-07-02 ストラタシス,インコーポレイテッド 熱硬化性組成物及びそれからの三次元物体の形成
US11945152B2 (en) * 2017-03-06 2024-04-02 Maxell, Ltd. Model material ink set, support material composition, ink set, three-dimensional shaped object, and method for manufacturing three-dimensional shaped object
JP7020495B2 (ja) * 2017-04-28 2022-02-16 エルジー・ケム・リミテッド シール材組成物
PL3687949T3 (pl) 2017-11-03 2024-11-04 Covestro (Netherlands) B.V. Układy blokujące wodę zawierające włókna powleczone ciekłymi, utwardzanymi promieniowaniem kompozycjami sap
JP7215654B2 (ja) 2017-12-15 2023-01-31 コベストロ (ネザーランズ) ビー.ブイ. 粘性熱硬化性樹脂を高温噴射して、積層造形を介して固体物品を作製するための組成物及び方法
TWI692502B (zh) 2017-12-29 2020-05-01 法商阿科瑪法國公司 可固化組成物
CA3086053A1 (en) 2018-01-09 2019-07-18 Valinge Innovation Ab Set of panels
JP2021516180A (ja) * 2018-03-02 2021-07-01 フォームラブス, インコーポレーテッドFormlabs, Inc. 潜在性硬化樹脂および関連する方法
US10793735B2 (en) * 2018-03-15 2020-10-06 Ricoh Company, Ltd. Curable composition, curable ink, storing container, two-dimensional or three-dimensional image forming device, two-dimensional or three-dimensional image forming method, cured product, printed matter, and adhesive label
WO2020003133A1 (en) * 2018-06-29 2020-01-02 3M Innovative Properties Company Hydrated orthodontic articles, kits, and methods of making same
CN111624853B (zh) * 2019-07-10 2023-07-14 住华科技股份有限公司 着色树脂组成物、及应用其的彩色滤光片和显示设备
EP4117892A4 (en) * 2020-03-09 2023-11-22 Hewlett-Packard Development Company, L.P. THREE-DIMENSIONAL PRINTING WITH A CHARGED YELLOW WATER-SOLUBLE DYE-BASED FLUID
SE545292C2 (en) * 2020-07-08 2023-06-20 Perstorp Ab A radiation curable composition comprising a biobased reactive diluent
EP4206820A1 (en) 2021-12-30 2023-07-05 Arkema France Hybrid photocurable composition

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3835003A (en) * 1968-08-20 1974-09-10 American Can Co Photopolymerization of oxetanes
US3708296A (en) * 1968-08-20 1973-01-02 American Can Co Photopolymerization of epoxy monomers
PT71476A (en) 1979-07-03 1980-08-01 Sagami Chem Res Process for producing oxygen-containing hydrocarbon compounds
US4339567A (en) 1980-03-07 1982-07-13 Ciba-Geigy Corporation Photopolymerization by means of sulphoxonium salts
US4383025A (en) 1980-07-10 1983-05-10 Ciba-Geigy Corporation Photopolymerization by means of sulfoxonium salts
US4398014A (en) 1980-11-04 1983-08-09 Ciba-Geigy Corporation Sulfoxonium salts and their use as polymerization catalysts
EP0094914B1 (de) 1982-05-19 1986-09-24 Ciba-Geigy Ag Photopolymerisation mittels organometallischer Salze
DE3369398D1 (en) 1982-05-19 1987-02-26 Ciba Geigy Ag Curable compositions containing metallocen complexes, activated primers obtained therefrom and their use
ATE37242T1 (de) 1984-02-10 1988-09-15 Ciba Geigy Ag Verfahren zur herstellung einer schutzschicht oder einer reliefabbildung.
GB8414525D0 (en) 1984-06-07 1984-07-11 Ciba Geigy Ag Sulphoxonium salts
US4694029A (en) * 1985-04-09 1987-09-15 Cook Paint And Varnish Company Hybrid photocure system
US4772530A (en) 1986-05-06 1988-09-20 The Mead Corporation Photosensitive materials containing ionic dye compounds as initiators
US4772541A (en) 1985-11-20 1988-09-20 The Mead Corporation Photohardenable compositions containing a dye borate complex and photosensitive materials employing the same
DE3677527D1 (de) 1985-11-20 1991-03-21 Mead Corp Ionische farbstoffe als initiatoren enthaltende fotosensitive materialien.
US4751102A (en) 1987-07-27 1988-06-14 The Mead Corporation Radiation-curable ink and coating compositions containing ionic dye compounds as initiators
US5002856A (en) 1989-08-02 1991-03-26 E. I. Du Pont De Nemours And Company Thermally stable carbazole diazonium salts as sources of photo-initiated strong acid
TW269017B (OSRAM) 1992-12-21 1996-01-21 Ciba Geigy Ag
US5364737A (en) * 1994-01-25 1994-11-15 Morton International, Inc. Waterbone photoresists having associate thickeners
KR950034472A (ko) * 1994-04-06 1995-12-28 가나이 쓰토무 패턴형성방법 및 그것에 사용되는 투영노광장치
US5665792A (en) 1995-06-07 1997-09-09 E. I. Du Pont De Nemours And Company Stabilizers for use with photoacid precursor formulations
WO1996041237A1 (en) 1995-06-07 1996-12-19 E.I. Du Pont De Nemours And Company Sensitizers and photoacid precursors
JP3161583B2 (ja) * 1995-07-21 2001-04-25 東亞合成株式会社 活性エネルギー線硬化型組成物
JP3849989B2 (ja) * 1996-04-09 2006-11-22 株式会社Adeka 光学的立体造形用樹脂組成物および光学的立体造形法
TW329539B (en) * 1996-07-05 1998-04-11 Mitsubishi Electric Corp The semiconductor device and its manufacturing method
EP0822445B2 (de) 1996-07-29 2005-02-09 Huntsman Advanced Materials (Switzerland) GmbH Flüssige, strahlungshärtbare Zusammensetzung, insbesondere für die Stereolithographie
EP1655633A3 (en) * 1996-08-27 2006-06-21 Seiko Epson Corporation Exfoliating method, transferring method of thin film device, thin film integrated circuit device, and liquid crystal display device
JP4197361B2 (ja) * 1996-12-02 2008-12-17 株式会社Adeka 光学的立体造形用樹脂組成物および光学的立体造形方法
JP3626302B2 (ja) * 1996-12-10 2005-03-09 Jsr株式会社 光硬化性樹脂組成物
US5821897A (en) 1996-12-20 1998-10-13 Wiltron Company Simulator for testing a collision avoidance radar system
FR2757530A1 (fr) 1996-12-24 1998-06-26 Rhodia Chimie Sa Utilisation pour la stereophotolithographie - d'une composition liquide photoreticulable par voie cationique comprenant un photoamorceur du type sels d'onium ou de complexes organometalliques
JP3913350B2 (ja) * 1998-01-13 2007-05-09 ナブテスコ株式会社 光学的造形用樹脂組成物
US6287745B1 (en) * 1998-02-18 2001-09-11 Dsm N.V. Photocurable liquid resin composition comprising an epoxy-branched alicyclic compound
DE69906076T2 (de) * 1998-06-11 2003-12-24 Dow Global Technologies, Inc. Photohärtende elastomere polymere
JP4350832B2 (ja) * 1999-04-19 2009-10-21 Jsr株式会社 立体造形用光硬化性樹脂組成物およびこれを硬化してなる造形物
US6413699B1 (en) * 1999-10-11 2002-07-02 Macdermid Graphic Arts, Inc. UV-absorbing support layers and flexographic printing elements comprising same
JP3893833B2 (ja) * 2000-02-09 2007-03-14 ブラザー工業株式会社 インクジェット記録方式用エネルギー線硬化型組成物
JP2001310938A (ja) * 2000-04-28 2001-11-06 Showa Denko Kk 重合性組成物、その硬化物と製造方法
JP3974336B2 (ja) * 2001-03-01 2007-09-12 ナブテスコ株式会社 光学的立体造形用の活性エネルギー線硬化性樹脂組成物
US20030149124A1 (en) * 2001-11-27 2003-08-07 Thommes Glen A. Radiation curable resin composition for making colored three dimensional objects

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006503154A (ja) * 2002-10-18 2006-01-26 ディーエスエム アイピー アセッツ ビー.ブイ. 硬化性組成物およびそれを用いるラピッドプロトタイピング方法
JP2007513234A (ja) * 2003-12-02 2007-05-24 ディーエスエム アイピー アセッツ ビー.ブイ. 難燃性の放射線硬化性組成物
JP2008533273A (ja) * 2005-03-18 2008-08-21 ペルストルプ スペシヤルテイ ケミカルズ アーベー 紫外線硬化性樹脂組成物
JP2009513764A (ja) * 2005-10-27 2009-04-02 ハンツマン アドバンスト マテリアルズ (スイッツァランド) ゲーエムベーハー アンチモンを含まない光硬化性樹脂組成物及び三次元物品
KR101376401B1 (ko) 2005-10-27 2014-03-27 3디 시스템즈 인코오퍼레이티드 무-안티몬 광경화성 수지 조성물 및 3차원 물품
JP2010520947A (ja) * 2007-03-14 2010-06-17 ハンツマン・アドヴァンスト・マテリアルズ・(スイッツランド)・ゲーエムベーハー Abs様物品を製造するための光硬化性組成物
JP2011509313A (ja) * 2007-11-27 2011-03-24 ハンツマン・アドバンスド・マテリアルズ・アメリカズ・エルエルシー 高透明性を有する三次元物品を製造するための光硬化型樹脂組成物
JP2009173781A (ja) * 2008-01-25 2009-08-06 Cmet Inc 光学的立体造形用樹脂組成物
JP2013023574A (ja) * 2011-07-21 2013-02-04 Jsr Corp 光学的立体造形用放射線硬化性液状樹脂組成物、及びそれを光硬化させて得られる光造形物
WO2015137504A1 (ja) * 2014-03-14 2015-09-17 コニカミノルタ株式会社 3d造形用光硬化性組成物および3d造形物の製造方法
JPWO2015137504A1 (ja) * 2014-03-14 2017-04-06 コニカミノルタ株式会社 3d造形用光硬化性組成物および3d造形物の製造方法

Also Published As

Publication number Publication date
JP2010189641A (ja) 2010-09-02
CN1650231A (zh) 2005-08-03
ES2405107T3 (es) 2013-05-30
CN100576069C (zh) 2009-12-30
HK1080554A1 (zh) 2006-04-28
WO2003093901A1 (en) 2003-11-13
EP2466378A3 (en) 2012-09-05
US7183040B2 (en) 2007-02-27
KR101176747B1 (ko) 2012-08-23
AU2003224516A1 (en) 2003-11-17
CN101706639A (zh) 2010-05-12
JP5656419B2 (ja) 2015-01-21
EP2466378B1 (en) 2014-01-08
US20080064780A1 (en) 2008-03-13
US20070154840A1 (en) 2007-07-05
EP1502155B1 (en) 2013-01-30
EP1502155A1 (en) 2005-02-02
US20040142274A1 (en) 2004-07-22
KR20110051258A (ko) 2011-05-17
KR20120086737A (ko) 2012-08-03
EP2466378A2 (en) 2012-06-20
KR20050007372A (ko) 2005-01-17

Similar Documents

Publication Publication Date Title
JP5656419B2 (ja) 照射硬化可能な樹脂組成物及びそれを用いるラピッドプロトタイピング法
US9090020B2 (en) Photo-curable resin composition
US8501033B2 (en) Radiation curable resin composition and rapid three-dimensional imaging process using the same
KR101048603B1 (ko) 경화성 조성물 및 이를 사용한 급속 조형 방법
KR20040030694A (ko) 방사선-경화성 수지 조성물 및 이를 사용한 신속프로토타이핑 방법
EP2019975A1 (en) Radiation curable resin composition and rapid three dimensional imaging process using the same
JP2005510603A (ja) 着色された三次元物品を製造するための照射硬化性樹脂組成物
JP2002060463A (ja) 光硬化性樹脂組成物および立体形状物
HK1080554B (en) Radiation curable resin composition and rapid prototyping process using the same
HK1143864A (en) Radiation curable resin composition and rapid prototyping process using the same
US20040054025A1 (en) Compositions comprising a benzophenone photoinitiator
WO2004001507A1 (en) Compositions comprising a benzophenone photoinitiator
HK1120869A (en) Photo-curable resin composition
HK1084679B (en) Curable compositions and rapid prototyping process using the same

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20060428

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060725

RD03 Notification of appointment of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7423

Effective date: 20060823

RD04 Notification of resignation of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7424

Effective date: 20060901

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20080708

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20080930

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20090105

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20090106

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20090113

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20090114

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090330

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20091020