JP2004530034A5 - - Google Patents
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- Publication number
- JP2004530034A5 JP2004530034A5 JP2003503698A JP2003503698A JP2004530034A5 JP 2004530034 A5 JP2004530034 A5 JP 2004530034A5 JP 2003503698 A JP2003503698 A JP 2003503698A JP 2003503698 A JP2003503698 A JP 2003503698A JP 2004530034 A5 JP2004530034 A5 JP 2004530034A5
- Authority
- JP
- Japan
- Prior art keywords
- nanocomposite
- rubber
- halogenated
- clay
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002114 nanocomposite Substances 0.000 claims 84
- 229920001971 elastomer Polymers 0.000 claims 29
- 150000001412 amines Chemical class 0.000 claims 28
- 239000004927 clay Substances 0.000 claims 26
- 238000000034 method Methods 0.000 claims 24
- 239000000806 elastomer Substances 0.000 claims 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 16
- -1 ammonium ions Chemical class 0.000 claims 16
- 239000000203 mixture Substances 0.000 claims 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 12
- 239000003795 chemical substances by application Substances 0.000 claims 12
- 239000005060 rubber Substances 0.000 claims 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 11
- 125000000217 alkyl group Chemical group 0.000 claims 11
- 239000000126 substance Substances 0.000 claims 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 9
- 125000003342 alkenyl group Chemical group 0.000 claims 9
- 150000002148 esters Chemical class 0.000 claims 9
- 150000002825 nitriles Chemical class 0.000 claims 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N 2-propanol Substances CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims 8
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims 8
- 125000003277 amino group Chemical group 0.000 claims 8
- 229920005557 bromobutyl Polymers 0.000 claims 8
- 239000006229 carbon black Substances 0.000 claims 8
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 8
- 229920002857 polybutadiene Polymers 0.000 claims 8
- 239000000377 silicon dioxide Substances 0.000 claims 8
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 6
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 5
- 125000001931 aliphatic group Chemical group 0.000 claims 5
- 125000000524 functional group Chemical group 0.000 claims 5
- VMEZXMFPKOMWHR-UHFFFAOYSA-N (dimethylamino)methyl prop-2-enoate Chemical compound CN(C)COC(=O)C=C VMEZXMFPKOMWHR-UHFFFAOYSA-N 0.000 claims 4
- VKKTUDKKYOOLGG-UHFFFAOYSA-N 1-(diethylamino)propan-1-ol Chemical compound CCC(O)N(CC)CC VKKTUDKKYOOLGG-UHFFFAOYSA-N 0.000 claims 4
- SUZOCIFIGKCISE-UHFFFAOYSA-N 1-(dimethylamino)propan-1-ol Chemical compound CCC(O)N(C)C SUZOCIFIGKCISE-UHFFFAOYSA-N 0.000 claims 4
- JBAUPCNQUQGXJT-UHFFFAOYSA-N 1-ethenyl-4-methylbenzene;2-methylprop-1-ene Chemical class CC(C)=C.CC1=CC=C(C=C)C=C1 JBAUPCNQUQGXJT-UHFFFAOYSA-N 0.000 claims 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 4
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims 4
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 claims 4
- QUBNFZFTFXTLKH-UHFFFAOYSA-N 2-aminododecanoic acid Chemical compound CCCCCCCCCCC(N)C(O)=O QUBNFZFTFXTLKH-UHFFFAOYSA-N 0.000 claims 4
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 claims 4
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims 4
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims 4
- 244000043261 Hevea brasiliensis Species 0.000 claims 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical class CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 4
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 4
- 229920000459 Nitrile rubber Polymers 0.000 claims 4
- 239000005062 Polybutadiene Substances 0.000 claims 4
- 229920002367 Polyisobutene Polymers 0.000 claims 4
- 229920005683 SIBR Polymers 0.000 claims 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 4
- 125000003172 aldehyde group Chemical group 0.000 claims 4
- 150000001336 alkenes Chemical class 0.000 claims 4
- 150000003973 alkyl amines Chemical class 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 4
- 229960003237 betaine Drugs 0.000 claims 4
- VLLYOYVKQDKAHN-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene Chemical compound C=CC=C.CC(=C)C=C VLLYOYVKQDKAHN-UHFFFAOYSA-N 0.000 claims 4
- 229920005549 butyl rubber Polymers 0.000 claims 4
- 150000001721 carbon Chemical class 0.000 claims 4
- 125000002843 carboxylic acid group Chemical group 0.000 claims 4
- 229920005556 chlorobutyl Polymers 0.000 claims 4
- 229920001577 copolymer Polymers 0.000 claims 4
- 238000004132 cross linking Methods 0.000 claims 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims 4
- 239000000194 fatty acid Substances 0.000 claims 4
- 229930195729 fatty acid Natural products 0.000 claims 4
- 150000004665 fatty acids Chemical class 0.000 claims 4
- 239000000945 filler Substances 0.000 claims 4
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 claims 4
- 229920003052 natural elastomer Polymers 0.000 claims 4
- 229920001194 natural rubber Polymers 0.000 claims 4
- 125000002081 peroxide group Chemical group 0.000 claims 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims 4
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims 4
- 229920001084 poly(chloroprene) Polymers 0.000 claims 4
- 239000004848 polyfunctional curative Substances 0.000 claims 4
- 229920001195 polyisoprene Polymers 0.000 claims 4
- 229920000642 polymer Polymers 0.000 claims 4
- 229920002379 silicone rubber Polymers 0.000 claims 4
- 229920003048 styrene butadiene rubber Polymers 0.000 claims 4
- 239000011593 sulfur Substances 0.000 claims 4
- 229910052717 sulfur Inorganic materials 0.000 claims 4
- 125000003396 thiol group Chemical group [H]S* 0.000 claims 4
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical group [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 claims 4
- 239000011701 zinc Substances 0.000 claims 4
- 229910052725 zinc Inorganic materials 0.000 claims 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims 4
- 125000000746 allylic group Chemical group 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- 238000000465 moulding Methods 0.000 claims 2
- 150000005376 secondary alkyl halides Chemical class 0.000 claims 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 150000005375 primary alkyl halides Chemical class 0.000 claims 1
- 239000004945 silicone rubber Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29687301P | 2001-06-08 | 2001-06-08 | |
| US29791501P | 2001-06-13 | 2001-06-13 | |
| PCT/US2002/016796 WO2002100935A1 (en) | 2001-06-08 | 2002-05-29 | Low permeability nanocomposites |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004530034A JP2004530034A (ja) | 2004-09-30 |
| JP2004530034A5 true JP2004530034A5 (enExample) | 2006-01-05 |
| JP4485191B2 JP4485191B2 (ja) | 2010-06-16 |
Family
ID=26969859
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003503698A Expired - Fee Related JP4485191B2 (ja) | 2001-06-08 | 2002-05-29 | 低透過性ナノ複合物 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7485677B2 (enExample) |
| EP (1) | EP1404749B1 (enExample) |
| JP (1) | JP4485191B2 (enExample) |
| CN (1) | CN100551955C (enExample) |
| AT (1) | ATE423806T1 (enExample) |
| CA (1) | CA2448615C (enExample) |
| DE (1) | DE60231306D1 (enExample) |
| RU (2) | RU2003137562A (enExample) |
| WO (1) | WO2002100935A1 (enExample) |
Families Citing this family (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7714043B2 (en) * | 2000-10-18 | 2010-05-11 | Exxonmobil Chemical Patents Inc. | Tire innerliners having improved cold temperature properties |
| US20060167184A1 (en) * | 2000-10-18 | 2006-07-27 | Waddell Walter H | Innerliners for use in tires |
| WO2002100935A1 (en) | 2001-06-08 | 2002-12-19 | Exxonmobil Chemical Patents Inc. | Low permeability nanocomposites |
| DE60213812T2 (de) * | 2001-06-13 | 2007-02-01 | Exxonmobil Chemical Patents Inc., Baytown | Nanoverbundwerkstoffe mit geringer permeabilität |
| CA2406895A1 (en) * | 2002-10-09 | 2004-04-09 | Richard Pazur | Filled elastomeric butyl compounds |
| EP1642914B1 (en) * | 2002-11-14 | 2007-11-14 | Rohm and Haas Company | Curable clay composition : composition, processes, and uses thereof |
| EP1583780B1 (en) * | 2002-12-18 | 2013-09-04 | Bridgestone Corporation | Method for clay exfoliation, compositions therefore, and modified rubber contaiing same |
| JP4043403B2 (ja) * | 2003-05-13 | 2008-02-06 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| WO2006085957A2 (en) | 2004-07-06 | 2006-08-17 | Exxonmobil Chemical Patents, Inc. | Polymeric nanocomposites and processes for making the same |
| US7825181B2 (en) | 2004-12-03 | 2010-11-02 | Exxonmobil Chemical Patents Inc. | Modified layered fillers and their use to produce nanocomposite compositions |
| RU2373226C2 (ru) * | 2004-12-29 | 2009-11-20 | Эксонмобил Кемикэл Пейтентс Инк. | Подобранные эластомерные смеси и их применение в изделиях |
| US7906600B2 (en) | 2004-12-29 | 2011-03-15 | Exxonmobil Chemical Patents Inc. | Processable filled, curable halogenated isoolefin elastomers |
| US7572855B2 (en) * | 2005-01-28 | 2009-08-11 | Bridgestone Corporation | Nano-composite and compositions manufactured thereof |
| US7579398B2 (en) | 2005-02-02 | 2009-08-25 | Bridgestone Corporation | Nano-composite and compositions therefrom |
| US7514491B2 (en) * | 2005-07-18 | 2009-04-07 | Exxonmobil Chemical Patents Inc. | Functionalized isobutylene polymer-inorganic clay nanocomposites and organic-aqueous emulsion process |
| US7501460B1 (en) * | 2005-07-18 | 2009-03-10 | Exxonmobile Chemical Patents Inc. | Split-stream process for making nanocomposites |
| EP1922362B1 (en) * | 2005-08-26 | 2012-01-18 | Lanxess Inc. | Peroxide curable rubber compound containing high multiolefin halobutyl ionomers |
| CN101248134A (zh) * | 2005-08-26 | 2008-08-20 | 朗盛公司 | 含有高多烯烃卤丁基离聚物的过氧化物可固化的橡胶混合物 |
| EP1922361A4 (en) * | 2005-08-26 | 2010-03-10 | Lanxess Inc | PROCESS FOR THE PRODUCTION OF HIGH PEROXIDE-CURABLE HALOBUTYL AURO-HIGH OLEFINS |
| KR100776074B1 (ko) | 2005-10-28 | 2007-11-15 | 금호타이어 주식회사 | 공기입 타이어의 인너라이너용 조성물 및 그의 제조방법 |
| US8048947B2 (en) | 2005-11-08 | 2011-11-01 | Exxonmobil Chemical Patents Inc. | Nanocomposites and methods for making the same |
| US7585914B2 (en) * | 2005-11-09 | 2009-09-08 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions and methods for making the same |
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| US7638573B2 (en) | 2006-04-07 | 2009-12-29 | Exxonmobil Chemical Patents Inc. | Butyl nanocomposite via low Mw elastomer pre-blend |
| US7935184B2 (en) * | 2006-06-19 | 2011-05-03 | Bridgestone Corporation | Method of preparing imidazolium surfactants |
| US7498381B1 (en) | 2006-08-02 | 2009-03-03 | Exxonmobil Chemical Patents Inc. | Low permeability elastomeric-metal phosphate nanocomposites |
| US20100144920A1 (en) * | 2006-10-05 | 2010-06-10 | Polyone Corporation | Thermoplastic elastomers containing organoclays |
| CA2604409C (en) * | 2006-12-22 | 2015-04-07 | Lanxess Inc. | Butyl rubber ionomer nanocomposites |
| EP2209818B1 (en) * | 2007-11-14 | 2011-06-08 | ExxonMobil Chemical Patents Inc. | Triethylamine functionalized elastomer in barrier applications |
| CN101910278B (zh) * | 2008-01-18 | 2013-04-03 | 埃克森美孚化学专利公司 | 包含烃聚合物添加剂的弹性体组合物 |
| US8910684B2 (en) * | 2008-07-03 | 2014-12-16 | Bridgestone Corporation | Tire innerliner with improved resistance to air permeability |
| WO2010044776A1 (en) | 2008-10-14 | 2010-04-22 | Exxonmobil Chemical Patents Inc. | Polymer-clay nanocomposite and process for preparing same |
| WO2011031437A1 (en) * | 2009-09-10 | 2011-03-17 | Exxonmobil Chemical Patents Inc. | Elastomeric copolymers, copolymer compositions, and their use in articles |
| US20110094645A1 (en) * | 2009-10-26 | 2011-04-28 | Michael Brendan Rodgers | Innerliners for Off-Road, Farm, Large Truck and Aircraft Tires |
| US9475910B2 (en) | 2009-10-26 | 2016-10-25 | Exxonmobil Chemical Patents Inc. | Elastomer nanocomposites with incorporated process oils |
| EP2513202B1 (en) * | 2009-12-17 | 2013-10-23 | ExxonMobil Chemical Patents Inc. | Elastomeric nanocomposites, nanocomposite compositions, and methods of manufacture |
| JP5216028B2 (ja) * | 2010-01-18 | 2013-06-19 | 住友ゴム工業株式会社 | インナーライナー用ゴム組成物及び空気入りタイヤ |
| CA2792799C (en) * | 2010-03-24 | 2018-10-16 | Lanxess International Sa | Process for the production of rubber ionomers and polymer nanocomposites |
| US8461240B2 (en) | 2010-04-30 | 2013-06-11 | Exxonmobil Chemical Patents Inc. | Elastomeric nanocomposites, nanocomposite compositions, and methods of manufacture |
| JP4893877B2 (ja) * | 2010-06-02 | 2012-03-07 | 横浜ゴム株式会社 | 冷媒輸送用ホース |
| WO2012044317A1 (en) * | 2010-09-30 | 2012-04-05 | Michelin Recherche Et Technique S.A. | Barrier layer for inflatable articles |
| US9200152B2 (en) * | 2011-01-25 | 2015-12-01 | Exxonmobil Chemical Patents Inc. | Elastomeric nanocomposites, nanocomposite compositions, and methods of manufacture |
| US9574100B2 (en) * | 2011-06-22 | 2017-02-21 | Basf Se | Coated polymer foils with oxygen barrier properties |
| US9303138B2 (en) * | 2011-09-21 | 2016-04-05 | Exxonmobil Chemical Patents Inc. | Elastomeric composition for pharmaceutical articles |
| JP5788124B2 (ja) | 2012-03-29 | 2015-09-30 | スリーエム イノベイティブ プロパティズ カンパニー | ペンダントフリーラジカル重合性四級アンモニウム置換基を含むポリ（イソブチレン）コポリマーを含む接着剤 |
| JP6018951B2 (ja) * | 2013-02-28 | 2016-11-02 | 株式会社ブリヂストン | ゴム組成物、インナーライナー素材、及び、空気入りタイヤ |
| ITRM20130372A1 (it) * | 2013-06-27 | 2014-12-28 | Bridgestone Corp | Strato barriera contro l'emissione di idrocarburi da un pneumatico |
| WO2015130392A1 (en) * | 2014-02-28 | 2015-09-03 | Exxonmobil Chemical Patents Inc. | Nanocomposite mooney viscosity stability |
| CN105111602B (zh) * | 2015-09-28 | 2017-07-07 | 郑州翱翔医药科技股份有限公司 | 一种药用热塑性弹性体及其制备方法 |
| EP3356469B1 (en) * | 2015-09-30 | 2020-04-29 | ExxonMobil Chemical Patents Inc. | Polycyclic aromatic hydrocarbon functionalized isobutylene copolymers for dispersing graphene and graphite |
| WO2018004790A1 (en) * | 2016-06-29 | 2018-01-04 | Exxonmobil Chemical Patents Inc. | Graft copolymers for dispersing graphene and graphite |
| US10465064B2 (en) * | 2016-09-23 | 2019-11-05 | Baker Hughes, A Ge Company, Llc | Wear resistant and high temperature resistant elastomer nanocomposites |
| CN112639007A (zh) | 2018-05-14 | 2021-04-09 | 埃克森美孚化学专利公司 | 可膨胀的热塑性微球掺杂的轮胎内衬 |
| CN117500849A (zh) * | 2021-06-16 | 2024-02-02 | 3M创新有限公司 | 可自由基聚合的共聚物、包含其的可自由基聚合的组合物、以及来自其的聚合反应产物 |
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-
2002
- 2002-05-29 WO PCT/US2002/016796 patent/WO2002100935A1/en not_active Ceased
- 2002-05-29 RU RU2003137562/04A patent/RU2003137562A/ru unknown
- 2002-05-29 CA CA2448615A patent/CA2448615C/en not_active Expired - Fee Related
- 2002-05-29 DE DE60231306T patent/DE60231306D1/de not_active Expired - Lifetime
- 2002-05-29 RU RU2007121931/04A patent/RU2346961C1/ru active
- 2002-05-29 EP EP02739471A patent/EP1404749B1/en not_active Expired - Lifetime
- 2002-05-29 JP JP2003503698A patent/JP4485191B2/ja not_active Expired - Fee Related
- 2002-05-29 US US10/478,281 patent/US7485677B2/en not_active Expired - Lifetime
- 2002-05-29 CN CNB028113306A patent/CN100551955C/zh not_active Expired - Lifetime
- 2002-05-29 AT AT02739471T patent/ATE423806T1/de not_active IP Right Cessation
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