JP2004530035A5 - - Google Patents
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- Publication number
- JP2004530035A5 JP2004530035A5 JP2003503699A JP2003503699A JP2004530035A5 JP 2004530035 A5 JP2004530035 A5 JP 2004530035A5 JP 2003503699 A JP2003503699 A JP 2003503699A JP 2003503699 A JP2003503699 A JP 2003503699A JP 2004530035 A5 JP2004530035 A5 JP 2004530035A5
- Authority
- JP
- Japan
- Prior art keywords
- nanocomposite
- rubber
- group
- clay
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002114 nanocomposite Substances 0.000 claims description 70
- 239000003795 chemical substances by application Substances 0.000 claims description 37
- 239000004927 clay Substances 0.000 claims description 22
- -1 thiosulfate compound Chemical class 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 229920001971 elastomer Polymers 0.000 claims description 10
- 239000005060 rubber Substances 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 9
- 125000003172 aldehyde group Chemical group 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 6
- 125000002843 carboxylic acid group Chemical group 0.000 claims description 6
- 125000000524 functional group Chemical group 0.000 claims description 6
- 125000002081 peroxide group Chemical group 0.000 claims description 6
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 6
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical group [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 5
- 150000003973 alkyl amines Chemical class 0.000 claims 9
- 239000003760 tallow Substances 0.000 claims 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 6
- 150000001336 alkenes Chemical class 0.000 claims 6
- 125000000217 alkyl group Chemical group 0.000 claims 6
- 229920005557 bromobutyl Polymers 0.000 claims 6
- 229920002857 polybutadiene Polymers 0.000 claims 6
- 150000001412 amines Chemical class 0.000 claims 4
- 229910021529 ammonia Inorganic materials 0.000 claims 4
- 229920005549 butyl rubber Polymers 0.000 claims 4
- 229920001577 copolymer Polymers 0.000 claims 4
- JBAUPCNQUQGXJT-UHFFFAOYSA-N 1-ethenyl-4-methylbenzene;2-methylprop-1-ene Chemical class CC(C)=C.CC1=CC=C(C=C)C=C1 JBAUPCNQUQGXJT-UHFFFAOYSA-N 0.000 claims 3
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims 3
- 244000043261 Hevea brasiliensis Species 0.000 claims 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical class CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 3
- 229920000459 Nitrile rubber Polymers 0.000 claims 3
- 229920002367 Polyisobutene Polymers 0.000 claims 3
- 229920005683 SIBR Polymers 0.000 claims 3
- 235000021355 Stearic acid Nutrition 0.000 claims 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 3
- VLLYOYVKQDKAHN-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene Chemical compound C=CC=C.CC(=C)C=C VLLYOYVKQDKAHN-UHFFFAOYSA-N 0.000 claims 3
- 239000006229 carbon black Substances 0.000 claims 3
- 229920005556 chlorobutyl Polymers 0.000 claims 3
- NAPSCFZYZVSQHF-UHFFFAOYSA-N dimantine Chemical compound CCCCCCCCCCCCCCCCCCN(C)C NAPSCFZYZVSQHF-UHFFFAOYSA-N 0.000 claims 3
- VFLWKHBYVIUAMP-UHFFFAOYSA-N n-methyl-n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCCCCCC VFLWKHBYVIUAMP-UHFFFAOYSA-N 0.000 claims 3
- 229920003052 natural elastomer Polymers 0.000 claims 3
- 229920001194 natural rubber Polymers 0.000 claims 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 3
- 229920001084 poly(chloroprene) Polymers 0.000 claims 3
- 229920001195 polyisoprene Polymers 0.000 claims 3
- 229920000909 polytetrahydrofuran Polymers 0.000 claims 3
- 229920002379 silicone rubber Polymers 0.000 claims 3
- 239000008117 stearic acid Substances 0.000 claims 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims 3
- 239000011593 sulfur Substances 0.000 claims 3
- 229910052717 sulfur Inorganic materials 0.000 claims 3
- 239000011701 zinc Substances 0.000 claims 3
- 229910052725 zinc Inorganic materials 0.000 claims 3
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims 3
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 1
- 125000005210 alkyl ammonium group Chemical group 0.000 claims 1
- 125000000746 allylic group Chemical group 0.000 claims 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 claims 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 4
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 2
- 229940117916 cinnamic aldehyde Drugs 0.000 description 2
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000010954 inorganic particle Substances 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 description 2
- WTVOIJLLMIOCPT-UHFFFAOYSA-N S1(=S)(=O)OCCCCCCO1.[Na] Chemical compound S1(=S)(=O)OCCCCCCO1.[Na] WTVOIJLLMIOCPT-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29791501P | 2001-06-13 | 2001-06-13 | |
| US60/297,915 | 2001-06-13 | ||
| PCT/US2002/016797 WO2002100936A1 (en) | 2001-06-13 | 2002-05-29 | Low permeability nanocomposites |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004530035A JP2004530035A (ja) | 2004-09-30 |
| JP2004530035A5 true JP2004530035A5 (enExample) | 2006-01-05 |
| JP5002112B2 JP5002112B2 (ja) | 2012-08-15 |
Family
ID=23148255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003503699A Expired - Fee Related JP5002112B2 (ja) | 2001-06-13 | 2002-05-29 | 低透過性ナノ複合物 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7491764B2 (enExample) |
| EP (1) | EP1401933B1 (enExample) |
| JP (1) | JP5002112B2 (enExample) |
| CN (1) | CN1268673C (enExample) |
| AT (1) | ATE335784T1 (enExample) |
| CA (1) | CA2449075C (enExample) |
| DE (1) | DE60213812T2 (enExample) |
| RU (1) | RU2309167C2 (enExample) |
| WO (1) | WO2002100936A1 (enExample) |
Families Citing this family (76)
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| JP4683928B2 (ja) * | 2002-12-18 | 2011-05-18 | 株式会社ブリヂストン | クレイの剥離方法、該方法から得られた組成物、及び該組成物を含む変性ゴム |
| ES2279338T3 (es) | 2003-01-08 | 2007-08-16 | Sud-Chemie Ag | Composicion a base de nano-arcillas pre-exfoliadas y su uso. |
| US6875818B2 (en) | 2003-01-16 | 2005-04-05 | Bridgestone Corporation | Polymer nano-strings |
| WO2004111122A1 (de) | 2003-06-12 | 2004-12-23 | Süd-Chemie AG | Verfahren zur herstellung von nanocomposit-additiven mit verbesserter delaminierung in polymeren |
| CN100404596C (zh) * | 2003-08-07 | 2008-07-23 | 普立万公司 | 热塑性弹性体及其制备方法 |
| US7205370B2 (en) | 2004-01-12 | 2007-04-17 | Bridgestone Corporation | Polymeric nano-particles of flower-like structure and applications |
| US7112369B2 (en) | 2004-03-02 | 2006-09-26 | Bridgestone Corporation | Nano-sized polymer-metal composites |
| US20050215693A1 (en) * | 2004-03-29 | 2005-09-29 | Xiaorong Wang | Clay modified rubber composition and a method for manufacturing same |
| RU2393179C2 (ru) | 2004-07-06 | 2010-06-27 | Эксонмобил Кемикэл Пейтентс Инк. | Полимерные нанокомпозиты и способы их получения |
| DE102004039451A1 (de) * | 2004-08-13 | 2006-03-02 | Süd-Chemie AG | Polymerblend aus nicht verträglichen Polymeren |
| RU2375304C2 (ru) * | 2004-12-01 | 2009-12-10 | Акцо Нобель Н.В. | Глина, содержащая заряд-компенсирующие органические ионы, и нанокомпозиционные материалы, содержащие такую глину |
| CA2588910C (en) | 2004-12-03 | 2013-09-10 | Exxonmobil Chemical Patents Inc. | Modified layered fillers and their use to produce nanocomposite compositions |
| CA2592498C (en) | 2004-12-29 | 2011-09-13 | Exxonmobil Chemical Patents Inc. | Select elastomeric blends and their use in articles |
| US7906600B2 (en) | 2004-12-29 | 2011-03-15 | Exxonmobil Chemical Patents Inc. | Processable filled, curable halogenated isoolefin elastomers |
| US7572855B2 (en) | 2005-01-28 | 2009-08-11 | Bridgestone Corporation | Nano-composite and compositions manufactured thereof |
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| US12146062B2 (en) * | 2018-04-11 | 2024-11-19 | ExxonMobil Engineering & Technology Company | Propylene-based polymer additives for improved tire tread performance |
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-
2002
- 2002-05-29 WO PCT/US2002/016797 patent/WO2002100936A1/en not_active Ceased
- 2002-05-29 RU RU2003137563/04A patent/RU2309167C2/ru active IP Right Revival
- 2002-05-29 US US10/478,606 patent/US7491764B2/en not_active Expired - Lifetime
- 2002-05-29 CA CA2449075A patent/CA2449075C/en not_active Expired - Fee Related
- 2002-05-29 EP EP02739472A patent/EP1401933B1/en not_active Expired - Lifetime
- 2002-05-29 JP JP2003503699A patent/JP5002112B2/ja not_active Expired - Fee Related
- 2002-05-29 CN CNB028120221A patent/CN1268673C/zh not_active Expired - Lifetime
- 2002-05-29 DE DE60213812T patent/DE60213812T2/de not_active Expired - Lifetime
- 2002-05-29 AT AT02739472T patent/ATE335784T1/de not_active IP Right Cessation
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