JP2002513734A - 主族金属に基づく不斉触媒、およびその応用 - Google Patents

主族金属に基づく不斉触媒、およびその応用

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Publication number
JP2002513734A
JP2002513734A JP2000546729A JP2000546729A JP2002513734A JP 2002513734 A JP2002513734 A JP 2002513734A JP 2000546729 A JP2000546729 A JP 2000546729A JP 2000546729 A JP2000546729 A JP 2000546729A JP 2002513734 A JP2002513734 A JP 2002513734A
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JP
Japan
Prior art keywords
catalyst
chiral
group
racemic
nucleophile
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Pending
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JP2000546729A
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English (en)
Japanese (ja)
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JP2002513734A5 (https=
Inventor
エヌ ジャコブセン，エリック
エス シグマン，マシュー
Original Assignee
プレジデント・アンド・フェロウズ・オブ・ハーバード・カレッジ
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Publication of JP2002513734A publication Critical patent/JP2002513734A/ja
Publication of JP2002513734A5 publication Critical patent/JP2002513734A5/ja
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/30—Preparation of optical isomers
    • C07C227/32—Preparation of optical isomers by stereospecific synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/348—1,4-additions, e.g. conjugate additions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0244—Pincer-type complexes, i.e. consisting of a tridentate skeleton bound to a metal, e.g. by one to three metal-carbon sigma-bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2000546729A 1998-05-01 1999-04-30 主族金属に基づく不斉触媒、およびその応用 Pending JP2002513734A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/071,842 1998-05-01
US09/071,842 US6521561B1 (en) 1998-05-01 1998-05-01 Main-group metal based asymmetric catalysts and applications thereof
PCT/US1999/009570 WO1999056699A2 (en) 1998-05-01 1999-04-30 Main-group metal-based asymmetric catalysts and applications thereof

Publications (2)

Publication Number Publication Date
JP2002513734A true JP2002513734A (ja) 2002-05-14
JP2002513734A5 JP2002513734A5 (https=) 2006-06-29

Family

ID=22103940

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000546729A Pending JP2002513734A (ja) 1998-05-01 1999-04-30 主族金属に基づく不斉触媒、およびその応用

Country Status (5)

Country Link
US (3) US6521561B1 (https=)
EP (1) EP1073613A2 (https=)
JP (1) JP2002513734A (https=)
CA (1) CA2329316A1 (https=)
WO (1) WO1999056699A2 (https=)

Cited By (8)

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WO2006109442A1 (ja) * 2005-04-12 2006-10-19 Japan Science And Technology Agency 光学活性なα－ヒドロキシホスホン酸及びその誘導体の製造方法、光学活性アルミニウム（サラレン）錯体及びその製造方法、並びにサラレン配位子の製造方法
JP2007231007A (ja) * 2006-02-01 2007-09-13 Sumitomo Chemical Co Ltd 光学活性なアルコール化合物の製造法およびそれに用いる不斉錯体
JP2007231006A (ja) * 2006-02-01 2007-09-13 Sumitomo Chemical Co Ltd 光学活性なアルコール化合物の製造方法およびそれに用いる不斉錯体
JP2008222611A (ja) * 2007-03-09 2008-09-25 Nissan Chem Ind Ltd アルミニウムサラレン錯体触媒を用いた光学活性スルホキシド化合物の製造法
JP2009039623A (ja) * 2007-08-07 2009-02-26 Sumitomo Chemical Co Ltd 金属錯体、並びにこの金属錯体を含有する触媒及び電極触媒
JP2013184935A (ja) * 2012-03-08 2013-09-19 Kyoto Univ 連続的な不斉合成法及びその方法に用いるｄｎａを含有するハイブリッド触媒
WO2014196542A1 (ja) * 2013-06-05 2014-12-11 デクセリアルズ株式会社 光学活性化合物の製造方法
JP2015229636A (ja) * 2014-06-03 2015-12-21 デクセリアルズ株式会社 光学活性化合物の製造方法

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KR100342541B1 (ko) * 1998-04-16 2002-06-28 나까니시 히로유끼 올레핀 중합촉매 및 중합방법
MXPA02004322A (es) * 1999-11-01 2002-11-07 W R Grace & Co Cohn Catalizador de polimerizacion de olefinas bidentado o tridentado soporte heterogeneo activo.
JP4535216B2 (ja) * 2000-04-12 2010-09-01 日産化学工業株式会社 光学活性コバルト錯体及び不斉シクロプロパン化反応
WO2002010096A1 (en) 2000-07-31 2002-02-07 Brandeis University Kinetic resolutions of chiral 2- and 3-substituted carboxylic acids
US6562967B2 (en) * 2000-07-31 2003-05-13 Brandeis University Kinetic resolutions of chiral 2-and-3-substituted carboxylic acids
US6703508B2 (en) 2000-12-04 2004-03-09 Sepracor, Inc. Methods for the stereoselective synthesis of substituted piperidines
BR0209292B1 (pt) 2001-04-30 2014-04-29 Ciba Sc Holding Ag Composto de complexo de metal, agente de lavagem, limpeza, desinfecção ou alvejamento, e preparação sólida
JP3968076B2 (ja) * 2001-06-27 2007-08-29 アールエス テック コーポレイション 新しいキラルサレン化合物、キラルサレン触媒及びこれを利用したラセミックエポキシ化合物からキラル化合物を製造する方法
US6974665B2 (en) 2001-09-06 2005-12-13 University Of Nebraska In situ screening to optimize variables in organic reactions
US7001863B2 (en) * 2001-12-18 2006-02-21 Univation Technologies, Llc Monoamide based catalyst compositions for the polymerization of olefins
US6864205B2 (en) * 2001-12-18 2005-03-08 Univation Technologies, Llc Heterocyclic-amide catalyst compositions for the polymerization of olefins
US7199255B2 (en) * 2001-12-18 2007-04-03 Univation Technologies, Llc Imino-amide catalysts for olefin polymerization
GB0209317D0 (en) * 2002-04-24 2002-06-05 Bp Chem Int Ltd Polymerisation catalyst
EP1590377B1 (en) 2003-02-07 2007-06-13 Basell Polyolefine GmbH Polymerization catalysts, organic transition metal compounds, process for preparing polyolefins
US7531662B2 (en) 2003-06-11 2009-05-12 Brandeis University Cinchona-alkaloid-based catalysts, and asymmetric alcoholysis of cyclic anhydrides using them
ATE460182T1 (de) 2004-01-27 2010-03-15 Univ South Florida An einem calixaren befestigte wachstumsfaktor- bindungsverbindungen
ES2302996T3 (es) * 2004-04-27 2008-08-01 Nestec S.A. Recipiente presurizado para la distribucion de un producto viscoso.
DE102004032581A1 (de) * 2004-07-05 2006-02-09 Basell Polyolefine Gmbh Polymerisationskatalysatoren, Hauptgruppenkoordinationsverbindungen, Verfahren zur Herstellung von Polyolefinen und Polyolefine
WO2007011910A2 (en) * 2005-07-19 2007-01-25 Trustees Of Boston University Chiral amine-catalyzed asymmetric addition of carbon-centered nucleophiles to imines
US8367871B2 (en) * 2007-03-09 2013-02-05 Nissan Chemical Industries, Ltd. Process for production of optically active sulfoxide compound using iron-salan complex catalyst
GB0708016D0 (en) * 2007-04-25 2007-06-06 Univ Newcastle Synthesis of cyclic carbonates
US20110015409A1 (en) 2008-03-07 2011-01-20 University Of Newcastle Upon Tyne Synthesis of cyclic carbonates
CN104193980B (zh) 2008-05-09 2018-11-13 康奈尔大学 环氧乙烷与二氧化碳的聚合物
US8633123B2 (en) 2008-08-22 2014-01-21 Novomer, Inc. Catalysts and methods for polymer synthesis
CA2736482C (en) 2008-09-08 2018-01-02 Novomer, Inc. Polycarbonate polyol compositions and methods
WO2010033703A1 (en) 2008-09-17 2010-03-25 Novomer, Inc. Purification of polycarbonates
CA2742119C (en) 2008-11-01 2018-05-29 Novomer, Inc. Polycarbonate block copolymers
GB0904654D0 (en) 2009-03-18 2009-04-29 Univ Newcastle Synthesis of cyclic carbonates
NO2515648T3 (https=) 2009-12-24 2018-01-13
KR101805648B1 (ko) 2010-09-14 2017-12-14 사우디 아람코 테크놀로지스 컴퍼니 중합체 합성용의 촉매 및 방법
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CN106939078B (zh) 2011-05-09 2020-12-11 沙特阿美技术公司 聚合物组合物及方法
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US9403861B2 (en) 2011-12-11 2016-08-02 Novomer, Inc. Salen complexes with dianionic counterions
KR102093604B1 (ko) 2011-12-20 2020-03-26 사우디 아람코 테크놀로지스 컴퍼니 폴리머 합성 방법
JP2015514848A (ja) 2012-04-16 2015-05-21 ノボマー， インコーポレイテッド 接着剤組成物および方法
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US9994599B2 (en) 2013-09-13 2018-06-12 University Of Florida Research Foundation, Inc. Biaryl ligands
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JP5952461B1 (ja) * 2015-05-12 2016-07-13 田中貴金属工業株式会社 異種複核錯体からなる化学蒸着用原料及び該化学蒸着用原料を用いた化学蒸着法
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JPH09132610A (ja) * 1995-11-07 1997-05-20 Daicel Chem Ind Ltd （メタ）アクリル酸エステルの重合法
JPH09249984A (ja) * 1996-03-13 1997-09-22 Otsuka Chem Co Ltd 光学活性エポキシド誘導体の製造方法
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