JP2000204121A5 - - Google Patents

Info

Publication number

JP2000204121A5

JP2000204121A5 JP2000034155A JP2000034155A JP2000204121A5 JP 2000204121 A5 JP2000204121 A5 JP 2000204121A5 JP 2000034155 A JP2000034155 A JP 2000034155A JP 2000034155 A JP2000034155 A JP 2000034155A JP 2000204121 A5 JP2000204121 A5 JP 2000204121A5

Authority

JP

Japan

Prior art keywords

compound

polymer

initiator

compounds

catalyst system

Prior art date

2000-01-06

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Ceased

Links

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• 238000000034 method Methods 0.000 description 18
• 150000001875 compounds Chemical class 0.000 description 16
• 229920000642 polymer Polymers 0.000 description 14
• 239000003999 initiator Substances 0.000 description 9
• 239000003054 catalyst Substances 0.000 description 7
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 7
• 239000004215 Carbon black (E152) Substances 0.000 description 6
• 229930195733 hydrocarbon Natural products 0.000 description 6
• 150000002430 hydrocarbons Chemical class 0.000 description 6
• 239000000203 mixture Substances 0.000 description 6
• 239000002904 solvent Substances 0.000 description 6
• 229940126062 Compound A Drugs 0.000 description 5
• NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 5
• 150000001993 dienes Chemical class 0.000 description 5
• AFRJJFRNGGLMDW-UHFFFAOYSA-N lithium amide Chemical compound [Li+].[NH2-] AFRJJFRNGGLMDW-UHFFFAOYSA-N 0.000 description 4
• 239000000178 monomer Substances 0.000 description 4
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
• 125000000129 anionic group Chemical group 0.000 description 3
• 125000004432 carbon atom Chemical group C* 0.000 description 3
• 238000006243 chemical reaction Methods 0.000 description 3
• 239000003426 co-catalyst Substances 0.000 description 3
• 238000006116 polymerization reaction Methods 0.000 description 3
• WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
• 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
• 150000001342 alkaline earth metals Chemical class 0.000 description 2
• 125000000217 alkyl group Chemical group 0.000 description 2
• 229910052744 lithium Inorganic materials 0.000 description 2
• 229910052751 metal Inorganic materials 0.000 description 2
• 239000002184 metal Substances 0.000 description 2
• OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
• XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
• 125000002015 acyclic group Chemical group 0.000 description 1
• -1 alkyl lithium compound Chemical class 0.000 description 1
• 229910052788 barium Inorganic materials 0.000 description 1
• DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical group [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
• BUZDJAHOKIZQIF-UHFFFAOYSA-L barium(2+);2-(2-ethoxy-2-oxoethoxy)acetate Chemical group [Ba+2].CCOC(=O)COCC([O-])=O.CCOC(=O)COCC([O-])=O BUZDJAHOKIZQIF-UHFFFAOYSA-L 0.000 description 1
• SBMJKCDBJMFHGS-UHFFFAOYSA-L barium(2+);2-nonylphenolate Chemical group [Ba+2].CCCCCCCCCC1=CC=CC=C1[O-].CCCCCCCCCC1=CC=CC=C1[O-] SBMJKCDBJMFHGS-UHFFFAOYSA-L 0.000 description 1
• 229910052791 calcium Chemical group 0.000 description 1
• 239000011575 calcium Chemical group 0.000 description 1
• 239000007795 chemical reaction product Substances 0.000 description 1
• 125000000753 cycloalkyl group Chemical group 0.000 description 1
• 230000000694 effects Effects 0.000 description 1
• 238000007306 functionalization reaction Methods 0.000 description 1
• NVMMPHVQFFIBOS-UHFFFAOYSA-N lithium;dibutylazanide Chemical compound [Li+].CCCC[N-]CCCC NVMMPHVQFFIBOS-UHFFFAOYSA-N 0.000 description 1
• 238000004519 manufacturing process Methods 0.000 description 1
• 150000002736 metal compounds Chemical class 0.000 description 1
• 230000000379 polymerizing effect Effects 0.000 description 1
• LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
• 239000012763 reinforcing filler Substances 0.000 description 1
• 229910052712 strontium Inorganic materials 0.000 description 1
• CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical group [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
• 229910052717 sulfur Inorganic materials 0.000 description 1
• 239000011593 sulfur Substances 0.000 description 1
• LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1