IT1309590B1 - Derivati di 1-alcossi-polialchil-piperidine e loro impiego comeregolatori della polimerizzazione. - Google Patents
Derivati di 1-alcossi-polialchil-piperidine e loro impiego comeregolatori della polimerizzazione.Info
- Publication number
- IT1309590B1 IT1309590B1 IT1999MI000453A ITMI990453A IT1309590B1 IT 1309590 B1 IT1309590 B1 IT 1309590B1 IT 1999MI000453 A IT1999MI000453 A IT 1999MI000453A IT MI990453 A ITMI990453 A IT MI990453A IT 1309590 B1 IT1309590 B1 IT 1309590B1
- Authority
- IT
- Italy
- Prior art keywords
- comeregulatory
- piperidins
- alcoxy
- polyalkyl
- polymerization
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D211/40—Oxygen atoms
- C07D211/44—Oxygen atoms attached in position 4
- C07D211/46—Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D211/72—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D211/74—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
- C07D211/94—Oxygen atom, e.g. piperidine N-oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Hydrogenated Pyridines (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
- Plural Heterocyclic Compounds (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98810194 | 1998-03-09 | ||
| EP98810531 | 1998-06-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ITMI990453A1 ITMI990453A1 (it) | 2000-09-05 |
| IT1309590B1 true IT1309590B1 (it) | 2002-01-24 |
Family
ID=26151881
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT1999MI000453A IT1309590B1 (it) | 1998-03-09 | 1999-03-05 | Derivati di 1-alcossi-polialchil-piperidine e loro impiego comeregolatori della polimerizzazione. |
Country Status (18)
| Country | Link |
|---|---|
| US (4) | US6353107B1 (enExample) |
| JP (1) | JP4651137B2 (enExample) |
| KR (1) | KR100581654B1 (enExample) |
| CN (1) | CN1171871C (enExample) |
| AT (1) | AT408655B (enExample) |
| AU (1) | AU754927B2 (enExample) |
| BE (1) | BE1012399A3 (enExample) |
| BR (1) | BR9900977B1 (enExample) |
| CA (1) | CA2264460A1 (enExample) |
| CH (1) | CH693416A5 (enExample) |
| CZ (1) | CZ78999A3 (enExample) |
| DE (1) | DE19909767B4 (enExample) |
| ES (1) | ES2155014B1 (enExample) |
| FR (1) | FR2777892B1 (enExample) |
| GB (1) | GB2335190B (enExample) |
| IT (1) | IT1309590B1 (enExample) |
| NL (1) | NL1011493C2 (enExample) |
| SG (1) | SG82601A1 (enExample) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH693416A5 (de) * | 1998-03-09 | 2003-07-31 | Ciba Sc Holding Ag | 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler. |
| CA2337482A1 (en) * | 1998-07-31 | 2000-02-17 | Ciba Specialty Chemicals Holding Inc. | Open chain alkoxyamine compounds and their use as polymerization regulators |
| US6734269B1 (en) | 1998-10-06 | 2004-05-11 | Atofina | Method for controlled free radical polymerization or copolymerization of ethylene under high pressure in the presence of an initiator-controller |
| TWI225483B (en) | 1998-10-16 | 2004-12-21 | Ciba Sc Holding Ag | Heterocyclic alkoxyamines as regulators in controlled radical polymerization process |
| US6875831B1 (en) * | 1999-07-02 | 2005-04-05 | Ciba Specialty Chemicals Corp. | Mono and multifunctional alkoxyamines for the preparation of functionalized macromers |
| TW546311B (en) * | 1999-11-25 | 2003-08-11 | Ciba Sc Holding Ag | Composition and method for color improvement of nitroxyl containing polymers |
| TW541303B (en) * | 2000-03-22 | 2003-07-11 | Ciba Sc Holding Ag | 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides |
| KR100842407B1 (ko) * | 2000-05-19 | 2008-07-01 | 시바 홀딩 인코포레이티드 | 폴리에틸렌 또는 폴리에틸렌 배합물의 분자량 제어 증가방법 |
| TW572896B (en) * | 2000-05-26 | 2004-01-21 | Ciba Sc Holding Ag | Process for the synthesis of amine ethers from secondary amino oxides |
| TWI225492B (en) * | 2000-09-25 | 2004-12-21 | Ciba Sc Holding Ag | Composition and process for enhancing controlled free radical polymerization |
| TW574236B (en) * | 2000-09-25 | 2004-02-01 | Ciba Sc Holding Ag | Process for controlled radical polymerization in aqueous dispersion |
| TWI236482B (en) * | 2000-11-13 | 2005-07-21 | Ciba Sc Holding Ag | Process for the (co)polymerization of vinyl chloride in the presence of a stable free nitroxyl radical |
| TW557305B (en) * | 2000-12-14 | 2003-10-11 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith |
| TWI274053B (en) * | 2000-12-14 | 2007-02-21 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization |
| US6849679B2 (en) | 2001-05-21 | 2005-02-01 | Ciba Specialty Chemicals Corporation | Pigment compositions with modified block copolymer dispersants |
| ATE491687T1 (de) * | 2001-06-13 | 2011-01-15 | Basf Se | 4-imin-n-alkoxy- oder oxy-polyalkyl-piperidin- verbindungen zur verwendung als polymerisationsregulatoren |
| US7868171B2 (en) * | 2001-11-12 | 2011-01-11 | Ciba Specialty Chemicals Corp. | N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators |
| TW200407307A (en) * | 2001-11-26 | 2004-05-16 | Ciba Sc Holding Ag | Process for the synthesis of amine ethers from secondary amino oxides |
| ES2263957T3 (es) * | 2002-03-05 | 2006-12-16 | Ciba Specialty Chemicals Holding Inc. | Alcoxiaminas de cadena abierta y sus nitroxidos correspondientes para polimerizacion controlada por radicales a baja temperatura. |
| DE10212831A1 (de) * | 2002-03-22 | 2003-10-02 | Tesa Ag | Verfahren zur Herstellung copolymerer Polyacrylat-Haftklebemassen, damit erhaltene Nitroxid-modifizierte Polyacrylate und Kamm-Blockpolymere |
| KR100985091B1 (ko) * | 2002-05-01 | 2010-10-04 | 시바 홀딩 인코포레이티드 | Pvc 중합의 사슬 중단 방법 |
| EP1375457A1 (en) | 2002-06-25 | 2004-01-02 | Bayer Aktiengesellschaft | One-pot process for the preparation of functionalized alkoxyamines |
| EP1375476A1 (en) * | 2002-06-25 | 2004-01-02 | Bayer Aktiengesellschaft | A new process for the synthesis of alkoxyamines active in controlled radical polymerization |
| CA2514167A1 (en) * | 2003-02-10 | 2004-08-19 | Ciba Specialty Chemicals Holding Inc. | Comb copolymers with defined side chains and process for their manufacture |
| JP4107996B2 (ja) * | 2003-04-25 | 2008-06-25 | 大塚化学株式会社 | リビングラジカルポリマーの製造方法及びポリマー |
| JP4046678B2 (ja) * | 2003-10-15 | 2008-02-13 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ |
| EP1754762A4 (en) * | 2004-06-09 | 2009-07-22 | Hitachi Chemical Co Ltd | ADHESIVE COMPOSITION, CIRCUIT CONNECTING MATERIAL, CONNECTING CONSTRUCTION FOR CIRCUIT ELEMENT AND SEMICONDUCTOR DEVICE |
| WO2006074969A1 (en) * | 2005-01-11 | 2006-07-20 | Ciba Specialty Chemicals Holding Inc. | Process for the post-modification of homo and copolymers prepared by controlled free radical polymerization processes |
| JP4046734B2 (ja) | 2005-01-18 | 2008-02-13 | 横浜ゴム株式会社 | ポリマーの変性方法 |
| ATE482985T1 (de) * | 2005-04-04 | 2010-10-15 | Basf Se | Verfahren zur herstellung von stern- und blockcopolymeren über epoxidfunktionelle alkoxyamine |
| ATE465183T1 (de) * | 2005-08-30 | 2010-05-15 | Basf Se | Aus nitroxylradikalpolymerisation gewonnene polymere |
| EP2038704B9 (en) * | 2006-07-11 | 2019-03-27 | Basf Se | Color filter composition |
| US20080087380A1 (en) * | 2006-10-13 | 2008-04-17 | Dow Global Technologies Inc. | Reactively-coupled articles and related methods |
| EP2129363A2 (en) * | 2007-04-05 | 2009-12-09 | Basf Se | Sunscreen and personal care compositions comprising a select copolymer |
| WO2008145595A1 (en) * | 2007-06-01 | 2008-12-04 | Basf Se | Modified printable surfaces |
| WO2009077396A1 (en) * | 2007-12-18 | 2009-06-25 | Basf Se | Biodiesel cold flow improver |
| JP5631217B2 (ja) | 2008-01-17 | 2014-11-26 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | ポリマー染毛剤 |
| US9062209B2 (en) * | 2009-12-01 | 2015-06-23 | Silberline Manufacturing Company, Inc. | Polymer encapsulated aluminum particulates |
| KR101524342B1 (ko) | 2010-03-30 | 2015-07-06 | 바스프 에스이 | 말단-관능화 중합체 |
| RU2013103600A (ru) | 2010-06-29 | 2014-08-10 | Басф Се | Способ улучшения свойств текучести расплавов полимеров |
| US8912252B2 (en) | 2010-07-20 | 2014-12-16 | Silberline Manufacturing Company, Inc. | Film-forming pigments and coating system including the same |
| US8815982B2 (en) | 2010-07-20 | 2014-08-26 | Silberline Manufacturing Company, Inc. | Colored system |
| CN103025809B (zh) * | 2010-07-22 | 2016-01-20 | 巴斯夫欧洲公司 | 用于密封剂应用的添加剂混合物 |
| US20140298591A1 (en) | 2011-10-25 | 2014-10-09 | Basf Se | Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes |
| EP3778768A1 (en) | 2012-02-23 | 2021-02-17 | Basf Se | Fluorinated acrylate block copolymers with low dynamic surface tension |
| CN103073695B (zh) * | 2012-12-27 | 2015-03-11 | 中山大学 | 一种本征型室温自修复结晶性聚合物 |
| WO2014154508A1 (en) | 2013-03-27 | 2014-10-02 | Basf Se | Block copolymers as soil release agents in laundry processes |
| ES2761604T3 (es) | 2013-07-08 | 2020-05-20 | Basf Se | Estabilizadores frente a la luz |
| KR101595084B1 (ko) * | 2015-09-23 | 2016-02-29 | 주식회사 엘림산업 | 피혁용 버핑머신 |
| KR101595087B1 (ko) * | 2015-09-23 | 2016-02-18 | 주식회사 엘림산업 | 피혁용 버핑머신 구동롤러 |
| KR101635582B1 (ko) * | 2015-10-02 | 2016-07-20 | (주)이미인 | 원단 유연화 장치 |
| CN111278934B (zh) | 2017-10-23 | 2022-04-12 | 巴斯夫欧洲公司 | 硅氧烷聚合物水乳液 |
| WO2022112190A1 (en) | 2020-11-30 | 2022-06-02 | Basf Se | Process of producing polymer dispersions |
| CN117062872A (zh) | 2021-03-26 | 2023-11-14 | 巴斯夫欧洲公司 | 作为分散剂的包含聚丙烯酸系嵌段共聚物和芳族基聚氧化烯的聚合物组合物 |
| CN121913988A (zh) * | 2025-12-22 | 2026-04-24 | 广东润昌南星新材料有限公司 | 一种光催化合成自由基引发剂烷氧基胺的方法 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1173290A (en) * | 1966-08-24 | 1969-12-03 | Sankyo Co | Piperidine Nitroxides and process for preparing the same |
| JPS4940557B1 (enExample) * | 1969-03-06 | 1974-11-02 | ||
| US3975357A (en) | 1973-04-19 | 1976-08-17 | Sankyo Company Limited | Stabilized synthetic polymer compositions |
| JPS5848580B2 (ja) * | 1975-05-28 | 1983-10-29 | 三共株式会社 | ゴウセイコウブンシザイリヨウヨウアンテイザイ |
| GB1496844A (en) * | 1975-05-28 | 1978-01-05 | Ciba Geigy Ag | Stabilization of polymers |
| GB1493996A (en) * | 1975-05-28 | 1977-12-07 | Sankyo Co | 4-siloxy derivatives of polyalkylated piperidines |
| GB1478261A (en) * | 1975-05-28 | 1977-06-29 | Ciba Geigy Ag | Derivatives of 4-oxopiperidines |
| GB1492494A (en) * | 1975-05-28 | 1977-11-23 | Sankyo Co | Derivatives of 4-aminopiperidine |
| US4141883A (en) | 1975-05-28 | 1979-02-27 | Sankyo Company, Limited | Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives |
| DE3486145T2 (de) * | 1983-07-11 | 1993-09-23 | Commw Scient Ind Res Org | Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere. |
| AU571240B2 (en) * | 1983-07-11 | 1988-04-14 | Commonwealth Scientific And Industrial Research Organisation | Alkoxy-amines, useful as initiators |
| JPS6089452A (ja) * | 1983-07-11 | 1985-05-20 | コモンウエルス サイエンテイフイツク アンド インダストリアル リサ−チ オ−ガニゼ−シヨン | 遊離基重合開始用化合物 |
| EP0155912A3 (de) | 1984-03-20 | 1986-06-04 | Ciba-Geigy Ag | Strahlenstabilisierte polymere Zusammensetzungen |
| US5185448A (en) | 1991-05-07 | 1993-02-09 | Ciba-Geigy Corporation | Substituted 1-oxy-4-acyloxypiperidine and 1-oxy-4-acylaminopiperidine stabilizers |
| TW270131B (enExample) * | 1993-07-13 | 1996-02-11 | Ciba Geigy | |
| EP0638617A1 (de) | 1993-08-13 | 1995-02-15 | Ciba-Geigy Ag | Pigmentsalze |
| US5608023A (en) | 1995-03-30 | 1997-03-04 | Xerox Corporation | Rate enhanced polymerization processes |
| TW358820B (en) | 1995-04-11 | 1999-05-21 | Ciba Sc Holding Ag | Synergistic stabilizer mixture |
| EP0792911A3 (en) | 1996-02-27 | 1998-01-14 | Fmc Corporation | Flame resistant polyolefin compositions |
| DE69701517T2 (de) | 1996-03-29 | 2000-11-09 | The Dow Chemical Co., Midland | In situ blockcopolymerbildung während der polymerisation eines vinylaromatischen monomers |
| TW467931B (en) | 1996-08-22 | 2001-12-11 | Ciba Sc Holding Ag | Stabilizer mixtures |
| DE69708896T2 (de) | 1996-09-25 | 2002-06-20 | Akzo Nobel N.V., Arnheim/Arnhem | Nitroso verbindungen zur pseudo-lebenden radikalpolymerisation |
| KR100504055B1 (ko) | 1997-01-10 | 2005-07-27 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 중합체 분자량 및 구조의 조절 방법 |
| US6281311B1 (en) | 1997-03-31 | 2001-08-28 | Pmd Holdings Corp. | Controlled free radical polymerization process |
| JP2001510208A (ja) * | 1997-07-15 | 2001-07-31 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | ニトロソ化合物又はニトロン化合物から誘導されたアルコキシアミン化合物を含む重合可能な組成物 |
| SG74700A1 (en) | 1998-02-25 | 2000-08-22 | Ciba Sc Holding Ag | Preparation of sterically hindered amine ethers |
| TW495515B (en) * | 1998-03-09 | 2002-07-21 | Ciba Sc Holding Ag | 1-alkoxy-polyalkyl-piperidine derivatives, a polymerizable composition containing the same and a process for polymerization |
| CH693416A5 (de) * | 1998-03-09 | 2003-07-31 | Ciba Sc Holding Ag | 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler. |
| KR100575170B1 (ko) * | 1998-09-03 | 2006-04-28 | 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 | 에틸렌성 불포화 단량체의 중합체로의 그라프팅 |
| TW541303B (en) * | 2000-03-22 | 2003-07-11 | Ciba Sc Holding Ag | 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides |
-
1999
- 1999-03-02 CH CH00379/99A patent/CH693416A5/de not_active IP Right Cessation
- 1999-03-02 SG SG9901047A patent/SG82601A1/en unknown
- 1999-03-04 BE BE9900152A patent/BE1012399A3/fr not_active IP Right Cessation
- 1999-03-04 US US09/262,804 patent/US6353107B1/en not_active Expired - Lifetime
- 1999-03-05 CZ CZ99789A patent/CZ78999A3/cs unknown
- 1999-03-05 CA CA002264460A patent/CA2264460A1/en not_active Abandoned
- 1999-03-05 IT IT1999MI000453A patent/IT1309590B1/it active
- 1999-03-05 DE DE1999109767 patent/DE19909767B4/de not_active Expired - Lifetime
- 1999-03-08 GB GB9905152A patent/GB2335190B/en not_active Expired - Lifetime
- 1999-03-08 JP JP06019899A patent/JP4651137B2/ja not_active Expired - Lifetime
- 1999-03-08 AU AU18636/99A patent/AU754927B2/en not_active Ceased
- 1999-03-08 AT AT0038799A patent/AT408655B/de not_active IP Right Cessation
- 1999-03-08 CN CNB991020987A patent/CN1171871C/zh not_active Expired - Lifetime
- 1999-03-08 FR FR9902814A patent/FR2777892B1/fr not_active Expired - Lifetime
- 1999-03-08 ES ES009900470A patent/ES2155014B1/es not_active Expired - Fee Related
- 1999-03-09 NL NL1011493A patent/NL1011493C2/nl not_active IP Right Cessation
- 1999-03-09 BR BRPI9900977-3B1A patent/BR9900977B1/pt active IP Right Grant
- 1999-03-09 KR KR1019990007738A patent/KR100581654B1/ko not_active Expired - Lifetime
-
2001
- 2001-12-11 US US10/013,884 patent/US6683142B2/en not_active Expired - Lifetime
-
2003
- 2003-04-24 US US10/422,497 patent/US6927295B2/en not_active Expired - Lifetime
-
2005
- 2005-01-14 US US11/035,915 patent/US7402639B2/en not_active Expired - Fee Related
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