BR9900977B1 - Compostos e derivados de 1-alcóxi-polialquil-piperidina, composições polimerizáveis compreendendo os mesmos e processos de preparação de oligômeros, co-oligômeros, polímeros ou copolímeros (em bloco ou aleatórios) - Google Patents

Compostos e derivados de 1-alcóxi-polialquil-piperidina, composições polimerizáveis compreendendo os mesmos e processos de preparação de oligômeros, co-oligômeros, polímeros ou copolímeros (em bloco ou aleatórios)

Info

Publication number
BR9900977B1
BR9900977B1 BRPI9900977-3B1A BR9900977A BR9900977B1 BR 9900977 B1 BR9900977 B1 BR 9900977B1 BR 9900977 A BR9900977 A BR 9900977A BR 9900977 B1 BR9900977 B1 BR 9900977B1
Authority
BR
Brazil
Prior art keywords
oligomers
randoms
alcoxy
polyalkyl
copolymers
Prior art date
Application number
BRPI9900977-3B1A
Other languages
English (en)
Portuguese (pt)
Other versions
BR9900977A (pt
Inventor
Andreas Dr Kramer
Peter Dr Nesvadba
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of BR9900977A publication Critical patent/BR9900977A/pt
Publication of BR9900977B1 publication Critical patent/BR9900977B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/40—Oxygen atoms
    • C07D211/44—Oxygen atoms attached in position 4
    • C07D211/46—Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D211/72—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D211/74—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrogenated Pyridines (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Graft Or Block Polymers (AREA)
BRPI9900977-3B1A 1998-03-09 1999-03-09 Compostos e derivados de 1-alcóxi-polialquil-piperidina, composições polimerizáveis compreendendo os mesmos e processos de preparação de oligômeros, co-oligômeros, polímeros ou copolímeros (em bloco ou aleatórios) BR9900977B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP98810194 1998-03-09
EP98810531 1998-06-11

Publications (2)

Publication Number Publication Date
BR9900977A BR9900977A (pt) 2000-03-21
BR9900977B1 true BR9900977B1 (pt) 2013-10-29

Family

ID=26151881

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9900977-3B1A BR9900977B1 (pt) 1998-03-09 1999-03-09 Compostos e derivados de 1-alcóxi-polialquil-piperidina, composições polimerizáveis compreendendo os mesmos e processos de preparação de oligômeros, co-oligômeros, polímeros ou copolímeros (em bloco ou aleatórios)

Country Status (18)

Country Link
US (4) US6353107B1 (enExample)
JP (1) JP4651137B2 (enExample)
KR (1) KR100581654B1 (enExample)
CN (1) CN1171871C (enExample)
AT (1) AT408655B (enExample)
AU (1) AU754927B2 (enExample)
BE (1) BE1012399A3 (enExample)
BR (1) BR9900977B1 (enExample)
CA (1) CA2264460A1 (enExample)
CH (1) CH693416A5 (enExample)
CZ (1) CZ78999A3 (enExample)
DE (1) DE19909767B4 (enExample)
ES (1) ES2155014B1 (enExample)
FR (1) FR2777892B1 (enExample)
GB (1) GB2335190B (enExample)
IT (1) IT1309590B1 (enExample)
NL (1) NL1011493C2 (enExample)
SG (1) SG82601A1 (enExample)

Families Citing this family (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH693416A5 (de) * 1998-03-09 2003-07-31 Ciba Sc Holding Ag 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler.
JP2002522415A (ja) * 1998-07-31 2002-07-23 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 開鎖アルコキシアミンおよび重合調節剤としてのそれらの使用
JP5000038B2 (ja) 1998-10-06 2012-08-15 トタル ペトロケミカルス フランス 開始／制御剤の存在下でエチレンを高圧フリーラジカル重合または共重合する方法
TWI225483B (en) 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
EP1189875B1 (en) * 1999-07-02 2004-08-04 Ciba SC Holding AG Mono and multifunctional alkoxyamines for the preparation of functionalized macromers
TW546311B (en) * 1999-11-25 2003-08-11 Ciba Sc Holding Ag Composition and method for color improvement of nitroxyl containing polymers
TW541303B (en) * 2000-03-22 2003-07-11 Ciba Sc Holding Ag 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
EP1655303B1 (en) 2000-05-19 2011-02-23 Basf Se Process for the Controlled Increase in Molecular Weight of Polyethylene or Polyethylene Blends
TW572896B (en) * 2000-05-26 2004-01-21 Ciba Sc Holding Ag Process for the synthesis of amine ethers from secondary amino oxides
TWI225492B (en) * 2000-09-25 2004-12-21 Ciba Sc Holding Ag Composition and process for enhancing controlled free radical polymerization
TW574236B (en) * 2000-09-25 2004-02-01 Ciba Sc Holding Ag Process for controlled radical polymerization in aqueous dispersion
TWI236482B (en) * 2000-11-13 2005-07-21 Ciba Sc Holding Ag Process for the (co)polymerization of vinyl chloride in the presence of a stable free nitroxyl radical
TW557305B (en) * 2000-12-14 2003-10-11 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith
TWI274053B (en) * 2000-12-14 2007-02-21 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
US6849679B2 (en) * 2001-05-21 2005-02-01 Ciba Specialty Chemicals Corporation Pigment compositions with modified block copolymer dispersants
DE60238606D1 (de) * 2001-06-13 2011-01-27 Basf Se 4-imin-n-alkoxy- oder oxy-polyalkyl-piperidin-verboren
US7868171B2 (en) * 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
TW200407307A (en) * 2001-11-26 2004-05-16 Ciba Sc Holding Ag Process for the synthesis of amine ethers from secondary amino oxides
JP4602671B2 (ja) * 2002-03-05 2010-12-22 チバ ホールディング インコーポレーテッド 制御された低温ラジカル重合のための開鎖アルコキシアミン及びそれらの相当するニトロキシド。
DE10212831A1 (de) * 2002-03-22 2003-10-02 Tesa Ag Verfahren zur Herstellung copolymerer Polyacrylat-Haftklebemassen, damit erhaltene Nitroxid-modifizierte Polyacrylate und Kamm-Blockpolymere
WO2003093330A1 (en) * 2002-05-01 2003-11-13 Ciba Specialty Chemicals Holding Inc. Process for chain stopping of pvc polymerization
EP1375476A1 (en) * 2002-06-25 2004-01-02 Bayer Aktiengesellschaft A new process for the synthesis of alkoxyamines active in controlled radical polymerization
EP1375457A1 (en) 2002-06-25 2004-01-02 Bayer Aktiengesellschaft One-pot process for the preparation of functionalized alkoxyamines
EP1615962A2 (en) * 2003-02-10 2006-01-18 Ciba SC Holding AG Comb copolymers with defined side chains and process for their manufacture
JP4107996B2 (ja) * 2003-04-25 2008-06-25 大塚化学株式会社 リビングラジカルポリマーの製造方法及びポリマー
JP4046678B2 (ja) * 2003-10-15 2008-02-13 横浜ゴム株式会社 タイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ
KR20100009561A (ko) 2004-06-09 2010-01-27 히다치 가세고교 가부시끼가이샤 필름상 접착제, 필름상 회로접속재, 회로부재의 접속구조 및 반도체 장치
EP1861429B1 (en) * 2005-01-11 2013-03-13 Basf Se Process for the post-modification of homo and copolymers prepared by controlled free radical polymerization processes
JP4046734B2 (ja) 2005-01-18 2008-02-13 横浜ゴム株式会社 ポリマーの変性方法
US20090299013A1 (en) * 2005-04-04 2009-12-03 Jochen Fink Process for the Preparation of Star and Block-Copolymers Via Epoxy-Functionalized Alkoxyamines
EP1919962B1 (en) * 2005-08-30 2010-04-21 Basf Se Polymers obtained via nitroxyl radical polymerization
EP2038704B9 (en) * 2006-07-11 2019-03-27 Basf Se Color filter composition
US20080087380A1 (en) * 2006-10-13 2008-04-17 Dow Global Technologies Inc. Reactively-coupled articles and related methods
US20080247975A1 (en) * 2007-04-05 2008-10-09 Dueva-Koganov Olga V Sunscreen and personal care compositions comprising a select copolymer
WO2008145595A1 (en) * 2007-06-01 2008-12-04 Basf Se Modified printable surfaces
WO2009077396A1 (en) * 2007-12-18 2009-06-25 Basf Se Biodiesel cold flow improver
US8097045B2 (en) 2008-01-17 2012-01-17 Basf Se Polymeric hair dyes
WO2011068596A2 (en) 2009-12-01 2011-06-09 Silberline Manufacturing Company, Inc. Polymer encapsulated aluminum particulates
US10316114B2 (en) 2010-03-30 2019-06-11 Basf Se End-functionalized polymers
US9309391B2 (en) 2010-06-29 2016-04-12 Basf Se Process for improving the flow of properties of polymer melts
US8912252B2 (en) 2010-07-20 2014-12-16 Silberline Manufacturing Company, Inc. Film-forming pigments and coating system including the same
US8815982B2 (en) 2010-07-20 2014-08-26 Silberline Manufacturing Company, Inc. Colored system
JP5875584B2 (ja) * 2010-07-22 2016-03-02 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 封止剤用途のための組合せ添加剤
RU2014120925A (ru) 2011-10-25 2015-12-10 Басф Се Применение гребенчатых или блок-сополимеров в качестве средств против повторного осаждения загрязнения и грязеотталкивающих средств в процессах стирки
JP6242822B2 (ja) 2012-02-23 2017-12-06 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 低い動的表面張力を有するフッ素化されたアクリレートブロックコポリマー
CN103073695B (zh) * 2012-12-27 2015-03-11 中山大学 一种本征型室温自修复结晶性聚合物
US9790452B2 (en) 2013-03-27 2017-10-17 Basf Se Block copolymers as soil release agents in laundry processes
EP3019474B1 (en) 2013-07-08 2019-09-11 Basf Se Light stabilizers
KR101595084B1 (ko) * 2015-09-23 2016-02-29 주식회사 엘림산업 피혁용 버핑머신
KR101595087B1 (ko) * 2015-09-23 2016-02-18 주식회사 엘림산업 피혁용 버핑머신 구동롤러
KR101635582B1 (ko) * 2015-10-02 2016-07-20 (주)이미인 원단 유연화 장치
US11292906B2 (en) 2017-10-23 2022-04-05 Basf Se Aqueous silicone polymer emulsion
CN116490535A (zh) 2020-11-30 2023-07-25 巴斯夫欧洲公司 制备聚合物分散体的方法
US20240182746A1 (en) 2021-03-26 2024-06-06 Basf Se Polymer composition comprising polyacrylic block copolymer and aromatic based polyalkyleneoxide as dispersant

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3503982A (en) * 1966-08-24 1970-03-31 Sankyo Co 2,2-dimethyl-6,6 disubstituted-4-substituted aminopiperidine-1-oxides
JPS4940557B1 (enExample) * 1969-03-06 1974-11-02
US3975357A (en) 1973-04-19 1976-08-17 Sankyo Company Limited Stabilized synthetic polymer compositions
GB1493996A (en) * 1975-05-28 1977-12-07 Sankyo Co 4-siloxy derivatives of polyalkylated piperidines
US4141883A (en) 1975-05-28 1979-02-27 Sankyo Company, Limited Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives
GB1496844A (en) * 1975-05-28 1978-01-05 Ciba Geigy Ag Stabilization of polymers
GB1478261A (en) * 1975-05-28 1977-06-29 Ciba Geigy Ag Derivatives of 4-oxopiperidines
GB1492494A (en) * 1975-05-28 1977-11-23 Sankyo Co Derivatives of 4-aminopiperidine
JPS5848580B2 (ja) * 1975-05-28 1983-10-29 三共株式会社 ゴウセイコウブンシザイリヨウヨウアンテイザイ
AU571240B2 (en) * 1983-07-11 1988-04-14 Commonwealth Scientific And Industrial Research Organisation Alkoxy-amines, useful as initiators
JPS6089452A (ja) * 1983-07-11 1985-05-20 コモンウエルス　サイエンテイフイツク　アンド　インダストリアル　リサ−チ　オ−ガニゼ−シヨン 遊離基重合開始用化合物
US4581429A (en) * 1983-07-11 1986-04-08 Commonwealth Scientific And Industrial Research Organization Polymerization process and polymers produced thereby
EP0155912A3 (de) 1984-03-20 1986-06-04 Ciba-Geigy Ag Strahlenstabilisierte polymere Zusammensetzungen
US5185448A (en) 1991-05-07 1993-02-09 Ciba-Geigy Corporation Substituted 1-oxy-4-acyloxypiperidine and 1-oxy-4-acylaminopiperidine stabilizers
TW270131B (enExample) * 1993-07-13 1996-02-11 Ciba Geigy
EP0638617A1 (de) 1993-08-13 1995-02-15 Ciba-Geigy Ag Pigmentsalze
US5608023A (en) 1995-03-30 1997-03-04 Xerox Corporation Rate enhanced polymerization processes
TW358820B (en) 1995-04-11 1999-05-21 Ciba Sc Holding Ag Synergistic stabilizer mixture
EP0792911A3 (en) 1996-02-27 1998-01-14 Fmc Corporation Flame resistant polyolefin compositions
BR9708300A (pt) * 1996-03-29 1999-08-03 Dow Chemical Co Processo de polimerização em massa por radical livre
TW467931B (en) 1996-08-22 2001-12-11 Ciba Sc Holding Ag Stabilizer mixtures
AU4773997A (en) 1996-09-25 1998-04-17 Akzo Nobel N.V. No-compounds for pseudo-living radical polymerization
US6271340B1 (en) 1997-01-10 2001-08-07 E. I. Du Pont De Nemours And Company Method of controlling polymer molecular weight and structure
US6281311B1 (en) 1997-03-31 2001-08-28 Pmd Holdings Corp. Controlled free radical polymerization process
WO1999003894A1 (en) * 1997-07-15 1999-01-28 Ciba Specialty Chemicals Holding Inc. Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds
SG74700A1 (en) 1998-02-25 2000-08-22 Ciba Sc Holding Ag Preparation of sterically hindered amine ethers
TW495515B (en) * 1998-03-09 2002-07-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives, a polymerizable composition containing the same and a process for polymerization
CH693416A5 (de) * 1998-03-09 2003-07-31 Ciba Sc Holding Ag 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler.
CN1298755C (zh) * 1998-09-03 2007-02-07 西巴特殊化学品控股有限公司 烯属不饱和单体在聚合物上的接枝方法
TW541303B (en) * 2000-03-22 2003-07-11 Ciba Sc Holding Ag 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides

Also Published As

Publication number Publication date
BE1012399A3 (fr) 2000-10-03
JPH11322714A (ja) 1999-11-24
NL1011493C2 (nl) 1999-10-28
US20050131177A1 (en) 2005-06-16
DE19909767A1 (de) 1999-09-16
GB2335190A (en) 1999-09-15
FR2777892B1 (fr) 2000-12-29
ITMI990453A1 (it) 2000-09-05
CN1171871C (zh) 2004-10-20
GB9905152D0 (en) 1999-04-28
US6683142B2 (en) 2004-01-27
IT1309590B1 (it) 2002-01-24
CZ78999A3 (cs) 1999-09-15
CA2264460A1 (en) 1999-09-09
US20030220423A1 (en) 2003-11-27
CH693416A5 (de) 2003-07-31
AU1863699A (en) 1999-09-23
JP4651137B2 (ja) 2011-03-16
ATA38799A (de) 2001-06-15
NL1011493A1 (nl) 1999-09-10
AT408655B (de) 2002-02-25
US7402639B2 (en) 2008-07-22
AU754927B2 (en) 2002-11-28
ES2155014B1 (es) 2001-12-01
US6353107B1 (en) 2002-03-05
KR19990077710A (ko) 1999-10-25
US20020107397A1 (en) 2002-08-08
BR9900977A (pt) 2000-03-21
CN1228424A (zh) 1999-09-15
KR100581654B1 (ko) 2006-05-22
SG82601A1 (en) 2001-08-21
FR2777892A1 (fr) 1999-10-29
ES2155014A1 (es) 2001-04-16
US6927295B2 (en) 2005-08-09
DE19909767B4 (de) 2015-04-30
GB2335190B (en) 2000-05-31

Similar Documents

Publication Publication Date Title
BR9900977B1 (pt) Compostos e derivados de 1-alcóxi-polialquil-piperidina, composições polimerizáveis compreendendo os mesmos e processos de preparação de oligômeros, co-oligômeros, polímeros ou copolímeros (em bloco ou aleatórios)
FI980788A7 (fi) Olefiinipolymeroinnin katalysaattorikomponentti, sen valmistus ja käyttö
PT1062249E (pt) Catalisadores de polimerizacao
NO973244L (no) Fremgangsmåte for fremstilling av vannopplöselige polymerer, de oppnådde polymerer og deres anvendelse
ATE288926T1 (de) Polymerisationskatalysator
DE69941841D1 (de) Polymere anordnungen
ATE253087T1 (de) Olefinpolymerisation
DE69918684D1 (de) Polymerisationskatalysatoren
NO20021862D0 (no) Katalysatorsammensetninger, fremgangsmåter for polymerisasjon og polymerer derfra
ID27764A (id) Katalis-katalis polimerisasi
DE69805208D1 (de) Antimikrobielle hydrogel-bildende absorbierende polymere
NO993182D0 (no) 1,3-disubstituerte 6-aminouraciler for stabilisering av halogenerte polymerer
ID26028A (id) Komposisi penghambat polimerisasi, penghambat polimerisasi dan metode penghambatan polimerisasi
NO20013016D0 (no) Amfifiliske blokk-kopolymerer
FI961500L (fi) Kylmäsaumattavia koossapysyviä polymeereja
GB2340830B (en) Novel monomers for photoresist polymers thereof and photoresist compositions using the same
DE69718257D1 (de) Polymerisationsverfahren
ATE280787T1 (de) Olefinpolymerisation
DE69717737D1 (de) Polymerisationsverfahren
ID25818A (id) Senyawa-senyawa heterosiklik, produksinya dan penggunaannya
DE69925121D1 (de) Polymerisationsverfahren
ID26656A (id) Formulasi polimer manik
DE69905519D1 (de) Blockcopolymer und Zusammensetzung enthaltend das Blockcopolymer
NO20021252L (no) Fremgangsmåte for oppnåelse av vannopplöselige polymerer, de derved oppnådde polymerer samt deres anvendelse
ATE371677T1 (de) Isobuten polymerisationsverfahren

Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) 8O, 11, 24 E 25 DA LPI.

B12B Appeal against refusal [chapter 12.2 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 29/10/2013, OBSERVADAS AS CONDICOES LEGAIS.