HUE034818T2 - Katalizátor klór elõállítására és eljárás klór elõállítására a katalizátor alkalmazásával - Google Patents

Katalizátor klór elõállítására és eljárás klór elõállítására a katalizátor alkalmazásával Download PDF

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Publication number
HUE034818T2
HUE034818T2 HUE10756188A HUE10756188A HUE034818T2 HU E034818 T2 HUE034818 T2 HU E034818T2 HU E10756188 A HUE10756188 A HU E10756188A HU E10756188 A HUE10756188 A HU E10756188A HU E034818 T2 HUE034818 T2 HU E034818T2
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HU
Hungary
Prior art keywords
catalyst
chlorine
supported catalyst
hydrogen chloride
carrier
Prior art date
Application number
HUE10756188A
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English (en)
Inventor
Takashi Nabeta
Nobuhiko Horiuchi
Kenichi Sugimoto
Kenji Iwata
Masami Murakami
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Mitsui Chemicals Inc
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Publication date
Application filed by Mitsui Chemicals Inc filed Critical Mitsui Chemicals Inc
Publication of HUE034818T2 publication Critical patent/HUE034818T2/hu

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/01—Chlorine; Hydrogen chloride
    • C01B7/03—Preparation from chlorides
    • C01B7/04—Preparation of chlorine from hydrogen chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (2)

  1. Szabadalmi Igénypontok I. Klór előállítás? eljárás, előállító katalizátor jelenlétében oxidáltunk, ahol a klót-előáll í?ó katalizátor gömbalaké?. 0t9ö''i^s»^^iWí'ádagOá Alerid tás à részecskék alakjában van jelen, melyben egy rézesoportha tartozó elem (A), egy alkálifém elem p) és egy lantanoida elem (€}, mini aktív komponens van feümrdva egy porózus sziliciumdioaid hordozóra, ahol a lantanoida elem {€} egy vagy több, prazeodimium (Pr>, neodimium (Nd>, promeíiurn i PmVfStomárium (Sro>, eumpiuní (En|, gadolinium (Gd), teiMüm (Thp diszprőzium py), kolmipm (Ho). erbium (Er),iuliurn (Tat:) ahol aí katdizátörbanplenlíl^ő rézcsopörtfealmtozó féttegM - 4.5 iöméifl, a katálkátoEsmr jelenlévő álkllllfeá^atíSÍMt^H^sIge OJ. * :5<0iÄ#g%s. á Má* lizálorban jelenlévő lantanoida elem (C) mennyisége 0.3 ~ !0,i:tőmeg%f és a hordozó nyisége 98 -· 65 töraegH, a klór-elóálhtó katalizátor f 09 tőmegfs mennyiségére számítva. és ahol a katalizátor-részecskék huiditása olyan, hogy a bómérsékietlhlónhség kisebb, mint 62°C, az alábbi idrllmények te^l.^ghatárözvát ·· kvarchomokot helyezünk egy I ő nun belső átmérőjű reakeióosőbe, melyben egy 3 mm vastagságú, üreges részben e Ihel yezkedo üvegszürö van; «•21.5 ml katalizátort töltünk a reakciöcsoben elhelyezkedő üvegszüróre; - 90.0 Nml/pere illetve 45.0 Nmi/perc mennyiségben sósavat Illetve oxigént táplálnak be a .reakcióeső aljáról; - ami g a gáz futidizálja a katalizátort, a reakciót atmoszférikus nyomáson és 3ő0f"C reakció-honférseldeien iartj?.?k; - és mérj ük a hőmérséklet-különbséget a katalizátor réteg alsó oldala és az üvegszörö felett! 40 mm-es magasság, azaz. az űvegszürövel érintkező rész és 40 mm-el az üvegszürö feletti rész között, Ά Az 1 > igénypont szerinti klór eidáliitási eljárás, almi a katalizátorban levő rézcsoportba tartozó elem (A) és az alkálifém elem (8; tömegaránya 1:0.2 és I ;4.0 közötti tartományban vtio, if§ s::^^|?z||^baE.lëv^.rêif.csoporiba tartu/o etem {&amp;} és &amp; ImiMomda nest IC} tömegaránya f ;Θ.2 és Wte % fe l. igénypont sœü» éli»« «|Ä#i t káMÜssálMban levő rézcsoponfea tar-tűm dem (Λ) és a? sikálj fém elem CB} témegaráPpitÖd és M.ÖMsötü imumà^bm m tSäkmMmm^&amp;n levő re/o «ο poriba taromé dem (A) és a lantanoida elem (C) tömegaránya ílvlil és 1;3.0 kdrotü tartományban van, 4. A ? í~3. igénypontok bárnvdske s?ejen dm tK\Uj\b" eh uh^ alios a kaueAUorK„m Se^ó iántásbMa elem (C) az apra/oodimiunp sieodimiítmg ssmnánum éá éJ»p». ÄÖl'?ilei0ti: dérnek legalább egyike.
  2. 5. Az idd. igénypontok bármelyike szerinti klór éfôSIÎÂl éljltëàt, Â>î a kátóiiéiebál. lÄl alkálifém elem , 3} a unnám es \ak η \ o és ol ta< ,o,i dánok ,ugaiahh „v s i - e
HUE10756188A 2009-03-26 2010-03-25 Katalizátor klór elõállítására és eljárás klór elõállítására a katalizátor alkalmazásával HUE034818T2 (hu)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2009076920 2009-03-26
JP2009076923 2009-03-26
JP2009076921 2009-03-26

Publications (1)

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HUE034818T2 true HUE034818T2 (hu) 2018-02-28

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HUE10756188A HUE034818T2 (hu) 2009-03-26 2010-03-25 Katalizátor klór elõállítására és eljárás klór elõállítására a katalizátor alkalmazásával

Country Status (8)

Country Link
US (1) US9108845B2 (hu)
EP (1) EP2418016B1 (hu)
JP (1) JP5468065B2 (hu)
KR (1) KR101287296B1 (hu)
CN (1) CN102341173B (hu)
BR (1) BRPI1009832A2 (hu)
HU (1) HUE034818T2 (hu)
WO (1) WO2010110392A1 (hu)

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CN102000583B (zh) * 2010-11-18 2012-08-15 烟台万华聚氨酯股份有限公司 一种氯化氢氧化制氯气的催化剂及其制备方法
CN105642318B (zh) * 2014-11-11 2018-08-21 上海氯碱化工股份有限公司 氯化氢催化氧化制氯气的催化剂制法及应用
US10322683B2 (en) * 2016-10-11 2019-06-18 Todd David Lawrence Motorized vehicle with a tool holding apparatus
EP3549907A4 (en) * 2016-12-02 2020-08-19 Mitsui Chemicals, Inc. PROCESS FOR THE PRODUCTION OF CHLORINE BY OXIDIZING HYDROGEN CHLORIDE
CN110961096B (zh) * 2018-09-30 2022-09-27 中国石油化工股份有限公司 一种费托合成催化剂及其制备方法和应用
CN111252737A (zh) * 2020-01-19 2020-06-09 无锡玖汇科技有限公司 一种用于盐酸原位制氯气的固体反应物
WO2021239944A1 (en) 2020-05-29 2021-12-02 Basf Se Catalyst for hydrogen chloride oxidation and production thereof

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Publication number Publication date
US20120009117A1 (en) 2012-01-12
JPWO2010110392A1 (ja) 2012-10-04
WO2010110392A1 (ja) 2010-09-30
EP2418016A1 (en) 2012-02-15
KR101287296B1 (ko) 2013-07-17
KR20110116241A (ko) 2011-10-25
CN102341173A (zh) 2012-02-01
US9108845B2 (en) 2015-08-18
JP5468065B2 (ja) 2014-04-09
EP2418016A4 (en) 2013-01-30
BRPI1009832A2 (pt) 2019-09-24
CN102341173B (zh) 2014-05-21
EP2418016B1 (en) 2017-05-24

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