HRP20191628T1 - Mješavina polimera - Google Patents

Mješavina polimera Download PDF

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Publication number
HRP20191628T1
HRP20191628T1 HRP20191628T HRP20191628T1 HR P20191628 T1 HRP20191628 T1 HR P20191628T1 HR P20191628 T HRP20191628 T HR P20191628T HR P20191628 T1 HRP20191628 T1 HR P20191628T1
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HR
Croatia
Prior art keywords
film
aliphatic polycarbonate
polyolefin
weight
percent
Prior art date
Application number
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English (en)
Inventor
Scott D Allen
Sanjeev Naik
Original Assignee
Novomer Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Novomer Inc filed Critical Novomer Inc
Publication of HRP20191628T1 publication Critical patent/HRP20191628T1/hr

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001—Combinations of extrusion moulding with other shaping operations
    • B29C48/0018—Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/02—Aliphatic polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31507—Of polycarbonate

Claims (16)

1. Ekstrudirana polimerna mješavina koja sadržava barem jedan alifatski polikarbonat i barem jedan poliolefin, naznačena time, da ekstrudirana polimerna smjesa sadržava više alifatskog polikarbonata od poliolefina.
2. Ekstrudirana polimerna mješavina u skladu s patentnim zahtjevom 1, naznačena time, da alifatski polikarbonat sadržava kopolimer ugljičnog dioksida i jedan ili više epoksida.
3. Ekstrudirana polimerna mješavina u skladu s patentnim zahtjevom 1, naznačena time, da (a) poliolefin je odabran iz: i. skupine koja se sastoji od: polietilena, polipropilena, polistirena, poli(alfa olefina), polivinilklorida i smjese ili kopolimera bilo kojeg od dva ili članova skupine, ili (ii) skupine koja se sastoji od LDPE, LLDPE, HDPE, polipropilena ili bilo koje kombinacije od gore navedenih; ili pri čemu (b) poliolefin sadržava polietilen ili polipropilen.
4. Ekstrudirana polimerna mješavina u skladu s patentnim zahtjevom 1, naznačena time, da sadržava (a) poli(propilen karbonat) ili (b) poli(etilen karbonat) ili (c) dodatno sadržava barem jedan kompatibilizator.
5. Plastični film, naznačen time, da sadržava ekstrudiranu polimernu mješavinu u skladu s bilo kojim od patentnih zahtjeva 1 do 4.
6. Plastični artikl za injektiranje, naznačen time, da sadržava ekstrudiranu polimernu mješavinu u skladu s bilo kojim od patentnih zahtjeva 1 do 4.
7. Plastični film u skladu s patentnim zahtjevom 5, koji sadržava barem 70 % težinskih udjela alifatskog polikarbonata, naznačen time, da film ima produljenje prije vrijednosti loma, izmjereno u skladu s ASTM D882, barem 100 %.
8. Plastični film u skladu s patentnim zahtjevom 7, naznačen time, da (a) alifatski polikarbonat sadržava jedan ili više poli(propilenkarbonata) i poli(etilenkarbonata), poželjno je da alifatski polikarbonat sadržava poli(propilenkarbonat) ili (b) plastični film nadalje sadržava jedan ili više polukristalnih polimera.
9. Plastični film u skladu s patentnim zahtjevom 7, naznačen time, da taj film sadržava najmanje 80, ili najmanje 85, ili najmanje 90, ili najmanje 95 težinskih postotaka alifatskog polikarbonata.
10. Plastični film u skladu s patentnim zahtjevom 7, naznačen time, da nadalje sadržava jedan ili više poliolefinskih polimera, poželjno je od oko 0,5 do oko 30 postotnih težinskih udjela jednog ili više poliolefinskih polimera ili od oko 1 do oko 25 postotnih težinskih udjela jednog ili više poliolefinskih polimera ili od oko 1 do oko 10 postotnih težinskih udjela jednog ili više poliolefinskih polimera ili od oko 2 do oko 8 postotnih težinskih udjela jednog ili više poliolefinskih polimera ili oko 5 postotnih težinskih udjela jednog ili više poliolefinskih polimera.
11. Plastični film u skladu s patentnim zahtjevom 10, naznačen time, da poliolefinski polimer sadržava jedan ili više sljedećih tvari: polietilen, polipropilen i polietilen-ko-propilen, poželjno je (a) da sadržava polietilen, poželjnije je polietilen LDPE; ili (b) da sadržava polipropilen.
12. Plastični film u skladu s patentnim zahtjevom 7, naznačen time, da (a) dodatno sadržava jedan ili više kompatibilizatora; ili (b) film je istegnut, poželjno je i. film je istegnut dvoosno, ili ii. vrijednost elongacije filma pri prekidu, izmjereno u skladu s postupkom ASTM D882, manja je od 50 % u odnosu na stanje filma prije rastezanja; ili (c) film je proizveden postupkom puhanja filma.
13. Postupak za proizvodnju plastičnog filma u skladu s patentnim zahtjevom 7, naznačen time, da sadržava korake: (a) upotreba alifatskog polikarbonata, naznačenog time, da kada se alifatski polikarbonat preradi u film, film ima svojstvenu vrijednost elongacije pri prekidu, izmjereno u skladu s postupkom ASTM D882, manju od 50 %; (b) miješanje do oko 30 postotnih težinskih udjela polukristalnog polimera radi dobivanja smjese koja sadržava najmanje 70 postotnih težinskih udjela alifatskog polikarbonata; (c) dobivanje filma iz smjese iz koraka (b); i (d) istezanje filma iz koraka (c) da se dobije film koji ima vrijednost elongacije pri prekidu, izmjereno u skladu s postupkom ASTM D882, koja je veća od 100 %.
14. Postupak u skladu s patentnim zahtjevom 13, naznačen time, da (a) koraci (c) i (d) izvode se istovremeno korištenjem postupka puhanog filma za proizvodnju filma ili pri čemu (b) korak formiranja filma sadržava ekstrudiranje filma ili pri čemu (c) korak istezanja filma obuhvaća jednoosno ili dvoosno istezanje filma.
15. Postupak u skladu s patentnim zahtjevima 13 ili 14, naznačen time, da alifatski polikarbonat sadržava poli(propilen karbonat).
16. Postupak u skladu s patentnim zahtjevom 15, naznačen time, da je (a) polukristalni polimer pomiješan u koraku (b) sadržava poliolefin, pri čemu je poželjno da poliolefin sadržava LDPE; ili (b) korak (b) obuhvaća miješanje od oko 1 % do oko 10 % polukristalnog polimera; ili (c) omjer vrijednosti elongacije pri kidanju filma izrađenog samo iz alifatskog polikarbonata navedenog u koraku (a) i vrijednosti elongacije pri kidanju konačnog filma iz koraka (d) veća je od 2, poželjno je veća od 3, poželjnije veća od 5, najpoželjnije veća od 10.
HRP20191628 2010-10-11 2019-09-11 Mješavina polimera HRP20191628T1 (hr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US39201010P 2010-10-11 2010-10-11
US201161535573P 2011-09-16 2011-09-16
EP11833280.8A EP2627713B1 (en) 2010-10-11 2011-10-11 Polymer blends
PCT/US2011/055846 WO2012051219A2 (en) 2010-10-11 2011-10-11 Polymer blends

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HRP20191628T1 true HRP20191628T1 (hr) 2019-12-13

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US (1) US9738784B2 (hr)
EP (1) EP2627713B1 (hr)
JP (2) JP6376755B2 (hr)
KR (1) KR20130121106A (hr)
CN (1) CN103261269A (hr)
BR (1) BR112013008836A2 (hr)
CY (1) CY1122016T1 (hr)
DK (1) DK2627713T3 (hr)
ES (1) ES2746204T3 (hr)
HR (1) HRP20191628T1 (hr)
HU (1) HUE046261T2 (hr)
LT (1) LT2627713T (hr)
PT (1) PT2627713T (hr)
SI (1) SI2627713T1 (hr)
WO (1) WO2012051219A2 (hr)

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US9738784B2 (en) 2017-08-22
JP2013542290A (ja) 2013-11-21
JP2017057422A (ja) 2017-03-23
SI2627713T1 (sl) 2019-11-29
KR20130121106A (ko) 2013-11-05
BR112013008836A2 (pt) 2016-06-21
ES2746204T3 (es) 2020-03-05
LT2627713T (lt) 2019-10-25
CY1122016T1 (el) 2020-10-14
HUE046261T2 (hu) 2020-02-28
JP6376755B2 (ja) 2018-08-22
DK2627713T3 (da) 2019-10-07
WO2012051219A3 (en) 2012-06-21
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US20130209775A1 (en) 2013-08-15

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