HRP20140464T1 - Smjese mezoionskih pesticida - Google Patents
Smjese mezoionskih pesticida Download PDFInfo
- Publication number
- HRP20140464T1 HRP20140464T1 HRP20140464AT HRP20140464T HRP20140464T1 HR P20140464 T1 HRP20140464 T1 HR P20140464T1 HR P20140464A T HRP20140464A T HR P20140464AT HR P20140464 T HRP20140464 T HR P20140464T HR P20140464 T1 HRP20140464 T1 HR P20140464T1
- Authority
- HR
- Croatia
- Prior art keywords
- methyl
- oxo
- hydroxy
- pyrido
- chloro
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims 16
- 239000000575 pesticide Substances 0.000 title 1
- -1 C 1 -C 4 alkoxy Chemical group 0.000 claims 81
- 150000003839 salts Chemical class 0.000 claims 61
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 50
- CZPWVGJYEJSRLH-UHFFFAOYSA-O hydron;pyrimidine Chemical compound C1=CN=C[NH+]=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-O 0.000 claims 19
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 19
- 150000001875 compounds Chemical class 0.000 claims 12
- 125000001424 substituent group Chemical group 0.000 claims 12
- 229910052736 halogen Inorganic materials 0.000 claims 8
- 150000002367 halogens Chemical group 0.000 claims 8
- 125000004076 pyridyl group Chemical group 0.000 claims 8
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims 6
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Aalpha Natural products C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 claims 6
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 5
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 claims 4
- WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 claims 4
- 125000004198 2-fluorophenyl group Chemical group [H]C1=C([H])C(F)=C(*)C([H])=C1[H] 0.000 claims 4
- 239000005660 Abamectin Substances 0.000 claims 4
- 241000193388 Bacillus thuringiensis Species 0.000 claims 4
- 229940097012 bacillus thuringiensis Drugs 0.000 claims 4
- 239000003795 chemical substances by application Substances 0.000 claims 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims 4
- 125000000714 pyrimidinyl group Chemical group 0.000 claims 3
- 125000000335 thiazolyl group Chemical group 0.000 claims 3
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims 2
- ZXQYGBMAQZUVMI-RDDWSQKMSA-N (1S)-cis-(alphaR)-cyhalothrin Chemical compound CC1(C)[C@H](\C=C(/Cl)C(F)(F)F)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-RDDWSQKMSA-N 0.000 claims 2
- LZTIMERBDGGAJD-SNAWJCMRSA-N (2e)-2-(nitromethylidene)-1,3-thiazinane Chemical compound [O-][N+](=O)\C=C1/NCCCS1 LZTIMERBDGGAJD-SNAWJCMRSA-N 0.000 claims 2
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims 2
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 claims 2
- PGOOBECODWQEAB-UHFFFAOYSA-N (E)-clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 claims 2
- CFRPSFYHXJZSBI-DHZHZOJOSA-N (E)-nitenpyram Chemical compound [O-][N+](=O)/C=C(\NC)N(CC)CC1=CC=C(Cl)N=C1 CFRPSFYHXJZSBI-DHZHZOJOSA-N 0.000 claims 2
- IQVNEKKDSLOHHK-FNCQTZNRSA-N (E,E)-hydramethylnon Chemical compound N1CC(C)(C)CNC1=NN=C(/C=C/C=1C=CC(=CC=1)C(F)(F)F)\C=C\C1=CC=C(C(F)(F)F)C=C1 IQVNEKKDSLOHHK-FNCQTZNRSA-N 0.000 claims 2
- HOKKPVIRMVDYPB-UVTDQMKNSA-N (Z)-thiacloprid Chemical compound C1=NC(Cl)=CC=C1CN1C(=N/C#N)/SCC1 HOKKPVIRMVDYPB-UVTDQMKNSA-N 0.000 claims 2
- CKPCAYZTYMHQEX-NBVRZTHBSA-N (e)-1-(2,4-dichlorophenyl)-n-methoxy-2-pyridin-3-ylethanimine Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=N/OC)/CC1=CC=CN=C1 CKPCAYZTYMHQEX-NBVRZTHBSA-N 0.000 claims 2
- NFGXHKASABOEEW-UHFFFAOYSA-N 1-methylethyl 11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate Chemical compound COC(C)(C)CCCC(C)CC=CC(C)=CC(=O)OC(C)C NFGXHKASABOEEW-UHFFFAOYSA-N 0.000 claims 2
- LHZOTJOOBRODLL-UHFFFAOYSA-O 4-oxo-1-(pyrimidin-5-ylmethyl)-3-[3-(trifluoromethyl)phenyl]-5h-pyrido[1,2-a]pyrimidine-1,5-diium-2-olate Chemical compound O=C1N2C=CC=CC2=[N+](CC=2C=NC=NC=2)C(O)=C1C1=CC=CC(C(F)(F)F)=C1 LHZOTJOOBRODLL-UHFFFAOYSA-O 0.000 claims 2
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 claims 2
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 claims 2
- 239000005875 Acetamiprid Substances 0.000 claims 2
- 239000005877 Alpha-Cypermethrin Substances 0.000 claims 2
- 239000005878 Azadirachtin Substances 0.000 claims 2
- 108700003918 Bacillus Thuringiensis insecticidal crystal Proteins 0.000 claims 2
- 239000005884 Beta-Cyfluthrin Substances 0.000 claims 2
- 239000005874 Bifenthrin Substances 0.000 claims 2
- 239000005740 Boscalid Substances 0.000 claims 2
- 239000005885 Buprofezin Substances 0.000 claims 2
- JFLRKDZMHNBDQS-UCQUSYKYSA-N CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C Chemical compound CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C JFLRKDZMHNBDQS-UCQUSYKYSA-N 0.000 claims 2
- 239000005886 Chlorantraniliprole Substances 0.000 claims 2
- 239000005944 Chlorpyrifos Substances 0.000 claims 2
- 239000005888 Clothianidin Substances 0.000 claims 2
- 239000005889 Cyantraniliprole Substances 0.000 claims 2
- 239000005946 Cypermethrin Substances 0.000 claims 2
- 239000005891 Cyromazine Substances 0.000 claims 2
- 239000005892 Deltamethrin Substances 0.000 claims 2
- 239000005894 Emamectin Substances 0.000 claims 2
- 239000005895 Esfenvalerate Substances 0.000 claims 2
- FNELVJVBIYMIMC-UHFFFAOYSA-N Ethiprole Chemical compound N1=C(C#N)C(S(=O)CC)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl FNELVJVBIYMIMC-UHFFFAOYSA-N 0.000 claims 2
- HMIBKHHNXANVHR-UHFFFAOYSA-N Fenothiocarb Chemical compound CN(C)C(=O)SCCCCOC1=CC=CC=C1 HMIBKHHNXANVHR-UHFFFAOYSA-N 0.000 claims 2
- 239000005899 Fipronil Substances 0.000 claims 2
- 239000005901 Flubendiamide Substances 0.000 claims 2
- 239000005903 Gamma-cyhalothrin Substances 0.000 claims 2
- 239000005906 Imidacloprid Substances 0.000 claims 2
- 239000005907 Indoxacarb Substances 0.000 claims 2
- 239000005912 Lufenuron Substances 0.000 claims 2
- 239000005914 Metaflumizone Substances 0.000 claims 2
- MIFOMMKAVSCNKQ-HWIUFGAZSA-N Metaflumizone Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)N\N=C(C=1C=C(C=CC=1)C(F)(F)F)\CC1=CC=C(C#N)C=C1 MIFOMMKAVSCNKQ-HWIUFGAZSA-N 0.000 claims 2
- 239000005916 Methomyl Substances 0.000 claims 2
- 239000005917 Methoxyfenozide Substances 0.000 claims 2
- 150000001204 N-oxides Chemical class 0.000 claims 2
- 239000005950 Oxamyl Substances 0.000 claims 2
- 239000005925 Pymetrozine Substances 0.000 claims 2
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 claims 2
- 239000005663 Pyridaben Substances 0.000 claims 2
- 239000005926 Pyridalyl Substances 0.000 claims 2
- 239000005927 Pyriproxyfen Substances 0.000 claims 2
- 229930001406 Ryanodine Natural products 0.000 claims 2
- 239000005929 Spinetoram Substances 0.000 claims 2
- GOENIMGKWNZVDA-OAMCMWGQSA-N Spinetoram Chemical compound CO[C@@H]1[C@H](OCC)[C@@H](OC)[C@H](C)O[C@H]1OC1C[C@H]2[C@@H]3C=C4C(=O)[C@H](C)[C@@H](O[C@@H]5O[C@H](C)[C@H](CC5)N(C)C)CCC[C@H](CC)OC(=O)CC4[C@@H]3CC[C@@H]2C1 GOENIMGKWNZVDA-OAMCMWGQSA-N 0.000 claims 2
- 239000005930 Spinosad Substances 0.000 claims 2
- 239000005664 Spirodiclofen Substances 0.000 claims 2
- 239000005665 Spiromesifen Substances 0.000 claims 2
- 239000005931 Spirotetramat Substances 0.000 claims 2
- 239000005937 Tebufenozide Substances 0.000 claims 2
- 239000005940 Thiacloprid Substances 0.000 claims 2
- 239000005941 Thiamethoxam Substances 0.000 claims 2
- 239000005942 Triflumuron Substances 0.000 claims 2
- 241000700605 Viruses Species 0.000 claims 2
- QQODLKZGRKWIFG-RUTXASTPSA-N [(R)-cyano-(4-fluoro-3-phenoxyphenyl)methyl] (1S)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(Cl)Cl)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-RUTXASTPSA-N 0.000 claims 2
- KAATUXNTWXVJKI-QPIRBTGLSA-N [(s)-cyano-(3-phenoxyphenyl)methyl] 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-QPIRBTGLSA-N 0.000 claims 2
- 229950008167 abamectin Drugs 0.000 claims 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims 2
- 229960002587 amitraz Drugs 0.000 claims 2
- QXAITBQSYVNQDR-ZIOPAAQOSA-N amitraz Chemical compound C=1C=C(C)C=C(C)C=1/N=C/N(C)\C=N\C1=CC=C(C)C=C1C QXAITBQSYVNQDR-ZIOPAAQOSA-N 0.000 claims 2
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims 2
- VEHPJKVTJQSSKL-UHFFFAOYSA-N azadirachtin Natural products O1C2(C)C(C3(C=COC3O3)O)CC3C21C1(C)C(O)C(OCC2(OC(C)=O)C(CC3OC(=O)C(C)=CC)OC(C)=O)C2C32COC(C(=O)OC)(O)C12 VEHPJKVTJQSSKL-UHFFFAOYSA-N 0.000 claims 2
- FTNJWQUOZFUQQJ-IRYYUVNJSA-N azadirachtin A Natural products C([C@@H]([C@]1(C=CO[C@H]1O1)O)[C@]2(C)O3)[C@H]1[C@]23[C@]1(C)[C@H](O)[C@H](OC[C@@]2([C@@H](C[C@@H]3OC(=O)C(\C)=C/C)OC(C)=O)C(=O)OC)[C@@H]2[C@]32CO[C@@](C(=O)OC)(O)[C@@H]12 FTNJWQUOZFUQQJ-IRYYUVNJSA-N 0.000 claims 2
- FTNJWQUOZFUQQJ-NDAWSKJSSA-N azadirachtin A Chemical compound C([C@@H]([C@]1(C=CO[C@H]1O1)O)[C@]2(C)O3)[C@H]1[C@]23[C@]1(C)[C@H](O)[C@H](OC[C@@]2([C@@H](C[C@@H]3OC(=O)C(\C)=C\C)OC(C)=O)C(=O)OC)[C@@H]2[C@]32CO[C@@](C(=O)OC)(O)[C@@H]12 FTNJWQUOZFUQQJ-NDAWSKJSSA-N 0.000 claims 2
- YFXPPSKYMBTNAV-UHFFFAOYSA-N bensultap Chemical compound C=1C=CC=CC=1S(=O)(=O)SCC(N(C)C)CSS(=O)(=O)C1=CC=CC=C1 YFXPPSKYMBTNAV-UHFFFAOYSA-N 0.000 claims 2
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 claims 2
- WYEMLYFITZORAB-UHFFFAOYSA-N boscalid Chemical compound C1=CC(Cl)=CC=C1C1=CC=CC=C1NC(=O)C1=CC=CN=C1Cl WYEMLYFITZORAB-UHFFFAOYSA-N 0.000 claims 2
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 claims 2
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 claims 2
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 claims 2
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 claims 2
- DVBUIBGJRQBEDP-UHFFFAOYSA-N cyantraniliprole Chemical compound CNC(=O)C1=CC(C#N)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl DVBUIBGJRQBEDP-UHFFFAOYSA-N 0.000 claims 2
- 229960001591 cyfluthrin Drugs 0.000 claims 2
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 claims 2
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 claims 2
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims 2
- 229960005424 cypermethrin Drugs 0.000 claims 2
- LVQDKIWDGQRHTE-UHFFFAOYSA-N cyromazine Chemical compound NC1=NC(N)=NC(NC2CC2)=N1 LVQDKIWDGQRHTE-UHFFFAOYSA-N 0.000 claims 2
- 229950000775 cyromazine Drugs 0.000 claims 2
- 229960002483 decamethrin Drugs 0.000 claims 2
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims 2
- 229950006824 dieldrin Drugs 0.000 claims 2
- DFBKLUNHFCTMDC-PICURKEMSA-N dieldrin Chemical compound C([C@H]1[C@H]2[C@@]3(Cl)C(Cl)=C([C@]([C@H]22)(Cl)C3(Cl)Cl)Cl)[C@H]2[C@@H]2[C@H]1O2 DFBKLUNHFCTMDC-PICURKEMSA-N 0.000 claims 2
- NGPMUTDCEIKKFM-UHFFFAOYSA-N dieldrin Natural products CC1=C(Cl)C2(Cl)C3C4CC(C5OC45)C3C1(Cl)C2(Cl)Cl NGPMUTDCEIKKFM-UHFFFAOYSA-N 0.000 claims 2
- 239000003085 diluting agent Substances 0.000 claims 2
- FBOUIAKEJMZPQG-BLXFFLACSA-N diniconazole-M Chemical compound C1=NC=NN1/C([C@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1Cl FBOUIAKEJMZPQG-BLXFFLACSA-N 0.000 claims 2
- YKBZOVFACRVRJN-UHFFFAOYSA-N dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 claims 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 2
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 claims 2
- RDYMFSUJUZBWLH-SVWSLYAFSA-N endosulfan Chemical compound C([C@@H]12)OS(=O)OC[C@@H]1[C@]1(Cl)C(Cl)=C(Cl)[C@@]2(Cl)C1(Cl)Cl RDYMFSUJUZBWLH-SVWSLYAFSA-N 0.000 claims 2
- NYPJDWWKZLNGGM-RPWUZVMVSA-N esfenvalerate Chemical compound C=1C([C@@H](C#N)OC(=O)[C@@H](C(C)C)C=2C=CC(Cl)=CC=2)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-RPWUZVMVSA-N 0.000 claims 2
- HJUFTIJOISQSKQ-UHFFFAOYSA-N fenoxycarb Chemical compound C1=CC(OCCNC(=O)OCC)=CC=C1OC1=CC=CC=C1 HJUFTIJOISQSKQ-UHFFFAOYSA-N 0.000 claims 2
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- XRJLAOUDSILTFT-UHFFFAOYSA-N pyroquilon Chemical compound O=C1CCC2=CC=CC3=C2N1CC3 XRJLAOUDSILTFT-UHFFFAOYSA-N 0.000 claims 1
- 229960002132 pyrrolnitrin Drugs 0.000 claims 1
- MXMXHPPIGKYTAR-UHFFFAOYSA-N silthiofam Chemical compound CC=1SC([Si](C)(C)C)=C(C(=O)NCC=C)C=1C MXMXHPPIGKYTAR-UHFFFAOYSA-N 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- PUYXTUJWRLOUCW-UHFFFAOYSA-N spiroxamine Chemical compound O1C(CN(CC)CCC)COC11CCC(C(C)(C)C)CC1 PUYXTUJWRLOUCW-UHFFFAOYSA-N 0.000 claims 1
- 229960005322 streptomycin Drugs 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- ROZUQUDEWZIBHV-UHFFFAOYSA-N tecloftalam Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(=O)NC1=CC=CC(Cl)=C1Cl ROZUQUDEWZIBHV-UHFFFAOYSA-N 0.000 claims 1
- XQTLDIFVVHJORV-UHFFFAOYSA-N tecnazene Chemical compound [O-][N+](=O)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl XQTLDIFVVHJORV-UHFFFAOYSA-N 0.000 claims 1
- LITQZINTSYBKIU-UHFFFAOYSA-F tetracopper;hexahydroxide;sulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]S([O-])(=O)=O LITQZINTSYBKIU-UHFFFAOYSA-F 0.000 claims 1
- 238000002560 therapeutic procedure Methods 0.000 claims 1
- 239000004308 thiabendazole Substances 0.000 claims 1
- 229960004546 thiabendazole Drugs 0.000 claims 1
- 235000010296 thiabendazole Nutrition 0.000 claims 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 claims 1
- YFNCATAIYKQPOO-UHFFFAOYSA-N thiophanate Chemical compound CCOC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OCC YFNCATAIYKQPOO-UHFFFAOYSA-N 0.000 claims 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical group COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 claims 1
- 229960002447 thiram Drugs 0.000 claims 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims 1
- VJQYLJSMBWXGDV-UHFFFAOYSA-N tiadinil Chemical compound N1=NSC(C(=O)NC=2C=C(Cl)C(C)=CC=2)=C1C VJQYLJSMBWXGDV-UHFFFAOYSA-N 0.000 claims 1
- OBZIQQJJIKNWNO-UHFFFAOYSA-N tolclofos-methyl Chemical compound COP(=S)(OC)OC1=C(Cl)C=C(C)C=C1Cl OBZIQQJJIKNWNO-UHFFFAOYSA-N 0.000 claims 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 claims 1
- IQGKIPDJXCAMSM-UHFFFAOYSA-N triazoxide Chemical compound N=1C2=CC=C(Cl)C=C2[N+]([O-])=NC=1N1C=CN=C1 IQGKIPDJXCAMSM-UHFFFAOYSA-N 0.000 claims 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 claims 1
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 claims 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims 1
- RROQIUMZODEXOR-UHFFFAOYSA-N triforine Chemical compound O=CNC(C(Cl)(Cl)Cl)N1CCN(C(NC=O)C(Cl)(Cl)Cl)CC1 RROQIUMZODEXOR-UHFFFAOYSA-N 0.000 claims 1
- JARYYMUOCXVXNK-IMTORBKUSA-N validamycin Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-IMTORBKUSA-N 0.000 claims 1
- DBXFMOWZRXXBRN-LWKPJOBUSA-N valifenalate Chemical compound CC(C)OC(=O)N[C@@H](C(C)C)C(=O)NC(CC(=O)OC)C1=CC=C(Cl)C=C1 DBXFMOWZRXXBRN-LWKPJOBUSA-N 0.000 claims 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 claims 1
- FJBGIXKIXPUXBY-UHFFFAOYSA-N {2-[3-(4-chlorophenyl)propyl]-2,4,4-trimethyl-1,3-oxazolidin-3-yl}(imidazol-1-yl)methanone Chemical compound C1=CN=CN1C(=O)N1C(C)(C)COC1(C)CCCC1=CC=C(Cl)C=C1 FJBGIXKIXPUXBY-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
Claims (14)
1. Kompozicija koja sadrži (a) najmanje jedan spoj izabran od spojeva formule 1, njihovih N-oksida i soli,
[image]
naznačena time što
R1 je fenil izborno supstituiran sa do 5 supstituenata nezavisno izabranih od R3, ili piridinil izborno supstituiran sa do 4 supstituenta nezavisno izabrana od R3;
R2 je C1-C4 haloalkil; ili tiazolil, piridinil ili pirimidinil, svaki izborno supstituiran sa do 2 supstituenta nezavisno izabrana iz grupe koju čine halogen i C1-C4 alkil;
svako R3 je nezavisno halogen, cijano, C1-C4 alkil, C1-C4 haloalkil, C1-C4 alkoksi, C1-C4 haloalkoksi, C(R4)=NOR4 ili Q;
svako R4 je nezavisno C1-C4 alkil;
Z je CH=CH ili S; i
svako Q je nezavisno fenil ili piridinil, svaki izborno supstituiran sa do 3 supstituenta nezavisno izabrana iz grupe koju čine halogen, cijano, C1-C4 alkil, C1-C4 haloalkil, C1-C4 alkoksi i C1-C4 haloalkoksi;
i
(b) najmanje jedno sredstvo za kontrolu štetnog beskičmenjaka je izabrano iz grupe koju čine abamektin, acetamiprid, amitraz, avermektin, azadirahtin, bensultap, bifentrin, buprofezin, kartap, klorantraniliprol, klorfenapir, klorpirifos, klotianidin, cijantraniliprol, ciflutrin, beta-ciflutrin, cihalotrin, gama-cihalothrin, lambda-cihalotrin, cipermetrin, alfa-cipermetrin, zeta-cipermetrin, ciromazin, deltametrin, dieldrin, dinotefuran, diofenolan, emamektin, endosulfan, esfenvalerat, etiprol, fenotiokarb, fenoksikarb, fenvalerat, fipronil, flonikamid, flubendiamid, flufenoksuron, heksaflumuron, hidrametilnon, imidakloprid, indoksakarb, lufenuron, metaflumizon, metomil, metopren, metoksifenozid, nitenpiram, nitiazin, novaluron, oksamil, fosmet, pimetrozin, piretrin, piridaben, piridalil, piriproksifen, rijanodin, spinetoram, spinosad, spirodiklofen, spiromesifen, spirotetramat, tebufenozid, tiakloprid, tiametoksam, tiodikarb, tiosultap-natrij, tolfenpirad, tralometrin, triazamat, triflumuron, Bacillus thuringiensis delta-endotoksini, svi sojevi Bacillus thuringiensis i svi sojevi Nucleo polyhydrosis virusa.
uz uvjet da (a) kada je R1 nesupstituirani fenil i R2 je CF3, tada Z je S; (b) kada je R1 jednako 2-fluorofenil i R2 je 2-kloro-5-tiazolil, tada Z je S; i (c) kada je R1 jednako 2-fluorofenil ili 3-(trifluorometoksi)fenil i R2 je 6-kloro-3-piridinil, tada Z je CH=CH.
2. Kompozicija prema patentnom zahtjevu 1 naznačena time što komponenta (a) je spoj formule 1 u kojem je R1 je fenil izborno supstituiran sa do 3 supstituenta nezavisno izabrana od R3, ili piridinil izborno supstituiran sa do 2 supstituenta nezavisno izabrana od R3.
3. Kompozicija prema patentnom zahtjevu 2 naznačena time što komponenta (a) je spoj formule 1 u kojem R1 je fenil izborno supstituiran sa do 3 supstituenta nezavisno izabrana od R3; i svaki R3 je nezavisno halogen, C1-C2 alkil, C1-C2 haloalkil, C1-C2 alkoksi, C1-C2 haloalkoksi ili Q.
4. Kompozicija prema patentnom zahtjevu 3 u kojem komponenta (a) je spoj formule 1 u kojem R2 je tiazolil, piridinil ili pirimidinil, svaki izborno supstituiran sa do 2 supstituenta nezavisno izabrana iz grupe koju čine halogen i C1-C4 alkil.
5. Kompozicija prema patentnom zahtjevu 3 ili patentnom zahtjevu 4 naznačena time što komponenta (a) je spoj formule 1 u kojem Z je CH=CH.
6. Kompozicija prema patentnom zahtjevu 1 naznačena time što komponenta (a) je spoj formule 1 izabran iz grupe koju čine:
1-[((2-kloro-5-tiazolil)metil]-3-(2,6-difluorofenil)-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-3-(2,6-dimetoksifenil)-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-2-hidroksi-3-(2-metoksifenil)-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((3,5-dimetoksifenil)-1-[(6-fluoro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-fluoro-3-piridinil)metil]-2-hidroksi-4-okso-3-[3-(trifluorometil)fenil]-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-kloro-3-piridinil)metil]-3-(2-fluoro-3-metoksifenil)-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((4-fluorofenil)-2-hidroksi-1-[(2-metil-5-tiazolil)metil]-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
2-hidroksi-4-okso-3-fenil-1-(5-tiazolilmetil)-4H-pirido[1,2-a]pyrmidinij unutrašnja sol;
3-((2-fluorofenil)-1-[(6-fluoro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-fluoro-3-piridinil)metil]-2-hidroksi-4-okso-3-[3-(trifluorometoksi)fenil]-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((5-bromo-2-metoksifenil)-1-[(6-kloro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-kloro-3-piridinil)metil]-3-[2-kloro-5-(trifluorometil)fenil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-fluoro-3-piridinil)metil]-3-[2-fluoro-3-(trifluorometil)fenil]-2-hidroksi-4-okso-4H-pirido[1,2-a]piriminidij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-3-[3-(6-fluoro-3-piridinil)-5-(trifluorometoksi)fenil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-3-[3-kloro-5-(trifluorometoksi)fenil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-3-[3-kloro-5-(trifluorometil)fenil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-kloro-3-piridinil)metil]-2-hidroksi-4-okso-3-(2,3,6-trifluorofenil)-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((3-kloro-2,6-difluorofenil)-1-[(6-kloro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((2,3-difluorofenil)-1-[(6-fluoro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((5-kloro-2-metoksifenil)-1-[(6-fluoro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((5-kloro-2-metoksifenil)-1-[(2-kloro-5-tiazolil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-fluoro-3-piridinil)metil]-2-hidroksi-3-[2-metoksi-5-(trifluorometil)fenil]-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-2-hidroksi-3-[2-metoksi-5-(trifluorometil)fenil]-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((2,4-difluorofenil)-2-hidroksi-4-okso-1-(5-tiazolilmetil)-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((2-fluorofenil)-2-hidroksi-4-okso-1-[(2-metil-5-tiazolil)metil]-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((2-kloro-6-fluorofenil)-1-[(6-kloro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-3-(2-etoksifenil)-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-fluoro-3-piridinil)metil]-3-[2-fluoro-5-(trifluorometoksi)fenil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-2-hidroksi-3-(3-metilfenil)-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-kloro-3-piridinil)metil]-2-hidroksi-3-(3-metoksifenil)-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-kloro-3-piridinil)metil]-3-(2-fluorofenil)-2-hydxoxy-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-kloro-3-piridinil)metil]-3-(2,5-difluorofenil)-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((5-kloro-2-fluorofenil)-1-[(6-kloro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-kloro-3-piridinil)metil]-2-hidroksi-4-okso-3-(2,4,6-trifluorofenil)-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-kloro-3-piridinil)metil]-3-(2,3-difluorofenil)-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((5-bromo-2-fluorofenil)-1-[(6-kloro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-kloro-3-piridinil)metil]-3-(2,6-difluorofenil)-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-3-[3-(trifluorometoksi)fenil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((6-bromo-3-piridinil)metil]-3-(2,4-difluorofenil)-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-2-hidroksi-3-(3-metoksifenil)-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-[3-bromo-5-(trifluorometoksi)fenil]-1-[(2-kloro-5-tiazolil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-[3-bromo-5-(trifluorometil)fenil]-1-[(2-kloro-5-tiazolil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((3-kloro-2-fluorofenil)-1-[(6-kloro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
2-hidroksi-4-okso-1-(5-pirimidinilmetil)-3-[3-(trifluorometil)fenil]-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-2-hidroksi-4-okso-3-(4’-(trifluorometil)[1,1’-bifenil]-3-il)-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-3-(4’-fluoro[1,1’-bifenil]-3-il)-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((5-kloro-2-fluorofenil)-1-[(6-fluoro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
8-[((6-kloro-3-piridinil)metil]-6-(2,3-difluorofenil)-7-hidroksi-5-okso-5H-tiazolo[3,2-a]pirimidinij unutrašnja sol;
3-((2,4-difluorofenil)-1-[(6-fluoro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-2-hidroksi-4-okso-3-[4-(trifluorometil)-2-piridinil]-4H-pirido[1,2-a]pirimidinij unutrašnja sol; i
3-((4-cijano-2-fluorofenil)-1-[(6-kloro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol.
7. Kompozicija prema bilo kojem od patentnih zahtjeva 1 do 6 naznačena time što dalje sadrži najmanje jednu dodatnu komponentu izabranu iz grupe koju čine surfaktanti, čvrsti razblaživači i tekući razblaživači.
8. Kompozicija prema patentnom zahtjevu 7 naznačena time što dalje sadrži najmanje jedan dodatni biološki aktivnispoj ili sredstvo.
9. Kompozicija za zaštitu životinje od štetnog parazitskog beskičmenjaka koja sadrži paraziticidno efikasnu količinu kompozicije prema bilo kojem od patentnih zahtjeva 1 do 6 i najmanje jedan nosač.
10. Neterapeutski postupak za kontrolu štetnog beskičmenjaka koji sadrži dovođenje u dodir štetočine ili njegove životne sredine sa biološki efikasnom količinom kompozicije prema bilo kojem od patentnih zahtjeva 1 do 8.
11. Tretirano sjeme koje sadrži kompoziciju prema bilo kojem od patentnih zahtjeva 1 do 8 u količini od oko 0.0001 do 1 težinskih % sjemena prije tretmana.
12. Kompozicija koja sadrži (a) najmanje jedno spoj izabran od spojeva formule 1, njegovih N-oksida i soli,
[image]
naznačena time što
R1 je fenil izborno supstituiran sa do 5 supstituenata nezavisno izabranih od R3, ili piridinil izborno supstituiran sa do 4 supstituenta nezavisno izabrana od R3;
R2 je C1-C4 haloalkil; ili tiazolil, piridinil ili pirimidinil, svaki izborno supstituiran sa do 2 supstituenta nezavisno izabrana iz grupe koju čine halogen i C1-C4 alkil;
svako R3 je nezavisno halogen, cijano, C1-C4 alkil, C1-C4 haloalkil, C1-C4 alkoksi, C1-C4 haloalkoksi, C(R4)=NOR4 ili Q;
svako R4 je nezavisno C1-C4 alkil;
Z je CH=CH ili S; i
svako Q je nezavisno fenil ili piridinil, svaki izborno supstituiran sa do 3 supstituenta nezavisno izabrana iz grupe koju čine halogen, cijano, C1-C4 alkil, C1-C4 haloalkil, C1-C4 alkoksi and C1-C4 haloalkoksi;
i
(b) najmanje jedno sredstvo za kontrolu štetnog beskičmenjaka je izabrano iz grupe koju čine abamektin, acetamiprid, amitraz, avermektin, azadirahtin, bensultap, bifentrin, buprofezin, kartap, klorantraniliprol, klorfenapir, klorpirifos, klotianidin, cijantraniliprol, ciflutrin, beta-ciflutrin, cihalotrin, gama-cihalothrin, lambda-cihalotrin, cipermetrin, alfa-cipermetrin, zeta-cipermetrin, ciromazin, deltametrin, dieldrin, dinotefuran, diofenolan, emamektin, endosulfan, esfenvalerat, etiprol, fenotiokarb, fenoksikarb, fenvalerat, fipronil, flonikamid, flubendiamid, flufenoksuron, heksaflumuron, hidrametilnon, imidakloprid, indoksakarb, lufenuron, metaflumizon, metomil, metopren, metoksifenozid, nitenpiram, nitiazin, novaluron, oksamil, fosmet, pimetrozin, piretrin, piridaben, piridalil, piriproksifen, rijanodin, spinetoram, spinosad, spirodiklofen, spiromesifen, spirotetramat, tebufenozid, tiakloprid, tiametoksam, tiodikarb, tiosultap-natrijum, tolfenpirad, tralometrin, triazamat, triflumuron, Bacillus thuringiensis delta-endotoksini, svi sojevi Bacillus thuringiensis i svi sojevi Nucleo polyhydrosis virusa; i
c) najmanje jedan fungicid;
uz uvjet da kada je najmanje jedan dodatni biološko aktivnispoj ili sredstvo izabrano iz grupe (b) i (i) kada je R1 nesupstituirani fenil i R2 je CF3, tada Z je S; (ii) kada je R1 jednako 2-fluorofenil i R2 je 2-kloro-5-tiazolil, tada Z je S; i (iii) kada je R1 jednako 2-fluorofenil ili 3-(trifluorometoksi)fenil i R2 je 6-kloro-3-piridinil, tada Z je CH=CH.
13. Kompozicija prema patentnom zahtjevu 12 naznačena time što je najmanje jedan fungicid izabran iz grupe koju čine 1-[4-[4-[5-(2,6-difluorofenil)-4,5-dihidro-3-izoksazolil]-2-tiazolil]-1-piperidinil]-2-[5-metil-3-(trifluorometil)-1H-pirazol-1-il]etanon, acibenzolar, aldimorf, amisulbrom, azakonazol, azoksistrobin, benalaksil, benomil, bentiavalikarb, bentiavalikarb-izopropil, binomial, bifenil, bitertanol, blasticidin-S, „Bordeaux“ smjesa (trobazni bakreni sulfat), boskalid/nikobifen, bromukonazol, bupirimat, butiobat, karboksin, karpropamid, kaptafol, kaptan, karbendazim, kloroneb, klorotalonil, klozolinat, klotrimazol, bakreni oksiklorid, soli bakra kao što su bakreni sulfat i bakreni hidroksid, cijazofamid, ciflunamid, cimoksanil, ciprokonazol, ciprodinil, diklofluanid, diklocimet, diklomezin, dikloran, dietofenkarb, difenokonazol, dimetomorf, dimoksistrobin, dinikonazol, dinikonazol-M, dinokap, diskostrobin, ditianon, dodemorf, dodin, ekonazol, etakonazol, edifenfos, epoksikonazol, etaboksam, etirimol, etridiazol, famoksadon, fenamidon, fenarimol, fenbukonazol, fenkaramid, fenfuram, fenheksamid, fenoksanil, fenpiklonil, fenpropidin, fenpropimorf, fentin acetat, fentin hidroksid, ferbam, ferfurazoat, ferimzon, fluazinam, fludioksolnil, flumetover, fluopikolid, fluoksastrobin, fluhinkonazol, fluhinkonazol, flusilazol, flusulfamid, flutolanil, flutriafol, fluksapiroksad, folpet, fosetil-aluminij, ftalid, fuberidazol, furalaksil, furametpir, heksakonazol, himeksazol, guazatin, imazalil, imibenkonazol, iminoktadin, jodikarb, ipkonazol, iprobenfos, iprodion, iprovalikarb, izokonazol, izoprotiolan, izotianil, kasugamicin, kresolksim-metil, mankozeb, mandipropamid, maneb, mapanipirin, mefenoksam, mepronil, metalaksil, metkonazol, metasulfokarb, metiram, metominostrobin/fenominostrobin, mepanipirim, metrafenon, mikonazol, miklobutanil, neo-asolzin (željezni (III) metanarsolnat), nuarimol, oktilinon, ofurak, orisastrobin, oksadiksil, oksolinska kiselina, okspokonazol, oksikarboksin, paklobutrazol, penkonazol, pencikuron, penflufen, pentiopirad, perfurazoat, fosfonska kiselina, ftalid, pikobenzamid, pikoksistrobin, polioksin, probenazol, prokloraz, procimidon, propamokarb, propamokarb-hidroklorid, propikonazol, propineb, prokvinazid, protiokonazol, piraklostrobin, pirametostrobin, piraoksistrobin, priazofos, pirifenoks, pirimetanil, pirifenoks, piriofenon, pirolnitrin, pirokvilon, kvinkonazol, hinoksifen, hintozen, siltiofam, simekonazol, spiroksamin, streptomicin, sumpor, tebukonazol, tebuflokvin, tehrazen, tekloftalam, teknazen, tetrakonazol, tiabendazol, tifluzamid, tiofanat, tiofanat-metil, tiram, tiadinil, tolklofos-metil, tolifluanid, triadimefon, triadimenol, triarimol, triazoksid, tridemorf, trimorfamid, triciklazol, trifloksistrobin, triforin, tritikonazol, unikonazol, validamicin, valifenalat, vinklozolin, zineb, ziram i zoksamid.
14. Spoj izabran iz grupe koju čine:
3-((2-kloro-6-fluorofenil)-1-[(6-kloro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-3-(2-etoksifenil)-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-2-hidroksi-3-(3-metilfenil)-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
3-((3-kloro-2-fluorofenil)-1-[(6-kloro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
2-hidroksi-4-okso-1-(5-pirimidinilmetil)-3-[3-(trifluorometil)fenil]-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-2-hidroksi-4-okso-3-(4’-(trifluorometil)[1,1’-bifenil]-3-il)-4H-pirido[1,2-a]pirimidinij unutrašnja sol;
1-[((2-kloro-5-tiazolil)metil]-3-(4’-fluoro[1,1’-bifenil]-3-il)-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol; i
3-((5-kloro-2-fluorofenil)-1-[(6-fluoro-3-piridinil)metil]-2-hidroksi-4-okso-4H-pirido[1,2-a]pirimidinij unutrašnja sol.
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