GB1597680A - Manufacture of acicular ferromagnetic pigment particles - Google Patents
Manufacture of acicular ferromagnetic pigment particles Download PDFInfo
- Publication number
- GB1597680A GB1597680A GB12882/78A GB1288278A GB1597680A GB 1597680 A GB1597680 A GB 1597680A GB 12882/78 A GB12882/78 A GB 12882/78A GB 1288278 A GB1288278 A GB 1288278A GB 1597680 A GB1597680 A GB 1597680A
- Authority
- GB
- United Kingdom
- Prior art keywords
- particles
- starting material
- iron
- alkaline earth
- earth metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002245 particle Substances 0.000 title claims description 51
- 239000000049 pigment Substances 0.000 title claims description 21
- 230000005294 ferromagnetic effect Effects 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 33
- AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 claims description 24
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 claims description 22
- 230000005291 magnetic effect Effects 0.000 claims description 21
- 229910052742 iron Inorganic materials 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 16
- 239000007858 starting material Substances 0.000 claims description 16
- 229910000462 iron(III) oxide hydroxide Inorganic materials 0.000 claims description 14
- 229910021519 iron(III) oxide-hydroxide Inorganic materials 0.000 claims description 14
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- -1 carboxylic acid compound Chemical class 0.000 claims description 9
- 150000001735 carboxylic acids Chemical class 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 229910052788 barium Inorganic materials 0.000 claims description 6
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 150000001341 alkaline earth metal compounds Chemical class 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 229910052712 strontium Inorganic materials 0.000 claims description 4
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 4
- 239000004135 Bone phosphate Substances 0.000 claims description 3
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims description 2
- 159000000009 barium salts Chemical class 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 235000015165 citric acid Nutrition 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000003756 stirring Methods 0.000 description 9
- 239000000725 suspension Substances 0.000 description 8
- 230000005415 magnetization Effects 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000009826 distribution Methods 0.000 description 6
- 230000006698 induction Effects 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 229910052598 goethite Inorganic materials 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000002923 metal particle Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000004438 BET method Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- MZZSDCJQCLYLLL-UHFFFAOYSA-N Secalonsaeure A Natural products COC(=O)C12OC3C(CC1=C(O)CC(C)C2O)C(=CC=C3c4ccc(O)c5C(=O)C6=C(O)CC(C)C(O)C6(Oc45)C(=O)OC)O MZZSDCJQCLYLLL-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- ZUDYPQRUOYEARG-UHFFFAOYSA-L barium(2+);dihydroxide;octahydrate Chemical compound O.O.O.O.O.O.O.O.[OH-].[OH-].[Ba+2] ZUDYPQRUOYEARG-UHFFFAOYSA-L 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013500 data storage Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000005347 demagnetization Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000005307 ferromagnetism Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008241 heterogeneous mixture Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- 229910021506 iron(II) hydroxide Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 239000006249 magnetic particle Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000015654 memory Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/032—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
- H01F1/04—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
- H01F1/06—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder
- H01F1/065—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder obtained by a reduction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/20—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from solid metal compounds
- B22F9/22—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from solid metal compounds using gaseous reductors
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B15/00—Other processes for the manufacture of iron from iron compounds
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/62—Record carriers characterised by the selection of the material
- G11B5/68—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent
- G11B5/70—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer
- G11B5/714—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer characterised by the dimension of the magnetic particles
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Hard Magnetic Materials (AREA)
- Compounds Of Iron (AREA)
- Paints Or Removers (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Magnetic Record Carriers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2714588A DE2714588C2 (de) | 1977-04-01 | 1977-04-01 | Verfahren zur Herstellung nadelförmiger ferromagnetischer Eisenteilchen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1597680A true GB1597680A (en) | 1981-09-09 |
Family
ID=6005364
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB12425/78A Expired GB1597679A (en) | 1977-04-01 | 1978-04-03 | Manufacture of acicular ferromagnetic pigment particles |
| GB12882/78A Expired GB1597680A (en) | 1977-04-01 | 1978-04-03 | Manufacture of acicular ferromagnetic pigment particles |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB12425/78A Expired GB1597679A (en) | 1977-04-01 | 1978-04-03 | Manufacture of acicular ferromagnetic pigment particles |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4178171A (enExample) |
| JP (1) | JPS53123898A (enExample) |
| DE (1) | DE2714588C2 (enExample) |
| FR (1) | FR2385476A1 (enExample) |
| GB (2) | GB1597679A (enExample) |
| NL (1) | NL7803460A (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2815712A1 (de) * | 1978-04-12 | 1979-10-25 | Bayer Ag | Eisenoxide zur magnetischen signalaufzeichnung und verfahren zu deren herstellung |
| DE2907255A1 (de) * | 1979-02-24 | 1980-09-04 | Basf Ag | Verfahren zur herstellung nadelfoermiger ferromagnetischer eisenteilchen |
| DE2935357A1 (de) * | 1979-09-01 | 1981-09-10 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung nadelfoermiger ferromagnetischer eisenteilchen und deren verwendung |
| DE2935358A1 (de) * | 1979-09-01 | 1981-03-26 | Basf Ag, 67063 Ludwigshafen | Verfahren zur herstellung nadelfoermiger ferromagnetischer eisenteilchen und deren verwendung |
| JPS5677931A (en) * | 1979-11-28 | 1981-06-26 | Tdk Corp | Magnetic recording medium and its producton |
| DE3021111A1 (de) | 1980-06-04 | 1981-12-17 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von nadelfoermigen, im wesentlichen aus eisen bestehenden, ferromagnetischen metallteilchen |
| EP0041727B1 (en) * | 1980-06-11 | 1987-09-09 | Hitachi Maxell Ltd. | Process for preparing ferromagnetic particles comprising metallic iron |
| DE3026696A1 (de) | 1980-07-15 | 1982-02-18 | Basf Ag, 6700 Ludwigshafen | Ferromagnetische, im wesentlichen aus eisen bestehende metallteilchen mit einem oberflaechenueberzug, verfahren zu deren herstellung sowie ihre verwendung zur herstellung von magnetischen aufzeichnungstraegern |
| DE3228669A1 (de) * | 1982-07-31 | 1984-02-02 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung nadelfoermiger, im wesentlichen aus eisen bestehender ferromagnetischer metallteilchen |
| JPS59157204A (ja) * | 1983-02-23 | 1984-09-06 | Chisso Corp | 強磁性金属微粒子の製造方法 |
| JPS6161404A (ja) * | 1984-08-31 | 1986-03-29 | Sony Corp | 金属磁性粉末の製造方法 |
| US10336648B1 (en) * | 1986-03-21 | 2019-07-02 | Alvin R. Stetson | Slip composition |
| US4849120A (en) * | 1986-05-13 | 1989-07-18 | Price John T | Magnetically controllable couplings containing ferrafluids |
| US4957644A (en) * | 1986-05-13 | 1990-09-18 | Price John T | Magnetically controllable couplings containing ferrofluids |
| US5069216A (en) * | 1986-07-03 | 1991-12-03 | Advanced Magnetics Inc. | Silanized biodegradable super paramagnetic metal oxides as contrast agents for imaging the gastrointestinal tract |
| US5219554A (en) * | 1986-07-03 | 1993-06-15 | Advanced Magnetics, Inc. | Hydrated biodegradable superparamagnetic metal oxides |
| JPS6367704A (ja) * | 1986-09-09 | 1988-03-26 | Nissan Chem Ind Ltd | 高分散性磁性鉄粉の製造方法 |
| JPH06345437A (ja) * | 1993-06-04 | 1994-12-20 | Natl Sci Council | γ−酸化鉄磁気粉末の製造方法 |
| RU2160697C2 (ru) * | 1998-09-11 | 2000-12-20 | Акционерное общество закрытого типа "Тетра" | Способ управления формой синтезируемых частиц и получения материалов и устройств, содержащих ориентированные анизотропные частицы и наноструктуры (варианты) |
| US8857603B1 (en) * | 2013-06-20 | 2014-10-14 | Alan Nippert | System for adjusting conveyor direction |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1219009B (de) * | 1963-06-26 | 1966-06-16 | Bayer Ag | Verfahren zur Herstellung von gamma-FeOOH |
| NL162233C (nl) * | 1968-03-05 | 1980-04-15 | Philips Nv | Werkwijze ter bereiding van een in hoofdzaak uit ijzer bestaand magnetisch stabiel poeder, voor magnetische registratie. |
| US3904540A (en) * | 1972-02-11 | 1975-09-09 | Pfizer | Magnetic impulse record member |
| DE2249274A1 (de) * | 1972-10-07 | 1974-04-18 | Bayer Ag | Herstellung von gefaelltem rotem eisen(iii)-oxid |
| US4066726A (en) * | 1972-11-18 | 1978-01-03 | Gottfried Mehnert | Multi-stage method of blow molding hollow shaped articles |
| JPS5024799A (enExample) * | 1973-07-04 | 1975-03-17 | ||
| DE2434058C2 (de) * | 1974-07-16 | 1985-12-19 | Basf Ag, 6700 Ludwigshafen | Nadelförmige, vorwiegend aus Eisen bestehende ferromagnetische Metallteilchen und Verfahren zu ihrer Herstellung |
| DE2434096C2 (de) * | 1974-07-16 | 1985-10-17 | Basf Ag, 6700 Ludwigshafen | Nadelförmige, vorwiegend aus Eisen bestehende ferromagnetische Metallteilchen und Verfahren zu ihrer Herstellung |
-
1977
- 1977-04-01 DE DE2714588A patent/DE2714588C2/de not_active Expired
-
1978
- 1978-03-20 US US05/888,508 patent/US4178171A/en not_active Expired - Lifetime
- 1978-03-31 NL NL7803460A patent/NL7803460A/xx unknown
- 1978-03-31 JP JP3692978A patent/JPS53123898A/ja active Granted
- 1978-03-31 FR FR7809509A patent/FR2385476A1/fr active Granted
- 1978-04-03 GB GB12425/78A patent/GB1597679A/en not_active Expired
- 1978-04-03 GB GB12882/78A patent/GB1597680A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2714588A1 (de) | 1978-10-12 |
| DE2714588C2 (de) | 1986-06-05 |
| JPS53123898A (en) | 1978-10-28 |
| GB1597679A (en) | 1981-09-09 |
| JPS6217362B2 (enExample) | 1987-04-17 |
| FR2385476A1 (fr) | 1978-10-27 |
| NL7803460A (nl) | 1978-10-03 |
| FR2385476B1 (enExample) | 1983-02-04 |
| US4178171A (en) | 1979-12-11 |
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Effective date: 19950714 |