FR3102008B1 - Procede de recyclage des batteries li-ion - Google Patents

Procede de recyclage des batteries li-ion Download PDF

Info

Publication number
FR3102008B1
FR3102008B1 FR1911251A FR1911251A FR3102008B1 FR 3102008 B1 FR3102008 B1 FR 3102008B1 FR 1911251 A FR1911251 A FR 1911251A FR 1911251 A FR1911251 A FR 1911251A FR 3102008 B1 FR3102008 B1 FR 3102008B1
Authority
FR
France
Prior art keywords
metal
solution
ions
treated
ion battery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1911251A
Other languages
English (en)
Other versions
FR3102008A1 (fr
Inventor
Emmanuel Billy
Sandrine Barthelemy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1911251A priority Critical patent/FR3102008B1/fr
Application filed by Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to CN202080071531.3A priority patent/CN114585756A/zh
Priority to EP20796631.8A priority patent/EP4041926A1/fr
Priority to PCT/FR2020/051737 priority patent/WO2021069822A1/fr
Priority to CA3156827A priority patent/CA3156827A1/fr
Priority to US17/754,586 priority patent/US20220411896A1/en
Priority to JP2022521458A priority patent/JP2022552492A/ja
Priority to KR1020227015318A priority patent/KR20220079922A/ko
Publication of FR3102008A1 publication Critical patent/FR3102008A1/fr
Application granted granted Critical
Publication of FR3102008B1 publication Critical patent/FR3102008B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B47/00—Obtaining manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B23/0461—Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C22B7/007—Wet processes by acid leaching
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/54—Reclaiming serviceable parts of waste accumulators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/84—Recycling of batteries or fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Secondary Cells (AREA)

Abstract

Procédé de recyclage d’une batterie comportant les étapes suivantes :a) dissolution d’un déchet de batterie, par exemple une électrode, comportant du lithium et un métal choisi parmi le cobalt et le manganèse, moyennant quoi on forme une solution à traiter contenant des ions lithium et des ions du métal,b) ajout d’un sel de peroxomonosulfate à la solution à traiter, la solution à traiter étant régulée à un pH allant de 1 à 4 lorsque le métal est le cobalt ou à un pH allant de 0,1 à 2,5 lorsque le métal est le manganèse, moyennant quoi on fait précipiter sélectivement les ions du métal sous forme d’oxyhydroxyde de métal,c) séparation des ions lithium de la solution à traiter. Avantageusement, la solution comprend, en outre, des ions nickel. Figure pour l’abrégé : 1
FR1911251A 2019-10-10 2019-10-10 Procede de recyclage des batteries li-ion Active FR3102008B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR1911251A FR3102008B1 (fr) 2019-10-10 2019-10-10 Procede de recyclage des batteries li-ion
EP20796631.8A EP4041926A1 (fr) 2019-10-10 2020-10-05 Procede de recyclage des batteries li-ion
PCT/FR2020/051737 WO2021069822A1 (fr) 2019-10-10 2020-10-05 Procede de recyclage des batteries li-ion
CA3156827A CA3156827A1 (fr) 2019-10-10 2020-10-05 Procede de recyclage des batteries li-ion
CN202080071531.3A CN114585756A (zh) 2019-10-10 2020-10-05 用于回收锂电池的方法
US17/754,586 US20220411896A1 (en) 2019-10-10 2020-10-05 Method for recycling li-ion batteries
JP2022521458A JP2022552492A (ja) 2019-10-10 2020-10-05 Ｌｉイオン電池のリサイクル方法
KR1020227015318A KR20220079922A (ko) 2019-10-10 2020-10-05 Li-이온 배터리를 재활용하는 방법

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1911251A FR3102008B1 (fr) 2019-10-10 2019-10-10 Procede de recyclage des batteries li-ion
FR1911251 2019-10-10

Publications (2)

Publication Number Publication Date
FR3102008A1 FR3102008A1 (fr) 2021-04-16
FR3102008B1 true FR3102008B1 (fr) 2021-09-24

Family

ID=69173016

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1911251A Active FR3102008B1 (fr) 2019-10-10 2019-10-10 Procede de recyclage des batteries li-ion

Country Status (8)

Country Link
US (1) US20220411896A1 (fr)
EP (1) EP4041926A1 (fr)
JP (1) JP2022552492A (fr)
KR (1) KR20220079922A (fr)
CN (1) CN114585756A (fr)
CA (1) CA3156827A1 (fr)
FR (1) FR3102008B1 (fr)
WO (1) WO2021069822A1 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102680508B1 (ko) 2020-08-24 2024-07-01 그린 라이온 피티이. 리미티드 리튬이온 배터리의 재활용에서의 불순물 제거 공정
CN113957255B (zh) * 2021-09-30 2022-11-15 广东邦普循环科技有限公司 一种废旧三元锂电池中有价金属分离回收的方法
CN114277251B (zh) * 2021-12-24 2023-08-15 中南大学 一种分离和回收废弃锂电池中金属的方法
AU2023223959B2 (en) 2022-02-23 2025-04-03 Green Li-Ion Pte. Ltd Processes and systems for purifying and recycling lithium-ion battery waste streams
TWI890995B (zh) 2022-04-18 2025-07-21 新加坡商綠色鋰離子私人有限公司 用於自鋰離子電池組回收鋰之方法及系統
KR102906431B1 (ko) * 2022-10-25 2025-12-31 공형진 폐리튬이온 배터리 재활용 장치
US20240313212A1 (en) * 2023-03-13 2024-09-19 Ascend Elements, Inc. Doped cathode material precursor from recycled lithium-ion batteries
US12322771B2 (en) 2023-08-23 2025-06-03 Green Li-Ion Pte. Ltd. Adaptable processes and systems for purifying co-precipitated or independent streams of manganese, nickel, and cobalt from lithium-ion battery waste streams
EP4663787A1 (fr) 2024-06-13 2025-12-17 Solvay SA Séparation de manganèse à partir de masse noire de batteries li-ion recyclées avec un peracide inorganique contenant du soufre

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE830450A (fr) * 1975-06-19 1975-12-19 Procede d'elimination des impuretes contenues dans une solution de sulfate du groupe du zinc et du cadmium
JP3425206B2 (ja) * 1994-01-20 2003-07-14 住友金属鉱山株式会社 使用済みリチウム二次電池からの有価物の回収方法
JP2002088420A (ja) * 2000-09-13 2002-03-27 Mitsubishi Heavy Ind Ltd 海中リチウム採取装置
JP4506002B2 (ja) * 2001-02-21 2010-07-21 住友金属鉱山株式会社 使用済みニッケル水素二次電池からの有価金属回収方法
FR2868603B1 (fr) 2004-04-06 2006-07-14 Recupyl Sa Sa Procede de recyclage en melange de piles et batteries a base d'anode en lithium
JP4801372B2 (ja) * 2005-05-10 2011-10-26 正同化学工業株式会社 硫酸コバルト溶液からマンガンを除去する方法
US7442323B2 (en) * 2006-06-02 2008-10-28 E. I. Du Pont De Nemours And Company Potassium monopersulfate solutions
WO2008157345A2 (fr) * 2007-06-13 2008-12-24 Advanced Technology Materials, Inc. Compositions et procédés de récupération de plaquette
JP5408412B2 (ja) * 2009-03-20 2014-02-05 三菱マテリアル株式会社 白金の回収処理方法
JP2011132562A (ja) * 2009-12-22 2011-07-07 Asahi Pretec Corp Ｃｏ化合物の回収方法
JP2012001750A (ja) * 2010-06-15 2012-01-05 Mitsui Mining & Smelting Co Ltd Ｃｏ含有溶液の製造方法
CN101871048B (zh) * 2010-06-25 2012-05-23 浙江华友钴业股份有限公司 一种从废旧锂电池中回收钴、镍和锰的方法
US9238850B2 (en) * 2010-08-20 2016-01-19 Advanced Technology Materials, Inc. Sustainable process for reclaiming precious metals and base metals from e-waste
FR2976295B1 (fr) 2011-06-07 2013-07-05 Sarp Ind Procede de separation de metaux a partir de batteries contenant du lithium
JP2015036430A (ja) * 2013-08-12 2015-02-23 三菱マテリアル株式会社 Ｃｅの高純度回収方法
JP2015209584A (ja) * 2014-04-30 2015-11-24 三菱電機株式会社 金の剥離液、およびそれを用いた金の回収方法、回収装置
JP2016009613A (ja) * 2014-06-25 2016-01-18 日産自動車株式会社 リチウムイオン二次電池の正極からの有価物の回収方法
CH710357A1 (de) * 2014-11-11 2016-05-13 Bogaert Jean-Pierre Kosmetisches und pharmazeutisches Mittel zur Behandlung von Hautrissen.
JP6439530B2 (ja) * 2015-03-24 2018-12-19 住友金属鉱山株式会社 スカンジウムの回収方法
JP6459797B2 (ja) * 2015-06-24 2019-01-30 住友金属鉱山株式会社 廃ニッケル水素電池からのフェロニッケル製造用原料の回収方法及びその回収装置
JP6402686B2 (ja) * 2015-06-24 2018-10-10 住友金属鉱山株式会社 廃ニッケル水素電池からのニッケル、コバルト、及びアルミニウム系二次電池の製造用原料の回収方法及びその回収装置
CN105591171B (zh) * 2015-12-18 2017-12-08 浙江天能能源科技股份有限公司 一种废旧镍钴锰三元锂离子电池中有价金属的回收方法
WO2017145099A1 (fr) * 2016-02-24 2017-08-31 Attero Recycling Pvt. Ltd. Procédé de récupération d'oxyde de cobalt pur à partir de batteries au lithium-ion usagées ayant une teneur élevée en manganèse
CN105907977A (zh) * 2016-07-08 2016-08-31 长沙理工大学 一种从废旧锂离子电池中回收钴酸锂的方法
CN106048222A (zh) * 2016-07-26 2016-10-26 中国科学院兰州化学物理研究所 一种高镍溶液中锰离子的分离净化方法
CN108002408B (zh) 2016-10-31 2021-06-04 湖南金源新材料股份有限公司 电池废料制备硫酸镍、锰、锂、钴及四氧化三钴的方法
KR20200059192A (ko) * 2017-06-08 2020-05-28 어반 마이닝 피티와이 엘티디 리튬을 회수하는 방법
WO2018227237A1 (fr) * 2017-06-14 2018-12-20 Urban Mining Pty Ltd Procédé de production de cobalt et d'oxydes associés à partir de divers matériaux de charge
JP7031263B2 (ja) * 2017-12-04 2022-03-08 住友金属鉱山株式会社 リチウムの回収方法
CN108163960A (zh) * 2017-12-28 2018-06-15 吉林建筑大学 一种利用单过硫酸盐强化锰砂去除水中锰离子的方法
CN110306056B (zh) * 2019-06-20 2020-09-22 厦门大学 一种从锰矿渣中提取高纯度锰的方法

Also Published As

Publication number Publication date
KR20220079922A (ko) 2022-06-14
EP4041926A1 (fr) 2022-08-17
US20220411896A1 (en) 2022-12-29
CA3156827A1 (fr) 2021-04-15
JP2022552492A (ja) 2022-12-16
CN114585756A (zh) 2022-06-03
WO2021069822A1 (fr) 2021-04-15
FR3102008A1 (fr) 2021-04-16

Similar Documents

Publication Publication Date Title
FR3102008B1 (fr) Procede de recyclage des batteries li-ion
CA3077604C (fr) Procede de separation de cuivre de nickel et de colbalt
Larouche et al. Progress and status of hydrometallurgical and direct recycling of Li-ion batteries and beyond
CA3086627C (fr) Procede de separation de cuivre, de nickel et de colbalt
JP6897466B2 (ja) 銅とニッケルおよびコバルトの分離方法
JP6519628B2 (ja) 銅とニッケルおよびコバルトの分離方法
CN101871048A (zh) 一种从废旧锂电池中回收钴、镍和锰的方法
TW200840115A (en) Method for recycling noble metal from battery slag containing Co, Ni, Mn
KR20120126946A (ko) 리튬이온전지의 재생공정을 위한 전처리방법
MA61490A1 (fr) Procédé de séparation et de récupération de métaux de valeur à partir de batteries au lithium ternaire
JP6958235B2 (ja) 銅とニッケルおよびコバルトの分離方法
JP5247877B2 (ja) リチウムイオン電池用正極材から集電体及び正極活物質を分離回収する方法
JP4099057B2 (ja) リチウムイオン電池内のコバルト回収方法およびコバルト回収システム
WO2019102765A1 (fr) Procédé de traitement de déchets de batterie lithium-ion
Liu et al. Simultaneous peeling of precious metals in cathode and anode of spent ternary batteries using electrolysis
JP2020029586A (ja) 銅とニッケル及びコバルトの分離方法
RU1819297C (ru) Способ электрохимического разделени металлов
EP0620607B1 (fr) Procédé de traitement de piles usagées par électrolyse
FR3034104A1 (fr) Procede de dissolution d'un oxyde metallique en presence d'un metal reducteur.
Kuznetsova et al. AC electrochemical oxidation of nickel and VNZh alloy in alkaline-ammonium solutions
BE1030447B1 (nl) Additief-vrije Cu Elektrowinning
RU2380437C2 (ru) Способ извлечения меди из оксидных или сульфидных руд и их концентратов
JP6992691B2 (ja) 銅とニッケル及び／又はコバルトとを分離する方法
RU2258768C1 (ru) Способ извлечения золота и серебра из полиметаллического сырья
Pavithra et al. Recovery Approaches for Spent Batteries: A Review

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 2

PLSC Publication of the preliminary search report

Effective date: 20210416

PLFP Fee payment

Year of fee payment: 3

PLFP Fee payment

Year of fee payment: 4

PLFP Fee payment

Year of fee payment: 5

PLFP Fee payment

Year of fee payment: 6

PLFP Fee payment

Year of fee payment: 7