FR08C0037I1 - - Google Patents
Info
- Publication number
- FR08C0037I1 FR08C0037I1 FR08C0037C FR08C0037I1 FR 08C0037 I1 FR08C0037 I1 FR 08C0037I1 FR 08C0037 C FR08C0037 C FR 08C0037C FR 08C0037 I1 FR08C0037 I1 FR 08C0037I1
- Authority
- FR
- France
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
- C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
- C07D487/04—Ortho-condensed systems
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D333/52—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes
- C07D333/62—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
- C07D333/66—Nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2655696P | 1996-09-24 | 1996-09-24 | |
PCT/US1997/016867 WO1998013367A1 (en) | 1996-09-24 | 1997-09-23 | N-([1,2,4] triazoloazinyl)benzenesulfonamide and pyridinesulfonamide compounds and their use as herbicides |
Publications (2)
Publication Number | Publication Date |
---|---|
FR08C0037I1 true FR08C0037I1 (it) | 2008-10-17 |
FR08C0037I2 FR08C0037I2 (it) | 2010-06-11 |
Family
ID=21832490
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR08C0037C Active FR08C0037I2 (it) | 1996-09-24 | 2008-09-10 |
Country Status (23)
Country | Link |
---|---|
US (5) | US5858924A (it) |
EP (1) | EP0877745B1 (it) |
JP (2) | JP4215824B2 (it) |
KR (1) | KR100488277B1 (it) |
CN (2) | CN1092195C (it) |
AR (1) | AR012020A1 (it) |
AU (1) | AU723666B2 (it) |
BG (1) | BG63123B1 (it) |
BR (1) | BR9706774B1 (it) |
CA (1) | CA2238316C (it) |
CO (1) | CO4900002A1 (it) |
CZ (1) | CZ297521B6 (it) |
DE (2) | DE122009000052I2 (it) |
DK (1) | DK0877745T3 (it) |
EA (1) | EA001064B1 (it) |
ES (1) | ES2158513T3 (it) |
FR (1) | FR08C0037I2 (it) |
GR (1) | GR3036961T3 (it) |
HU (2) | HU228039B1 (it) |
PL (1) | PL190282B1 (it) |
TR (1) | TR199800906T1 (it) |
UA (1) | UA59350C2 (it) |
WO (1) | WO1998013367A1 (it) |
Families Citing this family (71)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19525162A1 (de) | 1995-07-11 | 1997-01-16 | Bayer Ag | Sulfonylamino(thio)carbonylverbindungen |
JP2001233718A (ja) * | 2000-02-22 | 2001-08-28 | Dow Chem Japan Ltd | 除草剤組成物 |
TWI287547B (en) | 2000-06-14 | 2007-10-01 | Dow Agrosciences Llc | Process for the selective deprotonation and functionalization of 3-substituted benzotrifluorides |
HU228907B1 (hu) * | 2000-06-16 | 2013-06-28 | Dow Agrosciences Llc | Eljárás 2-amino-5,8-dimetoxi[1,2,4]triazolo[1,5-c]pirimidin elõállítására |
US6433169B1 (en) | 2000-09-26 | 2002-08-13 | Dow Agrosciences Llc | Process for the preparation of 2-alkoxy-6-trifluoromethyl-N-([1,2,4]triazolo[1,5-c]pyrimidin-2-yl) benzenesulfonamides |
DK1242425T3 (da) | 2000-11-03 | 2004-07-05 | Dow Agrosciences Llc | N-(5,7-dimethoxy[1,2,4]triazolo[1,5-a]pyrimidin-2-yl)arylsulfonamid-forbindelser og deres anvendelse som herbicider |
EP1330458B1 (en) * | 2000-11-03 | 2009-06-03 | Dow AgroSciences LLC | N-( 1,2,4 triazoloazinyl) thiophenesulfonamide compounds as herbicides |
DE10063116A1 (de) * | 2000-12-18 | 2002-06-20 | Bayer Ag | Azinylsulfonylimidazole |
US7250619B2 (en) * | 2001-05-14 | 2007-07-31 | Prismedical Corporation | Powered sterile solution device |
KR20050044575A (ko) * | 2001-11-23 | 2005-05-12 | 바스프 악티엔게젤샤프트 | 살충제로서의 피리딘-3-술포닐 화합물 |
US20030166469A1 (en) * | 2001-12-21 | 2003-09-04 | Bahr James T. | Crop harvesting method using a 1,2,4-triazol-1-ylpropanoic acid and derivatives |
WO2004080182A2 (en) | 2003-03-13 | 2004-09-23 | Basf Aktiengesellschaft | Herbicidal mixtures |
CA2550874C (en) * | 2003-12-23 | 2012-04-10 | Dow Agrosciences Llc | Process for the preparation of triazolopyrimidines |
ZA200605471B (en) * | 2003-12-23 | 2007-11-28 | Dow Agrosciences Llc | Process for the preparation of pyridine derivatives |
CA2558245C (en) * | 2004-03-26 | 2012-01-03 | Christopher Thomas Hamilton | An improved process for the preparation of n-([1,2,4]triazolopyrimidin-2-yl)aryl sulfonamides |
WO2006012320A1 (en) * | 2004-06-25 | 2006-02-02 | Dow Agrosciences Llc | Process for the preparation of 4-trifluoromethyl-2(1h)-pyridinone |
CN102578086B (zh) * | 2004-08-11 | 2014-06-11 | 组合化学工业株式会社 | 农药组合物 |
ES2729946T3 (es) * | 2005-02-11 | 2019-11-07 | Dow Agrosciences Llc | Penoxsulam como un herbicida para césped, viñedos y huertos |
WO2008089310A2 (en) * | 2007-01-18 | 2008-07-24 | Lexicon Pharmaceuticals, Inc. | Delta 5 desaturase inhibitors for the treatment of obesity |
WO2008089307A2 (en) * | 2007-01-18 | 2008-07-24 | Lexicon Pharmaceuticals, Inc. | Delta 5 desaturase inhibitors for the treatment of pain, inflammation and cancer |
WO2009006211A1 (en) * | 2007-06-29 | 2009-01-08 | Dow Agrosciences Llc | An improved process for the preparation of 4-trifluoromethyl-2(1h)-pyridinone |
US8288320B2 (en) | 2007-10-04 | 2012-10-16 | Oms Investments, Inc. | Methods for preparing granular weed control products having improved distribution of agriculturally active ingredients coated thereon |
GB0719803D0 (en) * | 2007-10-10 | 2007-11-21 | Cancer Rec Tech Ltd | Therapeutic compounds and their use |
EP2110019A1 (de) * | 2008-04-19 | 2009-10-21 | Bayer CropScience AG | Herbizide Verbindungen auf Basis von N-Azinyl-N'-phenylsulfonylharnstoffen |
CN102348379A (zh) * | 2009-03-11 | 2012-02-08 | 住友化学株式会社 | 除草组合物以及杂草的防除方法 |
CN102459258B (zh) | 2009-06-05 | 2015-11-25 | 赛福伦公司 | 1,2,4-三唑并[1,5a]吡啶衍生物的制备和用途 |
EP3424324A1 (en) * | 2009-10-28 | 2019-01-09 | Dow AgroSciences LLC | Synergistic herbicidal composition containing fluroxypyr and an als inhibitor herbicide from the class of imidazoles |
IN2012DN06595A (it) * | 2010-01-29 | 2015-10-23 | Dow Agrosciences Llc | |
US20110190135A1 (en) * | 2010-02-03 | 2011-08-04 | Dow Agrosciences Llc | Synergistic herbicidal composition containing penoxsulam and butachlor |
PT2531035E (pt) * | 2010-02-03 | 2014-09-05 | Dow Agrosciences Llc | Composição herbicida sinérgica contendo penoxsulame e flazassulfurão |
PL2851367T3 (pl) | 2010-05-25 | 2017-05-31 | Dow Agrosciences, Llc | Sposób wytwarzania 2-amino-5,8-alkoksy[1,2,4]triazolo[1,5-c]pirymidyny przez reakcję 5-halogeno-8-alkoksy[1,2,4]triazolo[1,5-c]pirymidyno-2-aminy z alkoholanem metalu alkalicznego w alkoholowym rozpuszczalniku |
US20120053055A1 (en) | 2010-08-30 | 2012-03-01 | Dow Agrosciences Llc | Synergistic herbicidal composition containing penoxsulam and bentazon |
CN102020647B (zh) * | 2010-11-18 | 2013-09-11 | 孙智华 | 1-(2,2-二氟乙氧基)-6-三氟甲基-n-([1,2,4]三氮唑[1,5-c]嘧啶-2-)苯磺酰胺的制备方法 |
JP5841613B2 (ja) * | 2010-12-21 | 2016-01-13 | ダウ アグロサイエンシィズ エルエルシー | ペノキススラムおよびベンフレセートを含む相乗的除草剤組成物 |
EP2663191A4 (en) | 2011-01-14 | 2014-06-04 | Dow Agrosciences Llc | INHIBITION OF COTTON GROWTH BY MEANS OF PENOXSULAM |
CN103442560B (zh) | 2011-01-18 | 2015-11-25 | 陶氏益农公司 | 含有五氟磺草胺、绿草定和咪草烟或咪草啶酸的协同性除草组合物 |
MY184170A (en) | 2011-02-04 | 2021-03-24 | Dow Agrosciences Llc | Synergistic herbicidal composition containing penoxsulam and glyphosate |
AR087147A1 (es) | 2011-03-16 | 2014-02-26 | Dow Agrosciences Llc | Composicion sinergica herbicida que contiene penoxsulam y piroxsulam |
US8962528B2 (en) | 2011-03-30 | 2015-02-24 | Dow Agrosciences, Llc. | Penoxsulam as an herbicide in alfalfa |
CN102792957A (zh) * | 2011-05-23 | 2012-11-28 | 山东滨农科技有限公司 | 含有五氟磺草胺和氯吡嘧磺隆的除草剂组合物 |
CA2845331C (en) | 2011-08-16 | 2019-09-10 | Dow Agrosciences Llc | Synergistic herbicidal composition containing penoxsulam and florasulam |
CN102415393A (zh) * | 2011-10-28 | 2012-04-18 | 陕西美邦农药有限公司 | 一种含乙氧磺隆与五氟磺草胺的除草组合物 |
WO2013082228A1 (en) | 2011-11-30 | 2013-06-06 | Dow Agrosciences Llc | Synergistic herbicidal composition containing penoxsulam and glufosinate-ammonium |
WO2014043087A1 (en) * | 2012-09-14 | 2014-03-20 | Dow Agrosciences Llc | Process for the preparation of 2-amino-5,8-dimethoxy[1,2,4]triazolo[1,5-c]pyrimidine from 4-chloro-2,5-dimethoxypyrimidine |
KR20150096448A (ko) | 2012-12-12 | 2015-08-24 | 다우 아그로사이언시즈 엘엘씨 | 페녹스술람 및 메페나세트의 적용에 의한 상승작용적 잡초 방제 |
CN105120661B (zh) | 2013-02-25 | 2018-08-07 | 美国陶氏益农公司 | 菠萝中的杂草防治方法 |
US9288989B2 (en) | 2013-02-25 | 2016-03-22 | Dow Agrosciences Llc | Synergistic weed control from applications of penoxsulam and acetochlor |
EP2967051B1 (en) | 2013-03-15 | 2018-08-08 | Dow AgroSciences LLC | Synergistic weed control from applications of penoxsulam and pethoxamid |
AU2014237409B2 (en) | 2013-03-15 | 2018-02-01 | Dow Agrosciences Llc | Synergistic weed control from applications of penoxsulam and benzobicyclon or clomazone and benzobicyclon |
CN103232453A (zh) * | 2013-04-18 | 2013-08-07 | 黑龙江大学 | 2-氨基-5,8-二甲氧基[1,2,4]-三唑并[1,5-c]-嘧啶的合成方法 |
CN104738060B (zh) * | 2013-04-28 | 2017-04-26 | 江苏龙灯化学有限公司 | 复配除草组合物 |
CN103229773B (zh) * | 2013-04-28 | 2015-06-17 | 江苏龙灯化学有限公司 | 一种复配除草组合物 |
CN103329911B (zh) * | 2013-06-25 | 2015-04-01 | 山东滨农科技有限公司 | 一种含有氯酯磺草胺和甲氧咪草烟的除草组合物 |
CN103392712B (zh) * | 2013-06-30 | 2016-04-06 | 广东中迅农科股份有限公司 | 含有噁嗪草酮和五氟磺草胺的除草组合物 |
CN103319489B (zh) * | 2013-07-12 | 2015-04-08 | 黑龙江大学 | 三唑并嘧啶磺酰胺化合物及合成方法和应用 |
CN103518747A (zh) * | 2013-09-12 | 2014-01-22 | 广东中迅农科股份有限公司 | 一种含五氟磺草胺与环酯草醚的除草组合物 |
RU2654634C2 (ru) | 2013-09-25 | 2018-05-21 | ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи | Способы борьбы с сорняками в цикории |
CN104094944B (zh) * | 2014-06-13 | 2016-08-24 | 广东中迅农科股份有限公司 | 一种含有氟丙嘧草酯和五氟磺草胺的除草组合物 |
CN107406450B (zh) * | 2015-03-10 | 2019-06-04 | 泸州东方农化有限公司 | 一种制备高纯度磺胺化合物的方法及其中间体 |
CN106916087B (zh) * | 2015-12-25 | 2018-08-14 | 沈阳化工研究院有限公司 | 一种2-氟-6-三氟甲基苯磺酰氯的合成方法 |
CN105399746B (zh) * | 2015-12-28 | 2017-11-07 | 黑龙江凯奥科技开发有限公司 | 三唑并嘧啶磺酰胺化合物、含有该化合物的组合物及其应用 |
CN106432067B (zh) * | 2016-09-18 | 2019-04-19 | 北京天弘天达医药科技有限公司 | 一种3-吡啶磺酰氯的绿色化学合成方法 |
GB2555635B (en) * | 2016-11-07 | 2022-04-13 | Rotam Agrochem Int Co Ltd | A novel form of penoxsulam, a process for its preparation and use of the same |
CN107668053A (zh) * | 2017-11-27 | 2018-02-09 | 浙江永太科技股份有限公司 | 一种含哒草特和五氟磺草胺的除草剂组合物 |
CN108395435B (zh) * | 2018-05-10 | 2021-02-05 | 深圳大学 | 三唑并嘧啶磺酰胺类化合物及其制备方法和应用 |
CN108558744A (zh) * | 2018-07-04 | 2018-09-21 | 常州大学 | 一种2-甲氧基-4-三氟甲基-3-吡啶磺酰氯的制备方法 |
CN108707109A (zh) * | 2018-08-29 | 2018-10-26 | 常州沃腾化工科技有限公司 | 一种2-甲氧基-4-三氟甲基吡啶-3-磺酰氯的制备方法 |
US12077505B2 (en) | 2018-12-27 | 2024-09-03 | Corteva Agriscience Llc | Preparation of sulfonamide herbicide process intermediates |
US11390587B2 (en) | 2018-12-27 | 2022-07-19 | Corteva Agriscience Llc | Preparation of sulfonamide herbicide process intermediates |
CN111217817B (zh) * | 2020-02-26 | 2022-06-10 | 山东潍坊润丰化工股份有限公司 | 一种三唑并嘧啶类除草剂的制备方法 |
CN112730689B (zh) * | 2020-12-29 | 2023-04-07 | 营口昌成新材料科技有限公司 | 2-氨基-5,8-二甲氧基[1,2,4]三唑并[1,5-c]嘧啶液相色谱分析方法 |
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BE758749A (fr) * | 1969-11-12 | 1971-05-10 | Ciba Geigy | Procede de preparation de nouveaux acides pyridine-sulfoniques |
US3787573A (en) * | 1970-03-18 | 1974-01-22 | R Mizzoni | Pyridine sulfonic acids as diuretics |
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US3671512A (en) * | 1970-04-01 | 1972-06-20 | Aba Gelgy Corp | 6-amino-3-pyridinesulfonamides |
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DE3539386A1 (de) * | 1985-11-04 | 1987-05-14 | Schering Ag | N-(s-triazolo(1,5-a)pyrimidin-2-yl)-2-alkoxy-benzolsulfonamide, verfahren zur herstellung dieser verbindungen sowie diese enthaltende mittel mit herbizider und pflanzenwachstumsregulierender wirkung |
EP0244948A3 (en) * | 1986-04-30 | 1989-03-15 | Schering Agrochemicals Limited | Triazolopyrimidine herbicides |
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US5272128A (en) * | 1992-04-01 | 1993-12-21 | Rohm And Haas Company | Phosphosulfonate herbicides |
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-
1997
- 1997-09-23 DE DE122009000052C patent/DE122009000052I2/de active Active
- 1997-09-23 CN CN97191491A patent/CN1092195C/zh not_active Expired - Lifetime
- 1997-09-23 AU AU47363/97A patent/AU723666B2/en not_active Expired
- 1997-09-23 CZ CZ0156398A patent/CZ297521B6/cs not_active IP Right Cessation
- 1997-09-23 HU HU0002072A patent/HU228039B1/hu unknown
- 1997-09-23 PL PL97327108A patent/PL190282B1/pl unknown
- 1997-09-23 JP JP51578798A patent/JP4215824B2/ja not_active Expired - Lifetime
- 1997-09-23 EA EA199800478A patent/EA001064B1/ru not_active IP Right Cessation
- 1997-09-23 UA UA98052683A patent/UA59350C2/uk unknown
- 1997-09-23 KR KR10-1998-0703833A patent/KR100488277B1/ko not_active IP Right Cessation
- 1997-09-23 CA CA002238316A patent/CA2238316C/en not_active Expired - Lifetime
- 1997-09-23 WO PCT/US1997/016867 patent/WO1998013367A1/en active IP Right Grant
- 1997-09-23 TR TR1998/00906T patent/TR199800906T1/xx unknown
- 1997-09-23 HU HU1200420A patent/HU229886B1/hu unknown
- 1997-09-23 AR ARP970104360A patent/AR012020A1/es active IP Right Grant
- 1997-09-23 CN CNB02118609XA patent/CN1159297C/zh not_active Expired - Lifetime
- 1997-09-23 BR BRPI9706774-1A patent/BR9706774B1/pt not_active IP Right Cessation
- 1997-09-23 DE DE69705821T patent/DE69705821T2/de not_active Expired - Lifetime
- 1997-09-23 EP EP97909857A patent/EP0877745B1/en not_active Expired - Lifetime
- 1997-09-23 US US08/936,046 patent/US5858924A/en not_active Expired - Lifetime
- 1997-09-23 DK DK97909857T patent/DK0877745T3/da active
- 1997-09-23 ES ES97909857T patent/ES2158513T3/es not_active Expired - Lifetime
- 1997-09-24 CO CO97055758A patent/CO4900002A1/es unknown
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1998
- 1998-05-22 BG BG102478A patent/BG63123B1/bg unknown
- 1998-07-31 US US09/127,378 patent/US6130335A/en not_active Expired - Lifetime
- 1998-07-31 US US09/127,384 patent/US5965490A/en not_active Expired - Lifetime
- 1998-07-31 US US09/127,328 patent/US6005108A/en not_active Expired - Lifetime
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2000
- 2000-03-16 US US09/527,857 patent/US6303814B1/en not_active Expired - Lifetime
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2001
- 2001-10-22 GR GR20010401831T patent/GR3036961T3/el unknown
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2008
- 2008-09-05 JP JP2008228377A patent/JP4958862B2/ja not_active Expired - Lifetime
- 2008-09-10 FR FR08C0037C patent/FR08C0037I2/fr active Active