FI102730B - Hyvän rikinsietokyvyn omaava hydrauskatalyytti - Google Patents
Hyvän rikinsietokyvyn omaava hydrauskatalyytti Download PDFInfo
- Publication number
- FI102730B FI102730B FI972545A FI972545A FI102730B FI 102730 B FI102730 B FI 102730B FI 972545 A FI972545 A FI 972545A FI 972545 A FI972545 A FI 972545A FI 102730 B FI102730 B FI 102730B
- Authority
- FI
- Finland
- Prior art keywords
- aluminum
- silica
- compound
- alumina
- silicon
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract description 91
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 239000011593 sulfur Substances 0.000 title claims description 54
- 229910052717 sulfur Inorganic materials 0.000 title claims description 54
- 230000036571 hydration Effects 0.000 title 1
- 238000006703 hydration reaction Methods 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 112
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 75
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 52
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 27
- 239000003570 air Substances 0.000 claims abstract description 22
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 21
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000001301 oxygen Substances 0.000 claims abstract description 6
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 6
- 239000002210 silicon-based material Substances 0.000 claims abstract description 5
- 150000002739 metals Chemical class 0.000 claims abstract description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 28
- 238000006243 chemical reaction Methods 0.000 claims description 26
- 150000003377 silicon compounds Chemical class 0.000 claims description 26
- -1 silicon alkoxides Chemical class 0.000 claims description 23
- 238000011282 treatment Methods 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 15
- 229910052710 silicon Inorganic materials 0.000 claims description 13
- 230000004048 modification Effects 0.000 claims description 11
- 238000012986 modification Methods 0.000 claims description 11
- 239000010703 silicon Substances 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 5
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000007858 starting material Substances 0.000 claims description 4
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical compound [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 claims description 3
- 150000002902 organometallic compounds Chemical class 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- VEJOYRPGKZZTJW-FDGPNNRMSA-N (z)-4-hydroxypent-3-en-2-one;platinum Chemical compound [Pt].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O VEJOYRPGKZZTJW-FDGPNNRMSA-N 0.000 claims description 2
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- JPUHCPXFQIXLMW-UHFFFAOYSA-N aluminium triethoxide Chemical compound CCO[Al](OCC)OCC JPUHCPXFQIXLMW-UHFFFAOYSA-N 0.000 claims description 2
- 239000005049 silicon tetrachloride Substances 0.000 claims description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 claims description 2
- 230000003197 catalytic effect Effects 0.000 claims 2
- 239000011248 coating agent Substances 0.000 claims 2
- 238000000576 coating method Methods 0.000 claims 2
- 238000000354 decomposition reaction Methods 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 230000000887 hydrating effect Effects 0.000 claims 1
- NWAHZABTSDUXMJ-UHFFFAOYSA-N platinum(2+);dinitrate Chemical compound [Pt+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O NWAHZABTSDUXMJ-UHFFFAOYSA-N 0.000 claims 1
- 238000004381 surface treatment Methods 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- 229910000510 noble metal Inorganic materials 0.000 description 26
- 239000000969 carrier Substances 0.000 description 20
- 229910021536 Zeolite Inorganic materials 0.000 description 16
- 239000010457 zeolite Substances 0.000 description 16
- 238000005470 impregnation Methods 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000012071 phase Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 9
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 8
- NOWPEMKUZKNSGG-UHFFFAOYSA-N azane;platinum(2+) Chemical compound N.N.N.N.[Pt+2] NOWPEMKUZKNSGG-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000007791 liquid phase Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000010970 precious metal Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- 229910002064 alloy oxide Inorganic materials 0.000 description 2
- 239000011959 amorphous silica alumina Substances 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000007792 gaseous phase Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002429 nitrogen sorption measurement Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 239000003784 tall oil Substances 0.000 description 2
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- ZYZCALPXKGUGJI-DDVDASKDSA-M (e,3r,5s)-7-[3-(4-fluorophenyl)-2-phenyl-5-propan-2-ylimidazol-4-yl]-3,5-dihydroxyhept-6-enoate Chemical compound C=1C=C(F)C=CC=1N1C(\C=C\[C@@H](O)C[C@@H](O)CC([O-])=O)=C(C(C)C)N=C1C1=CC=CC=C1 ZYZCALPXKGUGJI-DDVDASKDSA-M 0.000 description 1
- KZEVSDGEBAJOTK-UHFFFAOYSA-N 1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-2-[5-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]ethanone Chemical compound N1N=NC=2CN(CCC=21)C(CC=1OC(=NN=1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)=O KZEVSDGEBAJOTK-UHFFFAOYSA-N 0.000 description 1
- CZRCFAOMWRAFIC-UHFFFAOYSA-N 5-(tetradecyloxy)-2-furoic acid Chemical class CCCCCCCCCCCCCCOC1=CC=C(C(O)=O)O1 CZRCFAOMWRAFIC-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910002621 H2PtCl6 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- AJNVQOSZGJRYEI-UHFFFAOYSA-N digallium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ga+3].[Ga+3] AJNVQOSZGJRYEI-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005184 irreversible process Methods 0.000 description 1
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 150000002941 palladium compounds Chemical class 0.000 description 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 1
- 150000003058 platinum compounds Chemical class 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Peptides Or Proteins (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Road Signs Or Road Markings (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI972545A FI102730B (fi) | 1997-06-16 | 1997-06-16 | Hyvän rikinsietokyvyn omaava hydrauskatalyytti |
| JP50384399A JP4222637B2 (ja) | 1997-06-16 | 1998-06-16 | 高い耐硫化汚染性を有する水添触媒 |
| EP98925684A EP0993338B1 (en) | 1997-06-16 | 1998-06-16 | Use of catalyst with high sulphur tolerance for hydrogenation |
| CA002293649A CA2293649C (en) | 1997-06-16 | 1998-06-16 | Hydrogenation catalyst with high sulphur tolerance |
| AU77706/98A AU7770698A (en) | 1997-06-16 | 1998-06-16 | Hydrogenation catalyst with high sulphur tolerance |
| CN98808172A CN1104948C (zh) | 1997-06-16 | 1998-06-16 | 耐高含硫量的加氢催化剂 |
| PCT/FI1998/000521 WO1998057742A1 (en) | 1997-06-16 | 1998-06-16 | Hydrogenation catalyst with high sulphur tolerance |
| DE69839995T DE69839995D1 (de) | 1997-06-16 | 1998-06-16 | Verwendung eines katalysators mit hoher schwefeltoleranz zur hydrierung |
| AT98925684T ATE407734T1 (de) | 1997-06-16 | 1998-06-16 | Verwendung eines katalysators mit hoher schwefeltoleranz zur hydrierung |
| US09/446,035 US6288007B1 (en) | 1997-06-16 | 1998-06-16 | Hydrogenation catalyst with high sulphur tolerance |
| NO996220A NO996220L (no) | 1997-06-16 | 1999-12-15 | Hydrogeneringskatalysator med høy svoveltoleranse |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI972545A FI102730B (fi) | 1997-06-16 | 1997-06-16 | Hyvän rikinsietokyvyn omaava hydrauskatalyytti |
| FI972545 | 1997-06-16 |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI972545A0 FI972545A0 (fi) | 1997-06-16 |
| FI972545L FI972545L (fi) | 1998-12-17 |
| FI102730B1 FI102730B1 (fi) | 1999-02-15 |
| FI102730B true FI102730B (fi) | 1999-02-15 |
Family
ID=8549058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI972545A FI102730B (fi) | 1997-06-16 | 1997-06-16 | Hyvän rikinsietokyvyn omaava hydrauskatalyytti |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6288007B1 (enExample) |
| EP (1) | EP0993338B1 (enExample) |
| JP (1) | JP4222637B2 (enExample) |
| CN (1) | CN1104948C (enExample) |
| AT (1) | ATE407734T1 (enExample) |
| AU (1) | AU7770698A (enExample) |
| CA (1) | CA2293649C (enExample) |
| DE (1) | DE69839995D1 (enExample) |
| FI (1) | FI102730B (enExample) |
| NO (1) | NO996220L (enExample) |
| WO (1) | WO1998057742A1 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7226884B2 (en) * | 2002-02-07 | 2007-06-05 | China Petroleum & Chemical Corporation | Composite for catalytic distillation and its preparation |
| JP2005218958A (ja) * | 2004-02-05 | 2005-08-18 | Tottori Univ | 芳香族化合物の水素化反応触媒および芳香族化合物の水素化方法 |
| US7462338B2 (en) * | 2004-12-28 | 2008-12-09 | Umicore Ag & Co. Kg | Boron-alumina catalyst support |
| CA2665177C (en) * | 2006-10-06 | 2016-10-25 | W.R. Grace & Co.-Conn. | Sulfur tolerant alumina catalyst support |
| CA2665997C (en) | 2006-10-06 | 2016-11-08 | W.R. Grace & Co.-Conn. | Sulfur tolerant alumina catalyst support |
| US20090098032A1 (en) * | 2007-10-11 | 2009-04-16 | Basf Catalysts Llc | Methods of making aluminosilicate coated alumina |
| US9365664B2 (en) | 2009-01-29 | 2016-06-14 | W. R. Grace & Co. -Conn. | Catalyst on silica clad alumina support |
| CA2750535A1 (en) * | 2009-01-29 | 2010-08-05 | W.R. Grace & Co.-Conn. | Catalyst on silica clad alumina support |
| US9409149B2 (en) | 2009-10-08 | 2016-08-09 | W. R. Grace & Co.-Conn. | Sulfur resistant cladded titania—alumina supports |
| US9303096B2 (en) | 2010-04-20 | 2016-04-05 | Rhodia Operations | Expandable elastomeric material in the presence of water or oil |
| KR20130120487A (ko) * | 2010-11-16 | 2013-11-04 | 로디아 오퍼레이션스 | 내황성 알루미나 촉매 지지체 |
| CN103071491B (zh) * | 2011-10-26 | 2015-03-11 | 中国石油化工股份有限公司 | 具有大比表面和低酸量的加氢催化剂及其应用 |
| KR101375541B1 (ko) | 2012-02-02 | 2014-03-26 | 희성촉매 주식회사 | 알루미나 지지체로의 촉매 활성성분 열적 고정 공정 개선 |
| JP6444265B2 (ja) * | 2014-06-02 | 2018-12-26 | 株式会社豊田中央研究所 | 排ガス浄化触媒、その製造方法、及び、それを用いた排ガス浄化方法 |
| US10227535B2 (en) | 2014-06-09 | 2019-03-12 | Exxonmobil Research And Engineering Company | Method and system for producing low aromatic hydrocarbon products |
| US10023814B2 (en) * | 2014-06-09 | 2018-07-17 | Exxonmobil Research And Engineering Company | Noble metal hydrogenation catalysts with low cracking activity |
| US10227539B2 (en) * | 2014-06-09 | 2019-03-12 | Exxonmobil Research And Engineering Company | Noble metal hydrogenation catalysts and aromatic saturation methods |
| US11426717B2 (en) | 2014-11-17 | 2022-08-30 | The Regents Of The University Of Colorado, A Body Corporate | Catalyst, structures, reactors, and methods of forming same |
| CN106607066B (zh) * | 2015-10-23 | 2019-10-18 | 上海浦景化工技术股份有限公司 | 一种用于加氢制乙醛的催化剂及其制备方法和应用 |
| EP3478799B1 (en) | 2016-06-30 | 2021-04-28 | ExxonMobil Research and Engineering Company | Method for producing a lubricant |
| CN115920950B (zh) * | 2021-08-23 | 2024-06-14 | 中国石油化工股份有限公司 | 一种低生焦多产btx的催化裂化催化剂制备方法 |
| EP4527499A1 (en) | 2023-09-19 | 2025-03-26 | Indian Oil Corporation Limited | A catalyst for hydrogenation of unsaturated hydrocarbons and a method for preparation thereof |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB790476A (en) * | 1953-04-27 | 1958-02-12 | Socony Mobil Oil Co Inc | Catalytic reforming |
| BE642626A (enExample) * | 1963-04-11 | |||
| US3657153A (en) * | 1969-04-08 | 1972-04-18 | Inst De Cercetari Pentru Prelu | Process for the preparation of a catalyst for the reforming and aromatization of benzines |
| US3703461A (en) * | 1971-07-16 | 1972-11-21 | Union Oil Co | Hydrogenation process and catalyst |
| IT1001614B (it) | 1973-10-31 | 1976-04-30 | Snam Progetti | Procedimento per preparare materia li aventi proprieta meccaniche e termiche migliorate e materiali ottenuti |
| DE2617287A1 (de) * | 1976-04-21 | 1977-11-03 | Masljanskij | Katalysator zum hydrieren aromatischer kohlenwasserstoffe |
| US4538008A (en) * | 1982-11-10 | 1985-08-27 | Uop Inc. | Preparation of ortho-alkylated phenols |
| US4677095A (en) * | 1985-01-31 | 1987-06-30 | Engelhard Corporation | Stabilized alumina catalyst support coatings |
| CA1276002C (en) * | 1985-12-31 | 1990-11-06 | Lawrence L. Murrell | Catalysts comprising silica supported on alumina their preparation and use |
| US4721696A (en) * | 1987-03-11 | 1988-01-26 | Phillips Petroleum Company | Silica-modified alumina and process for its preparation |
| US4966682A (en) * | 1989-07-03 | 1990-10-30 | Exxon Research & Engineering Company | Reforming with modified alumina catalysts |
| FI84562C (fi) * | 1990-01-16 | 1991-12-27 | Neste Oy | Foerfarande och anordning foer framstaellning av heterogena katalysatorer. |
| FI87892C (fi) * | 1991-07-16 | 1993-03-10 | Neste Oy | Foerfarande foer framstaellning av heterogena katalysatorer med oenskad metallhalt |
| US5114562A (en) | 1990-08-03 | 1992-05-19 | Uop | Two-stage hydrodesulfurization and hydrogenation process for distillate hydrocarbons |
| IT1247813B (it) * | 1991-01-25 | 1995-01-02 | Ausimont Spa | Processo per la preparazione di peraloolefine |
| US5183556A (en) | 1991-03-13 | 1993-02-02 | Abb Lummus Crest Inc. | Production of diesel fuel by hydrogenation of a diesel feed |
| IT1252323B (it) * | 1991-07-18 | 1995-06-08 | Snam Progetti | Catalizzatore ottenuto mediante un particolare procedimento di preparazione e suo impiego in un procedimento per produrre olefine terziarie a partire da alchil-ter-alchil-eteri. |
| CN1087618A (zh) * | 1992-12-02 | 1994-06-08 | 华东化工学院 | 丙二醇醚合成催化精馏工艺 |
| DE69403885T2 (de) * | 1993-12-24 | 1998-01-29 | Mitsubishi Chem Corp | Verfahren zur Herstellung von Cycloolefinen |
| US5520799A (en) | 1994-09-20 | 1996-05-28 | Mobil Oil Corporation | Distillate upgrading process |
| IT1292390B1 (it) * | 1997-06-20 | 1999-02-08 | Snam Progetti | Sistema catalitico e procedimento per deidrogenare l'etilbenzene a stirene |
-
1997
- 1997-06-16 FI FI972545A patent/FI102730B/fi active
-
1998
- 1998-06-16 CA CA002293649A patent/CA2293649C/en not_active Expired - Fee Related
- 1998-06-16 US US09/446,035 patent/US6288007B1/en not_active Expired - Fee Related
- 1998-06-16 DE DE69839995T patent/DE69839995D1/de not_active Expired - Fee Related
- 1998-06-16 JP JP50384399A patent/JP4222637B2/ja not_active Expired - Fee Related
- 1998-06-16 CN CN98808172A patent/CN1104948C/zh not_active Expired - Fee Related
- 1998-06-16 AT AT98925684T patent/ATE407734T1/de not_active IP Right Cessation
- 1998-06-16 EP EP98925684A patent/EP0993338B1/en not_active Expired - Lifetime
- 1998-06-16 AU AU77706/98A patent/AU7770698A/en not_active Abandoned
- 1998-06-16 WO PCT/FI1998/000521 patent/WO1998057742A1/en not_active Ceased
-
1999
- 1999-12-15 NO NO996220A patent/NO996220L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| FI972545L (fi) | 1998-12-17 |
| NO996220D0 (no) | 1999-12-15 |
| EP0993338A1 (en) | 2000-04-19 |
| FI102730B1 (fi) | 1999-02-15 |
| JP4222637B2 (ja) | 2009-02-12 |
| US6288007B1 (en) | 2001-09-11 |
| DE69839995D1 (de) | 2008-10-23 |
| JP2002504857A (ja) | 2002-02-12 |
| CA2293649C (en) | 2007-10-02 |
| EP0993338B1 (en) | 2008-09-10 |
| NO996220L (no) | 1999-12-15 |
| CA2293649A1 (en) | 1998-12-23 |
| CN1267233A (zh) | 2000-09-20 |
| WO1998057742A1 (en) | 1998-12-23 |
| CN1104948C (zh) | 2003-04-09 |
| ATE407734T1 (de) | 2008-09-15 |
| FI972545A0 (fi) | 1997-06-16 |
| AU7770698A (en) | 1999-01-04 |
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