ES2536678T3 - Método de oxidación selectiva de hidratos de carbono mediante el uso de catalizadores de oro soportados - Google Patents

Método de oxidación selectiva de hidratos de carbono mediante el uso de catalizadores de oro soportados Download PDF

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Publication number
ES2536678T3
ES2536678T3 ES10011677.1T ES10011677T ES2536678T3 ES 2536678 T3 ES2536678 T3 ES 2536678T3 ES 10011677 T ES10011677 T ES 10011677T ES 2536678 T3 ES2536678 T3 ES 2536678T3
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ES
Spain
Prior art keywords
carbohydrates
selective oxidation
supported gold
gold catalysts
carbohydrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES10011677.1T
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English (en)
Inventor
Jörg Kowalczyk
Alireza Haji Begli
Ulf PRÜSSE
Heinz Berndt
Irene Pitsch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suedzucker AG
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Suedzucker AG
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Publication of ES2536678T3 publication Critical patent/ES2536678T3/es
Anticipated expiration legal-status Critical
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Saccharide Compounds (AREA)

Abstract

Método de oxidación selectiva de al menos un oligosacárido, de una mezcla de ellos o de una composición que lo(s) contiene, haciendo reaccionar con oxígeno una solución acuosa del oligosacárido, de la mezcla o de la composición en presencia de un catalizador de oro formado por partículas de oro nanodispersas distribuidas sobre un soporte de carbono, de modo que un grupo aldehído existente en el átomo de carbono C1 del o de los hidratos de carbono se oxida selectivamente a un grupo carboxilo o bien un grupo aldehído introducido en el átomo de carbono C1 de una 2-cetosa se oxida selectivamente a grupo carboxilo.

Description

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Claims (1)

  1. imagen1
ES10011677.1T 2003-05-05 2004-05-04 Método de oxidación selectiva de hidratos de carbono mediante el uso de catalizadores de oro soportados Expired - Lifetime ES2536678T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10319917 2003-05-05
DE10319917A DE10319917B4 (de) 2003-05-05 2003-05-05 Verfahren zur selektiven Kohlenhydrat-Oxidation unter Verwendung geträgerter Gold-Katalysatoren

Publications (1)

Publication Number Publication Date
ES2536678T3 true ES2536678T3 (es) 2015-05-27

Family

ID=33426669

Family Applications (2)

Application Number Title Priority Date Filing Date
ES10011677.1T Expired - Lifetime ES2536678T3 (es) 2003-05-05 2004-05-04 Método de oxidación selectiva de hidratos de carbono mediante el uso de catalizadores de oro soportados
ES04730988T Expired - Lifetime ES2373441T3 (es) 2003-05-05 2004-05-04 Método de oxidación selectiva de hidratos de carbono mediante el uso de catalizadores de oro soportados.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES04730988T Expired - Lifetime ES2373441T3 (es) 2003-05-05 2004-05-04 Método de oxidación selectiva de hidratos de carbono mediante el uso de catalizadores de oro soportados.

Country Status (13)

Country Link
US (1) US7982031B2 (es)
EP (2) EP1631537B1 (es)
JP (3) JP4838115B2 (es)
CN (1) CN1816516B (es)
AT (1) ATE525343T1 (es)
AU (2) AU2004235932B2 (es)
BR (1) BRPI0410059B1 (es)
DE (2) DE10319917B4 (es)
ES (2) ES2536678T3 (es)
NZ (2) NZ543384A (es)
PL (1) PL1631537T3 (es)
RU (1) RU2345059C2 (es)
WO (1) WO2004099114A1 (es)

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DE10319917B4 (de) * 2003-05-05 2009-01-02 Südzucker AG Mannheim/Ochsenfurt Verfahren zur selektiven Kohlenhydrat-Oxidation unter Verwendung geträgerter Gold-Katalysatoren
WO2005070534A1 (en) 2004-01-22 2005-08-04 Indian Institute Of Technology Adsorbent composition, a device and a method for decontaminating water containing pesticides
DE102005036890A1 (de) * 2005-08-05 2007-02-08 Südzucker AG Mannheim/Ochsenfurt Geträgerter Goldkatalysator
DE102007005528A1 (de) * 2007-02-03 2008-08-07 Südzucker AG Mannheim/Ochsenfurt Kohlenstoff-geträgerter Goldkatalysator
WO2008100228A1 (en) * 2007-02-13 2008-08-21 Agency For Science, Technology And Research Process for removing organic contaminants from aqueous media
DE102007017179A1 (de) * 2007-04-12 2008-10-23 Clariant International Ltd. Verfahren zur Herstellung von Alkylpolyglykolcarbonsäuren und Polyglykoldicarbonsäuren mittels Direktoxidation
EP2155650A2 (en) * 2007-06-05 2010-02-24 DSM IP Assets B.V. Novel reaction with a gold catalyst
JP5136017B2 (ja) * 2007-11-21 2013-02-06 住友化学株式会社 シクロアルカノール及び／又はシクロアルカノンの製造方法
DE102008053607A1 (de) * 2008-10-20 2010-04-22 Südzucker AG Mannheim/Ochsenfurt Solubilisierungsmittel für Metallionen
EP2204098A1 (en) 2008-12-19 2010-07-07 Südzucker Aktiengesellschaft Mannheim/Ochsenfurt Flavour enhancer
CN101591233B (zh) * 2009-06-19 2012-06-27 厦门大学 葡萄糖酸的制备方法
US9770705B2 (en) * 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
RU2468861C1 (ru) * 2011-05-04 2012-12-10 Государственное образовательное учреждение высшего профессионального образования "Юго-Западный государственный университет" (ЮЗГУ) Способ получения катализатора на пористом металлооксидном носителе для окисления углеводов
JP6086530B2 (ja) * 2012-02-17 2017-03-01 国立大学法人北陸先端科学技術大学院大学 Ｄ−グルコサミン酸又はその類縁体の製造方法、並びにそのための触媒組成物
CA2869649C (en) * 2012-04-04 2019-01-29 Stichting Dienst Landbouwkundig Onderzoek Catalytic oxidation of uronic acids to aldaric acids
EP2692843A1 (en) 2012-08-03 2014-02-05 Tiense Suikerraffinaderij N.V. Use of C1-oxidised starch hydrolysates
CN102875612A (zh) * 2012-10-12 2013-01-16 兰溪市苏格生物技术有限公司 催化氧化制备乳糖酸及乳糖酸盐的方法
FR3012347B1 (fr) 2013-10-30 2015-12-11 Commissariat Energie Atomique Complexes organo-metalliques a base d'iridium a titre de catalyseurs d'oxydation
KR101679914B1 (ko) * 2014-08-18 2016-11-25 현대자동차주식회사 글루카릭산 제조법
JP6789736B2 (ja) * 2016-09-07 2020-11-25 サンエイ糖化株式会社 ニッケル触媒を用いた糖カルボン酸の製造方法
US11123711B2 (en) 2017-12-28 2021-09-21 University Of Kentucky Research Foundation System and method for alcohol oxidation reaction of lignins
CN109382098A (zh) * 2018-10-31 2019-02-26 华南理工大学 一种Au@介孔氧化铝类蛋黄壳结构催化剂及其制备与应用
MX2021014482A (es) * 2019-05-28 2022-02-11 Dfi Usa Llc Métodos para la producción de sales de calcio, magnesio y zinc de azúcares ácidos.
US20220306563A1 (en) * 2019-06-27 2022-09-29 Rhodia Operations Method for preparing glycolic acid
BR112022017484A2 (pt) * 2020-03-06 2022-11-16 Solugen Inc Processo quimioenzimático para a preparação de um produto de glicose oxidada, processos quimioenzimáticos para a produção de ácido glucárico e para a produção de d-glucono-¿-1,5-lactona, e, processo de fabricação
CN112110961A (zh) * 2020-09-27 2020-12-22 山东齐都药业有限公司 葡萄糖酸钙中杂质的制备方法
CN114425444B (zh) * 2020-10-14 2024-01-26 中国石油化工股份有限公司 乙烯法合成醋酸乙烯催化剂及其制备方法
CN115806537B (zh) * 2021-09-13 2024-09-24 中国石油化工股份有限公司 一种制备糠酸的方法
EP4223882A1 (en) 2022-02-02 2023-08-09 Vilnius University Process for producing aldonic acids
CN115990485B (zh) * 2023-03-23 2023-07-14 农业农村部环境保护科研监测所 一种糖酸合成用双金属复合生物炭催化剂及糖酸合成方法和应用

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IT1313696B1 (it) * 1999-12-16 2002-09-09 Lonza Spa Procedimento per la produzione di acidi aldonici particolarmenteidonei come additivi alimentari.
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Also Published As

Publication number Publication date
JP2011236215A (ja) 2011-11-24
BRPI0410059A (pt) 2006-05-23
US20070112186A1 (en) 2007-05-17
DE10362249A1 (de) 2008-04-30
ATE525343T1 (de) 2011-10-15
EP1631537A1 (de) 2006-03-08
CN1816516B (zh) 2010-05-12
NZ585754A (en) 2011-12-22
EP1631537B1 (de) 2011-09-21
DE10362249B4 (de) 2014-05-15
DE10319917B4 (de) 2009-01-02
JP2010159280A (ja) 2010-07-22
DE10319917A1 (de) 2004-12-09
AU2010202821B2 (en) 2012-03-15
US7982031B2 (en) 2011-07-19
AU2004235932B2 (en) 2010-08-19
AU2004235932A1 (en) 2004-11-18
CN1816516A (zh) 2006-08-09
RU2345059C2 (ru) 2009-01-27
BRPI0410059B1 (pt) 2014-10-29
EP2332900B1 (de) 2015-02-25
NZ543384A (en) 2010-08-27
EP2332900A1 (de) 2011-06-15
ES2373441T3 (es) 2012-02-03
PL1631537T3 (pl) 2012-02-29
RU2005137687A (ru) 2006-04-27
JP4838115B2 (ja) 2011-12-14
JP5444054B2 (ja) 2014-03-19
WO2004099114A1 (de) 2004-11-18
WO2004099114A8 (de) 2005-02-24
AU2010202821A1 (en) 2010-07-22
JP2006525272A (ja) 2006-11-09

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