ES2276182T5 - Composición adhesiva epoxídica - Google Patents
Composición adhesiva epoxídica Download PDFInfo
- Publication number
- ES2276182T5 ES2276182T5 ES04005984.2T ES04005984T ES2276182T5 ES 2276182 T5 ES2276182 T5 ES 2276182T5 ES 04005984 T ES04005984 T ES 04005984T ES 2276182 T5 ES2276182 T5 ES 2276182T5
- Authority
- ES
- Spain
- Prior art keywords
- component
- weight
- acrylonitrile
- composition according
- epoxy adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 70
- 229920006332 epoxy adhesive Polymers 0.000 title claims abstract description 44
- 239000003822 epoxy resin Substances 0.000 claims abstract description 25
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 25
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 17
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004848 polyfunctional curative Substances 0.000 claims description 6
- 235000013824 polyphenols Nutrition 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 claims description 3
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical group 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 239000012745 toughening agent Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 description 13
- 230000001070 adhesive effect Effects 0.000 description 13
- 239000000047 product Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 239000010959 steel Substances 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 7
- 239000005060 rubber Substances 0.000 description 7
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 6
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 239000004823 Reactive adhesive Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000004841 bisphenol A epoxy resin Substances 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 239000002436 steel type Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QIRNGVVZBINFMX-UHFFFAOYSA-N 2-allylphenol Chemical compound OC1=CC=CC=C1CC=C QIRNGVVZBINFMX-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- -1 aliphatic diols Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000007725 thermal activation Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04005984.2A EP1574537B2 (en) | 2004-03-12 | 2004-03-12 | Epoxy adhesive composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2276182T3 ES2276182T3 (es) | 2007-06-16 |
| ES2276182T5 true ES2276182T5 (es) | 2015-04-10 |
Family
ID=34814318
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES04005984.2T Expired - Lifetime ES2276182T5 (es) | 2004-03-12 | 2004-03-12 | Composición adhesiva epoxídica |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7910656B2 (enExample) |
| EP (1) | EP1574537B2 (enExample) |
| JP (1) | JP5102018B2 (enExample) |
| KR (1) | KR101151092B1 (enExample) |
| CN (1) | CN1930206B (enExample) |
| AT (1) | ATE352576T1 (enExample) |
| BR (1) | BRPI0506523B1 (enExample) |
| CA (1) | CA2553251A1 (enExample) |
| DE (1) | DE602004004501T3 (enExample) |
| ES (1) | ES2276182T5 (enExample) |
| WO (1) | WO2005095484A1 (enExample) |
Families Citing this family (87)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1431325A1 (de) * | 2002-12-17 | 2004-06-23 | Sika Technology AG | Hitze-härtbare Epoxidharzzusammensetzung mit verbesserter Tieftemperatur-Schlagzähigkeit |
| US7125461B2 (en) | 2003-05-07 | 2006-10-24 | L & L Products, Inc. | Activatable material for sealing, baffling or reinforcing and method of forming same |
| US7199165B2 (en) | 2003-06-26 | 2007-04-03 | L & L Products, Inc. | Expandable material |
| US7557168B2 (en) * | 2003-07-07 | 2009-07-07 | Dow Global Technologies, Inc. | Applying adhesive stream of epoxy resin, rubber modified epoxy resin and capped isocyanate prepolymer |
| CA2529737C (en) * | 2003-07-07 | 2013-05-07 | Dow Global Technologies Inc. | Adhesive epoxy composition and process for applying it |
| EP1498441A1 (de) * | 2003-07-16 | 2005-01-19 | Sika Technology AG | Hitzehärtende Zusammensetzungen mit Tieftemperatur-Schlagzähigkeitsmodifikatoren |
| EP1602702B2 (en) * | 2004-06-01 | 2020-09-16 | Dow Global Technologies LLC | Epoxy adhesive composition |
| US8070994B2 (en) | 2004-06-18 | 2011-12-06 | Zephyros, Inc. | Panel structure |
| EP1695990A1 (en) * | 2005-02-28 | 2006-08-30 | Dow Global Technologies Inc. | Two-component epoxy adhesive composition |
| EP1728825B2 (en) * | 2005-06-02 | 2013-10-23 | Dow Global Technologies LLC | Toughened structural epoxy adhesive |
| EP1741734A1 (de) * | 2005-07-05 | 2007-01-10 | Sika Technology AG | Tieftemperaturschlagzähe hitze-härtbare Epoxidharzzusammensetzung mit Epoxidfestharzen |
| KR101303246B1 (ko) * | 2005-08-24 | 2013-09-06 | 헨켈 아일랜드 리미티드 | 개선된 내충격성을 갖는 에폭시 조성물 |
| EP1876194A1 (de) * | 2006-06-30 | 2008-01-09 | Sika Technology AG | Hitzehärtende Zusammensetzung geeignet zum Verkleben von beschichteten Substraten |
| KR101352811B1 (ko) | 2006-07-31 | 2014-02-17 | 헨켈 아게 운트 코. 카게아아 | 경화성 에폭시 수지-기재 접착성 조성물 |
| CA2665551A1 (en) | 2006-10-06 | 2008-04-17 | Henkel Ag & Co. Kgaa | Pumpable epoxy paste adhesives resistant to wash-off |
| EP1916272A1 (de) * | 2006-10-24 | 2008-04-30 | Sika Technology AG | Hitzehärtende Epoxidharzzusammensetzung enthaltend ein blockiertes und ein epoxidterminiertes Polyurethanprepolymer |
| DE602007010346D1 (de) * | 2006-12-21 | 2010-12-16 | Dow Global Technologies Inc | Zusammensetzung, die zur verwendung als klebstoff beim einbau von fahrzeugfenstern brauchbar ist |
| US8088245B2 (en) * | 2007-04-11 | 2012-01-03 | Dow Global Technologies Llc | Structural epoxy resins containing core-shell rubbers |
| US8097119B2 (en) * | 2007-04-11 | 2012-01-17 | Dow Global Technologies Llc | Heat-resistant structural epoxy resins |
| PT2160435E (pt) * | 2007-06-12 | 2012-02-08 | Zephyros Inc | Material adesivo endurecido |
| CN101679579B (zh) * | 2007-06-20 | 2012-05-30 | 陶氏环球技术公司 | 对温度变化的敏感性非常低的耐碰撞环氧粘合剂 |
| KR101572276B1 (ko) * | 2007-07-23 | 2015-11-26 | 다우 글로벌 테크놀로지스 엘엘씨 | 사용 온도 범위에 걸쳐 실질적으로 일정한 ｇ-계수를 갖는 2 부분 폴리우레탄 경화성 조성물 |
| EP2181156A1 (en) * | 2007-08-17 | 2010-05-05 | Dow Global Technologies Inc. | Two part crash durable epoxy adhesives |
| EP2205692B1 (en) * | 2007-10-30 | 2020-02-19 | Henkel AG & Co. KGaA | Epoxy paste adhesives resistant to wash-off |
| EP2085426B1 (de) * | 2008-01-30 | 2010-10-13 | Sika Technology AG | Auswaschbeständige hitzehärtende Epoxidharzklebstoffe |
| JP2011519978A (ja) * | 2008-03-26 | 2011-07-14 | ロード コーポレイション | エラストマー基体のための塗料 |
| GB0806434D0 (en) | 2008-04-09 | 2008-05-14 | Zephyros Inc | Improvements in or relating to structural adhesives |
| WO2010019539A2 (en) * | 2008-08-11 | 2010-02-18 | Dow Global Technologies Inc. | One-part structural epoxy resin adhesives containing elastomeric tougheners capped with phenols and hydroxy-terminated acrylates or hydroxy-terminated methacrylates |
| WO2010021793A1 (en) * | 2008-08-22 | 2010-02-25 | Dow Global Technologies Inc. | Adhesive composition adapted for bonding large mass parts to structures |
| BRPI1005818A2 (pt) | 2009-02-26 | 2016-03-08 | Dow Global Technologies Llc | adesivo estrutural monocomponente e método de aplicação de adesivo estrutural |
| KR101093348B1 (ko) * | 2009-08-17 | 2011-12-14 | 헨켈테크놀러지스 (유) | 접착용 다기능 처리제 및 이를 이용한 신발의 제조방법 |
| KR20110018061A (ko) | 2009-08-17 | 2011-02-23 | 헨켈테크놀러지스 (유) | 접착용 다기능 처리제를 이용한 신발의 제조방법 |
| GB0916205D0 (en) | 2009-09-15 | 2009-10-28 | Zephyros Inc | Improvements in or relating to cavity filling |
| JP5715638B2 (ja) | 2009-11-05 | 2015-05-13 | ダウ グローバル テクノロジーズ エルエルシー | ケトオキシムでキャップされたエラストマー強化剤を含む構造用エポキシ樹脂系接着剤 |
| WO2011109699A1 (en) | 2010-03-04 | 2011-09-09 | Zephyros, Inc. | Structural composite laminate |
| WO2012000171A1 (en) | 2010-06-29 | 2012-01-05 | Dow Global Technologies Llc | Storage-stable heat-activated tertiary amine catalysts for epoxy resins |
| EP2588554B1 (en) | 2010-06-29 | 2014-11-19 | Dow Global Technologies LLC | Storage-stable heat-activated tertiary amine catalysts for epoxy resins |
| US8440746B2 (en) | 2010-12-02 | 2013-05-14 | Ppg Industries Ohio, Inc | One component epoxy structural adhesive composition prepared from renewable resources |
| US9074040B2 (en) * | 2010-12-20 | 2015-07-07 | Mitsui Chemicals, Inc. | Curable adhesive compositions |
| CN103180400B (zh) | 2010-12-26 | 2016-08-17 | 陶氏环球技术有限责任公司 | 含有用酚、多酚或氨基酚化合物封端的扩链弹性体增韧剂的结构环氧树脂粘合剂 |
| KR101378817B1 (ko) | 2011-10-14 | 2014-04-03 | 주식회사 엘지화학 | 편광판용 접착제 및 이를 포함하는 편광판 |
| CN104136516B (zh) | 2012-03-23 | 2016-06-01 | 陶氏环球技术有限责任公司 | 阻燃结构环氧树脂粘合剂以及粘合金属构件的方法 |
| WO2013142750A2 (en) | 2012-03-23 | 2013-09-26 | Dow Global Technologies Llc | Crash-durable adhesive with enhanced stress durability |
| EP2730594A1 (de) | 2012-11-12 | 2014-05-14 | Sika Technology AG | Reaktive Flüssigkautschuke aus blockierten Isocyanat-terminierten Präpolymeren mit Glycolfänger |
| WO2014072515A1 (de) | 2012-11-12 | 2014-05-15 | Sika Technology Ag | Neue schlagzähigkeitsmodifikatoren für epoxy-basierte klebstoffe |
| US10577522B2 (en) | 2013-07-26 | 2020-03-03 | Zephyros, Inc. | Thermosetting adhesive films including a fibrous carrier |
| US20170107408A1 (en) * | 2014-07-08 | 2017-04-20 | Dow Europe Gmbh | DELAYED CURING HIGH Tg CRASH DURABLE ADHESIVE |
| WO2016014284A1 (en) | 2014-07-23 | 2016-01-28 | Dow Global Technologies Llc | Structural adhesives having improved wash-off resistance and method for dispensing same |
| GB201417985D0 (en) | 2014-10-10 | 2014-11-26 | Zephyros Inc | Improvements in or relating to structural adhesives |
| EP3218433A1 (en) * | 2014-11-11 | 2017-09-20 | Dow Global Technologies LLC | Adhesive composition with glass spheres |
| WO2016108958A1 (en) | 2014-12-31 | 2016-07-07 | Dow Global Technologies Llc | Crash durable epoxy adhesive compositions having improved low-temperature impact resistance and wash off resistance |
| US10081704B2 (en) | 2015-03-24 | 2018-09-25 | Evonik Degussa Gmbh | Epoxy systems having improved fracture toughness |
| WO2016196448A1 (en) * | 2015-06-02 | 2016-12-08 | Dow Global Technologies Llc | Blocked polyurethane tougheners for epoxy adhesives |
| JP2017031264A (ja) * | 2015-07-30 | 2017-02-09 | デンカ株式会社 | 組成物 |
| JP6886455B2 (ja) | 2015-09-10 | 2021-06-16 | ダウ グローバル テクノロジーズ エルエルシー | 改良された油性表面への接着および高いウォッシュオフ耐性を持つ、一液型の強靭化エポキシ接着剤 |
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-
2004
- 2004-03-12 AT AT04005984T patent/ATE352576T1/de not_active IP Right Cessation
- 2004-03-12 ES ES04005984.2T patent/ES2276182T5/es not_active Expired - Lifetime
- 2004-03-12 EP EP04005984.2A patent/EP1574537B2/en not_active Expired - Lifetime
- 2004-03-12 DE DE602004004501.2T patent/DE602004004501T3/de not_active Expired - Lifetime
-
2005
- 2005-03-07 BR BRPI0506523-2A patent/BRPI0506523B1/pt not_active IP Right Cessation
- 2005-03-07 CA CA002553251A patent/CA2553251A1/en not_active Abandoned
- 2005-03-07 JP JP2007502252A patent/JP5102018B2/ja not_active Expired - Fee Related
- 2005-03-07 CN CN2005800073567A patent/CN1930206B/zh not_active Expired - Lifetime
- 2005-03-07 WO PCT/EP2005/002361 patent/WO2005095484A1/en not_active Ceased
- 2005-03-07 KR KR1020067018504A patent/KR101151092B1/ko not_active Expired - Lifetime
- 2005-03-11 US US11/078,088 patent/US7910656B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP1574537B2 (en) | 2014-12-24 |
| EP1574537B1 (en) | 2007-01-24 |
| US20050209401A1 (en) | 2005-09-22 |
| ES2276182T3 (es) | 2007-06-16 |
| JP2007528923A (ja) | 2007-10-18 |
| DE602004004501D1 (de) | 2007-03-15 |
| CN1930206B (zh) | 2011-05-18 |
| KR20070021152A (ko) | 2007-02-22 |
| BRPI0506523B1 (pt) | 2021-10-13 |
| CN1930206A (zh) | 2007-03-14 |
| KR101151092B1 (ko) | 2012-06-01 |
| BRPI0506523A (pt) | 2007-02-27 |
| WO2005095484A1 (en) | 2005-10-13 |
| ATE352576T1 (de) | 2007-02-15 |
| EP1574537A1 (en) | 2005-09-14 |
| CA2553251A1 (en) | 2005-10-13 |
| DE602004004501T3 (de) | 2015-05-28 |
| US7910656B2 (en) | 2011-03-22 |
| JP5102018B2 (ja) | 2012-12-19 |
| DE602004004501T2 (de) | 2007-11-15 |
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