ES2231225T3 - Mezclas de polimeros con resistencia al impacto mejorada. - Google Patents
Mezclas de polimeros con resistencia al impacto mejorada.Info
- Publication number
- ES2231225T3 ES2231225T3 ES00949448T ES00949448T ES2231225T3 ES 2231225 T3 ES2231225 T3 ES 2231225T3 ES 00949448 T ES00949448 T ES 00949448T ES 00949448 T ES00949448 T ES 00949448T ES 2231225 T3 ES2231225 T3 ES 2231225T3
- Authority
- ES
- Spain
- Prior art keywords
- alkyl
- group
- composition according
- polymer
- glycidyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 111
- 229920000642 polymer Polymers 0.000 title claims abstract description 83
- -1 polyphenylene Polymers 0.000 claims abstract description 119
- 229920001577 copolymer Polymers 0.000 claims abstract description 66
- 239000004952 Polyamide Substances 0.000 claims abstract description 63
- 229920002647 polyamide Polymers 0.000 claims abstract description 63
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims abstract description 29
- 239000003999 initiator Substances 0.000 claims abstract description 28
- 238000002156 mixing Methods 0.000 claims abstract description 17
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- 238000010526 radical polymerization reaction Methods 0.000 claims abstract description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 70
- 239000000178 monomer Substances 0.000 claims description 63
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- 229920001955 polyphenylene ether Polymers 0.000 claims description 54
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- 238000000034 method Methods 0.000 claims description 38
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- 229910052739 hydrogen Inorganic materials 0.000 claims description 23
- 239000001257 hydrogen Substances 0.000 claims description 21
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 18
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 18
- 150000003254 radicals Chemical class 0.000 claims description 18
- 125000004429 atom Chemical group 0.000 claims description 17
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- 125000003545 alkoxy group Chemical group 0.000 claims description 13
- 150000001412 amines Chemical class 0.000 claims description 13
- 239000004609 Impact Modifier Substances 0.000 claims description 12
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 11
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- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 10
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 9
- 125000003342 alkenyl group Chemical group 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
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- 125000003282 alkyl amino group Chemical group 0.000 claims description 7
- 125000004414 alkyl thio group Chemical group 0.000 claims description 7
- 125000002947 alkylene group Chemical group 0.000 claims description 7
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 7
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 125000004450 alkenylene group Chemical group 0.000 claims description 6
- 125000000304 alkynyl group Chemical group 0.000 claims description 6
- 125000004103 aminoalkyl group Chemical group 0.000 claims description 6
- 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 claims description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
- 239000003607 modifier Substances 0.000 claims description 6
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- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 125000003884 phenylalkyl group Chemical group 0.000 claims description 5
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 5
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- 229920001195 polyisoprene Polymers 0.000 claims description 5
- 125000002030 1,2-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([*:2])C([H])=C1[H] 0.000 claims description 4
- 229910004013 NO 2 Inorganic materials 0.000 claims description 4
- 150000008064 anhydrides Chemical class 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 125000003367 polycyclic group Chemical group 0.000 claims description 4
- 101100516563 Caenorhabditis elegans nhr-6 gene Proteins 0.000 claims description 3
- 125000004423 acyloxy group Chemical group 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 125000005157 alkyl carboxy group Chemical group 0.000 claims description 3
- 125000001231 benzoyloxy group Chemical group C(C1=CC=CC=C1)(=O)O* 0.000 claims description 3
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 3
- 125000000592 heterocycloalkyl group Chemical group 0.000 claims description 3
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 2
- 125000004070 6 membered heterocyclic group Chemical group 0.000 claims description 2
- 125000003341 7 membered heterocyclic group Chemical group 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- 125000001188 haloalkyl group Chemical group 0.000 claims description 2
- 125000001624 naphthyl group Chemical group 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 229920002367 Polyisobutene Polymers 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims 1
- 229920000265 Polyparaphenylene Polymers 0.000 abstract description 11
- 238000009826 distribution Methods 0.000 abstract description 6
- 229920002959 polymer blend Polymers 0.000 abstract description 6
- SYNHCENRCUAUNM-UHFFFAOYSA-N Nitrogen mustard N-oxide hydrochloride Chemical group Cl.ClCC[N+]([O-])(C)CCCl SYNHCENRCUAUNM-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 21
- 238000006116 polymerization reaction Methods 0.000 description 21
- 239000002253 acid Substances 0.000 description 19
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- 238000006243 chemical reaction Methods 0.000 description 15
- 229920001400 block copolymer Polymers 0.000 description 14
- 239000004593 Epoxy Substances 0.000 description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 12
- 238000009472 formulation Methods 0.000 description 12
- 239000011572 manganese Substances 0.000 description 12
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- 239000003054 catalyst Substances 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
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- 150000002431 hydrogen Chemical class 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
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- 239000005060 rubber Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
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- 150000002170 ethers Chemical class 0.000 description 5
- 150000003951 lactams Chemical class 0.000 description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
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- 239000011541 reaction mixture Substances 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
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Classifications
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
- C08L71/123—Polyphenylene oxides not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerization Catalysts (AREA)
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| ES00949448T Expired - Lifetime ES2231225T3 (es) | 1999-08-12 | 2000-08-03 | Mezclas de polimeros con resistencia al impacto mejorada. |
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| JP2003073536A (ja) * | 2001-09-06 | 2003-03-12 | Asahi Kasei Corp | 耐熱性に優れたポリトリメチレンテレフタレート樹脂組成物 |
| WO2004000890A2 (en) * | 2002-06-20 | 2003-12-31 | Ciba Specialty Chemicals Holding Inc. | Grafting of nitroxyl terminated oligomers or polymers onto thermoplastic polymers |
| US7323528B2 (en) * | 2002-07-19 | 2008-01-29 | Cid Centro De Investigacion Y Desarrollo Tecnologico, S.A. De C.V. | Block copolymers containing functional groups |
| US7189204B2 (en) | 2002-12-04 | 2007-03-13 | Cardiac Pacemakers, Inc. | Sleep detection using an adjustable threshold |
| AU2003297182A1 (en) * | 2002-12-18 | 2004-07-22 | Crompton Corporation | Styrenic polymer composites |
| EP1615962A2 (en) * | 2003-02-10 | 2006-01-18 | Ciba SC Holding AG | Comb copolymers with defined side chains and process for their manufacture |
| US6967228B2 (en) * | 2003-05-01 | 2005-11-22 | Firestone Polymers, Llc | Stable free radical polymers |
| US20040220345A1 (en) * | 2003-05-01 | 2004-11-04 | Firestone Polymers, Llc | Stable free radical polymers |
| US7132063B2 (en) * | 2003-08-16 | 2006-11-07 | General Electric Company | Poly(arylene ether)/polyamide composition |
| US7118691B2 (en) * | 2003-08-16 | 2006-10-10 | General Electric Company | Poly(arylene ether)/polyamide composition |
| US7166243B2 (en) * | 2003-08-16 | 2007-01-23 | General Electric Company | Reinforced poly(arylene ether)/polyamide composition |
| US20060205872A1 (en) * | 2003-08-16 | 2006-09-14 | General Electric Company | Reinforced Poly(Arylene Ether)/Polyamide Composition and Articles Thereof |
| US7182886B2 (en) * | 2003-08-16 | 2007-02-27 | General Electric Company | Poly (arylene ether)/polyamide composition |
| US8606356B2 (en) | 2003-09-18 | 2013-12-10 | Cardiac Pacemakers, Inc. | Autonomic arousal detection system and method |
| US20050142070A1 (en) * | 2003-09-18 | 2005-06-30 | Hartley Jesse W. | Methods and systems for assessing pulmonary disease with drug therapy control |
| US7510531B2 (en) | 2003-09-18 | 2009-03-31 | Cardiac Pacemakers, Inc. | System and method for discrimination of central and obstructive disordered breathing events |
| US7720541B2 (en) * | 2003-08-18 | 2010-05-18 | Cardiac Pacemakers, Inc. | Adaptive therapy for disordered breathing |
| US7662101B2 (en) | 2003-09-18 | 2010-02-16 | Cardiac Pacemakers, Inc. | Therapy control based on cardiopulmonary status |
| US7668591B2 (en) * | 2003-09-18 | 2010-02-23 | Cardiac Pacemakers, Inc. | Automatic activation of medical processes |
| US7887493B2 (en) | 2003-09-18 | 2011-02-15 | Cardiac Pacemakers, Inc. | Implantable device employing movement sensing for detecting sleep-related disorders |
| US7591265B2 (en) * | 2003-09-18 | 2009-09-22 | Cardiac Pacemakers, Inc. | Coordinated use of respiratory and cardiac therapies for sleep disordered breathing |
| US7575553B2 (en) | 2003-09-18 | 2009-08-18 | Cardiac Pacemakers, Inc. | Methods and systems for assessing pulmonary disease |
| US7396333B2 (en) | 2003-08-18 | 2008-07-08 | Cardiac Pacemakers, Inc. | Prediction of disordered breathing |
| US7680537B2 (en) * | 2003-08-18 | 2010-03-16 | Cardiac Pacemakers, Inc. | Therapy triggered by prediction of disordered breathing |
| US8002553B2 (en) | 2003-08-18 | 2011-08-23 | Cardiac Pacemakers, Inc. | Sleep quality data collection and evaluation |
| US7610094B2 (en) | 2003-09-18 | 2009-10-27 | Cardiac Pacemakers, Inc. | Synergistic use of medical devices for detecting medical disorders |
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| US8192376B2 (en) | 2003-08-18 | 2012-06-05 | Cardiac Pacemakers, Inc. | Sleep state classification |
| CA2535344C (en) | 2003-08-19 | 2015-10-06 | Solvay Advanced Polymers, L.L.C. | Impact-modified polyamide hollow body |
| US7680534B2 (en) | 2005-02-28 | 2010-03-16 | Cardiac Pacemakers, Inc. | Implantable cardiac device with dyspnea measurement |
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-
2000
- 2000-08-03 EP EP00949448A patent/EP1203054B1/en not_active Expired - Lifetime
- 2000-08-03 ES ES00949448T patent/ES2231225T3/es not_active Expired - Lifetime
- 2000-08-03 CA CA002376569A patent/CA2376569C/en not_active Expired - Fee Related
- 2000-08-03 AU AU62799/00A patent/AU6279900A/en not_active Abandoned
- 2000-08-03 WO PCT/EP2000/007528 patent/WO2001012721A1/en not_active Ceased
- 2000-08-03 DE DE60015553T patent/DE60015553T2/de not_active Expired - Lifetime
- 2000-08-03 AT AT00949448T patent/ATE281496T1/de not_active IP Right Cessation
- 2000-08-03 JP JP2001517611A patent/JP4607403B2/ja not_active Expired - Fee Related
- 2000-08-08 US US09/634,441 patent/US6444754B1/en not_active Expired - Fee Related
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2002
- 2002-07-10 US US10/192,091 patent/US6765062B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP1203054A1 (en) | 2002-05-08 |
| EP1203054B1 (en) | 2004-11-03 |
| AU6279900A (en) | 2001-03-13 |
| DE60015553D1 (de) | 2004-12-09 |
| DE60015553T2 (de) | 2005-10-27 |
| WO2001012721A1 (en) | 2001-02-22 |
| US20030088027A1 (en) | 2003-05-08 |
| JP2003507516A (ja) | 2003-02-25 |
| ATE281496T1 (de) | 2004-11-15 |
| JP4607403B2 (ja) | 2011-01-05 |
| US6765062B2 (en) | 2004-07-20 |
| CA2376569A1 (en) | 2001-02-22 |
| CA2376569C (en) | 2009-02-17 |
| US6444754B1 (en) | 2002-09-03 |
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