ES2158488T3 - Procedimiento para la obtencion de aldehidos mediante hidroformilado de olefinas. - Google Patents
Procedimiento para la obtencion de aldehidos mediante hidroformilado de olefinas.Info
- Publication number
- ES2158488T3 ES2158488T3 ES97902245T ES97902245T ES2158488T3 ES 2158488 T3 ES2158488 T3 ES 2158488T3 ES 97902245 T ES97902245 T ES 97902245T ES 97902245 T ES97902245 T ES 97902245T ES 2158488 T3 ES2158488 T3 ES 2158488T3
- Authority
- ES
- Spain
- Prior art keywords
- hydroformilation
- phase
- aldehids
- complex
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 5
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 239000012071 phase Substances 0.000 abstract 5
- 239000002253 acid Substances 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- 229910052703 rhodium Inorganic materials 0.000 abstract 3
- 239000010948 rhodium Substances 0.000 abstract 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 3
- 150000001298 alcohols Chemical class 0.000 abstract 2
- 239000003791 organic solvent mixture Substances 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000002831 nitrogen free-radicals Chemical group 0.000 abstract 1
- 150000002897 organic nitrogen compounds Chemical class 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 238000007669 thermal treatment Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
- B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/36—Radicals substituted by singly-bound nitrogen atoms
- C07D213/38—Radicals substituted by singly-bound nitrogen atoms having only hydrogen or hydrocarbon radicals attached to the substituent nitrogen atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
- B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
LA INVENCION TRATA DE UN PROCEDIMIENTO PARA LA PRODUCCION DE ALDEHIDOS O ALDEHIDOS Y ALCOHOLES MEDIANTE LA HIDROFORMILACION DE OLEFINAS CON MAS DE TRES ATOMOS DE CARBONO. EL PROCEDIMIENTO CONSTA DE UNA FASE DE HIDROFORMILACION, EN LA QUE LA OLEFINA ES HIDROFORMILADA MEDIANTE UN CATALIZADOR DE RODIO DISUELTO EN UN MEDIO DE REACCION HOMOGENEO A UNA PRESION DE 50 A 1000 BAR Y A UNA TEMPERATURA DE 50 A 180 (GRADOS) C Y UNA FASE DE RECUPERACION DEL CATALIZADOR EN LA QUE SE EXTRAE EL CATALIZADOR DE RODIO. EL PROCEDIMIENTO CONSTA DE LAS SIGUIENTES FASES: (A) HIDROFORMILACION EN PRESENCIA DE UN COMPLEJO DE RODIO QUE, COMO LIGANTE, MUESTRA UN COMPUESTO DE NITROGENO ORGANICO LIBRE DE FOSFORO Y MULTIDENTADO, QUE ESTA CAPACITADO PARA FORMAR COMPLEJOS CON UNOS METALES DEL VIII GRUPO DEL SISTEMA PERIODICO, MOSTRANDO ADEMAS ESTE AL MENOS UN RADICAL DE NITROGENO TERCIARIO, QUE PUEDE SER PROTONIZADO POR UN ACIDO DEBIL; (B) EXTRACCION DEL PRODUCTO DE LA FASE DE HIDROFORMILACION, SI SE DIERA EL CASO, TRAS LASEPARACION TOTAL O PARCIAL DE LOS ALDEHIDOS Y ALCOHOLES, UTILIZANDO UNA SOLUCION ACUOSA DE UN ACIDO DESTILABLE; (C) TRATAMIENTO TERMICO DEL EXTRACTO ACIDO ACUOSO EN PRESENCIA DE UN DISOLVENTE ORGANICO O MEZCLA DE DISOLVENTE QUE ES INERTE BAJO LAS CONDICIONES DE HIDROFORMILACION, SIN QUE EL ACIDO ACUOSO SEA DESTILADO PARA ASI DESPROTONIZAR EL COMPLEJO Y TRANSFORMARLO EN LA FASE ORGANICA; Y (D) RECICLADO DE LA FASE ORGANICA QUE CONTIENE EL COMPLEJO CATALIZADOR EN LA FASE DE HIDROFORMILACION.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19603201A DE19603201A1 (de) | 1996-01-30 | 1996-01-30 | Verfahren zur Herstellung von Aldehyden durch Hydroformylierung von Olefinen |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2158488T3 true ES2158488T3 (es) | 2001-09-01 |
Family
ID=7784001
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES97902245T Expired - Lifetime ES2158488T3 (es) | 1996-01-30 | 1997-01-28 | Procedimiento para la obtencion de aldehidos mediante hidroformilado de olefinas. |
Country Status (8)
Country | Link |
---|---|
US (1) | US6107524A (es) |
EP (1) | EP0885183B1 (es) |
JP (1) | JP2000504001A (es) |
KR (1) | KR19990082119A (es) |
CN (1) | CN1210514A (es) |
DE (2) | DE19603201A1 (es) |
ES (1) | ES2158488T3 (es) |
WO (1) | WO1997028113A1 (es) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19801437A1 (de) | 1998-01-16 | 1999-07-22 | Basf Ag | Verfahren zur Herstellung von Aldehyden |
DE19908462A1 (de) * | 1999-02-26 | 2000-08-31 | Basf Ag | Verfahren zur Hydroformylierung von Olefinen |
CN100339158C (zh) * | 2003-11-20 | 2007-09-26 | 三菱化学株式会社 | 铑络合物催化剂的回收方法 |
WO2005058787A1 (en) * | 2003-12-18 | 2005-06-30 | Exxonmobil Chemical Patents Inc. | Improvements in or relating to hydroformylation |
CN101497561B (zh) * | 2008-01-29 | 2015-03-18 | 财团法人工业技术研究院 | 氢甲酰化制程 |
CN102649718B (zh) * | 2011-02-25 | 2014-05-28 | 中国石油化工股份有限公司 | 烯烃进行氢甲酰化的方法 |
CN111278560B (zh) * | 2017-11-13 | 2023-07-21 | 陶氏技术投资有限责任公司 | 从氢甲酰化方法回收铑的方法 |
CN114426469A (zh) * | 2020-09-28 | 2022-05-03 | 中国石油化工股份有限公司 | 一种烯烃氢甲酰化制备醇和醛的方法 |
CN116408147B (zh) * | 2023-04-10 | 2023-09-29 | 中国科学院兰州化学物理研究所 | 一种共价三嗪有机聚合物负载铑催化材料的制备及其应用 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3594425A (en) * | 1966-07-07 | 1971-07-20 | Jefferson Chem Co Inc | Hydroformylation process |
FR1530136A (fr) * | 1966-07-07 | 1968-06-21 | Jeferson Chemical Company | Procédé d'hydroformylation des oléfines et produits obtenus |
DE1902460C3 (de) * | 1969-01-18 | 1974-06-12 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Aldehyden und Alkoholen durch Oxo-Synthese |
US3857895A (en) * | 1969-05-12 | 1974-12-31 | Union Oil Co | Recovery of catalyst complexes |
DE2604545C3 (de) * | 1976-02-06 | 1978-08-17 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Alkylcarbonsäuren |
US4400547A (en) * | 1981-04-10 | 1983-08-23 | Eastman Kodak Company | Hydroformylation process utilizing an unmodified rhodium catalyst and the stabilization and regeneration thereof |
US4388476A (en) * | 1981-05-01 | 1983-06-14 | Eastman Kodak Company | Hydroformylation process with rhodium catalyst and oxygen stabilization thereof |
US4528403A (en) * | 1982-10-21 | 1985-07-09 | Mitsubishi Chemical Industries Ltd. | Hydroformylation process for preparation of aldehydes and alcohols |
DE4316180A1 (de) * | 1992-09-16 | 1994-11-17 | Basf Ag | Verfahren zur Herstellung von Aldehyden |
JPH06252086A (ja) * | 1993-02-24 | 1994-09-09 | Hitachi Ltd | 半導体製造装置 |
CA2121308C (en) * | 1993-04-19 | 2001-07-24 | Toshihiro Omatsu | Rhodium-containing catalyst |
DE4408950A1 (de) * | 1994-03-16 | 1995-09-21 | Basf Ag | Verfahren zur Herstellung von Alkoholen und/oder Aldehyden |
-
1996
- 1996-01-30 DE DE19603201A patent/DE19603201A1/de not_active Withdrawn
-
1997
- 1997-01-28 KR KR1019980705841A patent/KR19990082119A/ko not_active Application Discontinuation
- 1997-01-28 US US09/101,692 patent/US6107524A/en not_active Expired - Fee Related
- 1997-01-28 EP EP97902245A patent/EP0885183B1/de not_active Expired - Lifetime
- 1997-01-28 WO PCT/EP1997/000372 patent/WO1997028113A1/de not_active Application Discontinuation
- 1997-01-28 ES ES97902245T patent/ES2158488T3/es not_active Expired - Lifetime
- 1997-01-28 DE DE59703863T patent/DE59703863D1/de not_active Expired - Lifetime
- 1997-01-28 CN CN97191973A patent/CN1210514A/zh active Pending
- 1997-01-28 JP JP9527290A patent/JP2000504001A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
CN1210514A (zh) | 1999-03-10 |
EP0885183A1 (de) | 1998-12-23 |
EP0885183B1 (de) | 2001-06-20 |
US6107524A (en) | 2000-08-22 |
DE59703863D1 (de) | 2001-07-26 |
DE19603201A1 (de) | 1997-07-31 |
WO1997028113A1 (de) | 1997-08-07 |
JP2000504001A (ja) | 2000-04-04 |
KR19990082119A (ko) | 1999-11-15 |
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Legal Events
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---|---|---|---|
FG2A | Definitive protection |
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