ES2160293T3 - Procedimiento para la fabricacion de oxo-alcoholes superiores. - Google Patents

Procedimiento para la fabricacion de oxo-alcoholes superiores.

Info

Publication number
ES2160293T3
ES2160293T3 ES97118801T ES97118801T ES2160293T3 ES 2160293 T3 ES2160293 T3 ES 2160293T3 ES 97118801 T ES97118801 T ES 97118801T ES 97118801 T ES97118801 T ES 97118801T ES 2160293 T3 ES2160293 T3 ES 2160293T3
Authority
ES
Spain
Prior art keywords
mixable
cobalt catalyst
cobalt
organic
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97118801T
Other languages
English (en)
Inventor
Dietmar Dr Gubisch
Klaus Armbrust
Alfred Dr Kaizik
Bernhard Dr Scholz
Rudolf Dr Nehring
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH filed Critical Degussa GmbH
Application granted granted Critical
Publication of ES2160293T3 publication Critical patent/ES2160293T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

LA INVENCION TRATA DE UN PROCEDIMIENTO PARA FABRICAR ALCOHOLES CON DE 7 A 18 ATOMOS DE CARBONO MEDIANTE HIDROFORMILACION DE LAS OPORTUNAS OLEFINAS CON GAS DE SINTESIS EN PRESENCIA DE UNA FASE ORGANICA QUE CONTIENE UN CATALIZADOR DE COBALTO, A TEMPERATURAS DE ENTRE 50 Y 220 (GRADOS) C Y PRESIONES DE 100 A 400 BAR, Y SUBSIGUIENTE HIDROGENACION DE LOS ALDEHIDOS ASI OBTENIDOS; EL CATALIZADOR DE COBALTO SE FORMA MEDIANTE REACCION DE UNA SOLUCION SALINA DE COBALTO ACUOSA, EN PRESENCIA DE UN DISOLVENTE ORGANICO NO MEZCLABLE O DIFICILMENTE MEZCLABLE CON AGUA, CON GAS DE SINTESIS, Y LA FASE ORGANICA QUE CONTIENE EL CATALIZADOR DE COBALTO SE OBTIENE MEDIANTE EXTRACCION DEL CATALIZADOR DE COBALTO FORMADO A PARTIR DE LA FASE ACUOSA CON UN AGENTE DE EXTRACCION ORGANICO NO MEZCLABLE O DIFICILMENTE MEZCLABLE CON AGUA. LA FORMACION DEL CATALIZADOR DE COBALTO, LA EXTRACCION DEL CATALIZADOR DE COBALTO FORMADO EN LA FASE ORGANICA Y LA HIDROFORMILACION DE LAS OPORTUNAS OLEFINAS SE LLEVAN A CABO EN UN PROCESO DE UN UNICO PASO. LOS OXO ALCOHOLES FABRICADOS CON AYUDA DEL PROCEDIMIENTO SEGUN LA INVENCION SE EMPLEAN PARA LA FABRICACION DE ESTERES DE ACIDO ORGANICO COMO ABLANDADORES PARA PLASTICOS.
ES97118801T 1996-12-24 1997-10-29 Procedimiento para la fabricacion de oxo-alcoholes superiores. Expired - Lifetime ES2160293T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19654340A DE19654340A1 (de) 1996-12-24 1996-12-24 Verfahren zur Herstellung von höheren Oxo-Alkoholen

Publications (1)

Publication Number Publication Date
ES2160293T3 true ES2160293T3 (es) 2001-11-01

Family

ID=7816198

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97118801T Expired - Lifetime ES2160293T3 (es) 1996-12-24 1997-10-29 Procedimiento para la fabricacion de oxo-alcoholes superiores.

Country Status (23)

Country Link
US (1) US6015928A (es)
EP (1) EP0850905B1 (es)
JP (1) JP3877852B2 (es)
KR (1) KR100506965B1 (es)
CN (1) CN1082501C (es)
AR (1) AR008722A1 (es)
AT (1) ATE203230T1 (es)
BR (1) BR9706447A (es)
CA (1) CA2225773C (es)
CZ (1) CZ290974B6 (es)
DE (2) DE19654340A1 (es)
ES (1) ES2160293T3 (es)
ID (1) ID19255A (es)
IN (1) IN1997CH01832A (es)
MX (1) MX203748B (es)
MY (1) MY117877A (es)
PL (1) PL194180B1 (es)
RO (1) RO120483B1 (es)
RU (1) RU2183210C2 (es)
SA (1) SA97180684B1 (es)
SG (1) SG63790A1 (es)
TW (1) TW434209B (es)
ZA (1) ZA9711554B (es)

Families Citing this family (58)

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DE19842369A1 (de) 1998-09-16 2000-03-23 Oxeno Oelfinchemie Gmbh Verfahren zur Hydrierung von Hydroformylierungsgemischen
DE19842370A1 (de) 1998-09-16 2000-03-23 Oxeno Oelfinchemie Gmbh Verfahren zur selektiven Hydrierung von Hydroformylierungsgemischen
DE19842371A1 (de) 1998-09-16 2000-03-23 Oxeno Oelfinchemie Gmbh Verfahren zur Herstellung von höheren Oxo-Alkoholen aus Olefingemischen
DE19933348B4 (de) 1999-07-16 2005-11-17 Oxeno Olefinchemie Gmbh Verfahren zur Reduzierung oxidischer Hydrierkontakte
DE19939491A1 (de) 1999-08-20 2001-02-22 Basf Ag Kontinuierliches Verfahren zur Hydroformylierung von Olefinen mit 6 bis 20 Kohlenstoffatomen
KR100788218B1 (ko) * 2000-03-30 2007-12-26 쉘 인터내셔날 리서치 마챠피즈 비.브이. Ｄｍｃ 착물 촉매 및 그의 제조 방법
DE10034360A1 (de) * 2000-07-14 2002-01-24 Oxeno Olefinchemie Gmbh Mehrstufiges Verfahren zur Herstellung von Oxo-Aldehyden und/oder Alkoholen
DE10058383A1 (de) * 2000-11-24 2002-05-29 Oxeno Olefinchemie Gmbh Neue Phosphininverbindungen und deren Metallkomplexe
US20020115382A1 (en) * 2001-02-16 2002-08-22 Luthy G. Steve Method and apparatus to produce a precisely textured surface on a workpiece
DE10135906A1 (de) * 2001-07-24 2003-02-06 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von höheren Olefinen mit Kobaltverbindungen als Katalysator
AU2002327859B2 (en) * 2001-09-26 2007-08-09 Evonik Degussa Gmbh Phthalic acid alkylester mixtures with controlled viscosity
DE10149348A1 (de) 2001-10-06 2003-04-10 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefin mit Palladiumcarbenverbindungen
JP2003130499A (ja) * 2001-10-30 2003-05-08 Tgk Co Ltd 膨張弁
CN100503542C (zh) 2002-03-15 2009-06-24 奥克森诺奥勒芬化学股份有限公司 烯烃的加氢甲酰基化方法
AU2003222120A1 (en) * 2002-03-29 2003-10-13 Exxonmobil Chemical Patents Inc. Oxon process
WO2003082788A1 (en) * 2002-03-29 2003-10-09 Exxonmobil Chemical Patents Inc. Improved cobalt flash process
DE10220801A1 (de) * 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
DE10225565A1 (de) 2002-06-10 2003-12-18 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen
BR0313866A (pt) 2002-08-31 2005-07-05 Oxeno Olefinchemie Gmbh Processo para a hidroformilação de compostos olefinicamente insaturados, especialmente olefinas na presença de ésteres de ácido carbÈnico cìclicos
RU2336261C2 (ru) 2002-08-31 2008-10-20 Оксено Олефинхеми Гмбх Способ каталитического гидроформилирования высших олефинов в присутствии циклических эфиров угольной кислоты
DE10251262A1 (de) * 2002-11-04 2004-05-13 Basf Ag Verfahren zur Herstellung von Aldehyden aus Alkanen
DE10257499A1 (de) 2002-12-10 2004-07-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefinen durch katalytische Spaltung von 1-Alkoxyalkanen
DE10329042A1 (de) * 2003-06-27 2005-01-13 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Octen aus Crack-C4
DE10359628A1 (de) * 2003-12-18 2005-07-21 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Herstellung von 1-Olefinen aus 2-Hydroxyalkanen
DE10360771A1 (de) * 2003-12-23 2005-07-28 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von dreiwertigen Organophosphor-Verbindungen
DE10360772A1 (de) * 2003-12-23 2005-07-28 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Organoacylphosphiten
DE102004033410A1 (de) * 2004-02-14 2005-09-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Olefinen mit 8 bis 12 Kohlenstoffatomen
DE102004013514A1 (de) * 2004-03-19 2005-10-06 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen
DE102004021128A1 (de) * 2004-04-29 2005-11-24 Oxeno Olefinchemie Gmbh Vorrichtung und Verfahren für die kontinuierliche Umsetzung einer Flüssigkeit mit einem Gas an einem festen Katalysator
DE102005036039A1 (de) 2004-08-28 2006-03-02 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 2,7-Octadienylderivaten
DE102004059292A1 (de) 2004-12-09 2006-06-14 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Alkoholen aus Olefinen durch Hydroformylierung und Hydrierung
DE102004059293A1 (de) 2004-12-09 2006-06-14 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen
DE102004063673A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas
DE102005035816A1 (de) * 2005-07-30 2007-02-01 Oxeno Olefinchemie Gmbh Verfahren zur Hydrierung von Oxo-Aldehyden mit hohen Estergehalten
DE102005042464A1 (de) * 2005-09-07 2007-03-08 Oxeno Olefinchemie Gmbh Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen
DE102007006442A1 (de) 2007-02-05 2008-08-07 Evonik Oxeno Gmbh Gemisch von Diestern von Dianhydrohexitolderivaten mit Carbonsäuren der Summenformel C8H17COOH, Verfahren zur Herstellung dieser Diester und Verwendung dieser Gemische
US7939694B2 (en) 2007-05-29 2011-05-10 Lg Chem, Ltd. Method for the hydroformylation of olefins and apparatus using the same
DE102007061649A1 (de) 2007-12-20 2009-07-02 Evonik Oxeno Gmbh Einstufiges kontinuierliches Verfahren zur Hydroformylierung von höheren Olefinen oder Olefingemischen
DE102007061648A1 (de) * 2007-12-20 2009-07-02 Evonik Oxeno Gmbh Mehrstufiges kontinuierliches Verfahren zur Hydroformylierung von höheren Olefinen oder Olefingemischen
DE102008006400A1 (de) 2008-01-28 2009-07-30 Evonik Oxeno Gmbh Gemische von Diisononylestern der Terephthalsäure, Verfahren zu deren Herstellung und deren Verwendung
DE102008007080A1 (de) 2008-01-31 2009-08-06 Evonik Oxeno Gmbh Verfahren zur Herstellung von C9-Alkohol aus C8-Olefinen
DE102009001225A1 (de) * 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom
KR101251714B1 (ko) * 2009-08-20 2013-04-05 주식회사 엘지화학 올레핀의 하이드로포밀화 반응장치 및 이를 이용한 하이드로포밀화 방법
DE102009028975A1 (de) 2009-08-28 2011-03-03 Evonik Oxeno Gmbh Esterderivate der 2,5-Furandicarbonsäure und ihre Verwendung als Weichmacher
JP6516741B2 (ja) * 2013-11-18 2019-05-22 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ オレフィンのヒドロホルミル化法
US9115069B2 (en) 2013-11-18 2015-08-25 Basf Se Process for hydroformylation of olefins
DE102014209536A1 (de) 2014-05-20 2015-11-26 Evonik Degussa Gmbh Herstellung qualitativ hochwertiger Oxo-Alkohole aus unsteten Rohstoffquellen
RU2609264C1 (ru) 2015-12-09 2017-01-31 Акционерное Общество "Газпромнефть - Московский Нпз" (Ао "Газпромнефть - Мнпз") Способ получения высокооктановых компонентов из олефинов каталитического крекинга
CN110981692A (zh) * 2019-12-25 2020-04-10 中国科学院兰州化学物理研究所 一种联产异壬醇和碳八烷烃的方法及系统
CN113698280B (zh) * 2020-05-21 2023-10-13 中国石油化工股份有限公司 一种烯烃加氢甲酰化方法
CN114426469B (zh) * 2020-09-28 2024-07-09 中国石油化工股份有限公司 一种烯烃氢甲酰化制备醇和醛的方法
CN114656343B (zh) * 2020-12-23 2024-05-17 中国石油化工股份有限公司 一种制备醛和醇的方法
CN115701418B (zh) * 2021-08-02 2024-05-17 中国石油化工股份有限公司 醛醇组合物及其制备方法、一种连续制备醛、醇的方法
CN116063155B (zh) * 2021-10-29 2024-12-06 中国石油化工股份有限公司 一种烯烃氢甲酰化反应制备醇的方法
CN116063168B (zh) * 2021-10-29 2024-12-06 中国石油化工股份有限公司 一种烯烃氢甲酰化反应的方法
CN120129671A (zh) 2022-10-28 2025-06-10 巴斯夫欧洲公司 由可再生来源的乙醇制造异壬醇的方法
CN116730836A (zh) * 2023-06-16 2023-09-12 中国科学院兰州化学物理研究所 一种合成气活化的钴盐催化羰化酯化反应的方法

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Also Published As

Publication number Publication date
KR19980064557A (ko) 1998-10-07
IN1997CH01832A (es) 2006-09-22
AR008722A1 (es) 2000-02-09
CN1186060A (zh) 1998-07-01
DE19654340A1 (de) 1998-08-06
CZ401197A3 (cs) 1998-07-15
KR100506965B1 (ko) 2005-11-21
CA2225773C (en) 2005-10-25
RO120483B1 (ro) 2006-02-28
EP0850905B1 (de) 2001-07-18
EP0850905A1 (de) 1998-07-01
RU2183210C2 (ru) 2002-06-10
JP3877852B2 (ja) 2007-02-07
PL194180B1 (pl) 2007-05-31
MX9709932A (es) 1998-06-30
CZ290974B6 (cs) 2002-11-13
SG63790A1 (en) 1999-03-30
MX203748B (es) 2001-08-14
MY117877A (en) 2004-08-30
JPH10204009A (ja) 1998-08-04
BR9706447A (pt) 1999-06-01
SA97180684B1 (ar) 2006-04-22
ATE203230T1 (de) 2001-08-15
CA2225773A1 (en) 1998-06-24
ID19255A (id) 1998-06-28
US6015928A (en) 2000-01-18
TW434209B (en) 2001-05-16
PL323777A1 (en) 1998-07-06
CN1082501C (zh) 2002-04-10
DE59704070D1 (de) 2001-08-23
ZA9711554B (en) 1998-06-24

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