ES2146082T3 - Procedimiento para la obtencion de aldehidos mediante hidroformilacion con un catalizador de rodio y recuperacion del catalizador de rodio mediante extraccion. - Google Patents

Procedimiento para la obtencion de aldehidos mediante hidroformilacion con un catalizador de rodio y recuperacion del catalizador de rodio mediante extraccion.

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Publication number
ES2146082T3
ES2146082T3 ES97904422T ES97904422T ES2146082T3 ES 2146082 T3 ES2146082 T3 ES 2146082T3 ES 97904422 T ES97904422 T ES 97904422T ES 97904422 T ES97904422 T ES 97904422T ES 2146082 T3 ES2146082 T3 ES 2146082T3
Authority
ES
Spain
Prior art keywords
hydroformilation
rhodium
phase
rhodium catalyst
products
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97904422T
Other languages
English (en)
Inventor
Bernhard Geissler
Heinz-Josef Kneuper
Michael Roper
Rocco Paciello
Knut Oppenlander
Wolfgang Gunther
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2146082T3 publication Critical patent/ES2146082T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3817—Acids containing the structure (RX)2P(=X)-alk-N...P (X = O, S, Se)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0206—Polyalkylene(poly)amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

PROCEDIMIENTO PARA PREPARAR ALDEHIDOS O ALDEHIDOS Y ALCOHOLES POR HIDROFORMILACION DE OLEFINAS CON MAS DE 3 ATOMOS DE CARBONO, QUE COMPRENDE UNA FASE DE HIDROFORMILACION EN LA CUAL SE HIDROFORMILA LA OLEFINA MEDIANTE UN CATALIZADOR DE RODIO DISUELTO EN UN MEDIO REACTIVO HOMOGENEO, ENTRE 50 Y 1000 BAR Y A UNA TEMPERATURA DE ENTRE 50 Y 180 (GRADOS) C, Y UNA FASE DE RECUPERACION DEL CATALIZADOR POR EXTRACCION DEL RODIO CON UNA SOLUCION ACUOSA DE UN FORMADOR DE COMPLEJOS; AISLAMIENTO DEL ALCOHOL Y/O ALDEHIDO DE LOS PRODUCTOS DE HIDROFORMILACION EXTRAIDOS; EL EXTRACTO ACUOSO QUE CONTIENE RODIO SE SOMETE A UNA CARBONILIZACION PREVIA EN PRESENCIA DE MONOXIDO DE CARBONO, GAS DE SINTESIS O UN MONOXIDO DE CARBONO QUE CONTIENE UNA MEZCLA DE GAS, A UNA PRESION DE ENTRE 50 Y 1000 BAR Y A UNA TEMPERATURA DE ENTRE 50 Y 180 (GRADOS) C; SEPARACION DE LOS PRODUCTOS DE LA CARBONILIZACION PREVIA EN UNA FASE ORGANICA QUE CONTIENE LA PARTE PRINCIPAL DE RODIO Y UNA FASE ACUOSA QUE CONTIENE EL FORMADOR DE COMPLEJOS, Y REALIMENTACION DE LA FASE ORGANICA A LA FASE DE HIDROFORMILACION, EXTRAYENDOSE EL CATALIZADOR DE RODIO DE LOS PRODUCTOS DE HIDROFORMILACION CON UNA SOLUCION ACUOSA DE UN POLIMERO HIDROSOLUBLE, APTO PARA EL ENLACE COMPLEJO DE RODIO Y LIBRE DE GRUPOS DE ACIDO SULFONICO.
ES97904422T 1996-02-14 1997-02-12 Procedimiento para la obtencion de aldehidos mediante hidroformilacion con un catalizador de rodio y recuperacion del catalizador de rodio mediante extraccion. Expired - Lifetime ES2146082T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19605435A DE19605435A1 (de) 1996-02-14 1996-02-14 Verfahren zur Herstellung von Aldehyden durch Hydroformylierung mit einem Rhodiumkatalysator und Wiedergewinnung des Rhodiumkatalysators durch Extraktion

Publications (1)

Publication Number Publication Date
ES2146082T3 true ES2146082T3 (es) 2000-07-16

Family

ID=7785379

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97904422T Expired - Lifetime ES2146082T3 (es) 1996-02-14 1997-02-12 Procedimiento para la obtencion de aldehidos mediante hidroformilacion con un catalizador de rodio y recuperacion del catalizador de rodio mediante extraccion.

Country Status (8)

Country Link
US (1) US6225507B1 (es)
EP (1) EP0880494B1 (es)
JP (1) JP2000504705A (es)
KR (1) KR19990082542A (es)
CN (1) CN1210513A (es)
DE (2) DE19605435A1 (es)
ES (1) ES2146082T3 (es)
WO (1) WO1997030016A1 (es)

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DE19801437A1 (de) 1998-01-16 1999-07-22 Basf Ag Verfahren zur Herstellung von Aldehyden
EP1172143A1 (en) * 2000-07-14 2002-01-16 Dsm N.V. Process for the recovery of rhodium
DE10048301A1 (de) * 2000-09-29 2002-04-11 Oxeno Olefinchemie Gmbh Stabilisierung von Rhodiumkatalysatoren für die Hydroformylierung von Olefinen
US6764662B2 (en) * 2002-06-20 2004-07-20 Conocophillips Company Recover and recycle rhodium from spent partial oxidation catalysts
US6982355B2 (en) * 2003-08-25 2006-01-03 Syntroleum Corporation Integrated Fischer-Tropsch process for production of linear and branched alcohols and olefins
AU2003300727A1 (en) * 2003-12-31 2005-07-21 Council Of Scientific And Industrial Research Process for synthesis of alpha-substituted acroleins
US7141702B2 (en) * 2004-03-26 2006-11-28 Council Of Scientific And Industrial Research Process for the synthesis of α-substituted acroleins
US7431894B2 (en) * 2005-07-19 2008-10-07 Intercat Equipment, Inc. Catalyst withdrawal apparatus for regulating catalyst inventory in a fluid catalyst cracking unit
US20080234850A1 (en) * 2007-03-19 2008-09-25 Bowling William C Model based definition installation and assembly drawing process
DE102007053385A1 (de) * 2007-11-09 2009-05-20 Oxea Deutschland Gmbh Verfahren zur Herstellung von Aldehyden
EP2655511B1 (de) 2010-12-23 2016-04-06 INEOS Styrolution Europe GmbH Thermoplastische elastomer-zusammensetzung und verfahren zu deren herstellung
TWI654177B (zh) 2013-10-31 2019-03-21 德商巴斯夫歐洲公司 製備羧酸酯的方法及其作爲塑化劑的用途
ES2675527T3 (es) 2013-12-06 2018-07-11 Basf Se Composición plastificante que contiene derivados de tetrahidrofurano y ésteres de ácido 1,2-ciclohexano dicarboxílico
CA2936299A1 (en) 2014-01-09 2015-07-16 Basf Se Plasticizer composition containing furan derivatives and 1,2-cyclohexanedicarboxylic ester
TWI678359B (zh) 2014-04-22 2019-12-01 德商巴斯夫歐洲公司 製備羧酸酯的方法及其作爲塑化劑的用途
DE102015207291A1 (de) 2014-04-24 2016-03-10 Basf Se Weichmacher-Zusammensetzung, die Furanderivate und 1,2-Cyclohexandicarbonsäureester enthält
TW201609628A (zh) 2014-07-08 2016-03-16 巴斯夫歐洲公司 包含脂族二羧酸二酯及對苯二甲酸二烷基酯之塑化劑組成物
TW201605945A (zh) 2014-07-08 2016-02-16 巴斯夫歐洲公司 包含二羧酸的酯及１，２－環己烷二羧酸的酯之模製化合物
TWI706979B (zh) 2014-08-19 2020-10-11 德商巴斯夫歐洲公司 包含聚合二羧酸酯的塑化劑組成物
TWI686444B (zh) 2014-09-04 2020-03-01 德商巴斯夫歐洲公司 包含聚合二羧酸酯的塑化劑組成物
TW201619119A (zh) 2014-10-09 2016-06-01 巴斯夫歐洲公司 包含飽和二羧酸之環烷基酯及１，２－環己烷二羧酸酯的塑化劑組成物
TW201619120A (zh) 2014-10-09 2016-06-01 巴斯夫歐洲公司 包含飽和二羧酸之環烷基酯及對苯二甲酯之塑化劑組成物
EP3250635B1 (de) 2015-01-30 2018-10-24 Basf Se Weichmacher-zusammensetzung, die polymere dicarbonsäureester und terephthalsäuredialkylester enthält
RU2743641C1 (ru) 2015-09-30 2021-02-20 Басф Се Пластифицирующая композиция, содержащая полимерные сложные эфиры дикарбоновых кислот и сложные диалкиловые эфиры терефталевой кислоты
US20180291180A1 (en) 2015-09-30 2018-10-11 Basf Se Plasticizer composition containing polymeric dicarboxylic acid esters and dicarboxylic acid diesters
US20180282510A1 (en) 2015-09-30 2018-10-04 Basf Se Plasticizer composition containing polymeric dicarboxylic acid esters and dicarboxylic acid diesters
ES2769226T3 (es) 2016-01-20 2020-06-25 Basf Se Composición plastificante, que contiene ésteres y diésteres de ácidos dicarboxílicos alifáticos, que son elegidos de entre ésteres de ácido 1,2-ciclohexanodicarboxílicos y ésteres de ácido tereftálico
RU2743230C2 (ru) 2016-03-23 2021-02-16 Басф Се Полимерная композиция, содержащая циклоалкилалкилдикарбоновой кислоты сложный диэфир в качестве пластификатора
WO2018024597A1 (de) 2016-08-01 2018-02-08 Basf Se Weichmacher-zusammensetzung
US20190161597A1 (en) 2016-08-01 2019-05-30 Basf Se Plasticizer composition
WO2018024591A1 (de) 2016-08-01 2018-02-08 Basf Se Weichmacher-zusammensetzung
US11033890B2 (en) * 2017-11-13 2021-06-15 Dow Technology Investments Llc Processes for recovery of rhodium from a hydroformylation process
WO2019185409A1 (de) 2018-03-29 2019-10-03 Basf Se Pvc-zusammensetzung, enthaltend wenigstens einen weichmacher der wenigstens eine carbonsäureestergruppe aufweist und wenigstens eine carbodiimidverbindung
EP3747860B1 (de) 2019-06-04 2023-07-26 Basf Se Neue weichmacher auf cyclohexanon-basis
CN113698280B (zh) * 2020-05-21 2023-10-13 中国石油化工股份有限公司 一种烯烃加氢甲酰化方法
US12054455B2 (en) 2020-06-05 2024-08-06 SCION Holdings LLC Branched alcohols
US11680032B2 (en) 2020-06-05 2023-06-20 SCION Holdings LLC Alcohols production
WO2021247314A1 (en) * 2020-06-05 2021-12-09 SCION Holdings LLC Branched compounds
US20220194886A1 (en) 2020-12-17 2022-06-23 SCION Holdings LLC Branched Products
CN112791748B (zh) * 2021-01-15 2022-09-20 万华化学集团股份有限公司 一种从氢甲酰化反应液中回收催化金属的方法
CN113289695B (zh) * 2021-06-21 2022-07-12 万华化学集团股份有限公司 一种氢甲酰化催化剂的回收方法
WO2024133358A1 (de) 2022-12-21 2024-06-27 Basf Se Weichmacher-verbindung
WO2024153687A1 (de) 2023-01-19 2024-07-25 Basf Se Verfahren zur herstellung von 1,2-cyclohexandicarbonsäuredialkylestern

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DE4230871A1 (de) 1992-09-16 1994-03-17 Basf Ag Verfahren zur Herstellung von Aldehyden
DE4408950A1 (de) 1994-03-16 1995-09-21 Basf Ag Verfahren zur Herstellung von Alkoholen und/oder Aldehyden
DE4427428A1 (de) 1994-08-03 1996-02-29 Basf Ag Verfahren zur Herstellung von Aldehyden
DE4440801A1 (de) * 1994-11-17 1996-05-23 Basf Ag Verfahren zur Herstellung von Aldehyden

Also Published As

Publication number Publication date
DE19605435A1 (de) 1997-08-21
KR19990082542A (ko) 1999-11-25
DE59701574D1 (de) 2000-06-08
CN1210513A (zh) 1999-03-10
EP0880494A1 (de) 1998-12-02
JP2000504705A (ja) 2000-04-18
US6225507B1 (en) 2001-05-01
EP0880494B1 (de) 2000-05-03
WO1997030016A1 (de) 1997-08-21

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