ES2179577T3 - Procedimiento para la hidrogenacion de mezclas de hidroformilacion. - Google Patents

Procedimiento para la hidrogenacion de mezclas de hidroformilacion.

Info

Publication number
ES2179577T3
ES2179577T3 ES99115269T ES99115269T ES2179577T3 ES 2179577 T3 ES2179577 T3 ES 2179577T3 ES 99115269 T ES99115269 T ES 99115269T ES 99115269 T ES99115269 T ES 99115269T ES 2179577 T3 ES2179577 T3 ES 2179577T3
Authority
ES
Spain
Prior art keywords
hydrogenation
mixtures
hydroformylation
olefins
carried out
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99115269T
Other languages
English (en)
Inventor
Wilfried Dr Buschken
Dietmar Dr Gubisch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Oxeno Olefinchemie GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oxeno Olefinchemie GmbH filed Critical Oxeno Olefinchemie GmbH
Application granted granted Critical
Publication of ES2179577T3 publication Critical patent/ES2179577T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • C10G70/02—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

La hidrogenación de mezclas de reacción procedentes de la hidroformilación de 5-24C olefinas se realiza en la fase de vapor utilizando un catalizador de cobre-cromo no soportado. La hidrogenación de las mezclas de reacción procedentes de la hidroformilación de 5-24C olefinas se realiza en la fase de vapo utilizando un catalizador de cobre-cromo no soportado. Un procedimiento para la hidrogenación de mezclas de reacción a partir de la hidroformilación de 5-24C olefinas mediante hidrógeno que utiliza un catalizador sólido a temperatura elevada. La reacción se realiza en la fase de vapor utilizando un catalizador de cobre-cromo no soportado con la destilación de aldehído, alcohol, formiato y un material con punto de ebullición bajo de la mezcla de reacción.
ES99115269T 1998-09-16 1999-07-31 Procedimiento para la hidrogenacion de mezclas de hidroformilacion. Expired - Lifetime ES2179577T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19842369A DE19842369A1 (de) 1998-09-16 1998-09-16 Verfahren zur Hydrierung von Hydroformylierungsgemischen

Publications (1)

Publication Number Publication Date
ES2179577T3 true ES2179577T3 (es) 2003-01-16

Family

ID=7881138

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99115269T Expired - Lifetime ES2179577T3 (es) 1998-09-16 1999-07-31 Procedimiento para la hidrogenacion de mezclas de hidroformilacion.

Country Status (17)

Country Link
US (1) US6184424B1 (es)
EP (1) EP0987240B1 (es)
JP (1) JP2000086552A (es)
KR (1) KR20000023120A (es)
CN (1) CN1249293A (es)
AR (1) AR020447A1 (es)
AT (1) ATE220655T1 (es)
BR (1) BR9904202A (es)
CA (1) CA2282949A1 (es)
DE (2) DE19842369A1 (es)
ES (1) ES2179577T3 (es)
ID (1) ID23136A (es)
MY (1) MY118464A (es)
PL (1) PL335204A1 (es)
SG (1) SG79278A1 (es)
TW (1) TW486460B (es)
ZA (1) ZA995923B (es)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6278030B1 (en) * 1997-07-15 2001-08-21 Exxon Chemical Patents, Inc. Process for preparing alcohols by the Oxo process
DE19957528A1 (de) 1999-11-30 2001-05-31 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen
DE10058383A1 (de) 2000-11-24 2002-05-29 Oxeno Olefinchemie Gmbh Neue Phosphininverbindungen und deren Metallkomplexe
DE10062448A1 (de) 2000-12-14 2002-06-20 Oxeno Olefinchemie Gmbh Verfahren zur Hydrierung von Hydroformylierungsgemischen
DE10135906A1 (de) 2001-07-24 2003-02-06 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von höheren Olefinen mit Kobaltverbindungen als Katalysator
AU2002327859B2 (en) * 2001-09-26 2007-08-09 Evonik Degussa Gmbh Phthalic acid alkylester mixtures with controlled viscosity
DE10149348A1 (de) 2001-10-06 2003-04-10 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefin mit Palladiumcarbenverbindungen
DE10220801A1 (de) * 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
DE10225565A1 (de) 2002-06-10 2003-12-18 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen
JP2005537330A (ja) 2002-08-31 2005-12-08 オクセノ　オレフィンヒェミー　ゲゼルシャフト　ミット　ベシュレンクテル　ハフツング 環状カルボン酸エステルの存在で非変性金属錯体により触媒活性されるオレフィン不飽和化合物のヒドロホルミル化によりアルデヒドを製造する方法
RU2337090C2 (ru) 2002-08-31 2008-10-27 Оксено Олефинхеми Гмбх Способ гидроформилирования олефиновых соединений в присутствии циклических эфиров угольной кислоты
DE10257499A1 (de) 2002-12-10 2004-07-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefinen durch katalytische Spaltung von 1-Alkoxyalkanen
DE10329042A1 (de) * 2003-06-27 2005-01-13 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Octen aus Crack-C4
US6982355B2 (en) * 2003-08-25 2006-01-03 Syntroleum Corporation Integrated Fischer-Tropsch process for production of linear and branched alcohols and olefins
DE10359628A1 (de) * 2003-12-18 2005-07-21 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Herstellung von 1-Olefinen aus 2-Hydroxyalkanen
DE10360771A1 (de) * 2003-12-23 2005-07-28 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von dreiwertigen Organophosphor-Verbindungen
DE10360772A1 (de) 2003-12-23 2005-07-28 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Organoacylphosphiten
DE102004033410A1 (de) * 2004-02-14 2005-09-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Olefinen mit 8 bis 12 Kohlenstoffatomen
DE102004013514A1 (de) * 2004-03-19 2005-10-06 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen
DE102004021128A1 (de) * 2004-04-29 2005-11-24 Oxeno Olefinchemie Gmbh Vorrichtung und Verfahren für die kontinuierliche Umsetzung einer Flüssigkeit mit einem Gas an einem festen Katalysator
DE102005036039A1 (de) 2004-08-28 2006-03-02 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 2,7-Octadienylderivaten
DE102004059293A1 (de) 2004-12-09 2006-06-14 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen
DE102004059292A1 (de) 2004-12-09 2006-06-14 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Alkoholen aus Olefinen durch Hydroformylierung und Hydrierung
DE102004063673A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas
DE102005035816A1 (de) * 2005-07-30 2007-02-01 Oxeno Olefinchemie Gmbh Verfahren zur Hydrierung von Oxo-Aldehyden mit hohen Estergehalten
DE102005042464A1 (de) * 2005-09-07 2007-03-08 Oxeno Olefinchemie Gmbh Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen
DE102006040432A1 (de) * 2006-08-29 2008-03-20 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Herstellung von Isoolefinen
DE102007041380A1 (de) * 2007-08-31 2009-03-05 Evonik Oxeno Gmbh Hydrierkatalysator und Verfahren zur Herstellung von Alkoholen durch Hydrierung von Carbonylverbindungen
GB0719251D0 (en) * 2007-10-03 2007-11-14 Davy Process Techn Ltd Process
DE102008007080A1 (de) 2008-01-31 2009-08-06 Evonik Oxeno Gmbh Verfahren zur Herstellung von C9-Alkohol aus C8-Olefinen
WO2009124979A1 (de) * 2008-04-10 2009-10-15 Basf Se C17-alkoholgemisch
JP5746749B2 (ja) * 2010-03-15 2015-07-08 エクソンモービル・ケミカル・パテンツ・インク アルコールの製造方法
DE102013203117A1 (de) 2013-02-26 2014-08-28 Evonik Industries Ag Optimierte Trenntechnik zur Aufarbeitung von homogen katalysierten Hydroformylierungsmischungen
CN104151138B (zh) * 2014-08-13 2016-08-24 中国石油大学(华东) 一种丁辛醇残液生产醇类高碳有机溶剂的工艺
KR101757053B1 (ko) * 2014-09-25 2017-07-12 주식회사 엘지화학 고효율의 네오펜틸 글리콜의 제조방법 및 이의 제조장치
EP3059005B1 (de) 2015-02-18 2018-10-24 Evonik Degussa GmbH Abtrennung eines homogenkatalysators aus einem reaktionsgemisch mit hilfe organophiler nanofiltration unter besonderer berücksichtigung eines membran-leistungsindikators
CN111470962A (zh) * 2020-04-28 2020-07-31 浙江师范大学 一种由混合异构辛烯制备异壬酸的方法
EP4549622A1 (en) 2023-10-31 2025-05-07 Basf Se Hydrogenation of carbonyl compounds using hydrogen with low deuterium content

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE931888C (de) * 1940-07-27 1955-08-18 Dehydag Gmbh Verfahren zur Herstellung von verzweigtkettigen Alkoholen
DE1935900C3 (de) * 1969-07-15 1975-03-13 Chemische Werke Huels Ag, 4370 Marl Verfahren zur Entfernung von Aldehyden und Ketonen aus Kohlenmonoxid enthaltenden Gasströmen
DE2538037C3 (de) * 1975-08-27 1988-11-10 Hüls AG, 4370 Marl Verfahren zur Hydroformylierung von Olefinen
DE3542595A1 (de) 1985-12-03 1987-06-04 Basf Ag Verfahren zur herstellung von c(pfeil abwaerts)3(pfeil abwaerts)-c(pfeil abwaerts)2(pfeil abwaerts)(pfeil abwaerts)5(pfeil abwaerts)-alkanolen
DE19524969A1 (de) * 1995-07-08 1997-01-09 Huels Chemische Werke Ag Verfahren zur Herstellung von 3.3.5-Trimethylcyclohexanon
US5399793A (en) * 1993-11-29 1995-03-21 Exxon Chemical Patents Inc. Hydrogenation catalyst for oxo alcohol process
DE19524970A1 (de) * 1995-07-08 1997-01-09 Huels Chemische Werke Ag Verfahren zur Herstellung von 2-Ethylhexanal
DE19524971A1 (de) * 1995-07-08 1997-01-09 Huels Chemische Werke Ag Verfahren zur katalytischen Selektivhydrierung von mehrfach ungesättigten organischen Substanzen
DE19654340A1 (de) 1996-12-24 1998-08-06 Huels Chemische Werke Ag Verfahren zur Herstellung von höheren Oxo-Alkoholen
US5922921A (en) * 1997-10-27 1999-07-13 Celanese International Corporation Process for the production of n-butanol

Also Published As

Publication number Publication date
ZA995923B (en) 2000-04-04
EP0987240B1 (de) 2002-07-17
ID23136A (id) 2000-03-15
ATE220655T1 (de) 2002-08-15
CN1249293A (zh) 2000-04-05
PL335204A1 (en) 2000-03-27
EP0987240A1 (de) 2000-03-22
SG79278A1 (en) 2001-03-20
DE19842369A1 (de) 2000-03-23
MY118464A (en) 2004-11-30
KR20000023120A (ko) 2000-04-25
DE59902020D1 (de) 2002-08-22
US6184424B1 (en) 2001-02-06
BR9904202A (pt) 2000-09-05
CA2282949A1 (en) 2000-03-16
JP2000086552A (ja) 2000-03-28
TW486460B (en) 2002-05-11
AR020447A1 (es) 2002-05-15

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