ES2060548A1 - Derivados 1-hidrocarbiloxi-2,2,6,6,-tetrametil-piperidinicos de 1,3,5 triazinas, no migrantes, como estabilizadores de polimeros. - Google Patents
Derivados 1-hidrocarbiloxi-2,2,6,6,-tetrametil-piperidinicos de 1,3,5 triazinas, no migrantes, como estabilizadores de polimeros.Info
- Publication number
- ES2060548A1 ES2060548A1 ES09300939A ES9300939A ES2060548A1 ES 2060548 A1 ES2060548 A1 ES 2060548A1 ES 09300939 A ES09300939 A ES 09300939A ES 9300939 A ES9300939 A ES 9300939A ES 2060548 A1 ES2060548 A1 ES 2060548A1
- Authority
- ES
- Spain
- Prior art keywords
- hydrocarbyloxy
- tetramethylpiperdine
- migrating
- triazine derivatives
- polymer stabilizers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/285—Nitrogen containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
- C08G18/3842—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polyurethanes Or Polyureas (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
DERIVADOS 1-HIDROCARBILOXI-2,2,6,6-TETRAMETIL-PIPERIDINICOS DE 1,3,5 TRIAZINAS, NO MIGRANTES, COMO ESTABILIZADORES DE POLIMEROS. LOS DERIVADOS 1-HIDROCARBILOXI-2,2,6,6-TETRAMETIL-PIPERIDINICOS DE S-TRIAZINAS QUE CONTIENEN GRUPOS FUNCIONALES COMO HIDROXI, AMINO, CARBOXI, EPOXI, ISOCIANATO O SIMILARES, SON CAPACES DE UNIRSE QUIMICAMENTE COMO SUSTRATOS DE POLIMEROS QUE CONTIENEN GRUPOS ANHIDRIDO, EPOXIDO, ALCOXIMETILMELAMINA O ISOCIANATOS. ESTE ENLACE QUIMICO EVITA LA MIGRACION O PERDIDA DEL ESTABILIZANTE DURANTE EL SUBSECUENTE PROCESO O APLICACION FINAL DEL POLIMERO ESTABILIZADO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/878,678 US5216156A (en) | 1992-05-05 | 1992-05-05 | Non-migrating 1-hydrocarbyloxy-2,2,6,6-tetramethylpiperidine 1,3,5-triazine derivatives |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2060548A1 true ES2060548A1 (es) | 1994-11-16 |
ES2060548B1 ES2060548B1 (es) | 1997-12-01 |
Family
ID=25372567
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES09300939A Expired - Fee Related ES2060548B1 (es) | 1992-05-05 | 1993-05-04 | Derivados 1-hidrocarbiloxi-2,2,6,6,-tetrametil-piperidinicos de 1,3,5 triazinas, no migrantes, como estabilizadores de polimeros. |
Country Status (16)
Country | Link |
---|---|
US (2) | US5216156A (es) |
JP (1) | JP3259200B2 (es) |
KR (1) | KR100253765B1 (es) |
AT (1) | AT406162B (es) |
BE (1) | BE1007753A3 (es) |
BR (1) | BR9301745A (es) |
CA (1) | CA2095415C (es) |
DE (1) | DE4314721B4 (es) |
ES (1) | ES2060548B1 (es) |
FR (1) | FR2690920B1 (es) |
GB (1) | GB2266717B (es) |
IT (1) | IT1271467B (es) |
MX (1) | MX9302590A (es) |
NL (1) | NL195036C (es) |
SE (1) | SE505317C2 (es) |
TW (1) | TW237451B (es) |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1271711B (it) * | 1994-11-09 | 1997-06-04 | Ciba Geigy Spa | Derivati della 2,2,6,6-tetrametilpiperidina utili come stabilizzanti alla luce, al calore e all'ossidazione per materiali organici |
US6147163A (en) * | 1996-12-18 | 2000-11-14 | Basf Corporation | Acrylic oligomeric and polymeric durability enhancing agents, method therefore and cured coating compositions containing the same |
US6037441A (en) * | 1996-12-18 | 2000-03-14 | Basf Corporation | Non-acrylic durability enhancing agents, method therefore and cured coating compositions containing the same |
US6166148A (en) * | 1996-12-18 | 2000-12-26 | Basf Corporation | Durability enhancing agents, method therefore and cured coating compositions containing the same |
US6599963B2 (en) | 1997-06-30 | 2003-07-29 | Ciba Specialty Chemicals Corporation | Flame retardant compositions |
US6472456B1 (en) | 1997-06-30 | 2002-10-29 | Ciba Specialty Chemicals Corp. | Flame retardant compositions |
US5844026A (en) * | 1997-06-30 | 1998-12-01 | Ciba Specialty Chemicals Corporation | N,N',N''-tris{2,4-bis Hydrocarbyloxy-2,2,6,6-tetra-methylpiperidin-4-yl)alkylamino!-s-triazin-6-yl}-3,3'-ethylenediiminodipropylamines, their isomers and bridged derivatives and polymer compositions stabilized therewith |
US6383716B1 (en) | 1997-08-22 | 2002-05-07 | Asahi Kasei Kabushiki Kaisha | Stable photosensitive resin composition |
IL136409A0 (en) * | 1997-12-08 | 2001-06-14 | Cytec Tech Corp | Morpholino end-capped, hindered amine substituted aminotriazine and their use as light stabilizers |
SG74700A1 (en) * | 1998-02-25 | 2000-08-22 | Ciba Sc Holding Ag | Preparation of sterically hindered amine ethers |
ITMI980366A1 (it) | 1998-02-25 | 1999-08-25 | Ciba Spec Chem Spa | Preparazione di eteri amminici stericamente impediti |
AU738331B2 (en) * | 1999-02-19 | 2001-09-13 | Asahi Kasei Kabushiki Kaisha | Stable photosensitive resin composition |
TWI273115B (en) * | 2000-12-12 | 2007-02-11 | Ciba Sc Holding Ag | Improved weatherability of flame retardant polyolefin |
EP1465943B1 (en) * | 2001-12-10 | 2009-01-14 | Ciba Holding Inc. | Flame retardant conpositions |
US7323502B2 (en) * | 2002-03-12 | 2008-01-29 | Ciba Specialty Chemicals Corporation | Flame retardant compositions |
US20040002559A1 (en) * | 2002-04-10 | 2004-01-01 | Malisa Troutman | Flame retardant coatings |
MY139230A (en) * | 2002-10-17 | 2009-08-28 | Ciba Holding Inc | Flame retardant polymeric electrical parts |
MXPA05009108A (es) * | 2003-02-26 | 2005-10-20 | Ciba Sc Holding Ag | Alcoxiaminas sustituidas con hidroxi estericamente impedidas compatibles con agua. |
US7550599B2 (en) * | 2003-02-26 | 2009-06-23 | Ciba Specialty Chemicals Corporation | Water compatible sterically hindered alkoxyamines and hydroxy substituted alkoxyamines |
EP2993168B1 (en) | 2004-11-02 | 2017-05-17 | Basf Se | Process for the synthesis of n-alkoxyamines |
WO2007016175A1 (en) * | 2005-07-28 | 2007-02-08 | Guasch Michael N | Fuel repellent compositions, fabrics and articles |
EP1787989A1 (de) * | 2005-11-17 | 2007-05-23 | Degussa GmbH | Triazinverbindungen mit Aminogruppen- und Carboxygruppen-haltigen Substituenten |
CA2707047C (en) * | 2007-12-12 | 2017-11-28 | Rigel Pharmaceuticals, Inc. | Carboxamide, sulfonamide and amine compounds for metabolic disorders |
JP5734293B2 (ja) * | 2009-08-18 | 2015-06-17 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 安定化ポリマー封止材を有する光電モジュール |
JP5556395B2 (ja) * | 2009-08-28 | 2014-07-23 | Jsr株式会社 | 液晶配向剤、液晶配向膜、液晶表示素子 |
AR079493A1 (es) * | 2009-12-21 | 2012-02-01 | Nippon Soda Co | Compuesto de amina ciclica y acaricida |
AR081721A1 (es) | 2010-02-25 | 2012-10-17 | Nippon Soda Co | Compuesto de amina ciclica y acaricida |
JP5615425B2 (ja) | 2010-03-25 | 2014-10-29 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | ホスフィン酸塩およびニトロキシル誘導体の難燃性組成物 |
AU2011284866A1 (en) | 2010-07-28 | 2013-02-21 | Basf Se | Phosphinic acid hydrazide flame retardant compositions |
WO2012013565A1 (en) | 2010-07-29 | 2012-02-02 | Basf Se | Phosphinic acid hydrazide flame retardant compositions |
WO2014066358A1 (en) | 2012-10-23 | 2014-05-01 | Basf Se | Ethylenically unsaturated oligomers containing polymer stabilizer groups |
EP2743299A1 (de) | 2012-12-12 | 2014-06-18 | Zylum Beteiligungsgesellschaft mbH & Co. Patente II KG | Synergistische Zusammensetzung und deren Verwendung als Flammschutzmittel |
EP2816097A1 (en) | 2013-06-18 | 2014-12-24 | Shell Internationale Research Maatschappij B.V. | Lubricating oil composition |
ES2796486T3 (es) | 2013-09-27 | 2020-11-27 | Basf Se | Composiciones de poliolefina para materiales de construcción |
TWI685524B (zh) | 2013-12-17 | 2020-02-21 | 美商畢克美國股份有限公司 | 預先脫層之層狀材料 |
WO2016156328A1 (en) | 2015-03-31 | 2016-10-06 | Shell Internationale Research Maatschappij B.V. | Use of a lubricating composition comprising a hindered amine light stabilizer for improved piston cleanliness in an internal combustion engine |
US9752093B2 (en) * | 2015-06-04 | 2017-09-05 | Chevron Oronite Company Llc | Borated polyol ester of hindered phenol antioxidant/friction modifier with enhanced performance |
MX2018000881A (es) | 2015-07-20 | 2018-05-15 | Basf Se | Articulos pirorretardantes de poliolefina. |
EP3263560A1 (en) | 2016-06-29 | 2018-01-03 | Borealis Agrolinz Melamine GmbH | Novel triazine-precondensate-aldehyde condensation products and method for obtaining the same |
EP3263561A1 (en) | 2016-06-29 | 2018-01-03 | Borealis Agrolinz Melamine GmbH | Novel triazine precondensate and method for obtaining the same |
JP2019531980A (ja) | 2016-08-26 | 2019-11-07 | トタル リサーチ アンド テクノロジー フエリユイ | ポリエチレンから成る樹脂組成物で作られたキャップまたは密封具 |
CN112771108B (zh) | 2018-08-22 | 2023-05-05 | 巴斯夫欧洲公司 | 稳定的滚塑聚烯烃 |
KR20210137021A (ko) * | 2019-03-08 | 2021-11-17 | 바스프 에스이 | 입체 장애 아민 안정화제 혼합물 |
US20230220239A1 (en) | 2019-03-18 | 2023-07-13 | Basf Se | Uv curable compositions for dirt pick-up resistance |
US20220282064A1 (en) | 2019-07-30 | 2022-09-08 | Basf Se | Stabilizer composition |
EP4323445A1 (en) | 2021-04-13 | 2024-02-21 | TotalEnergies OneTech Belgium | Process to produce an additived composition of polyethylene comprising post-consumer resin and caps or closures made from this composition |
US20240059867A1 (en) | 2022-08-12 | 2024-02-22 | Carl Freudenberg Kg | Flame-retardant molded articles for electrical devices |
EP4321569A1 (en) | 2022-08-12 | 2024-02-14 | Carl Freudenberg KG | Flame-retardant crosslinked aliphatic polyketones |
CN115611863B (zh) * | 2022-10-14 | 2023-11-14 | 天津大学浙江绍兴研究院 | 一种多功能三嗪基室温磷光材料及制备方法与应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0138767A1 (de) * | 1983-10-11 | 1985-04-24 | Ciba-Geigy Ag | Stabilisierte polyolefinische Zusammensetzungen enthaltend Hydroxylaminderivate |
EP0209126A2 (en) * | 1985-07-16 | 1987-01-21 | ADEKA ARGUS CHEMICAL CO., Ltd. | Hydrocarbyl(polyphenol)-poly(2,2,6,6-tetramethyl piperidyl-1,3,5-triazines) as stabilizers for synthetic polymer compositions |
EP0209127A2 (en) * | 1985-07-17 | 1987-01-21 | ADEKA ARGUS CHEMICAL CO., Ltd. | Poly(2,2,6,6-tetramethyl-piperidyl-amino)-1,3,5-triazines as stabilizers for synthetic polymer compositions |
EP0309402A1 (en) * | 1987-09-21 | 1989-03-29 | Ciba-Geigy Ag | N-substituted hindered amine stabilizers |
EP0389431A2 (en) * | 1989-03-21 | 1990-09-26 | Ciba-Geigy Ag | N-Hydrocarbyloxy derivatives of hindered amine-substituted s-triazines |
EP0389428A2 (en) * | 1989-03-21 | 1990-09-26 | Ciba-Geigy Ag | N,N-Bis(l-hydroxycarbyloxy-2,2,6,6-tetramethyl-piperidin-4-yl) amino triazines and stabilized compositions |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2642374A1 (de) * | 1976-09-21 | 1978-03-23 | Bayer Ag | Permanent stabilisierte polyurethane |
DE2642386A1 (de) * | 1976-09-21 | 1978-03-23 | Bayer Ag | Permanent stabilisierte polyurethane |
EP0002754B1 (de) * | 1977-12-30 | 1983-05-18 | Ciba-Geigy Ag | Neue Polyalkylpiperidinderivate von s-Triazinen, ihre Verwendung zum Stabilisieren von Kunststoffen und die so stabilisierten Kunststoffe |
DE2862332D1 (en) * | 1977-12-30 | 1983-11-10 | Ciba Geigy Ag | Stabilisation of heat-curable metallic enamel paints against the action of light, humidity and oxygen by the addition of polyalkylpiperidine derivatives |
EP0006213B1 (de) * | 1978-06-21 | 1982-09-01 | Ciba-Geigy Ag | Lichtstabilisierung von sauerkatalysierten Einbrennlacken |
JPS58152881A (ja) * | 1982-03-08 | 1983-09-10 | Adeka Argus Chem Co Ltd | ビス(2−ヒドロキシエチル)アミノトリアジン化合物 |
US4619956A (en) * | 1985-05-03 | 1986-10-28 | American Cyanamid Co. | Stabilization of high solids coatings with synergistic combinations |
FR2587340B1 (fr) * | 1985-09-13 | 1990-04-20 | Sandoz Sa | Nouvelles tetraalkylpiperidines, leur preparation et leur utilisation comme stabilisants des matieres polymeres |
DE3888065T2 (de) * | 1987-09-21 | 1994-07-14 | Ciba-Geigy Ag, Basel | N-Acyloxy-substituierte sterisch gehinderte Aminstabilisatoren. |
US5112890A (en) * | 1987-09-21 | 1992-05-12 | Ciba-Geigy Corporation | Stabilization of acid catalyzed thermoset resins |
EP0365481A1 (en) * | 1988-10-19 | 1990-04-25 | Ciba-Geigy Ag | Polymeric substrates stabilized with N-substituted hindered amines |
US5096950A (en) * | 1988-10-19 | 1992-03-17 | Ciba-Geigy Corporation | Polyolefin compositions stabilized with NOR-substituted hindered amines |
US5145893A (en) * | 1989-03-21 | 1992-09-08 | Ciba-Geigy Corporation | Non-migrating 1-hydrocarbyloxy hindered amine derivatives as polymer stabilizers |
ES2086394T3 (es) * | 1989-03-21 | 1996-07-01 | Ciba Geigy Ag | Compuestos aminicos impedidos de 1-hidrocarbiloxilo no migrantes como estabilizadores de polimeros. |
US5019613A (en) * | 1989-03-21 | 1991-05-28 | Ciba-Geigy Corporation | N-hydrocarbyloxy derivatives of hindered amine-substituted S-triazines |
IT1230091B (it) * | 1989-04-27 | 1991-10-05 | Ciba Geigy Spa | Composti piperidin-triazinici atti all'impiego come stabilizzanti per materiali organici. |
DE3919691A1 (de) * | 1989-06-16 | 1990-12-20 | Hoechst Ag | Polymere polyalkyl-1-oxa-diazaspirodecane |
US5214084A (en) * | 1990-03-14 | 1993-05-25 | Sumitomo Chemical Company, Ltd. | Stabilized polypropylene resin composition |
US5359703A (en) * | 1990-08-02 | 1994-10-25 | Xerox Corporation | Moving an object in a three-dimensional workspace |
-
1992
- 1992-05-05 US US07/878,678 patent/US5216156A/en not_active Expired - Lifetime
-
1993
- 1993-03-12 US US02/030,999 patent/US5300544A/en not_active Expired - Lifetime
- 1993-04-29 BE BE9300432A patent/BE1007753A3/fr not_active IP Right Cessation
- 1993-04-30 GB GB9308964A patent/GB2266717B/en not_active Expired - Lifetime
- 1993-05-03 CA CA002095415A patent/CA2095415C/en not_active Expired - Lifetime
- 1993-05-03 IT ITMI930870A patent/IT1271467B/it active IP Right Grant
- 1993-05-03 AT AT0085893A patent/AT406162B/de not_active IP Right Cessation
- 1993-05-03 MX MX9302590A patent/MX9302590A/es unknown
- 1993-05-04 ES ES09300939A patent/ES2060548B1/es not_active Expired - Fee Related
- 1993-05-04 KR KR1019930007784A patent/KR100253765B1/ko not_active IP Right Cessation
- 1993-05-04 DE DE4314721A patent/DE4314721B4/de not_active Expired - Lifetime
- 1993-05-04 FR FR9305276A patent/FR2690920B1/fr not_active Expired - Lifetime
- 1993-05-04 NL NL9300751A patent/NL195036C/nl not_active IP Right Cessation
- 1993-05-04 BR BR9301745A patent/BR9301745A/pt not_active IP Right Cessation
- 1993-05-05 SE SE9301539A patent/SE505317C2/sv unknown
- 1993-05-06 JP JP12996293A patent/JP3259200B2/ja not_active Expired - Lifetime
- 1993-05-07 TW TW082103572A patent/TW237451B/zh not_active IP Right Cessation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0138767A1 (de) * | 1983-10-11 | 1985-04-24 | Ciba-Geigy Ag | Stabilisierte polyolefinische Zusammensetzungen enthaltend Hydroxylaminderivate |
EP0209126A2 (en) * | 1985-07-16 | 1987-01-21 | ADEKA ARGUS CHEMICAL CO., Ltd. | Hydrocarbyl(polyphenol)-poly(2,2,6,6-tetramethyl piperidyl-1,3,5-triazines) as stabilizers for synthetic polymer compositions |
EP0209127A2 (en) * | 1985-07-17 | 1987-01-21 | ADEKA ARGUS CHEMICAL CO., Ltd. | Poly(2,2,6,6-tetramethyl-piperidyl-amino)-1,3,5-triazines as stabilizers for synthetic polymer compositions |
EP0309402A1 (en) * | 1987-09-21 | 1989-03-29 | Ciba-Geigy Ag | N-substituted hindered amine stabilizers |
EP0389431A2 (en) * | 1989-03-21 | 1990-09-26 | Ciba-Geigy Ag | N-Hydrocarbyloxy derivatives of hindered amine-substituted s-triazines |
EP0389428A2 (en) * | 1989-03-21 | 1990-09-26 | Ciba-Geigy Ag | N,N-Bis(l-hydroxycarbyloxy-2,2,6,6-tetramethyl-piperidin-4-yl) amino triazines and stabilized compositions |
Also Published As
Publication number | Publication date |
---|---|
CA2095415A1 (en) | 1993-11-06 |
IT1271467B (it) | 1997-05-28 |
FR2690920A1 (fr) | 1993-11-12 |
ATA85893A (de) | 1999-07-15 |
NL9300751A (nl) | 1993-12-01 |
DE4314721B4 (de) | 2006-02-02 |
KR100253765B1 (ko) | 2000-09-01 |
JPH069582A (ja) | 1994-01-18 |
BR9301745A (pt) | 1993-11-09 |
ES2060548B1 (es) | 1997-12-01 |
DE4314721A1 (de) | 1993-11-11 |
CA2095415C (en) | 2004-08-10 |
AT406162B (de) | 2000-03-27 |
US5300544A (en) | 1994-04-05 |
GB9308964D0 (en) | 1993-06-16 |
TW237451B (es) | 1995-01-01 |
SE505317C2 (sv) | 1997-08-04 |
JP3259200B2 (ja) | 2002-02-25 |
NL195036C (nl) | 2003-06-25 |
MX9302590A (es) | 1993-11-01 |
FR2690920B1 (fr) | 1994-12-30 |
KR930023339A (ko) | 1993-12-18 |
SE9301539D0 (sv) | 1993-05-05 |
ITMI930870A0 (it) | 1993-05-03 |
GB2266717A (en) | 1993-11-10 |
GB2266717B (en) | 1996-07-24 |
ITMI930870A1 (it) | 1994-11-03 |
BE1007753A3 (fr) | 1995-10-17 |
US5216156A (en) | 1993-06-01 |
SE9301539L (sv) | 1993-11-06 |
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