ES2046983T3 - Modificador del peso molecular a utilizar con catalizadores de tipo lantanidos y actinidos. - Google Patents
Modificador del peso molecular a utilizar con catalizadores de tipo lantanidos y actinidos.Info
- Publication number
- ES2046983T3 ES2046983T3 ES87200661T ES87200661T ES2046983T3 ES 2046983 T3 ES2046983 T3 ES 2046983T3 ES 87200661 T ES87200661 T ES 87200661T ES 87200661 T ES87200661 T ES 87200661T ES 2046983 T3 ES2046983 T3 ES 2046983T3
- Authority
- ES
- Spain
- Prior art keywords
- molecular weight
- lantanid
- catalysts
- compound containing
- lantanides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Abstract
LOS SISTEMAS CATALITICOS LANTANIDOS Y ACTINIDOS NORMALMENTE PARECEN SER "PSEUDO VIVIENTES" CUANDO SE USAN PARA POLIMERIZAR MONOMEROS DIOLEFINICOS CONJUGADOS. LAS POLIMERIZACIONES CATALIZADAS CON DICHOS CATALIZADORES PRODUCEN POLIMEROS CUYO PESO MOLECULAR AUMENTA AL HACERLO LA CONVERSION DEL MONOMERO. EN CONSECUENCIA CUALQUIER CAMBIO EN EL TIEMPO DE POLIMERIZACION O EN LA CONVERSION PUEDE AFECTAR AL PESO MOLECULAR FINAL DEL POLIMERO. ESTO HA HECHO DIFICIL CONTROLAR EL PESO MOLECULAR DE POLIMEROS QUE SE HACEN UTILIZANDO CATALIZADORES LANTANIDOS Y ACTINIDOS. SE HA DESCUBIERTO INESPERADAMENTE QUE LOS HALUROS VINILICOS PUEDEN USARSE COMO REGULADORES DEL PESO MOLECULAR PARA POLIMERIZACIONES CATALIZADAS CON CATALIZADORES LANTANIDOS Y ACTINIDOS. DE ACUERDO CON ELLO, LA PRESENTE INVENCION SE REFIERE A UN PROCESO QUE COMPRENDE POLIMERIZAR AL MENOS UN MONOMERO DIOLEFINICO CONJUGADO EN PREENCIA DE A) UN CATALIZADOR FORMADO POR: 1) UN COMPUESTO ORGANOALUMINICO, 2) UN COMPUESTO ORGANOMETALICO QUE CONTIENE UN METAL DEL GRUPO III-B DEL SISTEMA PERIODICO Y 3) AL MENOS UN COMPUESTO QUE CONTIENE POR LO MENOS UN ION HALURO LABIL; Y B) UN HALURO VINILICO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/852,678 US4663405A (en) | 1986-04-16 | 1986-04-16 | Molecular weight modifier for use with lanthanide and actinide catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2046983T3 true ES2046983T3 (es) | 1994-02-16 |
Family
ID=25313956
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES87200661T Expired - Lifetime ES2046983T3 (es) | 1986-04-16 | 1987-04-07 | Modificador del peso molecular a utilizar con catalizadores de tipo lantanidos y actinidos. |
Country Status (20)
Country | Link |
---|---|
US (1) | US4663405A (es) |
EP (1) | EP0241996B1 (es) |
JP (1) | JP2536750B2 (es) |
KR (1) | KR870010087A (es) |
CN (1) | CN1030704C (es) |
AU (1) | AU593631B2 (es) |
BR (1) | BR8702191A (es) |
CA (1) | CA1281495C (es) |
CS (1) | CS273635B2 (es) |
DD (1) | DD272095A5 (es) |
DE (1) | DE3788366T2 (es) |
EG (1) | EG18394A (es) |
ES (1) | ES2046983T3 (es) |
IE (1) | IE61801B1 (es) |
IN (1) | IN169484B (es) |
MX (1) | MX164537B (es) |
PL (1) | PL148420B1 (es) |
PT (1) | PT84717B (es) |
TR (1) | TR24303A (es) |
ZA (1) | ZA872506B (es) |
Families Citing this family (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DD296496A5 (de) * | 1990-07-12 | 1991-12-05 | Buna Ag,De | Katalysatorsystem fuer die loesungsmittelfreie polymerisation von 1,3-dienen zu polydienen |
CA2058383A1 (en) * | 1991-05-17 | 1992-11-18 | Ted M. Pettijohn | Olefin polymerization |
US5405815A (en) * | 1993-06-17 | 1995-04-11 | The Goodyear Tire & Rubber Company | Process for preparing a catalyst system useful in the synthesis of isoprene-butadiene rubber |
IT1273753B (it) * | 1994-02-11 | 1997-07-10 | Eniriceche Spa | Sistema catalitico e processo per la produzione di polidiolefine |
US6001478A (en) * | 1997-08-08 | 1999-12-14 | Union Carbide Chemicals & Plastics Technology Corporation | Resin particle produced by diene polymerization with rare earth and transition metal catalysts |
DE19806931A1 (de) * | 1998-02-19 | 1999-08-26 | Bayer Ag | Verfahren zur Herstellung von Polydienen mit geregelter Mooney-Viskosität |
US6479601B1 (en) | 1999-08-06 | 2002-11-12 | The Goodyear Tire & Rubber Company | Transition metal catalysts for diene polymerizations |
US6871751B2 (en) * | 2001-10-19 | 2005-03-29 | The Goodyear Tire & Rubber Company | Rubber for baby bottle nipples, pacifiers, & syringe plungers |
US9226876B2 (en) | 2001-10-19 | 2016-01-05 | The Goodyear Tire & Rubber Company | Rubber for baby bottle nipples, pacifiers, and syringe plungers |
US7022783B2 (en) * | 2001-12-31 | 2006-04-04 | The Goodyear Tire & Rubber Company | Group III-B metal catalyst system |
US6780948B2 (en) | 2002-03-28 | 2004-08-24 | The Goodyear Tire & Rubber Company | Synthesis of polyisoprene with neodymium catalyst |
US7091150B2 (en) * | 2003-12-19 | 2006-08-15 | The Goodyear Tire & Rubber Company | Synthetic polyisoprene rubber |
US7741418B2 (en) * | 2007-12-31 | 2010-06-22 | Bridgestone Corporation | Process for producing polydienes |
US7825201B2 (en) * | 2007-12-31 | 2010-11-02 | Bridgestone Corporation | Process for producing polydienes |
US8623975B2 (en) | 2009-06-24 | 2014-01-07 | Bridgestone Corporation | Process for producing polydienes |
CN102234342B (zh) * | 2010-04-30 | 2013-03-06 | 青岛伊科思新材料股份有限公司 | 应用于异戊橡胶生产的稀土催化剂的制备方法 |
US9000107B2 (en) | 2011-01-31 | 2015-04-07 | Bridgestone Corporation | Process for producing polydienes |
RU2523799C1 (ru) | 2011-12-20 | 2014-07-27 | Чайна Петролеум Энд Кемикал Корпорейшн | Добавка и способ для обрыва полимеризации и/или снижения вязкости раствора полимера |
JP6231997B2 (ja) | 2012-02-27 | 2017-11-15 | 株式会社ブリヂストン | 高シスポリジエンを調製する方法 |
CN103360414A (zh) * | 2012-03-30 | 2013-10-23 | 青岛伊科思新材料股份有限公司 | 喹啉类稀土配合物、催化剂和聚合方法 |
US8598286B1 (en) | 2012-11-05 | 2013-12-03 | The Goodyear Tire & Rubber Company | High cis diene/phenylbutadiene copolymers prepared using a Ziegler/Natta neodymium catalyst |
EP2889157B1 (en) | 2013-12-19 | 2019-05-01 | The Goodyear Tire & Rubber Company | Tire having tread with tread groove-containing rubber block joining the tire carcass with the tread cap |
US9757986B2 (en) | 2013-12-19 | 2017-09-12 | The Goodyear Tire & Rubber Company | Tire having tread with tread groove-containing rubber block joining the tire carcass and extending through a tread base into a tread cap |
US20150174969A1 (en) | 2013-12-19 | 2015-06-25 | The Goodyear Tire & Rubber Company | Tire with heat transfer rubber conduit |
WO2016057985A1 (en) | 2014-10-10 | 2016-04-14 | Bridgestone Corporation | Polymerization catalyst composition and method of employing same |
US20160200899A1 (en) | 2015-01-13 | 2016-07-14 | The Goodyear Tire & Rubber Company | Tire with tread intended for both on and off-the-road service |
CN107428871B (zh) | 2015-01-28 | 2021-03-30 | 株式会社普利司通 | 具有改善的耐冷流性的顺式-1,4-聚二烯 |
JP6717840B2 (ja) | 2015-01-28 | 2020-07-08 | 株式会社ブリヂストン | 熟成ランタニド系触媒系及びシス−1,4−ポリジエンの調製における同触媒系の使用 |
US10202474B2 (en) | 2015-09-11 | 2019-02-12 | Bridgestone Corporation | Process for producing polydienes |
US10730985B2 (en) | 2016-12-19 | 2020-08-04 | Bridgestone Corporation | Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer |
CN111630075B (zh) | 2017-12-15 | 2023-04-28 | 株式会社普利司通 | 官能化聚合物、用于制备该官能化聚合物的方法和含有该官能化聚合物的橡胶组合物 |
JP7059378B2 (ja) | 2017-12-30 | 2022-04-25 | 株式会社ブリヂストン | 複数の末端官能化ポリマーを含む組成物 |
US11767388B1 (en) | 2019-09-18 | 2023-09-26 | The Goodyear Tire & Rubber Company | Silicon-functionalized rubber |
EP3838932B1 (en) | 2019-12-20 | 2022-08-10 | The Goodyear Tire & Rubber Company | Synthesis of isoprene-butadiene copolymer rubbers |
US11584808B2 (en) | 2019-12-30 | 2023-02-21 | Bridgestone Corporation | Polymerization catalyst composition and method of employing same |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3585178A (en) * | 1968-11-13 | 1971-06-15 | Japanese Geon Co Ltd | Process for the preparation of cis-1,4-isoprene polymer |
GB1313426A (en) * | 1969-05-31 | 1973-04-11 | Japan Synthetic Rubber Co Ltd | Process for producing conjugated diolefinic polymers |
US3846388A (en) * | 1970-03-10 | 1974-11-05 | Bridgestone Tire Co Ltd | Copolymer of a conjugated diolefin and vinyl chloride and manufacturing process therefor |
DE2625390A1 (de) * | 1976-06-05 | 1977-12-15 | Bayer Ag | Uranhaltige mischkatalysatoren sowie deren verwendung zur polymerisation von olefinen |
DE2830080A1 (de) * | 1978-07-08 | 1980-01-17 | Bayer Ag | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
DE2848964A1 (de) * | 1978-11-11 | 1980-05-22 | Bayer Ag | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
JPS5945337A (ja) * | 1982-09-07 | 1984-03-14 | Japan Synthetic Rubber Co Ltd | 生強度の改良されたポリブタジエンゴム組成物 |
-
1986
- 1986-04-16 US US06/852,678 patent/US4663405A/en not_active Expired - Lifetime
-
1987
- 1987-04-03 MX MX5890A patent/MX164537B/es unknown
- 1987-04-04 CN CN87103699A patent/CN1030704C/zh not_active Expired - Lifetime
- 1987-04-07 ES ES87200661T patent/ES2046983T3/es not_active Expired - Lifetime
- 1987-04-07 DE DE3788366T patent/DE3788366T2/de not_active Expired - Lifetime
- 1987-04-07 EP EP87200661A patent/EP0241996B1/en not_active Expired - Lifetime
- 1987-04-07 ZA ZA872506A patent/ZA872506B/xx unknown
- 1987-04-09 AU AU71356/87A patent/AU593631B2/en not_active Expired
- 1987-04-14 EG EG212/87A patent/EG18394A/xx active
- 1987-04-15 IE IE98287A patent/IE61801B1/en not_active IP Right Cessation
- 1987-04-15 DD DD87301856A patent/DD272095A5/de not_active IP Right Cessation
- 1987-04-15 BR BR8702191A patent/BR8702191A/pt not_active IP Right Cessation
- 1987-04-15 CA CA000534751A patent/CA1281495C/en not_active Expired - Lifetime
- 1987-04-15 IN IN283/MAS/87A patent/IN169484B/en unknown
- 1987-04-15 KR KR870003659A patent/KR870010087A/ko not_active Application Discontinuation
- 1987-04-15 TR TR87/0273A patent/TR24303A/xx unknown
- 1987-04-16 PT PT84717A patent/PT84717B/pt unknown
- 1987-04-16 PL PL1987265208A patent/PL148420B1/pl unknown
- 1987-04-16 CS CS274387A patent/CS273635B2/cs not_active IP Right Cessation
- 1987-04-16 JP JP62092117A patent/JP2536750B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
IE870982L (en) | 1987-10-16 |
US4663405A (en) | 1987-05-05 |
IE61801B1 (en) | 1994-11-30 |
EG18394A (en) | 1992-10-30 |
AU593631B2 (en) | 1990-02-15 |
EP0241996B1 (en) | 1993-12-08 |
PL148420B1 (en) | 1989-10-31 |
EP0241996A3 (en) | 1990-04-25 |
JP2536750B2 (ja) | 1996-09-18 |
PT84717A (en) | 1987-05-01 |
CA1281495C (en) | 1991-03-12 |
MX164537B (es) | 1992-08-25 |
DE3788366T2 (de) | 1994-06-01 |
EP0241996A2 (en) | 1987-10-21 |
TR24303A (tr) | 1991-08-01 |
DE3788366D1 (de) | 1994-01-20 |
BR8702191A (pt) | 1988-02-17 |
CN1030704C (zh) | 1996-01-17 |
DD272095A5 (de) | 1989-09-27 |
PT84717B (pt) | 1989-12-29 |
CN87103699A (zh) | 1988-09-21 |
JPS62295911A (ja) | 1987-12-23 |
KR870010087A (ko) | 1987-11-30 |
CS274387A2 (en) | 1990-08-14 |
CS273635B2 (en) | 1991-03-12 |
IN169484B (es) | 1991-10-26 |
ZA872506B (en) | 1987-11-25 |
AU7135687A (en) | 1987-10-22 |
PL265208A1 (en) | 1988-05-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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