EP2860308A1 - Tissu enduit étirable et son processus de production - Google Patents
Tissu enduit étirable et son processus de production Download PDFInfo
- Publication number
- EP2860308A1 EP2860308A1 EP13804596.8A EP13804596A EP2860308A1 EP 2860308 A1 EP2860308 A1 EP 2860308A1 EP 13804596 A EP13804596 A EP 13804596A EP 2860308 A1 EP2860308 A1 EP 2860308A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fabric
- stretchable
- synthetic resin
- coated fabric
- less
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 239000004744 fabric Substances 0.000 title claims abstract description 299
- 238000000034 method Methods 0.000 title claims description 52
- 230000008569 process Effects 0.000 title claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 132
- 239000005871 repellent Substances 0.000 claims abstract description 94
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 78
- 230000002940 repellent Effects 0.000 claims abstract description 75
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 74
- 239000000057 synthetic resin Substances 0.000 claims abstract description 74
- 239000000835 fiber Substances 0.000 claims abstract description 72
- 229920005989 resin Polymers 0.000 claims abstract description 63
- 239000011347 resin Substances 0.000 claims abstract description 63
- 238000000576 coating method Methods 0.000 claims abstract description 47
- 239000011248 coating agent Substances 0.000 claims abstract description 45
- 230000009974 thixotropic effect Effects 0.000 claims abstract description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 9
- 229920001577 copolymer Polymers 0.000 claims abstract description 9
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims abstract description 9
- 230000035699 permeability Effects 0.000 claims description 68
- 229920000728 polyester Polymers 0.000 claims description 19
- 238000005406 washing Methods 0.000 claims description 15
- 229920000178 Acrylic resin Polymers 0.000 claims description 10
- 239000004925 Acrylic resin Substances 0.000 claims description 10
- 238000009940 knitting Methods 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 7
- 239000004952 Polyamide Substances 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 229920002050 silicone resin Polymers 0.000 claims description 6
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 6
- YFSUTJLHUFNCNZ-UHFFFAOYSA-M 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctane-1-sulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YFSUTJLHUFNCNZ-UHFFFAOYSA-M 0.000 abstract description 3
- SNGREZUHAYWORS-UHFFFAOYSA-N perfluorooctanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SNGREZUHAYWORS-UHFFFAOYSA-N 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 45
- 239000000203 mixture Substances 0.000 description 22
- 230000000052 comparative effect Effects 0.000 description 20
- 230000000704 physical effect Effects 0.000 description 20
- 239000003431 cross linking reagent Substances 0.000 description 14
- 239000007787 solid Substances 0.000 description 12
- 238000010345 tape casting Methods 0.000 description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 6
- -1 and the like) Polymers 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 238000007865 diluting Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 4
- 239000002216 antistatic agent Substances 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 150000002513 isocyanates Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003961 penetration enhancing agent Substances 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920006306 polyurethane fiber Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920006304 triacetate fiber Polymers 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
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- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
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- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/18—Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
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- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B21/14—Fabrics characterised by the incorporation by knitting, in one or more thread, fleece, or fabric layers, of reinforcing, binding, or decorative threads; Fabrics incorporating small auxiliary elements, e.g. for decorative purposes
- D04B21/16—Fabrics characterised by the incorporation by knitting, in one or more thread, fleece, or fabric layers, of reinforcing, binding, or decorative threads; Fabrics incorporating small auxiliary elements, e.g. for decorative purposes incorporating synthetic threads
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
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- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
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- D06N3/042—Acrylic polymers
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
- D06N3/142—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
- D06N3/144—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer with polyurethane and polymerisation products, e.g. acrylics, PVC
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
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- D06M2101/34—Polyamides
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- D—TEXTILES; PAPER
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/02—Synthetic macromolecular fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/02—Synthetic macromolecular fibres
- D06N2201/0263—Polyamide fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N2203/041—Polyacrylic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06N2203/068—Polyurethanes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/142—Hydrophobic
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/10—Physical properties porous
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2403/00—Details of fabric structure established in the fabric forming process
- D10B2403/01—Surface features
- D10B2403/011—Dissimilar front and back faces
- D10B2403/0112—One smooth surface, e.g. laminated or coated
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2008—Fabric composed of a fiber or strand which is of specific structural definition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2041—Two or more non-extruded coatings or impregnations
- Y10T442/2098—At least two coatings or impregnations of different chemical composition
Definitions
- C6 fluorinated water repellent refers to a fluorinated water repellent that comprises a copolymer comprising a perfluoroalkyl group with six or less carbon atoms.
- Patent Literature 1 discloses a water-oil-repellent fabric using a C6 fluorinated water repellent and a process for producing the same.
- the C6 fluorinated water repellent has a relatively low water-oil-repellency, compared with the conventional C8 fluorinated water repellent. If the C6 fluorinated water repellent is used to treat a fiber fabric only for water-oil-repellency, the fabric obtains, as initial performance, similar water-oil-repellency to a fabric using the C8 fluorinated water repellent. However, when the fiber fabric is subsequently coated with a synthetic resin solution, the synthetic resin solution penetrates the fiber fabric. It is presumed that this phenomenon occurs because a fabric treated with a C6 fluorinated water repellent has a lower dynamic oil-repellency offered by coating, compared with a fabric treated with a C8 fluorinated water repellent. Consequently, it is difficult to form a continuous resin film on a surface of the fiber fabric, which causes the problem that the necessary performance (hydraulic resistance, moisture permeability, wind proof property, and the like) is not provided.
- the present disclosure has been developed in view of these problems, and directed to provide a stretchable coated fabric that exerts no influence on the environment and that is highly moisture permeable, waterproof, and windproof, and a process for producing the same.
- a stretchable coated fabric is a stretchable coated fabric produced by treating a stretchable fiber fabric for water repellency with a fluorinated water repellent that comprises a copolymer comprising a perfluoroalkyl group with six or less carbon atoms and applying a synthetic resin solution to at least one side of the stretchable fiber fabric to form a resin coating film that comprises a synthetic resin, wherein the stretchable fiber fabric treated for water repellency with the fluorinated water repellent has a toluene repellency of 100 seconds or longer, and the synthetic resin solution has a thixotropic index at 23°C in a range from 1.4 to 2.0, and wherein the synthetic resin has a 100% modulus of 5 kgf/cm 2 or greater.
- the synthetic resin is at least one selected from acrylic resins, urethane resins, and silicone resins.
- the stretchable fiber fabric is a fabric that primarily comprises polyamide fibers and/or polyester fibers having a total fineness of 84 dtex or less, and that has a basis weight of 200 g/m 2 or less, a warp elongation (JIS L1096 A Method) at a load of 0.5 kgf of 45% or less, and a warp elongation at a load of 2.0 kgf of 75% or less.
- JIS L1096 A Method JIS L1096 A Method
- a process for producing a stretchable coated fabric comprises a step of preparing a stretchable fiber fabric treated for water repellency with a fluorinated water repellent that comprises a copolymer comprising a perfluoroalkyl group with six or less carbon atoms, and a step of applying a solution of a synthetic resin in a solvent to at least one side of the stretchable fiber fabric, wherein the fluorinated water repellent is used to impart a toluene repellency of 100 seconds or longer to the stretchable fabric, and the synthetic resin solution has a thixotropic index at 23°C in a range from 1.4 to 2.0, and wherein the synthetic resin has a 100% modulus of 5 kgf/cm 2 or greater.
- the synthetic resin is at least one selected from acrylic resins, urethane resins, and silicone resins.
- the stretchable coated fabric according to the present disclosure is treated for water repellency with a fluorinated water repellent that comprises a copolymer comprising a perfluoroalkyl group with six or less carbon atoms (C6 fluorinated water repellent).
- a fluorinated water repellent that comprises a copolymer comprising a perfluoroalkyl group with six or less carbon atoms (C6 fluorinated water repellent).
- the stretchable fiber fabric treated for water repellency with a C6 fluorinated water repellent has a toluene repellency of 100 seconds or longer;
- the synthetic resin solution applied to at least one side of the stretchable fiber fabric has a thixotropic index at 23°C in a range from 1.4 to 2.0; and the synthetic resin has a 100% modulus of 5 kgf/cm 2 or greater. This prevents the synthetic resin from leaking to the back side, and allows formation of a resin coating film that has good film forming properties. Consequently, a stretchable coated fabric that has excellent moisture permeability, excellent waterproofness, and excellent windproof property can be provided.
- the stretchable coated fabric according to an embodiment of the present disclosure will be described in detail below.
- the stretchable coated fabric according to the embodiment is produced by treating a stretchable fiber fabric for water repellency with a C6 fluorinated water repellent and then applying a synthetic resin to at least one side of the stretchable fiber fabric.
- the stretchable fiber fabric used in the embodiment includes, for example, woven fabrics, knitted fabrics, nonwoven fabrics, and the like. Among them, knitted fabrics are preferred in terms of stretchablity.
- Fiber materials include, for example, natural fibers such as cotton, hemp, wool, and silk, regenerated fibers such as rayon and cupra, semisynthetic fibers such as acetate and triacetate, and synthetic fibers such as polyamides (nylon 6, nylon 66, and the like), polyesters (polyethylene terephthalate, polytrimethylene terephthalate, and the like), polyurethanes, and polyaclylics. Two or more of these materials may be used in combination.
- the yarns that constitute the stretchable fiber fabric have a total fineness of 84 dtex (decitex) or less. If the yarns used in the embodiment have a total fineness of greater than 84 dtex, the yarns produce a hard hand feeling.
- the stretchable fiber fabric is, for example, a knitted fabric, such yarns produce large irregularities in the surface of the stretchable fiber fabric. Thus, the film-forming properties are reduced. As a result, the fabric may not provide physical properties such as hydraulic resistance and air permeability that are required after coating.
- a water repellent used in the embodiment is a fluorinated water repellent that comprises a copolymer comprising a perfluoroalkyl group with six or less carbon atoms (C6 fluorinated water repellent), because such repellent can impart high water repellency and is environmentally and biologically friendly.
- the C6 fluorinated water repellent is preferably contained in an amount of 80-100% based on the overall water repellents used, and a paraffin-based water repellent and/or a silicone-based water repellent as another water-repellent may be contained in an amount of less than 20%.
- the C6 fluorinated water repellent used in the present disclosure may be individually used, or two or more thereof may be used in combination, as long as performance requirements such as water repellency and oil-repellency are met depending on usage.
- the synthetic resin solution used in the embodiment should have a thixotropic index at 23°C in a range from 1.4 to 2.0. More preferably, the thixotropic index is in a range from 1.45 to 1.7.
- the term thixotropic index refers to a viscosity at a low rotation speed divided by a viscosity at a high rotation speed, as determined with a rotary viscometer at constant temperature. If the thixotropic index is less than 1.4, the synthetic resin that has been coated onto the fiber fabric to a desired thickness is flowable until the resin cures, and thus the fabric is unable to retain the coating film. If the thixotropic index is more than 2.0, the viscosity significantly changes relative to shear stress during coating, and thus there is difficulty in controlling the coating form.
- the synthetic resin solution preferably has a viscosity at 23°C in a range from 8000 to 25000 mPa ⁇ s, and more preferably in a range from 10000 to 20000 mPa ⁇ s. If the viscosity at 23°C is less than 8000 mPa ⁇ s, the synthetic resin may deeply penetrate the fiber fabric and produce a hard hand feeling. And the synthetic resin solution may leak through the fiber fabric to the other side. On the other hand, if the viscosity at 23°C is more than 25000 mPa ⁇ s, streaks and air bubbles are prone to be formed during coating. As a result, it becomes difficult to form a resin film, and thus sufficient hydraulic resistance and sufficient windproof property may not be provided.
- the synthetic resin used in the present disclosure has a 100% modulus of 5 kgf/cm 2 or greater. If the synthetic resin used has a 100% modulus of less than 5 kgf/cm 2 , it becomes difficult to form a continuous film during coating. The film may also have a reduced strength, and the necessary physical properties such as hydraulic resistance and air permeability may not be achieved.
- the upper limit for the 100% modulus is preferably less than 60 kgf/cm 2 in order not to impair the hand feeling.
- the synthetic resin used in the present disclosure can be at least one selected from acrylic resins, urethane resins, and silicone resins. Particularly, the acrylic resins and the urethane resins can be preferably used, because these resins can provide the necessary film strength.
- the inorganic particulates added have an average particle size from 0.2 ⁇ m to 20 ⁇ m, the necessary hydraulic resistance, the necessary moisture permeability, and the necessary air permeability can be controlled, and the synthetic resin film does not have a significantly reduced strength. If the inorganic particulates added have an average particle size of more than 20 ⁇ m, the film strength is reduced, which is not preferred. If the inorganic particulates added have an average particle size of less than 0.2 ⁇ m, the necessary hydraulic resistance, the necessary moisture permeability, and the necessary air permeability may not be able to be controlled.
- the stretchable fiber fabric used in the embodiment is previously scoured and dyed according to routine procedures, and then treated, as normally, for water repellency with a C6 fluorinated water repellent as a pretreatment prior to coating.
- a padding process, a coating process, a gravure coating process, a spraying process, or the like can be employed.
- the C6 fluorinated water repellent alone may not impart wash resistance to the water repellency, and thus it is preferred to add a melamine or isocyanate crosslinking agent, a crosslinking catalyst, and/or the like, when the fabric is treated for water repellency.
- a melamine or isocyanate crosslinking agent such as sodium melamine or isocyanate
- a crosslinking catalyst such as sodium sulfate
- an antistatic agent, a sewability enhancer, and/or the like also may be added, where necessary.
- the fabric Before or after the treatment for water repellency, the fabric may also be calendered, where necessary.
- the coating resin is preferably applied in an amount so that the resin solids present in an amount from 12 to 25 g/m 2 . If the resin solids present in an amount of less than 12 g/m 2 , the fabric is less likely to provide the necessary physical properties such as hydraulic resistance and air permeability. On the other hand, if the resin solids present in an amount of more than 25 g/m 2 , the fabric tends to have a hard hand feeling.
- the stretchable coated fabric in the embodiment has a moisture permeability (JIS L1092 A-1 Method) of 3000 g/m 2 /24hr or greater. If the stretchable coated fabric has a moisture permeability of less than 3000 g/m 2 /24hr, the fabric becomes stuffy when worn as a garment, which may bring about a discomfort.
- JIS L1092 A-1 Method JIS L1092 A-1 Method
- the stretchable coated fabric in the embodiment has an air permeability of 6 cc/cm 2 /sec or less (JIS L1018 Frazier Method).
- the fabric can be used as a common windproof material.
- a stretchable coated fabric is required to have a smaller air permeability.
- some applications have required a smaller air permeability.
- a stretchable coated fabric in such application preferably has an air permeability from 1 to 3 cc/cm 2 /sec or less.
- the stretchable coated fabric having an air permeability of more than 6 cc/cm 2 /sec cannot provide sufficient windproofness, when worn as a sports garment.
- the uncoated side or the coated side may be used as the outer surface.
- the uncoated side is used as the outer surface for water repellency, although the coated side may be used as the outer surface. In the latter case, however, the water repellency is reduced due to the coating resin film, which is not preferred.
- stretchable coated fabrics according to Examples 1-5 of the present disclosure were produced to evaluate their performance. And for comparison, stretchable coated fabrics of Comparative Examples 1-4 were produced to evaluate their performance.
- the viscosity of the synthetic resin solutions is a viscosity at a rotation speed 12 rpm at 23°C, as determined with a Brookfield-type (BM-type) viscometer from Toki Sangyo Co., Ltd. with a No. 4 spindle (without guard).
- Measurement was made with a specimen having a width of 5 cm, a grip distance of 20 cm, a tensile speed of 200 mm/min, and a load of 0.5 kgf and 2.0 kgf.
- the hand feeling of a specimen was evaluated according to the following criteria.
- the coating resin does not significantly penetrate the fabric, and the resin film covers the coated surface of the fabric.
- the coating resin slightly penetrates the fabric, although the resin film almost covers the coated surface of the fabric.
- the coating resin mostly penetrates the fabric, and little resin film is formed on the coated surface.
- the fabric had an air permeability of 1 cc/cm 2 /sec, a hydraulic resistance of 300 mmH 2 O, a moisture permeability of 6568 g/m 2 /24hr, an initial water repellency of a fourth grade, and a water repellency after 20 washings of a third grade.
- the stretchable coated fabric had a soft hand feel.
- the coating resin did not significantly penetrate the fabric, and the resin film covered the coated surface of the fabric.
- a 22 dtex/24 filament polyester yarn was used to knit an interlock knitted fabric by a 40 gauge flat knitting machine. Then, the fabric was scoured and dyed according to routine procedures.
- the knitted fabric dyed had a basis weight of 55 g/m 2 .
- the knitted fabric had a warp elongation at a load of 0.5 kgf of 9.6% and a warp elongation at a load of 2.0 kgf of 23.0%.
- the knitted fabric produced above was immersed in an aqueous solution containing two types of C6 fluorinated water repellents as described above in Composition 1.
- the fabric was wrung out by a mangle (to a wet pick-up of 53% by weight), dried at 120°C for 60 seconds, and then treated with heat at 160°C for 60 seconds for water repellency.
- the toluene repellency of the water-repellent fabric was measured to be 144 seconds.
- the synthetic resin solution as described above in Composition 2 was applied by a floating knife coating process using a knife coater.
- the solution was applied to the knitted fabric in an amount so that the resin solids present in an amount of 16 g/m 2 , and then treated with heat at 120°C for a minute.
- the fabric was heat-set at 150°C to give a stretchable coated fabric of Example 2.
- the stretchable coated fabric had a basis weight of 71 g/m 2 .
- the fabric had an air permeability of 1 cc/cm 2 /sec, a hydraulic resistance of 220 mmH 2 O, a water-vapor permeability of 8384 g/m 2 /24hr, an initial water repellency of a fourth grade, and a water repellency after 20 washings of a third grade.
- the stretchable coated fabric had a soft hand feel.
- the coating resin did not significantly penetrate the fabric, and the resin film covered the coated surface of the fabric.
- a 56 dtex/48 filament 6 nylon yarn was used to knit a 32 gauge tricot knitted fabric. Then, the fabric was scoured and dyed according to routine procedures.
- the knitted fabric dyed had a basis weight of 178 g/m 2 .
- the knitted fabric had a warp elongation at a load of 0.5 kgf of 8.2% and a warp elongation at a load of 2.0 kgf of 19.3%.
- the knitted fabric produced above was immersed in an aqueous solution containing two types of C6 fluorinated water repellents having different performance characteristics as described above in Composition 1.
- the fabric was wrung out by a mangle (to a wet pick-up of 56% by weight), dried at 120°C for 60 seconds, and then treated with heat at 160°C for 60 seconds for water repellency.
- the toluene repellency of the water-repellent fabric was measured to be 174 seconds.
- the synthetic resin solution as described above in Composition 2 was applied by a floating knife coating process using a knife coater.
- the solution was applied to the knitted fabric in an amount so that the resin solids present in an amount of 16 g/m 2 , and then treated with heat at 120°C for a minute.
- the fabric was heat-set at 150°C to give a stretchable coated fabric of Example 3.
- the stretchable coated fabric had a basis weight of 194 g/m 2 .
- An 84 dtex/72 filament polyester yarn was used to knit an interlock knitted fabric by a 28 gauge flat knitting machine. Then, the fabric was scoured and dyed according to routine procedures.
- the knitted fabric dyed had a basis weight of 188 g/m 2 .
- the knitted fabric had a warp elongation at a load of 0.5 kgf of 5.3% and a warp elongation at a load of 2.0 kgf of 10.5%.
- the knitted fabric produced above was immersed in an aqueous solution containing two types of C6 fluorinated water repellents having different performance characteristics as described above in Composition 1.
- the fabric was wrung out by a mangle (to a wet pick-up of 54% by weight), dried at 120°C for 60 seconds, and then treated with heat at 160°C for 60 seconds for water repellency.
- the toluene repellency of the water-repellent fabric was measured to be 163 seconds.
- the synthetic resin solution as described above in Composition 2 was applied by a floating knife coating process using a knife coater.
- the solution was applied to the knitted fabric in an amount so that the resin solids present in an amount of 16 g/m 2 , and then treated with heat at 120°C for a minute.
- the fabric was heat-set at 150°C to give a stretchable coated fabric of Example 4.
- the stretchable coated fabric had a basis weight of 204 g/m 2 .
- the fabric had an air permeability of 1 cc/cm 2 /sec, a hydraulic resistance of 220 mmH 2 O, a moisture permeability of 8453 g/m 2 /24hr, an initial water repellency of a fourth grade, and a water repellency after 20 washings of a third grade.
- the stretchable coated fabric had a soft hand feel.
- the coating resin did not significantly penetrate the fabric, and the resin film covered the coated surface of the fabric.
- Example 2 To a water-repellent knitted fabric as used in Example 1, a synthetic resin solution as described in Composition 3 was applied by a floating knife coating process using a knife coater. The solution was applied to the knitted fabric in an amount so that the resin solids present in an amount of 19 g/m 2 , and then treated with heat at 120°C for a minute. Then, the fabric was heat-set at 150°C to give a stretchable coated fabric of Example 5. The stretchable coated fabric had a basis weight of 93 g/m 2 .
- the synthetic resin solution had a viscosity of 24800 mPa ⁇ s (as determined with a Brookfield-type (BM-type) viscometer) and a thixotropic index at 23°C of 1.69.
- Example 2 To a water-repellent knitted fabric as used in Example 1, a synthetic resin solution as described in Composition 6 was applied by a floating knife coating process using a knife coater. The solution was applied to the knitted fabric in an amount so that the resin solids present in an amount of 16 g/m 2 , and then treated with heat at 120°C for a minute. Then, the fabric was heat-set at 150°C to give a stretchable coated fabric of Comparative Example 3. The stretchable coated fabric had a basis weight of 90 g/m 2 .
- the fabric had an air permeability of 8 cc/cm 2 /sec, a hydraulic resistance of 140 mmH 2 O, a moisture permeability of 7920 g/m 2 /24hr, an initial water repellency of a fourth grade, and a water repellency after 20 washings of a third grade.
- the stretchable coated fabric had a slightly hard hand feel. When the quality of the coated surface was observed, the coating resin slightly penetrated the fabric, although the resin film almost covered the coated surface of the fabric.
- a knitted fabric as used in Example 2 was immersed in an aqueous solution containing a single type of a C6 fluorinated water repellent as described in Composition 7.
- the fabric was wrung out by a mangle (to a wet pick-up of 53% by weight), dried at 120°C for 60 seconds, and then treated with heat at 160°C for 60 seconds for water repellency. After the water-repellent treatment, the toluene repellency of the water-repellent fabric was measured to be 36 seconds.
- the synthetic resin solution as described above in Composition 2 was applied by a floating knife coating process using a knife coater.
- the solution was applied to the knitted fabric in an amount so that the resin solids present in an amount of 17 g/m 2 , and then treated with heat at 120°C for a minute.
- the fabric was heat-set at 150°C to give a stretchable coated fabric of Comparative Example 4.
- the stretchable coated fabric had a basis weight of 72 g/m 2 .
- the fabric had an air permeability of 10 cc/cm 2 /sec, a hydraulic resistance of 80 mmH 2 O, a moisture permeability of 7453 g/m 2 /24hr, an initial water repellency of a fourth grade, and a water repellency after 20 washings of a third grade.
- the stretchable coated fabric had a hard hand feel. When the quality of the coated surface was observed, the coating resin slightly penetrated the fabric, although the resin film almost covered the coated surface of the fabric.
- Example 1 Example 2
- Example 3 Example 4
- the fabrics had an initial water repellency of a fourth grade and a water repellency after 20 washings of a third grade, which were sufficient.
- the fabrics also had a soft hand feeling and a good quality of the coated surface, as their resin film almost covered the coated surface of the fabric.
- the synthetic resin (coating resin) of the stretchable coated fabric of Comparative Example 1 had a thixotropic index at 23°C of 1.32, which did not meet the requirement in a range from 1.4 to 2.0, a 100% modulus of 4 kgf/cm 2 , which did not meet the requirement of 5 kgf/cm 2 or greater. Consequently, the fabric had a large air permeability of 12 cc/cm 2 /sec and thus had insufficient windproof property. The fabric also had a low hydraulic resistance of 90 mmH 2 O, and thus the waterproofness was problematic. And the fabric had a hard hand feeling, and the quality of the coated surface was problematic.
- the stretchable coated fabric of Comparative Example 2 had no problem with the air permeability, the hydraulic resistance, the moisture permeability, the hand feeling, and the quality of the coated surface, although the fabric did not solve the environmentally sensitive problem, as the fabric uses a C8 fluorinated water repellent instead of a C6 fluorinated water repellent.
- the synthetic resin (coating resin) of the stretchable coated fabric of Comparative Example 3 had a thixotropic index at 23°C of 1.42, which met the requirement in a range from 1.4 to 2.0, and a 100% modulus of 4 kgf/cm 2 , which did not meet the requirement of 5 kgf/cm 2 or greater. Consequently, the fabric had a high air permeability of 8 cc/cm 2 /sec and thus had insufficient windproof property. The fabric also had a slightly insufficient hydraulic resistance of 140 mmH 2 O or higher. And the fabric also had a problem with the hand feel and the quality of the coated surface.
- the synthetic resin (coating resin) of the stretchable coated fabric of Comparative Example 4 had a thixotropic index at 23°C of 1.44, which met the requirement in a range from 1.4 to 2.0, and a 100% modulus of 9 kgf/cm 2 , which met the requirement of 5 kgf/cm 2 or greater.
- the fluorinated water repellent had a small toluene repellency of 36 seconds, which did not meet the requirement of 100 seconds or longer. Consequently, the fabric had a large air permeability of 10 cc/cm 2 /sec and thus had insufficient windproof property.
- the fabric also had an insufficient hydraulic resistance of 80 mmH 2 O or higher. And the fabric had a problem with the hand feel and the quality of the coated surface.
- the synthetic resin (coating resin) of the stretchable coated fabric of Example 5 had a thixotropic index at 23°C of 1.69, which was larger than the thixotropic index of 1.44 of the stretchable coated fabrics of Examples 1-4.
- the fabric had a smaller air permeability of 0.5 cc/cm 2 /sec and thus had particularly good_ windproof property.
- the fabric also had a larger hydraulic resistance of 360 mmH 2 O and thus had good waterproofness.
- the stretchable coated fabrics according to the embodiment and Examples have good water-vapor permeability, good waterproofness, and good windproofness.
- the fabrics are favorably used for outdoor and sports applications in the garment field.
- the stretchable coated fabric according to the present disclosure is suitable for a garment fabric used for outdoor and sports applications.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Knitting Of Fabric (AREA)
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Applications Claiming Priority (2)
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JP2012132309A JP5596081B2 (ja) | 2012-06-11 | 2012-06-11 | 伸縮性コーティング布帛及びその製造方法 |
PCT/JP2013/065950 WO2013187360A1 (fr) | 2012-06-11 | 2013-06-10 | Tissu enduit étirable et son processus de production |
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US (1) | US20150140884A1 (fr) |
EP (1) | EP2860308A4 (fr) |
JP (1) | JP5596081B2 (fr) |
CN (1) | CN104364437A (fr) |
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FR3120238A1 (fr) * | 2021-02-26 | 2022-09-02 | Induo | Textile en coton hydrophobe et procede de fabrication de textile teint fonctionnalise |
FR3120240A1 (fr) * | 2021-02-26 | 2022-09-02 | Induo | Procede de fabrication de textile teint fonctionnalise |
FR3120239A1 (fr) * | 2021-02-26 | 2022-09-02 | Induo | Procede de fonctionnalisation d’un textile |
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JP6759681B2 (ja) * | 2016-04-26 | 2020-09-23 | 東洋紡株式会社 | 防護シート、当該防護シート用いた防護衣材料、防護衣服、および防護用品 |
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-
2012
- 2012-06-11 JP JP2012132309A patent/JP5596081B2/ja active Active
-
2013
- 2013-06-10 WO PCT/JP2013/065950 patent/WO2013187360A1/fr active Application Filing
- 2013-06-10 RU RU2014154146A patent/RU2014154146A/ru unknown
- 2013-06-10 CN CN201380030539.5A patent/CN104364437A/zh active Pending
- 2013-06-10 US US14/406,510 patent/US20150140884A1/en not_active Abandoned
- 2013-06-10 EP EP13804596.8A patent/EP2860308A4/fr not_active Withdrawn
Cited By (4)
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WO2022180341A1 (fr) * | 2021-02-26 | 2022-09-01 | Induo | Procede de fabrication de textile teint fonctionnalise, utilisation d´une solution de blanchiment pour accroitre la tenue d´une fonctionnalisation chimique sur un textile teint, et textile teint |
FR3120238A1 (fr) * | 2021-02-26 | 2022-09-02 | Induo | Textile en coton hydrophobe et procede de fabrication de textile teint fonctionnalise |
FR3120240A1 (fr) * | 2021-02-26 | 2022-09-02 | Induo | Procede de fabrication de textile teint fonctionnalise |
FR3120239A1 (fr) * | 2021-02-26 | 2022-09-02 | Induo | Procede de fonctionnalisation d’un textile |
Also Published As
Publication number | Publication date |
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JP2013256727A (ja) | 2013-12-26 |
CN104364437A (zh) | 2015-02-18 |
JP5596081B2 (ja) | 2014-09-24 |
WO2013187360A1 (fr) | 2013-12-19 |
RU2014154146A (ru) | 2016-07-27 |
EP2860308A4 (fr) | 2016-03-16 |
US20150140884A1 (en) | 2015-05-21 |
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